Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by 'stepwise coupling polymerization'. The molecular weight of CP-T is as high as 1.7 x 10(5). It is a tough, elastic reactive ladderlike ...Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by 'stepwise coupling polymerization'. The molecular weight of CP-T is as high as 1.7 x 10(5). It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactive polysilsesquioxanes, which can be used as potential precursors in the synthesis of functional ladderlike polymers.展开更多
基金This project is financially supported by National Natural Science Foundation of China (No. 29874034).
文摘Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by 'stepwise coupling polymerization'. The molecular weight of CP-T is as high as 1.7 x 10(5). It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactive polysilsesquioxanes, which can be used as potential precursors in the synthesis of functional ladderlike polymers.
