COMPACT FOUR-COMPONENT 2-D FDFD METHOD WITH EQUIVALENT SURFACE IMPEDANCE BOUNDARY CONDITION FOR MULTILAYER METAL-COATED WAVEGUIDE

A compact four-component two-dimensional （2-D） finite-difference frequency domain （FDFD） method with the equivalent surface impedance boundary condition is used to analyze the dispersion characteristics of multilayer metal-coated waveguides. According to the equivalent surface impedance boundary condition,the relationship between transverse field components on the boundary can be easily depicted. Once the eigen equation is solved,the propagation constant can be obtained as the eigen value for a given frequency. Results of the proposed method agaree well with those of high frequency structure simulator（HFSS）.

In Situ Acquisition of Equivalent Circuit Parameters of Crystal Resonance during Copper Deposition and Dissolution in Acidic Solution by Electrochemical Quartz Crystal Impedance System

Electrochemical quartz crystal impedance system (EQCIS) which allows in situ dynamic quartz crystal impedance measurement in an electrochemical experiment was developed by combining an HP 4395A Network/Spectrum/Impedance analyzer with an EG&G M283 potentiostat. Equivalent circuit parameters of crystal resonance change significantly during electrodeposition and dissolution of copper in 0.1 mol/L H2SO4 aqueous solution in a cyclic potential sweep experiment, which is explained with an overall picture of mass loading, solution density and viscosity, etc..

Micro-source Inverters With Capacitive Equivalent Output Impedance for Improving Micro-grid Voltages

将分布式电源逆变器等效输出阻抗设计成容性可使其体现对系统无功电压调整过程相逆的电源特性,这种特性使得分布式电源逆变器更容易参与公共连接点处的电压调整。对比等效输出阻抗成感性、阻性和容性的3类逆变器下垂控制特性,对容性等效输出阻抗逆变器电压电流控制环进行数学建模;针对容性等效输出阻抗逆变器设计具备下垂调节和克服电压偏离功能的鲁棒功率外环控制器。对比仿真和实验证明,容性输出阻抗分布式电源逆变器控制器能够快速抑制系统功率变化带来的电压波动,能有效地参与系统电压调整。

Early Debonding Detection of Rebar-Concrete Interface due to External Loading Utilizing AC Impedance Spectroscopy

A novel method for detecting early damage at the steel-concrete interface due to external loading based on AC impedance spectroscopy technology was proposed.Firstly,alkali pretreatment was introduced to ensure the accuracy and repeatability of the AC impedance test.Secondly,the AC impedance spectroscopy between the steel bar and concrete surface of different bonding positions was tested,and then the physical quantities reflecting the bonding damage condition were obtained by equivalent circuit fitting.Theoretical debonding position calculation and AC conductive structure analysis indicate that the change of interface resistance and interface capacitance can seize the development of bonding damage during the loading process.As the interface damage develops,obvious changes in interface resistance and interface capacitance are observed,and they cannot be recovered after unloading.

Impedance spectroscopy for quantum dot light-emitting diodes

Impedance spectroscopy has been increasingly employed in quantum dot light-emitting diodes(QLEDs)to investigate the charge dynamics and device physics.In this review,we introduce the mathematical basics of impedance spectroscopy that applied to QLEDs.In particular,we focus on the Nyquist plot,Mott-Schottky analysis,capacitance-frequency and capacitance-voltage characteristics,and the d C/d V measurement of the QLEDs.These impedance measurements can provide critical information on electrical parameters such as equivalent circuit models,characteristic time constants,charge injection and recombination points,and trap distribution of the QLEDs.However,this paper will also discuss the disadvantages and limitations of these measurements.Fundamentally,this review provides a deeper understanding of the device physics of QLEDs through the application of impedance spectroscopy,offering valuable insights into the analysis of performance loss and degradation mechanisms of QLEDs.

Equivalent Impedance Parameter Calculation of Three-phase Symmetrical Loads for Harmonic Source Location

The equivalent impedance parameters of loads have been widely used to identify and locate the harmonic sources.However,the existing calculation methods suffer from outliers caused by the zero-crossing of the denominator.These outliers can result in inaccuracy and unreliability of harmonic source location.To address this issue,this paper proposes an innovative method of equivalent impedance parameter calculation of three-phase symmetrical loads that avoid outliers.The correctness and effectiveness of the proposed method are verified by simulations on Simulink using actual monitoring data.The results show that the proposed method is not only simple and easy to implement but also highly accurate.

An equivalent-tool theory for acoustic logging and applications

The influence of an acoustic logging tool on borehole guided wave propagation should be considered in the processing and inversion of the guided waves for formation acoustic property estimation. This study introduces an equivalent-tool theory that models the tool response using an elastic rod with an effective modulus and applies the theory to multipole acoustic logging for both wireline and logging while drilling （LWD） conditions. The theory can be derived by matching the tool’s acoustic impedance/conductance to that of the multipole acoustic wavefield around the tool, assuming that tool radius is small compared to wavelength. We have validated the effectiveness and accuracy of the theory using numerical modeling and its practicality using field data. In field data applications, one can calibrate the tool parameters by fitting the theoretical dispersion curve to field data without having to consider the actual tool’s structure and composition. We use a dispersion correction example to demonstrate an application of the simple theory to field data processing and the validity of the processing result.

Electrochemical Impedance of Ethanol Oxidation in Alkaline Media

Nickel modified NiOOH electrodes were used for the electrocatalytic oxidation of ethanol in alkaline so lutions. The electro-oxidation of ethanol in a 1 mol/L NaOH solution at different concentrations of ethanol was stu died by ac impedance spectroscopy. Electrooxidation of ethanol on Ni shows negative resistance on impedance plots. The impedance shows different patterns at different applied anodic potential. The influence of the electrode potential on impedance was studied and a quantitative explanation for the impedance of ethanol oxidation was given by means of a proposed mathematical model. At potentials higher than 0.52 V（vs. Ag/AgCl）, a pseudoinductive behavior was observed, but at those higher than 0.57 V, impedance patterns were reversed to the second and third quadrants. The conditions required for the reversing of impedance pattern were delineated with the impedance model.

Electrochemical impedance analysis of nanoporous TiO_2 electrode at low bias potential

TiO2 colloid was prepared by the sol-gel method and was bladed on transparent conduction glass to made nanoporous electrode. The impedance performance of TiO2 electrode was studied at various bias potential.A simplified equivalent circuit was proposed to investigate the charge transport impedance of TiO2 film and good fitting results were obtained.

Electrochemical impedance spectra of V_2O_5 xerogel films with intercalation of lithium ion

Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.

Analyzing Impedance Spectroscopy Results

In this contribution we briefly discuss several analysis techniques for impedance spectroscopy experiments.A number of different approaches,which differ even by the definition of the problem,are used in the literature.Some aimed towards finding an equivalent circuit.Others aimed towards finding directly dielectric properties of the material under an assumed model.Others towards finding distribution of relaxation times,either parametric or point-by point.No matter what the approach is,this will always be an ill-posed problem in the sense that there exist a large number of possible solutions that solve the problem (mathematically) equally well.Therefore some a-priori knowledge about the system must he used.In addition,we should remember that the ultimate goal is to get physical insight about the system.

A Study on a Partially Immersed Gold Electrode Using an Electrochemical Quartz Crystal Impedance System

The electrochemical quartz crystal impedance system (EQCIS) has been used for the study of a partially immersed Au electrode in 0.2 mol/L NaClO4 aqueous solution. The influences of the immersed area and height of the electrode on the EQCIS responses were evaluated, showing the highest response sensitivity to liquid loading at the center of the piezoelectric quartz crystal electrode. The increase in the immersed height of the Au electrode at oxygen reduction potentials during potential cycling was measured by this technique.

Electrochemical Impedance Spectroscopy Study on Novel Carbon-Sulfur Nano-Composite Cathodes in Lithium Rechargeable Batteries

Carbon-sulfur nano-composite cathodes for lithium rechargeable batteries were investigated by electrochemical impedance spectroscopy (EIS). The novel carbon-sulfur nano-composite material was synthesized by heating sublimed sulfur and high surface area activated carbon (HSAAC) in certain conditions. Equivalent circuits were used to fit the spectra at different discharge states. The variations of impedance spectra, charge-transfer resistance and double layer capacitance were discussed. The changes of EIS with potential were analyzed based on a plausible electrical equivalent circuit model, and some parameters were measured and analyzed about electrochemical performance and state of charge and discharge of the electrode. The good accuracy in fitting values of the model to the experimental data indicates that the mathematical model gives out a satisfying description upon the mechanism of high rate of capacity fade in lithium-sulfur battery.

The Equivalent Parameters for the Narrow Series Slot on a Sectoral Waveguide

The exact and approximate expressions for the field components of the TE modes in a sectoral waveguide are presented. Using the equivalence principle, the electric field distribution on the aperture surfaces of a narrow transverse slot cut in the curved broad wall of a sectoral waveguide is solved by the moment method (Galerkin's method). lmportant results such as the scattering parameter, the normalized equivalent series impedance, the resonant resistance and resonant length are studied.

Analysis of 3.4 Ah lithium-sulfur pouch cells by electrochemical impedance spectroscopy

Despite great progress in lithium-sulfur(Li-S) batteries, the electrochemical reactions in the cell are not yet fully understood. Electrode processes, complex interfaces and internal resistance may be characterized by electrochemical impedance spectroscopy(EIS). EIS is a non-destructive technique and easy to apply, though there are challenges in ensuring the reproducibility of measurements and the interpretation of impedance data. Here, we present the impedance behavior of a 3.4 Ah Li-S pouch cell characterized by EIS. The impedance changes were analyzed over the entire depth-of-discharge, depth-of-charge,and at various temperatures. Based on the formation of intermediates during(dis)charging, the changes of resistances are observed. Overall, the increase in temperature causes a decrease in electrolyte viscosity,lowering the surface energy which can improve the penetration of the electrolyte into the electrode pores. Moreover, the effect of superimposed AC current during EIS measurement was analyzed, and the results show the dependence of the charge transfer resistance on superimposed AC current which was lower compared to steady-state conditions and consents with theory.

AC Impedance Spectroscopy of a-nc-Si:H Thin Films

The AC impedance of amorphous-nano-crystalline silicon composite thin films (a-nc-Si:H) from mHz to MHz at different temperatures has been studied. The samples were prepared by Plasma Enhanced Chemical Vapor Deposition technique. The X-ray diffraction and high resolution electron microscopy showed that films consist of isolated nano-crystals embedded in amorphous matrix. In analysis of impedance data, two approaches were tested: the ideal Deby type equivalent circuit and modified one, with CPE (constant phase elements). It was found that the later better fits to results. The amorphous matrix showed larger resistance and lower capacity than nano-crystals. By heat treatment in vacuum, the capacity for both phases changes, according to expected change in size of ordered domains.

基于电路等效的并网逆变器失稳分析与稳定控制

以并网逆变器为功率接口的新能源发电系统在弱电网条件下易发生振荡失稳问题。该文将并网逆变器的控制回路可视化为电路元件组成的虚拟阻抗,基于该电路模型分析了弱电网条件下电流内环与锁相环交互作用导致并网逆变器振荡失稳的机理,在此基础上,提出了基于有源阻尼的稳定控制设计方法,并对不同有源阻尼控制的电路特性以及稳定性提升能力进行了对比分析。研究结果表明,针对锁相环引入负电阻造成的振荡失稳问题,阻抗-高通滤波器型有源阻尼控制策略具有更优的稳定性提升能力。最后通过PSCAD/EMTDC仿真和远宽StarSim控制器硬件在环实验对比了不同有源阻尼控制策略的振荡抑制效果,并验证了阻抗-高通滤波器型有源阻尼控制的动态性能。结果表明,所设计的稳定控制能够在200 ms内有效抑制系统振荡,并且可实现在短路比为1的极弱电网条件下稳定运行。

基于等效序阻抗差异特征的低频输电线路差动保护优化方案

低频输电线路故障时,两侧短路电流均由模块化多电平矩阵变换器提供,两侧短路电流相角均受控且幅值相当,导致差动保护灵敏度严重下降。分析了低频输电系统定电压控制侧和功率控制侧的等效正、负序阻抗特征,指出因控制策略不同,系统故障时两侧等效正、负序阻抗特征存在明显差异。分析了低频输电线路区内和区外故障两侧保护装置测量到的等效序阻抗之间的差异性和相似性,基于此特征构建了两侧等效序阻抗差异指标,提出了基于等效序阻抗差异指标的差动保护制动系数优化方法。仿真结果表明,所提方案能够显著提升低频输电线路区内故障时差动保护的动作速度和动作灵敏性。

基于盲源分离的工业谐波源负荷分类识别方法

针对传统谐波源辨识方法无法实现工业用户谐波源具体类型的非侵入式识别的问题,该文提出一种基于盲源分离的工业谐波源负荷分类识别方法。该方法仅依据工业用户进线处电压、电流数据即可实现谐波源负荷具体类型的非侵入式识别。首先,从负荷等值阻抗模型入手,建立工业用户多负荷等值阻抗并联电路模型;其次,采用集合经验模态分解与奇异值分解相结合的方法确定构成用户进线处监测点综合等值阻抗信号的源阻抗信号数目;然后,采用快速独立分量分析实现将谐波源负荷等值阻抗信号从综合负荷等值阻抗信号中分离;最后,将分离出谐波源负荷等值阻抗信号频率特征与典型谐波源负荷进行匹配,进而实现分类识别。仿真与实测实验结果均表明,所提方法能够准确识别工业用户所含多种谐波源负荷的具体类型,具有较好的可行性和实用性。

基于均匀相位采样提高阻抗谱测量精度的研究

周期性信号采样中,等效采样利用较低采样频率的A/D转换实现高频周期信号的采集,一定程度上弥补欠采样测量精度低的缺陷。为了有效地提高高频测量中阻抗谱测量精度与稳定性,提出一种基于等效采样思想的均匀相位采样的阻抗谱测量方法。利用单片机共时钟基准的模/数转换器(digital to analog convertor,DAC)与数/模转换器(analog to digital convertor,ADC)模块,在完成激励信号产生、输入输出信号同步采集的基础上,合理设计激励信号频率、采集频率与信号重构方法,实现高频信号单周期内均匀相位分布的等效高频采样,同时为克服常规A/D转换速度条件下难以准确实现高频阻抗谱测量的问题提供了新思路。从误差假设与拟合算法的角度,理论上分析证明了该方法降低误差的原因。并通过两种等效电路模型的阻抗谱测量对比实验,表明该方法在所设计的20~100 kHz高频段上,阻抗测量精度与稳定性得到了显著的提高。