Method for constructing the optimal water supply line and formulas for calculating the targets for single-contaminant regeneration recycling water systems are improved to apply to the situation of variational pararnet...Method for constructing the optimal water supply line and formulas for calculating the targets for single-contaminant regeneration recycling water systems are improved to apply to the situation of variational pararneters in this article. Based on these extending methods, the effect of varying freshwater consumption and regenerated water flow rate on the optimizing results are investigated. The interactions of parameters of regeneration recycling systems are summarized. Finally, all the conclusions are illustrated from the results of mathematical programming through an example.展开更多
High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategie...High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategies for the exhausted zeolite regeneration,the efficacy of some chemico-physical treatments on the zeolite loaded with four different sulfonamides was evaluated. The evolution of photolysis, Fenton-like reaction, thermal treatments, and solvent extractions and the occurrence in the zeolite pores of organic residues eventually entrapped was elucidated by a combined thermogravimetric（TGA–DTA）, diffractometric（XRPD）, and spectroscopic（FT-IR） approach. The chemical processes were not able to remove the organic guest from zeolite pores and a limited transformation on embedded molecules was observed. On the contrary, both thermal treatment and solvent extraction succeeded in the regeneration of the zeolite loaded from deionized and natural fresh water. The recyclability of regenerated zeolite was evaluated over several adsorption/regeneration cycles, due to the treatment efficacy and its stability as well as the ability to regain the structural features of the unloaded material.展开更多
基金Supported by the National Natural Science Foundation of China （No.20436040）.
文摘Method for constructing the optimal water supply line and formulas for calculating the targets for single-contaminant regeneration recycling water systems are improved to apply to the situation of variational pararneters in this article. Based on these extending methods, the effect of varying freshwater consumption and regenerated water flow rate on the optimizing results are investigated. The interactions of parameters of regeneration recycling systems are summarized. Finally, all the conclusions are illustrated from the results of mathematical programming through an example.
基金co-funded by the Italian Ministry of Education, University, and Research (No. PRIN 2008 BL2NWK: Zeolites as nano-reactors for the environment: efficiency, selectivity and stability in the adsorption of drugs from contaminated waters)
文摘High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategies for the exhausted zeolite regeneration,the efficacy of some chemico-physical treatments on the zeolite loaded with four different sulfonamides was evaluated. The evolution of photolysis, Fenton-like reaction, thermal treatments, and solvent extractions and the occurrence in the zeolite pores of organic residues eventually entrapped was elucidated by a combined thermogravimetric（TGA–DTA）, diffractometric（XRPD）, and spectroscopic（FT-IR） approach. The chemical processes were not able to remove the organic guest from zeolite pores and a limited transformation on embedded molecules was observed. On the contrary, both thermal treatment and solvent extraction succeeded in the regeneration of the zeolite loaded from deionized and natural fresh water. The recyclability of regenerated zeolite was evaluated over several adsorption/regeneration cycles, due to the treatment efficacy and its stability as well as the ability to regain the structural features of the unloaded material.
