Treatment of acyl chlorides and diaryl ketones with an activated Ti(o)reagent,prepared by reduction of TiCl_4 with Zn powder,effects an intermolecular reductive cross-coupling reaction leading to ketones.
基金Project supported by National Natural Science Foundation of China（Grant No. 20472048）, and Science Foundation of Shang-hai Municipal Commission of Science and Technology（ Grant No. 03ZR14033）
文摘Acetanilide was synthesized from nitrobenzene in the presence of acetic anhydride, acetic acid and samarium by a one-pot procedure in good yield.
文摘Treatment of acyl chlorides and diaryl ketones with an activated Ti(o)reagent,prepared by reduction of TiCl_4 with Zn powder,effects an intermolecular reductive cross-coupling reaction leading to ketones.
