A new approach to produce superfine WC-Co powder by direct reduction and carbonization is proposed. Water-soluble salts containing W and Co were used as raw materials. Tungsten and cobalt oxide powder (CoWO4/WO3) wa...A new approach to produce superfine WC-Co powder by direct reduction and carbonization is proposed. Water-soluble salts containing W and Co were used as raw materials. Tungsten and cobalt oxide powder (CoWO4/WO3) was first formed by a spray-pyrolysis technique, which was then mixed with carbon black and converted to WC-Co composite powder at 950℃ for 4 h in N2 atmosphere. The resulting powder has a particle size of 100-300 nm.展开更多
基金This work is sponsored by the National High—Tech Research and Development Pr0gram of China(863 Pr0gram)(special subject for nano—materials)(Grant No.2O02AA3O25O4,2002—2005)the Key Project for the Sci.& Tlech.Development Program of Wuhan.Hubei,China(Grant No.20041 003068一O4,2004—2006)+1 种基金the NationaI NaturaI Science Foundation of China(Key Pr0gram)(Grant No.50220160657,2003—2005) Key Project of Ministry of Education of China(2005—2006).
文摘A new approach to produce superfine WC-Co powder by direct reduction and carbonization is proposed. Water-soluble salts containing W and Co were used as raw materials. Tungsten and cobalt oxide powder (CoWO4/WO3) was first formed by a spray-pyrolysis technique, which was then mixed with carbon black and converted to WC-Co composite powder at 950℃ for 4 h in N2 atmosphere. The resulting powder has a particle size of 100-300 nm.