The chaotic behaviours of the Rydberg hydrogen atom near a metal surface are presented. A numerical comparison of Poincare surfaces of section with recurrence spectra for a few selected scaled energies indicates the c...The chaotic behaviours of the Rydberg hydrogen atom near a metal surface are presented. A numerical comparison of Poincare surfaces of section with recurrence spectra for a few selected scaled energies indicates the correspondence between classical motion and quantum properties of an excited electron. Both results demonstrate that the scaled energy dominates sensitively the dynamical properties of system. There exists a critical scaled energy εc, for ε 〈 εc, the system is near-integrable, and as the decrease of ε the spectrum is gradually rendered regular and finally turns into a pure Coulomb field situation. On the contrary, if ε 〉 εc, with the increase of ε, the system tends to be non-integrable, the ergodic motion in phase space presages that chaotic motion appears, and more and more electrons are adsorbed on the metal surface, thus the spectrum becomes gradually simple.展开更多
This paper presents recurrence spectra of highly excited lithium atoms with M = 1 state in parallel electric and magnetic fields at a fixed scaled energy ε = -0.03. Short-ranged potentials including ionic core potent...This paper presents recurrence spectra of highly excited lithium atoms with M = 1 state in parallel electric and magnetic fields at a fixed scaled energy ε = -0.03. Short-ranged potentials including ionic core potential and centrifugal barrier are taken into account. Their effects on the states and photo-absorption spectrum are analysed in detail. This demonstrates that the geometric features of classical orbits are of special importance for modulations of the spectral pattern. Thus the weak polarization as well as the reduction of correlation of electrons induced by short-ranged potentials give rise to the recurrence spectra of lithium M = 1 atoms more compact than that of the M = 0 one, which is in good agreement with the experimental prediction.展开更多
Making use of the molecular closed-orbit theory and a new model potential for the Rydberg molecule, we have calculated the recurrence spectra of He^2+ molecular ion in a magnetic field for different quantum defects. ...Making use of the molecular closed-orbit theory and a new model potential for the Rydberg molecule, we have calculated the recurrence spectra of He^2+ molecular ion in a magnetic field for different quantum defects. The Fourier transform spectra of He^2+ molecular ion may be used to perform a direct comparison between peaks in the spectra and the scaled action values of closed orbits of the excited electron in external fields. We find that the spectral modulations can be analysed in terms of the scattering of the excited electron on the molecular core. Unlike the case of the Rydberg atom where the elastic scattering is predominant, modulations produced by inelastic scattering are also vital to the photoabsorption spectrum of the Rydberg molecule. Our results are in good agreement with the quantum results, which suggests that our method is correct.展开更多
An expansion method for stationary states is applied to obtain the eigenfunctions and the eigenenergies of the quarter stadium billiard, and its nearest energy-level spacing distribution is obtained. The histogram is ...An expansion method for stationary states is applied to obtain the eigenfunctions and the eigenenergies of the quarter stadium billiard, and its nearest energy-level spacing distribution is obtained. The histogram is consistent with the standard Wigner distribution, which indicates that the stadium billiard system is chaotic. Particular attention is paid to pursuing the quantum manifestations of such classical chaos. The correspondences between the Fourier transformation of quantum spectra and classical orbits are investigated by using the closed-orbit theory. The analytical and numerical results are in agreement with the required resolution, which corroborates that the semiclassical method provides a physically meaningful image to understand such chaotic systems.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos 10774093 and 10374061)
文摘The chaotic behaviours of the Rydberg hydrogen atom near a metal surface are presented. A numerical comparison of Poincare surfaces of section with recurrence spectra for a few selected scaled energies indicates the correspondence between classical motion and quantum properties of an excited electron. Both results demonstrate that the scaled energy dominates sensitively the dynamical properties of system. There exists a critical scaled energy εc, for ε 〈 εc, the system is near-integrable, and as the decrease of ε the spectrum is gradually rendered regular and finally turns into a pure Coulomb field situation. On the contrary, if ε 〉 εc, with the increase of ε, the system tends to be non-integrable, the ergodic motion in phase space presages that chaotic motion appears, and more and more electrons are adsorbed on the metal surface, thus the spectrum becomes gradually simple.
基金Project supported by the National Natural Science Foundation of China(Grant Nos10774093 and 10374061)
文摘This paper presents recurrence spectra of highly excited lithium atoms with M = 1 state in parallel electric and magnetic fields at a fixed scaled energy ε = -0.03. Short-ranged potentials including ionic core potential and centrifugal barrier are taken into account. Their effects on the states and photo-absorption spectrum are analysed in detail. This demonstrates that the geometric features of classical orbits are of special importance for modulations of the spectral pattern. Thus the weak polarization as well as the reduction of correlation of electrons induced by short-ranged potentials give rise to the recurrence spectra of lithium M = 1 atoms more compact than that of the M = 0 one, which is in good agreement with the experimental prediction.
基金Project supported by the National Natural Science Foundation of China (Grant Nos 10604045 and 10674114)the Doctoral Scientific Research Startup Foundation of Ludong University (Grant No 202-23000301)
文摘Making use of the molecular closed-orbit theory and a new model potential for the Rydberg molecule, we have calculated the recurrence spectra of He^2+ molecular ion in a magnetic field for different quantum defects. The Fourier transform spectra of He^2+ molecular ion may be used to perform a direct comparison between peaks in the spectra and the scaled action values of closed orbits of the excited electron in external fields. We find that the spectral modulations can be analysed in terms of the scattering of the excited electron on the molecular core. Unlike the case of the Rydberg atom where the elastic scattering is predominant, modulations produced by inelastic scattering are also vital to the photoabsorption spectrum of the Rydberg molecule. Our results are in good agreement with the quantum results, which suggests that our method is correct.
基金Supported by the National Natural Science Foundation of China under Grant No 10374061.
文摘An expansion method for stationary states is applied to obtain the eigenfunctions and the eigenenergies of the quarter stadium billiard, and its nearest energy-level spacing distribution is obtained. The histogram is consistent with the standard Wigner distribution, which indicates that the stadium billiard system is chaotic. Particular attention is paid to pursuing the quantum manifestations of such classical chaos. The correspondences between the Fourier transformation of quantum spectra and classical orbits are investigated by using the closed-orbit theory. The analytical and numerical results are in agreement with the required resolution, which corroborates that the semiclassical method provides a physically meaningful image to understand such chaotic systems.