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Urban Landscaping Design and Carbon Reduction Planning Countermeasures
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作者 AN Shaoyuan 《Journal of Landscape Research》 2024年第3期11-14,共4页
As the most significant green ecological resource in densely populated and economically developed areas,urban landscaping plays a pivotal role in carbon sink value and multiple ecosystem service functions.It is a cruc... As the most significant green ecological resource in densely populated and economically developed areas,urban landscaping plays a pivotal role in carbon sink value and multiple ecosystem service functions.It is a crucial element in the advancement of green and low-carbon initiatives in China’s major cities and the realization of a carbon-neutral vision.By analyzing the relationship between carbon emission reduction and urban landscaping,the paper sorts out and summarizes the basic principles of urban landscaping design,proposes the role of landscape design in urban landscaping,and plans countermeasures for carbon reduction in urban landscaping,with a view to optimizing the construction and management of urban landscaping. 展开更多
关键词 Landscape architecture Climate change Carbon neutral Carbon source sink Carbon reduction strategy
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Study on Functions and Countermeasures of Disaster Prevention and Reduction of Urban Green Land 被引量:2
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作者 周建东 王浩 《Journal of Landscape Research》 2009年第1期6-10,共5页
From the advanced experiences at home and abroad,according to the requirements of emergency evacuation at earthquake disaster,then strategies and methods to disaster prevention and reduction functions of urban green l... From the advanced experiences at home and abroad,according to the requirements of emergency evacuation at earthquake disaster,then strategies and methods to disaster prevention and reduction functions of urban green land construction were put forward. 展开更多
关键词 Urban green LAND DISASTER PREVENTION and reduction Construction EARTHQUAKE
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Are energy conservation and emission reduction policy measures effective for industrial structure restructuring and upgrading? 被引量:1
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作者 Guoxing Zhang Peide Zhang +1 位作者 Jing Xiu Jian Chai 《Chinese Journal of Population,Resources and Environment》 2018年第1期12-27,共16页
The use of energy conservation emission reduction policies to promote industrial restructuring and upgrading and thus facilitate energy conservation and emission reduction is one of the 10 important strategies of envi... The use of energy conservation emission reduction policies to promote industrial restructuring and upgrading and thus facilitate energy conservation and emission reduction is one of the 10 important strategies of environmental management in China. The use of energy conservation emission reduction policies to promote industrial restructuring and upgrading and thus facilitate energy conservation and emission reduction is one of the important strategies of environmental management in China. Based on the systematic collection of 1,195 energy conservation emission reduction policies, we discuss the influence of individual measure and measure synergy of energy conservation and emission reduction policies respectively. The results show that the energy conservation and emission reduction policies have a significant effect on the overall promotion of industrial upgrading. The financial measures and guidance measures have a positive impact;the financial measures and guidance measures have significantly positive effect; however, the administrative measures, fiscal tax measures, and other economic measures do the opposite; the positive effect of the synergy of guidance measures and financial measures is greater than the negative effect of considering only the synergy of fiscal tax measures and other economic measures, and significantly greater than the negative effect of the synergy of administrative measures, fiscal tax measures, and other economic measures. We should strengthen and emphasize the use of the measure that has positive effect on industrial structure restructuring and upgrading individually and synergistically. 展开更多
关键词 Energy conservation and emission reduction policy quantification measure synergy HAC unit rootcointegration
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Formation mechanism of aerodynamic drag of high-speed train and some reduction measures 被引量:26
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作者 田红旗 《Journal of Central South University》 SCIE EI CAS 2009年第1期166-171,共6页
Aerodynamic drag is proportional to the square of speed. With the increase of the speed of train, aerodynamic drag plays an important role for high-speed train. Thus, the reduction of aerodynamic drag and energy consu... Aerodynamic drag is proportional to the square of speed. With the increase of the speed of train, aerodynamic drag plays an important role for high-speed train. Thus, the reduction of aerodynamic drag and energy consumption of high-speed train is one of the essential issues for the development of the desirable train system. Aerodynamic drag on the traveling train is divided into pressure drag and friction one. Pressure drag of train is the force caused by the pressure distribution on the train along the reverse running direction. Friction drag of train is the sum of shear stress, which is the reverse direction of train running direction. In order to reduce the aerodynamic drag, adopting streamline shape of train is the most effective measure. The velocity of the train is related to its length and shape. The outer wind shields can reduce train's air drag by about 15%. At the same time, the train with bottom cover can reduce the air drag by about 50%, compared with the train without bottom plate or skirt structure. 展开更多
关键词 aerodynamics of train high speed train aerodynamic drag drag reduction
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Study on Characteristics and Reduction Countermeasures of the Agricultural Carbon Emission in China 被引量:1
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作者 Liqing Xu Jianjun Bai 《Meteorological and Environmental Research》 CAS 2013年第11期58-62,共5页
Based on seven carbon sources including chemical fertilizer, pesticide, agricultural film, nitrogen fertilization, agricultural machinery, irri- gation and straw burning, the carbon emissions in agricultural productio... Based on seven carbon sources including chemical fertilizer, pesticide, agricultural film, nitrogen fertilization, agricultural machinery, irri- gation and straw burning, the carbon emissions in agricultural production of China during 1995-2011 was calculated. The results showed that both total agricultural carbon emission and per capita agricultural carbon emission overall presented growth trends, and the growth rate began to slow in recent years. The agricultural carbon emission intensity decreased year by year. Straw burning was the primary carbon source in China's agricul- ture, followed by chemical fertilizer. Total agricultural carbon emission in China in 17 years experienced three stages of "fluctuated growth -slow drop-new growth". Finally, suggestions and countermeasures of the low-carbon agriculture development in China from three aspects were proposed. 展开更多
关键词 Agricultural carbon emission General characteristics Carbon emission reduction COUNTERmeasures China
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Decomposition analysis of carbon reduction measures and carbon emission changes in five areas in China
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作者 江舒 万皓 +1 位作者 邵申 袁义 《Journal of Shanghai University(English Edition)》 CAS 2011年第6期522-528,共7页
Based on the analysis of primary energy consumption structure in five main provinces or municipalities in China,the factors that affect carbon emissions in the five study areas are analyzed quantitatively and comparat... Based on the analysis of primary energy consumption structure in five main provinces or municipalities in China,the factors that affect carbon emissions in the five study areas are analyzed quantitatively and comparatively with the decomposition analysis method.Empirical results demonstrate that the decomposition models of carbon emissions can be defined as "municipality model" and "provincial model",and the population factor of "municipal model" plays a significant role in carbon emissions than that of "provincial model".Either positive or negative effects of energy structure can be found in five different areas.However,there is a general trend that energy structure effort is becoming more and more important.Based on the characteristics and trends of carbon emissions in different areas,the carbon reduction measures are proposed as well. 展开更多
关键词 carbon emissions decomposition method carbon reduction measures provinces or municipalities
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Evaluation of Diesel Engine Noise Reduction Measures Based on Hierarchy Diagnosis 被引量:1
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作者 梁兴雨 舒歌群 +1 位作者 卫海桥 陈达亮 《Transactions of Tianjin University》 EI CAS 2007年第3期205-210,共6页
Effect of different noise reduction measures for diesel engines was evaluated based on hierarchy diagnosis. The hierarchy diagnosis chart and hierarchy judgment matrix were given. Through evaluation of noise reduction... Effect of different noise reduction measures for diesel engines was evaluated based on hierarchy diagnosis. The hierarchy diagnosis chart and hierarchy judgment matrix were given. Through evaluation of noise reduction measures, the main strategies of noise reduction were found. The result shows that the noise reduction level of different frequency belts varies from measure to measure. The reduction capacity of different measures could not add simply, which relates to the problem of parameter matching. 展开更多
关键词 diesel engine hierarchy diagnosis noise reduction power spectrum
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Some Implications of Theoretical Relation between RAW and RRW Measures on Risk Reduction Strategies
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作者 Ivan Vrbanic Pranab Samanta Ivica Basic 《Journal of Physical Science and Application》 2018年第3期38-45,共8页
In using risk-informed approaches for ensuring safety of operating NPPs(nuclear power plants),risk importance measures obtained from PRAs(probabilistic risk assessments)of the plants are integral elements of considera... In using risk-informed approaches for ensuring safety of operating NPPs(nuclear power plants),risk importance measures obtained from PRAs(probabilistic risk assessments)of the plants are integral elements of consideration in many cases.In PSA models and applications associated with NPPs the risk importance of a particular feature(e.g.function,system,component,failure mode or operator action)can be,most generally,divided into two categories:importance with respect to risk increase potential and importance with respect to risk decrease potential.The representative of the first category,as used for practical purposes,is RAW(risk achievement worth).Representative of the second category,as mentioned in consideration of risk importance,is RRW(risk reduction worth).It can be shown that the two risk importance measures,RAW and RRW,are dependent on each other.The only parameter in this mutual dependency is probability of failure of the considered feature.The paper discusses the relation between RAW and RRW and some of its implications,including those on the general strategies for the reduction of risk imposed for the operation of the considered facility.Two general risk reduction strategies which are considered in the discussion are:a)risk reduction by decreasing the failure probability of the considered feature;and b)risk reduction while keeping the failure probability of the considered feature at the same level.Simple examples are provided to illustrate the differences between two strategies and point to main issues and conclusions. 展开更多
关键词 Probabilistic RISK assessment RISK IMPORTANCE measures RISK ACHIEVEMENT WORTH RISK reduction WORTH RISK reduction strategy
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Strong synergy between physical and chemical properties:Insight into optimization of atomically dispersed oxygen reduction catalysts 被引量:5
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作者 Yifan Zhang Linsheng Liu +4 位作者 Yuxuan Li Xueqin Mu Shichun Mu Suli Liu Zhihui Dai 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期36-49,共14页
Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utiliz... Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utilization and exceptional catalytic functionality.Furthermore,accurately controlling atomic physical properties including spin,charge,orbital,and lattice degrees of atomically dispersed catalysts can realize the optimized chemical properties including maximum atom utilization efficiency,homogenous active centers,and satisfactory catalytic performance,but remains elusive.Here,through physical and chemical insight,we review and systematically summarize the strategies to optimize atomically dispersed ORR catalysts including adjusting the atomic coordination environment,adjacent electronic orbital and site density,and the choice of dual-atom sites.Then the emphasis is on the fundamental understanding of the correlation between the physical property and the catalytic behavior for atomically dispersed catalysts.Finally,an overview of the existing challenges and prospects to illustrate the current obstacles and potential opportunities for the advancement of atomically dispersed catalysts in the realm of electrocatalytic reactions is offered. 展开更多
关键词 Atomically dispersed catalysts Coordination environment Electronic orbitals Inter-site distance effect Oxygen reduction reaction
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Measures for Pollution Emission Reduction in Large-scale Livestock and Poultry Farm of Jilin Province
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作者 Duan Lijie Zhuang Yushi Chen Wenying 《Meteorological and Environmental Research》 CAS 2019年第1期55-58,共4页
In order to improve the level of livestock and poultry breeding pollution control,fulfill the requirements of pollution reduction and complete total emission reduction target of main pollutants in Jilin Province,based... In order to improve the level of livestock and poultry breeding pollution control,fulfill the requirements of pollution reduction and complete total emission reduction target of main pollutants in Jilin Province,based on the analysis of livestock and poultry breeding excrement characteristics,the current main problems existing in the management are deeply studied,and it puts forward the technique model suitable for livestock and poultry breeding pollution governance in Jilin Province,which is one of the important means to solve the rural environment pollution in Jilin Province. 展开更多
关键词 Jilin PROVINCE LIVESTOCK and POULTRY POLLUTION POLLUTION emission reduction
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HealthMeasures患者报告结局报告清单的解读
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作者 臧娴 宗旭倩 +4 位作者 袁长蓉 王玲 吴傅蕾 张雯 黄青梅 《护士进修杂志》 2024年第10期1088-1092,共5页
美国匹兹堡大学和HealthMeasures指导委员会及PROMIS健康组织标准委员会共同发表了HealthMeasures患者报告结局报告清单,旨在促进不同患者报告结局测量工具的标准化报告,帮助研究人员提高工具报告质量及结果解释的准确性,进一步改善跨... 美国匹兹堡大学和HealthMeasures指导委员会及PROMIS健康组织标准委员会共同发表了HealthMeasures患者报告结局报告清单,旨在促进不同患者报告结局测量工具的标准化报告,帮助研究人员提高工具报告质量及结果解释的准确性,进一步改善跨研究间的比较分析。本文对HealthMeasures患者报告结局报告清单的主要内容进行介绍和解读,以期为中国患者报告结局研究者提供参考和借鉴。 展开更多
关键词 患者报告结局 报告清单 测量工具 标准化 解读
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Boric Acid-Assisted Pyrolysis for High-Loading Single-Atom Catalysts to Boost Oxygen Reduction Reaction in Zn-Air Batteries 被引量:2
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作者 Chenxi Xu Jiexing Wu +12 位作者 Liang Chen Yi Gong Boyang Mao Jincan Zhang Jinhai Deng Mingxuan Mao Yan Shi Zhaohui Hou Mengxue Cao Huanxin Li Haihui Zhou Zhongyuan Huang Yafei Kuang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期102-110,共9页
The emerging of single-atom catalysts(SACs)offers a great opportunity for the development of advanced energy storage and conversion devices due to their excellent activity and durability,but the actual mass production... The emerging of single-atom catalysts(SACs)offers a great opportunity for the development of advanced energy storage and conversion devices due to their excellent activity and durability,but the actual mass production of high-loading SACs is still challenging.Herein,a facile and green boron acid(H_(3)BO_(3))-assisted pyrolysis strategy is put forward to synthesize SACs by only using chitosan,cobalt salt and H_(3)BO_(3)as precursor,and the effect of H_(3)BO_(3)is deeply investigated.The results show that molten boron oxide derived from H_(3)BO_(3)as ideal high-temperature carbonization media and blocking media play important role in the synthesis process.As a result,the acquired Co/N/B tri-doped porous carbon framework(Co-N-B-C)not only presents hierarchical porous structure,large specific surface area and abundant carbon edges but also possesses high-loading single Co atom(4.2 wt.%),thus giving rise to outstanding oxygen catalytic performance.When employed as a catalyst for air cathode in Zn-air batteries,the resultant Co-N-B-C catalyst shows remarkable power density and long-term stability.Clearly,our work gains deep insight into the role of H_(3)BO_(3)and provides a new avenue to synthesis of high-performance SACs. 展开更多
关键词 boric acid oxygen reduction reaction single-atom catalysts Zn-air batteries
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Cu-Based Materials for Enhanced C_(2+) Product Selectivity in Photo-/Electro-Catalytic CO_(2) Reduction: Challenges and Prospects 被引量:1
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作者 Baker Rhimi Min Zhou +2 位作者 Zaoxue Yan Xiaoyan Cai Zhifeng Jiang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第4期25-66,共42页
Carbon dioxide conversion into valuable products using photocatalysis and electrocatalysis is an effective approach to mitigate global environmental issues and the energy shortages. Among the materials utilized for ca... Carbon dioxide conversion into valuable products using photocatalysis and electrocatalysis is an effective approach to mitigate global environmental issues and the energy shortages. Among the materials utilized for catalytic reduction of CO_(2), Cu-based materials are highly advantageous owing to their widespread availability, cost-effectiveness, and environmental sustainability. Furthermore, Cu-based materials demonstrate interesting abilities in the adsorption and activation of carbon dioxide, allowing the formation of C_(2+) compounds through C–C coupling process. Herein, the basic principles of photocatalytic CO_(2) reduction reactions(PCO_(2)RR) and electrocatalytic CO_(2) reduction reaction(ECO_(2)RR) and the pathways for the generation C_(2+) products are introduced. This review categorizes Cu-based materials into different groups including Cu metal, Cu oxides, Cu alloys, and Cu SACs, Cu heterojunctions based on their catalytic applications. The relationship between the Cu surfaces and their efficiency in both PCO_(2)RR and ECO_(2)RR is emphasized. Through a review of recent studies on PCO_(2)RR and ECO_(2)RR using Cu-based catalysts, the focus is on understanding the underlying reasons for the enhanced selectivity toward C_(2+) products. Finally, the opportunities and challenges associated with Cu-based materials in the CO_(2) catalytic reduction applications are presented, along with research directions that can guide for the design of highly active and selective Cu-based materials for CO_(2) reduction processes in the future. 展开更多
关键词 Photocatalytic CO_(2)reduction Cu-based materials Electrocatalytic CO_(2)reduction
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Numerical Study on Reduction in Aerodynamic Drag and Noise of High-Speed Pantograph 被引量:1
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作者 Deng Qin Xing Du +1 位作者 Tian Li Jiye Zhang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第5期2155-2173,共19页
Reducing the aerodynamic drag and noise levels of high-speed pantographs is important for promoting environmentally friendly,energy efficient and rapid advances in train technology.Using computational fluid dynamics t... Reducing the aerodynamic drag and noise levels of high-speed pantographs is important for promoting environmentally friendly,energy efficient and rapid advances in train technology.Using computational fluid dynamics theory and the K-FWH acoustic equation,a numerical simulation is conducted to investigate the aerodynamic characteristics of high-speed pantographs.A component optimization method is proposed as a possible solution to the problemof aerodynamic drag and noise in high-speed pantographs.The results of the study indicate that the panhead,base and insulator are the main contributors to aerodynamic drag and noise in high-speed pantographs.Therefore,a gradual optimization process is implemented to improve the most significant components that cause aerodynamic drag and noise.By optimizing the cross-sectional shape of the strips and insulators,the drag and noise caused by airflow separation and vortex shedding can be reduced.The aerodynamic drag of insulator with circular cross section and strips with rectangular cross section is the largest.Ellipsifying insulators and optimizing the chamfer angle and height of the windward surface of the strips can improve the aerodynamic performance of the pantograph.In addition,the streamlined fairing attached to the base can eliminate the complex flow and shield the radiated noise.In contrast to the original pantograph design,the improved pantograph shows a 21.1%reduction in aerodynamic drag and a 1.65 dBA reduction in aerodynamic noise. 展开更多
关键词 High-speed pantograph aerodynamic drag aerodynamic noise reduction optimizing
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Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO_(2) Reduction 被引量:2
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作者 Kangwang Wang Zhuofeng Hu +8 位作者 Peifeng Yu Alina M.Balu Kuan Li Longfu Li Lingyong Zeng Chao Zhang Rafael Luque Kai Yan Huixia Luo 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期68-84,共17页
We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in... We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in S_(v)–In_(2)S_(3)@2H–MoTe_(2).The X-ray absorption near-edge structure shows that the formation of S_(v)–In_(2)S_(3)@2H–MoTe_(2) adjusts the coordination environment via interface engineering and forms Mo–S polarized sites at the interface.The interfacial dynamics and catalytic behavior are clearly revealed by ultrafast femtosecond transient absorption,time-resolved,and in situ diffuse reflectance–Infrared Fourier transform spectroscopy.A tunable electronic structure through steric interaction of Mo–S bridging bonds induces a 1.7-fold enhancement in S_(v)–In_(2)S_(3)@2H–MoTe_(2)(5)photogenerated carrier concentration relative to pristine S_(v)–In_(2)S_(3).Benefiting from lower carrier transport activation energy,an internal quantum efficiency of 94.01%at 380 nm was used for photocatalytic CO_(2)RR.This study proposes a new strategy to design photocatalyst through bridging sites to adjust the selectivity of photocatalytic CO_(2)RR. 展开更多
关键词 Quantum efficiency Electronic structure Steric interaction Bridging sites CO_(2)reduction
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Oxygen‑Coordinated Single Mn Sites for Efficient Electrocatalytic Nitrate Reduction to Ammonia 被引量:2
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作者 Shengbo Zhang Yuankang Zha +8 位作者 Yixing Ye Ke Li Yue Lin Lirong Zheng Guozhong Wang Yunxia Zhang Huajie Yin Tongfei Shi Haimin Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期147-159,共13页
Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites... Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites. 展开更多
关键词 Atomically dispersed Oxygen coordination Nitrate reduction reaction In situ spectroscopic studies Hydrogen evolution reaction
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Research on a Monte Carlo global variance reduction method based on an automatic importance sampling method 被引量:1
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作者 Yi-Sheng Hao Zhen Wu +3 位作者 Shen-Shen Gao Rui Qiu Hui Zhang Jun-Li Li 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第5期200-215,共16页
Global variance reduction is a bottleneck in Monte Carlo shielding calculations.The global variance reduction problem requires that the statistical error of the entire space is uniform.This study proposed a grid-AIS m... Global variance reduction is a bottleneck in Monte Carlo shielding calculations.The global variance reduction problem requires that the statistical error of the entire space is uniform.This study proposed a grid-AIS method for the global variance reduction problem based on the AIS method,which was implemented in the Monte Carlo program MCShield.The proposed method was validated using the VENUS-Ⅲ international benchmark problem and a self-shielding calculation example.The results from the VENUS-Ⅲ benchmark problem showed that the grid-AIS method achieved a significant reduction in the variance of the statistical errors of the MESH grids,decreasing from 1.08×10^(-2) to 3.84×10^(-3),representing a 64.00% reduction.This demonstrates that the grid-AIS method is effective in addressing global issues.The results of the selfshielding calculation demonstrate that the grid-AIS method produced accurate computational results.Moreover,the grid-AIS method exhibited a computational efficiency approximately one order of magnitude higher than that of the AIS method and approximately two orders of magnitude higher than that of the conventional Monte Carlo method. 展开更多
关键词 Monte Carlo Global variance reduction Reactor shielding Automatic importance sampling
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Single-atom catalysts for the electrochemical reduction of carbon dioxide into hydrocarbons and oxygenates 被引量:1
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作者 Karl Adrian Gandionco Juwon Kim +2 位作者 Lieven Bekaert Annick Hubin Jongwoo Lim 《Carbon Energy》 SCIE EI CAS CSCD 2024年第3期64-117,共54页
The electrochemical reduction of carbon dioxide offers a sound and economically viable technology for the electrification and decarbonization of the chemical and fuel industries.In this technology,an electrocatalytic ... The electrochemical reduction of carbon dioxide offers a sound and economically viable technology for the electrification and decarbonization of the chemical and fuel industries.In this technology,an electrocatalytic material and renewable energy-generated electricity drive the conversion of carbon dioxide into high-value chemicals and carbon-neutral fuels.Over the past few years,single-atom catalysts have been intensively studied as they could provide near-unity atom utilization and unique catalytic performance.Single-atom catalysts have become one of the state-of-the-art catalyst materials for the electrochemical reduction of carbon dioxide into carbon monoxide.However,it remains a challenge for single-atom catalysts to facilitate the efficient conversion of carbon dioxide into products beyond carbon monoxide.In this review,we summarize and present important findings and critical insights from studies on the electrochemical carbon dioxide reduction reaction into hydrocarbons and oxygenates using single-atom catalysts.It is hoped that this review gives a thorough recapitulation and analysis of the science behind the catalysis of carbon dioxide into more reduced products through singleatom catalysts so that it can be a guide for future research and development on catalysts with industry-ready performance for the electrochemical reduction of carbon dioxide into high-value chemicals and carbon-neutral fuels. 展开更多
关键词 ELECTROCATALYSIS electrochemical CO_(2)reduction hydrocarbons OXYGENATES single-atom catalysts
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The photo-decomposition and self-restructuring dynamic equilibrium mechanism of Cu_(2)(OH)_(2)CO_(3)for stable photocatalytic CO_(2)reduction 被引量:1
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作者 Yaqing Zhi Haoning Mao +5 位作者 Guangxing Yang Qiao Zhang Zhiting Liu Yonghai Cao Siyuan Yang Feng Peng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期104-112,共9页
Developing suitable photocatalysts and understanding their intrinsic catalytic mechanism remain key challenges in the pursuit of highly active,good selective,and long-term stable photocatalytic CO_(2)reduction(PCO_(2)... Developing suitable photocatalysts and understanding their intrinsic catalytic mechanism remain key challenges in the pursuit of highly active,good selective,and long-term stable photocatalytic CO_(2)reduction(PCO_(2)R)systems.Herein,monoclinic Cu_(2)(OH)_(2)CO_(3)is firstly proven to be a new class of photocatalyst,which has excellent catalytic stability and selectivity for PCO_(2)R in the absence of any sacrificial agent and cocatalysts.Based on a Cu_(2)(OH)_(2)^(13)CO_(3)photocatalyst and 13CO_(2)two-sided^(13)C isotopic tracer strategy,and combined with in situ diffused reflectance infrared Fourier transform spectroscopy(DRIFTS)analysis and density functional theory(DFT)calculations,two main CO_(2)transformation routes,and the photo-decomposition and self-restructuring dynamic equilibrium mechanism of Cu_(2)(OH)_(2)CO_(3)are definitely revealed.The PCO_(2)R activity of Cu_(2)(OH)_(2)CO_(3)is comparable to some of state-of-the-art novel photocatalysts.Significantly,the PCO_(2)R properties can be further greatly enhanced by simply combining Cu_(2)(OH)_(2)CO_(3)with typical TiO_(2)to construct composites photocatalyst.The highest CO_(2)and CH_(4)production rates by 7.5 wt%Cu_(2)(OH)_(2)CO_(3)-TiO_(2)reach 16.4μmol g^(-1)h^(-1)and 116.0μmol g^(-1)h^(-1),respectively,which are even higher than that of some of PCO_(2)R systems containing sacrificial agents or precious metals modified photocatalysts.This work provides a better understanding for the PCO_(2)R mechanism at the atomic levels,and also indicates that basic carbonate photocatalysts have broad application potential in the future. 展开更多
关键词 CO_(2)photocatalytic reduction PHOTOCATALYSIS Basic copper carbonate SELF-RECONSTRUCTION PHOTOCATALYST
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Porous metal oxides in the role of electrochemical CO_(2) reduction reaction 被引量:1
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作者 Ziqi Zhang Jinyun Xu +9 位作者 Yu Zhang Liping Zhao Ming Li Guoqiang Zhong Di Zhao Minjing Li Xudong Hu Wenju Zhu Chunming Zheng Xiaohong Sun 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期373-398,I0009,共27页
The global energy-related CO_(2) emissions have rapidly increased as the world economy heavily relied on fossil fuels.This paper explores the pressing challenge of CO_(2) emissions and highlights the role of porous me... The global energy-related CO_(2) emissions have rapidly increased as the world economy heavily relied on fossil fuels.This paper explores the pressing challenge of CO_(2) emissions and highlights the role of porous metal oxide materials in the electrocatalytic reduction of CO_(2)(CO_(2)RR).The focus is on the development of robust and selective catalysts,particularly metal and metal-oxide-based materials.Porous metal oxides offer high surface area,enhancing the accessibility to active sites and improving reaction kinetics.The tunability of these materials allows for tailored catalytic behavior,targeting optimized reaction mechanisms for CO_(2)RR.The work also discusses the various synthesis strategies and identifies key structural and compositional features,addressing challenges like high overpotential,poor selectivity,and low stability.Based on these insights,we suggest avenues for future research on porous metal oxide materials for electrochemical CO_(2) reduction. 展开更多
关键词 CO_(2)reduction Carbon dioxide TRANSFORMATION Porous metal oxides ELECTROCATALYSIS
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