Effect of radiolysis of TODGA on the extraction of TODGA/n-dodecane toward Eu(Ⅲ):an experimental and DFT study

N,N,N′,N′-Tetraoctyl diglycolamide(TODGA)is one of the most promising extractants tailored for high-level liquid radioactive waste treatment during nuclear fuel reprocessing.Theγ-radiolysis of TODGA(0.2 mol/L)in n-dodecane(n DD)solution with and without pre-equilibrated 3.0 mol/L HNO_(3)was investigated using HPLC and UPLC-QTOF-MS and compared with theγ-radiolysis of neat TODGA in this study.With increased absorbed doses,the concentration of TODGA decreased exponentially for the studied systems.Moreover,pre-equilibration with HNO_(3)(3.0 mol/L)slightly influenced theγ-radiolysis of TODGA in n DD.Seven radiolytic products generated from the rupture of the C–C,C–O,and C–N bonds in TODGA were identified in the studied extraction system.The influence ofγ-radiation on TODGA/n DD for the extraction of Eu(Ⅲ)was evaluated using the first combination of extraction experiments and density functional theory(DFT)calculations,in which the complexations of Eu(Ⅲ)with TODGA and its radiolytic products were systematically compared.Based on the radiolysis kinetic model of TODGA,the slope curve of the distribution ratio of Eu(Ⅲ)(D_(Eu))and the absorbed dose,and fluorescence titration analysis,the empirical equation of the absorbed dose and D_(Eu)was obtained successfully.Below 300 kGy,the experimental D_(Eu)agreed well with the obtained empirical equation for TODGA/n DD.Conversely,at a high absorbed dose,the experimental D_(Eu)was higher than the theoretical D_(Eu)based on the empirical equation because the radiolytic products of TODGA with similar coordination structures still possessed partial complexation toward Eu(Ⅲ),which was confirmed by DFT calculations.This work provides a method to predict the extraction distribution ratio of an irradiated extractant system and to understand the complex extraction process.

The Degradation of FB1 in Aqueous Acetonitrile and Corn Following γ-ray Irradiation

To investigate the degradation of FB1 in aqueous acetonitrile and corn af-ter γ-ray irradiation, the radiolytic products of FB1 was detected preliminarily. The results showed that γ-ray irradiation could degrade FB1 in aqueous acetonitrile;When the radiation dose was below 9 kGy, the degradation of FB1 in corn was not significant. The degradation rates of FB1 with concentrations of 0.8 mg/ml, 10.0 μg/ml, 1.0 μg/ml and 50 ng/ml after irradiation at 9 kGy were 22.5%, 51.0%, 59.0% and 64.8% respectively; when irradiation dose was increased to 100 kGy, the degrada-tion rate of FB1 with concentration of 0.8 mg/ml was up to 90%, and it was nearly 100% when irradiation dose was increased to 200 kGy. No representative products of FB1 were detected by LC/MS/MS analysis.