We present a bidirectional reflection distribution function (BRDF) model for thermal coating surfaces based on a three-component reflection assumption, in which the specular reflection is given according to the micr...We present a bidirectional reflection distribution function (BRDF) model for thermal coating surfaces based on a three-component reflection assumption, in which the specular reflection is given according to the microfacet theory and Snell's law, the multiple reflection is considered Nth cosine distributed, and the volume scattering is uniformly distributed in reflection angles according to the experimental results. This model describes the reflection characteristics of thermal coating surfaces more completely and reasonably. Simulation and measurement results of two thermal coating samples SR107 and S781 are given to validate that this three-component model significantly improves the modeling accuracy for thermal coating surfaces compared with the existing BRDF models.展开更多
The Kubelka-Munk revised theory was adopted to derive the mix design theory of high solar reflectance and high emissivity coatings.When the concentration of each colorant is within 20%,and the width of the coating is ...The Kubelka-Munk revised theory was adopted to derive the mix design theory of high solar reflectance and high emissivity coatings.When the concentration of each colorant is within 20%,and the width of the coating is more than 200 μm,each colorant has enough covering power in visible and near-infrared spectral range.It can be assumed that the addition of colorants in coatings can only change the solar spectral absorption ratio rather than solar spectral scattering coefficient.The spectral scattering coefficient of coatings tends to a constant.The spectral absorption-scattering property of each colorant can be characterized through one parameter.The spectral absorption-scattering coefficient of coatings can be calculated with the multivariate linear relationship of each pigment.Moreover,the results can be expanded for high solar reflectivity and high long-wave emissivity coating preparation.The accuracy of Kubelka-Munk revised theory has been tested and verified through comparison between the calculated value and tested value of coating reflectance.展开更多
As the developing of the traffic and transport, road signs coating materials become important more and more. This paper introduces the development and current situation of the traffic marking coating and discusses its...As the developing of the traffic and transport, road signs coating materials become important more and more. This paper introduces the development and current situation of the traffic marking coating and discusses its raw material and application operation. C 5 petroleum resin made in china is used as major material in a hot melt traffic marking coating. To get the best material composition, orthogonal test is used and wear resistant, water resistant, acidity proof, alkaline proof, adhesive strength, fluid characteristic of the coating is researched.展开更多
MnO_2/activated carbon composite(Mn-ACC) wave absorber was prepared by the reaction between Mn(CH_3COO)_2 and KMnO_4 on activated carbon. Then, a novel cement based composite absorbing coating(CB-CAC) was prepar...MnO_2/activated carbon composite(Mn-ACC) wave absorber was prepared by the reaction between Mn(CH_3COO)_2 and KMnO_4 on activated carbon. Then, a novel cement based composite absorbing coating(CB-CAC) was prepared by adding the Mn-ACC, manganese zinc ferrite and rubber particles into cement. XRD method was used to analyze the reaction products of the Mn-ACC. The tensile bond strength and the wave absorbing properties of the CB-CACs were also tested. The results showed that the crystallinity of MnO_2 formed in the Mn-ACC was poor. Adding Mn-ACC into the CB-CAC led to first increase and then decrease of the tensile bond strength. The tensile bond strength reached 1.89 MPa with 8.51% of the Mn-ACC. The CB-CACs obtained the optimal absorbing properties with the cement, manganese zinc ferrite, Mn-ACC, rubber particles and H_2O mass ratio of 7.5?7.5?1?1?5.5, respectively. The band width of the reflection below-10 dB was up to 8.8 GHz, which accounted for 57.14% of the test band.展开更多
Reflective and insulative composite coatings are a new energy-saving material with high solar reflectance and extremely low thermal conductivity for buildings.The optimization and impact of high solar reflectance and ...Reflective and insulative composite coatings are a new energy-saving material with high solar reflectance and extremely low thermal conductivity for buildings.The optimization and impact of high solar reflectance and low thermal conductivity on the insulating capacity of walls remain uncertain.This work investigates the dynamic thermal performance and energy efficiency of a reflective and insulative composite coating in regions with hot summer and warm winter.A simplified thermal resistance-heat capacitance model of an exterior building wall is established to predict thermal performance.The dynamic temperature and heat flow of the wall are predicted to reduce heat loss through the interior surface of the wall and compared to the conventional coating.The specific impact of the thermal conductivity and solar reflectance of the coating on the heat loss is further investigated to minimize heat loss of the wall.This research shows that the composite coating shows better performance on adjusting outdoor climate change than the other coating.Compared with cement,it reduces the maximum temperature of the exterior surface of the wall by 7.45°C,and the heat loss through the interior surface of the wall by 38%.The heat loss is reduced with the increase of solar reflectance and the reduction of thermal conductivity.The results can provide a useful reference and guidance for the application of reflective and insulative composite coating on building exterior wall to promote their energy-saving use on building envelopes.展开更多
Ta2O5 and Nb2O5 films are deposited on BK7 glass substrates using an electron beam evaporation method and are annealed at 673 K in the air. In this letter, comparative studies of the optical transmittance, microstruct...Ta2O5 and Nb2O5 films are deposited on BK7 glass substrates using an electron beam evaporation method and are annealed at 673 K in the air. In this letter, comparative studies of the optical transmittance, microstructure, chemical composition, optical absorption, and laser-induced damage threshold (LIDT) of the two films are conducted. Findings indicate that the substoichiometric defect is very harmful to the laser damage resistance of Ta2O5 and Nb2O5 films. The decrease of absorption improves the LIDT in films deposited by the same material. However, although the absorption of the Ta2O5 single layer is less than that of the Nb2O5 single layer, the LIDT of the former is lower than that of the latter. High-reflective (HR) coatings have a higher LIDT than single layers due to the thermal dissipation of the SiO2 layers and the decreased electric field intensity (EFI). In addition, the Nb2O5 HR coating achieves the highest LIDT at 25.6 J/cm^2 in both single layers and HR coatings.展开更多
The impurities in two kinds of HfO2 materials and in their corresponding single layer thin films were determined through glow discharge mass spectrum technology and secondary ion mass spectrometry (SIMS) equipment r...The impurities in two kinds of HfO2 materials and in their corresponding single layer thin films were determined through glow discharge mass spectrum technology and secondary ion mass spectrometry (SIMS) equipment respectively. It was found that ZrO2 was the main impurity in the two kinds of HfO2 either in the original HfO2 materials or in the electron beam deposited films. In addition, the difference of Zr content in the two kinds of HfO2 single layer films was much larger than that of the other impurities such as Ti and Fe, which showed that it was just ZrO2 that made the difference between the optical performance of the film products including the two kinds of HfO2. With these two kinds of HfO2 and the same kind of SiO2, we deposited HfO2/SiO2 multilayer reflective coatings at the wavelength of 266 nm. Experimental results showed that the reflectances of these two mirrors were about 99.85% and 99.15% respectively, which agreed well with the designed results what were based on the optical constants obtained from the corresponding single layer thin films.展开更多
The transmittance characteristics of ZnS ceramics with infrared (IR) (3-5 and 8-12um) antireflective coatings are studied. The film designs are optimized with programmed software. A double-side and double-layer scheme...The transmittance characteristics of ZnS ceramics with infrared (IR) (3-5 and 8-12um) antireflective coatings are studied. The film designs are optimized with programmed software. A double-side and double-layer scheme is employed. Two different double-layers with proper pa ameters are coated onto each side of a ZnS substrate. The measurement methods for transmittance are investigated. The measured transmittance for IR (3-5 and 8-12 um) surpasses 70%.展开更多
To predict sound-absorbing performance of anechoic materials,the acoustic reflection problem of a viscoelastic layer backed with periodically rib-stiffened infinite double plates is studied in this paper.The reason wh...To predict sound-absorbing performance of anechoic materials,the acoustic reflection problem of a viscoelastic layer backed with periodically rib-stiffened infinite double plates is studied in this paper.The reason why structural theories of plates are not applicable to viscoelastic plates is explained through comparing dispersion and attenuation curves of flexural waves with those of Lamb waves.As a result,(visco-)elastic theory is adopted to deal with(visco-)elastic plates,and ribs are treated by structural theories of plates.The coupling between ribs and plates are solved by Hull's method,and solution of the reflected field is obtained.The accuracy of present method is validated by comparing with the results by the structural theories of plates.The influence of a backing on the acoustic reflection of the viscoelatic layer is analyzed by computing reflection coefficients.Performances of different viscoelastic materials are evaluated by the average reflection coefficients.The computational results show that,influence of a backing on the acoustic reflection cannot be suppressed by the viscoelastic materials in low frequencies.The resonance is determined by the coupling of the fluid layer and the double plates.And ribs,which are coupled with the double plates,mainly reduce the acoustic reflection.展开更多
The cavity ring-down (CRD) technique is adopted for simultaneously measuring s- and p-polarization reflectivity of highly reflective coatings without employing any polarization optics. As the s- and p-polarized ligh...The cavity ring-down (CRD) technique is adopted for simultaneously measuring s- and p-polarization reflectivity of highly reflective coatings without employing any polarization optics. As the s- and p-polarized light trapped in the ring-down cavity decay independently, with a randomly polarized light source the ring-down signal recorded by a photodetector presents a double-exponential waveform consisting of ring-down signals of both s- and p-polarized light. The s- and p-polarization reflectivity values of a test mirror are therefore simultaneously determined by fitting the recorded ring-down signal with a double-exponential function. The determined s- and p-polarization reflectivity of 30° and 45° angle of incidence mirrors are in good agreement with the reflectivity values measured with the conventional CRD technique employing a polarizer for polarization control.展开更多
文摘We present a bidirectional reflection distribution function (BRDF) model for thermal coating surfaces based on a three-component reflection assumption, in which the specular reflection is given according to the microfacet theory and Snell's law, the multiple reflection is considered Nth cosine distributed, and the volume scattering is uniformly distributed in reflection angles according to the experimental results. This model describes the reflection characteristics of thermal coating surfaces more completely and reasonably. Simulation and measurement results of two thermal coating samples SR107 and S781 are given to validate that this three-component model significantly improves the modeling accuracy for thermal coating surfaces compared with the existing BRDF models.
基金Supported by the 12th Five-year National Science and Technology Support Plan(No.2011BAE27B04)the Natural Science Foundation of China(No.51378391)the China Scholarship Council(award to HE Yan for studying in the University of Toronto)
文摘The Kubelka-Munk revised theory was adopted to derive the mix design theory of high solar reflectance and high emissivity coatings.When the concentration of each colorant is within 20%,and the width of the coating is more than 200 μm,each colorant has enough covering power in visible and near-infrared spectral range.It can be assumed that the addition of colorants in coatings can only change the solar spectral absorption ratio rather than solar spectral scattering coefficient.The spectral scattering coefficient of coatings tends to a constant.The spectral absorption-scattering property of each colorant can be characterized through one parameter.The spectral absorption-scattering coefficient of coatings can be calculated with the multivariate linear relationship of each pigment.Moreover,the results can be expanded for high solar reflectivity and high long-wave emissivity coating preparation.The accuracy of Kubelka-Munk revised theory has been tested and verified through comparison between the calculated value and tested value of coating reflectance.
文摘As the developing of the traffic and transport, road signs coating materials become important more and more. This paper introduces the development and current situation of the traffic marking coating and discusses its raw material and application operation. C 5 petroleum resin made in china is used as major material in a hot melt traffic marking coating. To get the best material composition, orthogonal test is used and wear resistant, water resistant, acidity proof, alkaline proof, adhesive strength, fluid characteristic of the coating is researched.
基金Funded by the International Cooperation Office of the Ministry of Science and Technology of China(2013DFR50360)the Postdoctoral Research Foundation of Shenyang Ligong University,the Open Fund from Advanced Processing Technology of Metal Materials of Liaoning Key Laboratory,Shenyang Ligong Universitythe Guide Project from Liaoning Natural Science Foundation of China(No.201602646)
文摘MnO_2/activated carbon composite(Mn-ACC) wave absorber was prepared by the reaction between Mn(CH_3COO)_2 and KMnO_4 on activated carbon. Then, a novel cement based composite absorbing coating(CB-CAC) was prepared by adding the Mn-ACC, manganese zinc ferrite and rubber particles into cement. XRD method was used to analyze the reaction products of the Mn-ACC. The tensile bond strength and the wave absorbing properties of the CB-CACs were also tested. The results showed that the crystallinity of MnO_2 formed in the Mn-ACC was poor. Adding Mn-ACC into the CB-CAC led to first increase and then decrease of the tensile bond strength. The tensile bond strength reached 1.89 MPa with 8.51% of the Mn-ACC. The CB-CACs obtained the optimal absorbing properties with the cement, manganese zinc ferrite, Mn-ACC, rubber particles and H_2O mass ratio of 7.5?7.5?1?1?5.5, respectively. The band width of the reflection below-10 dB was up to 8.8 GHz, which accounted for 57.14% of the test band.
基金the National Natural Science Foundation of China(No.52078144)the National Natural Science Foundation of China(No.52108073)the Innovation Research for Postgraduates of Guangzhou University(No.2021GDJC-D15).
文摘Reflective and insulative composite coatings are a new energy-saving material with high solar reflectance and extremely low thermal conductivity for buildings.The optimization and impact of high solar reflectance and low thermal conductivity on the insulating capacity of walls remain uncertain.This work investigates the dynamic thermal performance and energy efficiency of a reflective and insulative composite coating in regions with hot summer and warm winter.A simplified thermal resistance-heat capacitance model of an exterior building wall is established to predict thermal performance.The dynamic temperature and heat flow of the wall are predicted to reduce heat loss through the interior surface of the wall and compared to the conventional coating.The specific impact of the thermal conductivity and solar reflectance of the coating on the heat loss is further investigated to minimize heat loss of the wall.This research shows that the composite coating shows better performance on adjusting outdoor climate change than the other coating.Compared with cement,it reduces the maximum temperature of the exterior surface of the wall by 7.45°C,and the heat loss through the interior surface of the wall by 38%.The heat loss is reduced with the increase of solar reflectance and the reduction of thermal conductivity.The results can provide a useful reference and guidance for the application of reflective and insulative composite coating on building exterior wall to promote their energy-saving use on building envelopes.
基金supported by the Fundamental Research Funds for the Central Universities under Grant No.2009A058
文摘Ta2O5 and Nb2O5 films are deposited on BK7 glass substrates using an electron beam evaporation method and are annealed at 673 K in the air. In this letter, comparative studies of the optical transmittance, microstructure, chemical composition, optical absorption, and laser-induced damage threshold (LIDT) of the two films are conducted. Findings indicate that the substoichiometric defect is very harmful to the laser damage resistance of Ta2O5 and Nb2O5 films. The decrease of absorption improves the LIDT in films deposited by the same material. However, although the absorption of the Ta2O5 single layer is less than that of the Nb2O5 single layer, the LIDT of the former is lower than that of the latter. High-reflective (HR) coatings have a higher LIDT than single layers due to the thermal dissipation of the SiO2 layers and the decreased electric field intensity (EFI). In addition, the Nb2O5 HR coating achieves the highest LIDT at 25.6 J/cm^2 in both single layers and HR coatings.
基金The authors are grateful to Mr.Yongming Cao and Peiyuan Fang from National Microanalysis Center in Fudan University for the SIMS measurement
文摘The impurities in two kinds of HfO2 materials and in their corresponding single layer thin films were determined through glow discharge mass spectrum technology and secondary ion mass spectrometry (SIMS) equipment respectively. It was found that ZrO2 was the main impurity in the two kinds of HfO2 either in the original HfO2 materials or in the electron beam deposited films. In addition, the difference of Zr content in the two kinds of HfO2 single layer films was much larger than that of the other impurities such as Ti and Fe, which showed that it was just ZrO2 that made the difference between the optical performance of the film products including the two kinds of HfO2. With these two kinds of HfO2 and the same kind of SiO2, we deposited HfO2/SiO2 multilayer reflective coatings at the wavelength of 266 nm. Experimental results showed that the reflectances of these two mirrors were about 99.85% and 99.15% respectively, which agreed well with the designed results what were based on the optical constants obtained from the corresponding single layer thin films.
文摘The transmittance characteristics of ZnS ceramics with infrared (IR) (3-5 and 8-12um) antireflective coatings are studied. The film designs are optimized with programmed software. A double-side and double-layer scheme is employed. Two different double-layers with proper pa ameters are coated onto each side of a ZnS substrate. The measurement methods for transmittance are investigated. The measured transmittance for IR (3-5 and 8-12 um) surpasses 70%.
基金supported by the Research Funds(9140A10040813CB04001)the Natural Science Foundation of Shandong Province(2013ZRF01039)
文摘To predict sound-absorbing performance of anechoic materials,the acoustic reflection problem of a viscoelastic layer backed with periodically rib-stiffened infinite double plates is studied in this paper.The reason why structural theories of plates are not applicable to viscoelastic plates is explained through comparing dispersion and attenuation curves of flexural waves with those of Lamb waves.As a result,(visco-)elastic theory is adopted to deal with(visco-)elastic plates,and ribs are treated by structural theories of plates.The coupling between ribs and plates are solved by Hull's method,and solution of the reflected field is obtained.The accuracy of present method is validated by comparing with the results by the structural theories of plates.The influence of a backing on the acoustic reflection of the viscoelatic layer is analyzed by computing reflection coefficients.Performances of different viscoelastic materials are evaluated by the average reflection coefficients.The computational results show that,influence of a backing on the acoustic reflection cannot be suppressed by the viscoelastic materials in low frequencies.The resonance is determined by the coupling of the fluid layer and the double plates.And ribs,which are coupled with the double plates,mainly reduce the acoustic reflection.
文摘The cavity ring-down (CRD) technique is adopted for simultaneously measuring s- and p-polarization reflectivity of highly reflective coatings without employing any polarization optics. As the s- and p-polarized light trapped in the ring-down cavity decay independently, with a randomly polarized light source the ring-down signal recorded by a photodetector presents a double-exponential waveform consisting of ring-down signals of both s- and p-polarized light. The s- and p-polarization reflectivity values of a test mirror are therefore simultaneously determined by fitting the recorded ring-down signal with a double-exponential function. The determined s- and p-polarization reflectivity of 30° and 45° angle of incidence mirrors are in good agreement with the reflectivity values measured with the conventional CRD technique employing a polarizer for polarization control.