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Gas chromatography-mass spectrometry analysis of various organic extracts of Merremia borneensis from Sabah 被引量:1
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作者 M Amzad Hossain Muhammad Dawood Shah Mahyar Sakari 《Asian Pacific Journal of Tropical Medicine》 SCIE CAS 2011年第8期637-641,共5页
Objective:To analyse the chemical composition of different extracts of Merremia borneensis(M. borneensis) by gas chromatography-mass spectrometry(GC-MS).Methods:The dried leaves powder was extracted with methanol at r... Objective:To analyse the chemical composition of different extracts of Merremia borneensis(M. borneensis) by gas chromatography-mass spectrometry(GC-MS).Methods:The dried leaves powder was extracted with methanol at room temperature by using Soxhlet extractor.Methanol crude extracts of M.borneensis were extrastel with hexane,chloroform,ethyl acetate and butanol. Results:Qualitative analyses of various organic crude extracts showed that majority of these are flavonoids,terpeniods,alkaloids and glycosides.Most of the identified compounds by GCMS are biologically important.Further the M.borneensii leaf possesses certain characteristics that can be ascribed to cultivation on a domestic plantation.Conclusions:The suitable extracts for respective compounds can be chosen on the basis of above GC-MS analysis.All the major compounds from different extracts are biologically active molecules.Thus the identification of a good number of compounds from various extracts M.borneensis might have some ecological significance. 展开更多
关键词 Merremia borneensis organIC EXTRACTS Qualilalive analysis gc-ms
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GC-MS法分析Fenton法处理焦化废水难降解有机物规律 被引量:4
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作者 唐传罡 蔡昌凤 《安徽工程大学学报》 CAS 2012年第2期16-19,共4页
利用Box-Behnken Design(BBD)的响应面分析方法(RSM),对Fenton试剂法处理焦化废水4个主要因素:初始pH、H2O2用量、[H2O2]/[Fe2+]摩尔比及反应时间的交互影响进行了分析,得到二次响应曲面模型,表明COD的去除率与各因素存在显著的相关性,... 利用Box-Behnken Design(BBD)的响应面分析方法(RSM),对Fenton试剂法处理焦化废水4个主要因素:初始pH、H2O2用量、[H2O2]/[Fe2+]摩尔比及反应时间的交互影响进行了分析,得到二次响应曲面模型,表明COD的去除率与各因素存在显著的相关性,以[Fe2+]:[H2O2](摩尔比)和H2O2投加量交互影响最为显著。以优化条件pH值为3.60、m(H2O2)∶m(CODcr)为1.95、[Fe2+]/[H2O2]摩尔比为1∶7.43、反应时间30.8min,分别处理原水、缺氧池出水、二沉池出水,COD去除率达到44.60%、47.30%、56.59%.GC-MS分析Fenton氧化法处理前后水样,表明Fenton体系中产生大量的.OH自由基,主要对焦化废水中的挥发酚类和含氮杂环化合物类污染物苯环上的C-C键进行攻击后断裂,降解产物以石油烃类为主及部分的酯类、醇类等.好氧工艺和Fenton法对挥发酚类去除效果显著. 展开更多
关键词 FENTON氧化 焦化废水 难降解有机物 gc-ms分析
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Rapid on-site identification of hazardous organic compounds at fire scenes using person-portable gas chromatography-mass spectrometry(GC-MS)—part 1:air sampling and analysis 被引量:2
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作者 Rylee Lam Chris Lennard +6 位作者 Graham Kingsland Paul Johnstone Andrew Symons Laura Wythes Jeremy Fewtrell David O’Brien Val Spikmans 《Forensic Sciences Research》 CSCD 2020年第2期134-149,共16页
Recent advancements in person-portable instrumentation have resulted in the potential to provide contemporaneous results through rapid in-field analyses.These technologies can be utilised in emergency response scenari... Recent advancements in person-portable instrumentation have resulted in the potential to provide contemporaneous results through rapid in-field analyses.These technologies can be utilised in emergency response scenarios to aid first responders in appropriate site risk assessment and management.Large metropolitan fires can pose great risk to human and environmental health due to the rapid release of hazardous compounds into the atmosphere.Understanding the release of these hazardous organics is critical in understanding their associated risks.Person-portable gas chromatography-mass spectrometry(GC-MS)was evaluated for its potential to provide rapid on-site analysis for real-time monitoring of hazardous organic compounds at fire scenes.Air sampling and analysis methods were developed for scenes of this nature.Controlled field testing demonstrated that the portable GC-MS was able to provide preliminary analytical results on the volatile organic compounds present in air samples collected from both active and extinguished fires.In-field results were confirmed using conventional laboratory-based air sampling and analysis procedures.The deployment of portable instrumentation could provide first responders with a rapid on-site assessment tool for the appropriate management of scenes,thereby ensuring environmental and human health is proactively protected and scientifically informed decisions are made for the provision of timely advice to stakeholders. 展开更多
关键词 Forensic sciences gas chromatography-mass spectrometry portable gc-ms air pollution fire volatile organic compounds field analysis needle trap
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长江流域难降解溶解态有机碳的入河量与断面输送通量及源贡献分析 被引量:1
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作者 田思雨 王芳 +3 位作者 张培培 晏维金 余其彪 储昭升 《环境科学学报》 CAS CSCD 北大核心 2023年第9期418-429,共12页
河流溶解态有机碳(DOC)的迁移转化对流域尺度碳循环与碳的源汇机制具有重要意义.河流系统DOC中有相当一部分的难降解溶解态有机碳(Refractory Dissolved Organic Carbon,RDOC)在迁移转化过程中较难去除,是一个重要的碳库,但其结构和来... 河流溶解态有机碳(DOC)的迁移转化对流域尺度碳循环与碳的源汇机制具有重要意义.河流系统DOC中有相当一部分的难降解溶解态有机碳(Refractory Dissolved Organic Carbon,RDOC)在迁移转化过程中较难去除,是一个重要的碳库,但其结构和来源及其相对贡献和对碳排放的意义仍不清晰.本研究基于2017-2018年长江干、支流关键断面(30个站点)的逐月水文、水化学参数,包括直门达站、寸滩站和大通站的傅立叶变换离子回旋共振质谱(FT-ICR MS)分析的水质参数等,分析了长江关键断面RDOC浓度、单位面积输出量和输出通量,自上游至下游RDOC的结构组成变化,以及长江水系RDOC的不同来源及其相对贡献.结果表明:(1)长江流域2017-2018年两年平均RDOC输出通量为4.62×10^(8)kg·a^(-1),输出模数为270.7 kg·km^(-2)·a^(-1);表征RDOC的主要组分“稳定岛分子”的相对丰度从长江上游(直门达和寸滩站)到下游大通站呈增加趋势,稠环芳烃和多酚类的相对丰度也有类似的变化趋势.(2)长江水系RDOC的浓度、输出模数及通量存在显著的空间变化,在干流基本呈显著增加趋势.长江RDOC的源贡献有显著的空间差异,面源RDOC的占比自直门达站的96%下降到大通站55%,相反点源RDOC的占比从0增加到45%.汉江对长江RDOC输出通量的贡献最大,贡献率为36.54%,乌江流域贡献最小,贡献比只有1.17%.(3)COD_(Mn)/DO随着RDOC浓度的增加而增加,表明以COD表征的水体可降解DOC可能高估了,相应的DOC转化所产生的碳排放也被高估了.长江RDOC的输出通量占长江入河DOC通量的13%,占大通站输出DOC通量的30%.本研究建议,忽略RDOC的输送通量,将会高估DOC转化所产生的碳排放,数值约为2.61×10^(8)kg·a^(-1). 展开更多
关键词 长江 难降解溶解性有机碳(RDOC) 分子组成 源贡献分析 碳排放
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