A NEW KIND OF SURFACTANT:LONG-CHAIN ALKYLTRIPHENYLPHOSPHONIUM HALIDES Ⅲ.AN“ABNORMAL”QUENCHING OF PYRENE FLUORESCENCE BY PHOSPHONIUMS WITH DIFFERENT LENGTHS OF ALKYL CHAIN

A study of the quenching of pyrene fluorescence by a series of alkyltriphenylphosphonium bromides indi- cated the coiling conformation of ionic surfactant in aqueous solution.Formation of pyrene excimer in cetyltriph- enylphosphonium solution strengthened the conclusion.