Developing highly active and selective catalysts for the hydrogenation of nitroarenes,an environmentally benign process to produce industrially important aniline intermediates,is highly desirable but very challenging....Developing highly active and selective catalysts for the hydrogenation of nitroarenes,an environmentally benign process to produce industrially important aniline intermediates,is highly desirable but very challenging.Pd catalysts are generally recognized as active but nonselective catalysts for this important reaction.Here,we report an effective strategy to greatly improve the selectivity of Pd catalysts based on the reactive metal–support interaction.展开更多
基金funding support from the National Natural Science Foundation of China(grant nos.U1932213,21431006,51732011,and 21761132008)the Foundation for Innovative Research Groups of the National Natural Sci-ence Foundationof China(grant no.21521001)+4 种基金and the Key Research Program of Frontier Sciences,CAS(grant no.QYZDJ-SSW-SLH036).H.W.L.is thankful for the support by the National Key Research and Development Program of China(no.2018YFA0702001)and the Fundamental Re-search Funds for the Central Universities(no.WK206-0190103).Z.Y.W.acknowledges the funding support from the National Natural Science Foundation of China(grant no.21703229)C.Q.H acknowledges the funding support from the Zhejiang Provincial Natural Science Foundation of Chi-na(grant no.LQ20B030008).W.X.L acknowledges the funding support from the National Natural Science Foun-dation of China(grant nos.91645202 and 91945302)the Key Research Programof Frontier Sciences,CAS(grantno.QYZDJ-SSW-SLH054)and the National Key Research and Development Program of China(grant nos.2018YFA-0208603 and 2017YFB0602205)partially carried out at the USTC Center for Micro and Nanoscale Research and Fabrication.
文摘Developing highly active and selective catalysts for the hydrogenation of nitroarenes,an environmentally benign process to produce industrially important aniline intermediates,is highly desirable but very challenging.Pd catalysts are generally recognized as active but nonselective catalysts for this important reaction.Here,we report an effective strategy to greatly improve the selectivity of Pd catalysts based on the reactive metal–support interaction.
