Flow characteristics and regime transition of aqueous foams in porous media over a wide range of quality,velocity,and surfactant concentration

Aqueous foam is broadly applicable to enhanced oil recovery(EOR).The rheology of foam as a function of foam quality,gas and liquid velocities,and surfactant concentration constitute the foundation of its application.The great variations of the above factors can affect the effectiveness of N2 foam in EOR continuously in complex formations,which is rarely involved in previous relevant studies.This paper presents an experimental study of foam flow in porous media by injecting pre-generated N2 foam into a sand pack under the conditions of considering a wide range of gas and liquid velocities and surfactant concentrations.The results show that in a wide range of gas and liquid velocities,the pressure gradient contours are L-shaped near the coordinate axes,but V-shaped in other regions.And the surfactant concentration is a strong factor influencing the trend of pressure gradient contours.Foam flow resistance is very sensitive to the surfactant concentration in both the high-and low-foam quality regime,especially when the surfactant concentration is less than CMC.The foam quality is an important variable to the flow resistance obtained.There exists a transition point from low-to high-quality regime in a particular flow system,where has the maximum flow resistance,the corresponding foam quality is called transition foam quality,which increases as the surfactant concentration increases.The results can add to our knowledge base of foam rheology in porous media,and can provide a strong basis for the field application of foams.

Micro-flow structure at regime transition from bubbling to turbulent fluidization in a fluidized bed

Gas-solid fluidized beds have found extensive utilization in frontline manufacturing,in particular as low-velocity beds.The fluidization status,the bubbling or turbulent flow regime and the transition in between,determine the system performance in practical applications.Though the convoluted hydrodynamics are quantitively evaluated through numerous data-processing methodologies,none of them alone can reflect all the critical information to identify the transition from the bubbling to the turbulent regime.Accordingly,this study was to exploit a coupling data processing methodology,in the combination of standard deviation,power spectrum density,probability density function,wavelet transform,and wavelet multiresolution method,to jointly explain the micro-flow structure at the regime transition from bubbling to turbulent fluidization.The transient differential pressure fluctuation was measured for the evaluation in a fluidized bed(0.267 m i.d.×2.5 m height)with FCC catalysts(d_(p)=65μm,ρ_(p)=1780kg/m^(3))at different superficial gas velocities(0.02–1.4 m/s).The results show that the onset of turbulent fluidization starts earlier in the top section of the bed than in the bottom section.The wavelet decomposition displays that the fluctuation of differential pressure mainly concentrates on the sub-signals with an intermediate frequency band.These sub-signals could be synthesized into three types of scales(micro-scale,meso-scale,and macro-scale),representing the multi-scale hydrodynamics in the fluidized bed.The micro-scale signal has the characteristic information of bubbling fluidization,and the characteristic information of turbulent fluidization is mainly represented by the meso-scale signal.This work provides a systematic comprehension of fluidization status assessment and serves as an impetus for more coupling analysis in this sector.

Game-theoretical explorations of the mesoscale flow structure and regime transitions in bubble columns

Understanding the mesoscale structure and regime transition in bubble columns is of great significance for reactor design and scaleup.Based on the energy-minimization multiscale(EMMS)model,a noncooperative game model with constraints is proposed to investigate the structural properties of gas-liquid systems in which small and large bubbles are chosen as players and the energy consumption form the objective function.The conservation equations of the system can be regarded as the constraints of the game.For the formulated noncooperative game model,the concept of the generalized Nash equilibrium(GNE)is used to characterize the solution.An algorithm is developed to numerically compute the GNE and some important structural parameters in the system.The numerical results show the existence of the GNE for all values of the superficial gas velocity Ug.As Ug varies,the trends in the state variables can be observed and the critical point of Ug identified.The overall trend of the flow regime transition agrees with the original EMMS model and experimental results,although the GNE calculation also reveals different single-bubble dominant mechanisms with increasing Ug.

Petrogenesis of the Early Cretaceous Laojunshan monzogranite at the southern margin of the North China Craton: Constrains on the transition of the tectonic regime

1 Introduction Voluminous Mesozoic magmatic rocks containing abundant Au-Mo polymetallic mineralization resources are developed in the Xiaoqinling-Xiong’ershan district of the southern margin of the North China Craton(NCC).

Large Signal Modulation Characteristics in the Transition Regime for Two-State Lasing Quantum Dot Lasers

Large-signal modulation capability, as an important performance indicator, is directly related to the high-speed optical communication technology involved. We experimentally and theoretically investigate the large-signal modulation characteristics of the simultaneous ground-state （GS） and the excited-state （ES） lasing in InAs/OaAs quantum dot laser diodes. The large-signal modulation capability of total light intensity in the transition regime from OS lasing to two-state lasing is unchanged as the bias-current increases. However, GS and ES large-signal eye diagrams show obvious variations during the transition. Relaxation oscillations and large-signal eye diagrams for OS, ES, and total light intensities are numerically simulated and analyzed in detail by using a rate-equation model. The -ndings show that a complementary relationship between the light intensities for OS and ES lasing exists in both the transition regime and the two-state lasing regime, leading to a much smaller overshooting power and a shorter settling time for the total light intensity. Therefore, the eye diagrams of GS or ES lasing are diffuse whereas those of total light intensity are constant as the bias-current increases in the transition regime.

Computer Simulation of Transition Regimes of Solitons in Four-Photon Resonant Parametric Processes in Case of Two-Photon Resonance

The transition regimes of solitons in four-photon resonant processes in the case of two-photon absorption of the fundamental radiation are numerically investigated. The standard system of equations for the amplitudes of probability of finding the system in state with certain energy is used to derive the expression for the induced polarization in the nonlinear medium. As for the equations for the amplitudes of the optical pulses, the general case is considered in which both the amplitudes and phases are space-time dependent. We focus on the finite difference methods and the case of simultaneously propagating solitons at all frequencies of the interacting waves (simultons). The obtained results indicate that upon certain threshold conditions all interacting pulses become the solitons of Lorentzian shape. The numerical analysis has also shown that the soliton amplitudes significantly depend on the ratio between the nonlinear polarizability at the fundamental frequency ω0 and that of combination of ω0 and the trigger-field frequency ω1(2ω0 + ω1). In the second part of the paper, we apply the method of phase planes to show that at typical values of parameters, the solitons are stable.

A Novel Model for the Prediction of Liquid Film Thickness Distribution in Pipe Gas-Liquid Flows

A model is proposed for liquid film profile prediction in gas-liquid two-phase flow,which is able to provide the film thickness along the circumferential direction and the pressure gradient in the flow direction.A two-fluid model is used to calculate both gas and liquid phases’flow characteristics.The secondary flow occurring in the gas phase is taken into account and a sailing boat mechanism is introduced.Moreover,energy conservation is applied for obtaining the liquid film thickness distribution along the circumference.Liquid film thickness distribution is calculated accordingly for different cases;its values are compared with other models and available experimental data.As a result,the newly proposed model is tested and good performances are demonstrated.The liquid film thickness distribution in small pipes and inclined pipes is also studied,and regime transition is revealed by liquid film profile evolution.The observed inflection point demonstrates that the liquid film thickness decreases steeply along the circumference,when the circle angle ranges between 30°and 50°for gas-liquid stratified flow with small superficial velocities.

The Geological Significance of the Deformation and Geochronology of the Xiaotian–Mozitan Shear Zone in the Dabie Orogenic Belt(East-Central China)

The Xiaotian–Mozitan Shear Zone(XMSZ)is the boundary of the Dabie High-grade Metamorphic Complex(DHMC)and the North Huaiyang Tectonic Belt.It was deformed in ductile conditions with a top-to-NW/WNW movement.Geothermometers applied to mineral parageneses in mylonites of the shear zone give a temperature range of 623–691°C for the predeformation and 515–568°C for the syndeformation,respectively,which indicates a retrograde process of evolution.A few groups of zircon U-Pb ages were obtained from undeformed granitic veins and different types of deformed rocks in the zone.Zircons from the felsic ultramylonites are all magmatic,producing a weighted mean 206Pb/238U age of 754±8.1 Ma,which indicates the time of magmatic activities caused by rifting in the Neoproterozoic.Zircons from the granitic veins,cutting into the mylonites,are also of magmatic origin,producing a weighted mean 206 Pb/238 U age of 130±2.5 Ma,which represents the time of regional magmatic activity in the Cretaceous.Zircons from the mylonitic gneisses are of anatectic-metamorphic origins and are characterized by a core-mantle interior texture,which yielded several populations of ages including the Neoproterozoic ages with a weighted mean 206 Pb/238 U age of 762±18 Ma,similar to that of the felsic ultramylonites and the Early Cretaceous ages with a weighted mean 206Pb/238U age of 143±1.8 Ma,indicating the anatectic metamorphism in the Dabie Orogenic Belt(DOB).Based on integrated analysis of the structure,thermal conditions of ductile deformation and the contact relations of the dated rocks,the activation time of the Xiaotian–Mozitan Shear Zone is constrained between~143 Ma and 130 Ma,during which the DOB was undergoing a transition in tectonic regime from compression to extension.Therefore,the deformation and evolution of this shear zone plays an instrumental role in fully understanding this process.This research also inclines us to the interpretation of it as an extensional detachment,with regard to the tectonic properties of the shear zone.It may also be part of a continental scale extension in the background of the North China Block’s cratonic destruction,dominated by the subduction and roll-back of the Paleo-Pacific plate,but more detailed work is needed in order to unravel its complicated development.

Hydrodynamic Behavior in a Tapered Bubble Column

The experiment was conducted to explore the hydrodynamics in a conical column with a height of 3.00 m, and a taper angle of 1.91°. Three regimes occur in succession with increasing superficial gas velocity. Overall gas holdup increases with an increase in gas velocity and a decrease in solid concentration or static slurry height. Axial solid holdup becomes more uniform with increasing gas velocity, while axial gas holdup decreases from the bottom to the top. Both dry and wet pressure drops across the gas distributor increase with an increase in superficial gas velocity.

Energy budget of cold and hot gas-solid fluidized beds through CFD-DEM simulations

Direct energy budget is carried out for both cold and hot flow in gas–solid fluidization systems.First,the energy paths are proposed from thermodynamic viewpoints.Energy consumption means total power input to the specific system,and it can be decomposed into energy retention and energy dissipation.Energy retention is the variation of accumulated mechanical energy in the system,and energy dissipation is the energy converted to heat by irreversible processes.Then based on the Computational Fluid Dynamics-Discrete Element Method(CFD-DEM)framework,different energy terms are quantified from the specific flow elements of fluid cells and particles as well as their interactions with the wall.In order to clarify the energy budget,it is important to identify which system is studied:the particle-fluid system or the particle sub-system.For the cold flow,the total energy consumption of the particle sub-system can well indicate the onset of bubbling and turbulent,while the variation of local energy consumption terms can reflect the evolution of heterogeneous structures.For the hot flow,different heat transfer mechanisms are analyzed and the solver is modified to reproduce the experimental results.The impact of the heat transfer mechanisms and heat production on energy consumption is also investigated.The proposed budget method has proven to be energy-conservative and easy to conduct,and it is hopeful to be applied to other multiphase flow systems.

Nonlinear characteristics analyses of particle motion for predicting flow regimes

Gas-solid flow regimes have a significant impact on particle transport and separation in a fluidized bed reactor.In this study,to determine flow regime transitions in gas-solid fluidized beds,an acoustic technique was used to detect and analyze the behavior of gas and solids.Algorithm complexity,fluctuation complexity,and Shannon entropy analyses of acoustic emission signals were performed to examine non linear system characteristics,and to determine the flow regime transiti on velocities uc,uk,and ufd-Moreover,using the standard deviation of pressure signals,pressure measurements and acoustic measurements were compared.The relative deviations(RDs)between the experimental and empirical values of uk were 8.8%,13.7%,8.8%,and 30.4%for the algorithm complexity,fluctuation complexity,Shannon entropy,and pressure signal standard deviation,respectively,while the respective RDs for Ufd were 15.7%,23.9%,15.7%,and 97.8%.The RDs between the experimental and empirical values of uc were all 6.4%.The experimental values obtained from acoustic signal measurements were therefore closer to the empirical values.In summary,the integration of non-intrusive acoustic measurements,complexity analysis,and Shannon entropy analysis is suitable for identifying flow regime transitions.

Metallogenetic model of Jiaodong-type gold deposits,eastern China

The genesis of giant gold provinces is an international scientific frontier,in which the source of a huge amount of gold and the drive for mineralization are key challenges.The mineralization intensity of the Jiaodong gold province in eastern China is a rare occasion in the world,because it owns gold reserves of~5500 tons within an area of less than 10,000 km^(2).The Jiaodong gold province formed in the superimposed domain of diverse tectonic regimes in an intracontinental setting.Paleoproterozoic regional peak metamorphism and Triassic continental collision are followed by the tectonic transition and gold mineralization at ca.120 Ma with time intervals of 1.9 billion years and about 100 million years,respectively.The Jiaodong gold deposits are different from orogenic and intrusion-related gold deposits in terms of the tectonic background,types of host rocks,and oreforming mechanism.These gold deposits show close spatial-temporal and genetic relationships to mafic igneous rocks,implying the derivation of ore-forming fluids from the metasomatic mantle domains.Mafic dykes in Jiaodong have negativeε_(Hf)(t)values of-29.9 to-9.1,Os content of 0.002-0.16 ppb,heavyδ^(18)O up to 8.23‰,and high initial^(187)Os/^(188)Os ratios of 0.1352-0.8858.These indicate that the lithospheric mantle was metasomatized by ancient crust-derived components.The lithospheric mantle in the western Jiaodong shows generally more enriched isotope features than that in the eastern part,which is explained to be an important reason for its huge gold resources.The mafic dykes show lighter Mg isotope characteristics(averageδ^(26)Mg of-0.33‰,n=50)and high Ca O content(overall greater than 6.5 wt%),indicating that the lithospheric mantle would also record the metasomatism by the carbonate rocks from the subducting oceanic slab.Under the background of the rollback of the subducting paleo-Pacific slab and the destruction of the North China Craton,partial melting of the lower crust would produce granitic magmas that led to the enrichment of gold in the residual crust.The syn-mineralization asthenosphere upwelling would promote the recycling of the lower crust and the partial melting of the metasomatic mantle domains.Basic magmas,produced by the partial melting,and the mantle itself would degas to form ore fluids.The ore fluids would further leach gold in the lower crust to increase its fertility.The auriferous fluids were transported to the middle to upper crust along the detachment and strike-slip faults.Water-rock interaction and fluid immiscibility,which occurred in and above the ductile-brittle transition zone to induce gold precipitation,formed the Jiaodong gold deposits.Given the unique geological features and genetic model of the Jiaodong gold deposits,they can be defined as“Jiaodong-type”gold deposits.

Effects of internals and distributors on the distribution and growth of bubbles in the conventional gas-solid fluidized bed

The effects of internals and gas distributors on the local dynamics of the bubbles in the conventional gas-solid fluidized bed were studied.Mesh-type internals with different opening areas(50%,70%and 90%)and different arrangements(two-layer and four-layer);and a sintered plate with a smaller pore size(1μm)and a perforated plate with a larger pore size as distributors were investigated.Differential pressure drops and local solids holdups were measured under various superficial gas velocities to compare the performances of the different types of internals and distributors.The instantaneous solids holdup signals from the optical fibre probe were used to further examine the local bubble dynamics in detail.Smaller bubbles were found,with the installation of internals or using the sintered plate,resulting in lower pressure drops and a higher bed expansion.Internals with reduced opening area or distributor with smaller pore size further leads to a higher changeover rate between the bubbles and dense phase,both axially and radially,and hence a better gas-solid contacting and an earlier transition to the turbulent flow regime of the bed.

Analysis of the energy-minimization multiscale model with multiobjective optimization

Gas-solid two-phase flow is ubiquitous in nature and many engineering fields,such as chemical engineering,energy,and mining.The closure of its hydrodynamic model is difficult owing to the complex multiscale structure of such flow.To address this problem,the energy-minimization multi-scale(EMMS)model introduces a stability condition that presents a compromise of the different dominant mechanisms involved in the systems,each expressed as an extremum tendency.However,in the physical system,each dominant mechanism should be expressed to a certain extent,and this has been formulated as a multiobjective optimization problem according to the EMMS principle generalized from the EMMS model.The mathematical properties and physical meanings of this multiobjective optimization problem have not yet been explored.This paper presents a numerical solution of this multiobjective optimization problem and discusses the correspondence between the solution characteristics and flow regimes in gas-solid fluidization.This suggests that,while the most probable flow structures may correspond to the stable states predicted by the EMMS model,the noninferior solutions are in qualitative agreement with the observable flow structures under corresponding conditions.This demonstrates that both the dominant mechanisms and stability condition proposed for the EMMS model are physically reasonable and consistent,suggesting a general approach of describing complex systems with multiple dominant mechanisms.

Solids behavior in dilute zone of a CFB riser under turbulent conditions

The behavior of the solid phase in the upper zone of a circulating fluidized bed riser was studied using a phase Doppler anemometer. Glass particles of mean diameter 107μm and superficial gas velocities UE covering the turbulent and the beginning of the fast fluidization regime were investigated. Three static bed heights were tested. Ascending and descending particles were found co-existing under all oper ating conditions tested, and at all measurement locations. Superficial gas velocity proved/happened to have a larger effect on descending particles at the wall and on ascending particles in the central region. Transversal particle velocities in both directions （toward the center and toward the wall） behaved rela- tively equivalently, with only slight difference observed at the wall. However, observation of the number of particles moving in either transversal direction showed a change in bed structure when increasing Ug. Furthermore, a balance was constantly observed between the core zone and the annulus zone where the mutual mass transfer between these two zones occurred continuously. Transition from a slow to a fast particle motion was accompanied by a transition to high levels of velocity fluctuations, and was found corresponding to the appearance of significant solid particle flow rate.