This study investigated the influence of the addition of Al to a Mg-7Bi(B7,wt%)alloy,particularly its recrystallization behavior during extrusion and its resulting mechanical properties.The addition of 2 wt%Al to the ...This study investigated the influence of the addition of Al to a Mg-7Bi(B7,wt%)alloy,particularly its recrystallization behavior during extrusion and its resulting mechanical properties.The addition of 2 wt%Al to the B7 alloy resulted in a lower grain size,a reduction in the number density of fine Mg3Bi2 particles,and a higher area fraction of relatively coarse Mg3Bi2 particles in the extrusion billet.These microstructural changes increased the nucleation sites for recrystallization,reduced the Zener pinning effect,and enhanced particle-stimulated nucleation,all of which promoted dynamic recrystallization behavior during extrusion.As a result,the area fraction of recrystallized grains in the extruded alloy increased from 77%to 94%.The extruded B7 alloy exhibited a strong<10-10>fiber texture,whereas the extruded Mg-7Bi-2Al(BA72)alloy had a weak<10-10>-<2-1-10>texture,which was attributed to the minimal presence of unrecrystallized grains and the dispersed orientation of the recrystallized grains.The tensile yield strength(TYS)of the extruded BA72 alloy was higher than that of the extruded B7 alloy(170 and 124 MPa,respectively),which resulted from the enhanced grain-boundary and solid-solution strengthening effects.The tensile elongation(EL)of the BA72 alloy also exceeded that of the B7 alloy(20.3%and 6.1%,respectively),the result of the uniform formation of fine twins under tension in the former and the formation of a few coarse twins among the unrecrystallized grains in the latter.Consequently,the addition of a small amount of Al to the B7 alloy significantly improved both the strength and ductility of the extruded alloy,resulting in a remarkable increase in the product of the TYS and EL from 756 to 3451 MPa%and expanding its potential range of applications as a lightweight extruded structural component.展开更多
Catalysts with varying Fe contents were prepared using a sequential impregnation method to investigate the effects of Fe addition on the physicochemical properties of Pt/Al_(2)O_(3) and their performance in methylcycl...Catalysts with varying Fe contents were prepared using a sequential impregnation method to investigate the effects of Fe addition on the physicochemical properties of Pt/Al_(2)O_(3) and their performance in methylcyclohexane(MCH)dehydrogenation.The results demonstrated that the addition of Fe to Pt/Al_(2)O_(3) enhanced the electron density of Pt and improved catalytic activity,while exhibiting negligible influence on the catalytic selectivity for toluene.When the Fe content was 0.057%,the catalyst exhibited the highest MCH consumption rate,which was approximately two times higher than that of the catalyst without Fe.Additionally,the incorporation of Fe inhibited the formation of coke and reduced the quantity of coke deposits on the catalyst,thereby improving its catalytic durability.Overall,Fe shows promise as a prospective secondary element for Pt/Al_(2)O_(3) to enhance the MCH dehydrogenation performance.展开更多
The study explored the influence of defatted flaxseed gum powder(DFGP) on the stability and quality of sesame paste by measuring and analyzing its composition, color, texture, particle size, centrifugal oil separation...The study explored the influence of defatted flaxseed gum powder(DFGP) on the stability and quality of sesame paste by measuring and analyzing its composition, color, texture, particle size, centrifugal oil separation rate,rheological properties, and microstructure. The results showed that the moisture and polysaccharide content of sesame paste was increased as the DFGP increased. Additionally, the hardness, gumminess, and chewiness of the sesame paste was improved, while the presence of particles with small particle size(1–100 μm) was decreased.The rate of oil precipitation was reduced by 28.99% when the amount of DFGP was 6%. The sesame paste samples exhibited pseudoplastic behavior, demonstrating shear thinning. As the shear rate increased, the apparent viscosity of sesame paste gradually decreased. Both the storage modulus(G’) and the loss modulus(G’’) increased as the shear frequency increased. The microstructure observation revealed that protein and oil were evenly distributed in the sesame paste system, and the addition of DFGP enhanced the bonding between oil and protein.This study can provide valuable references for high-quality sesame paste products in the food industry.展开更多
Atmospheric nitrogen(N)deposition is predicted to increase,especially in the subtropics.However,the responses of soil microorganisms to long-term N addition at the molecular level in N-rich subtropical forests have no...Atmospheric nitrogen(N)deposition is predicted to increase,especially in the subtropics.However,the responses of soil microorganisms to long-term N addition at the molecular level in N-rich subtropical forests have not been clarified.A long-term nutrient addition experiment was conducted in a subtropical evergreen old-growth forest in China.The four treatments were:control,low N(50 kg N ha^(-1)a^(-1)),high N(100 kg N ha^(-1)a^(-1)),and combined N and phosphorus(P)(100 kg N ha^(-1)a^(-1)+50 kg P ha^(-1)a^(-1)).Metagenomic sequencing characterized diversity and composition of soil microbial communities and used to construct bacterial/fungal co-occurrence networks.Nutrient-treated soils were more acidic and had higher levels of dissolved organic carbon than controls.There were no significant differences in microbial diversity and community composition across treatments.The addition of nutrients increased the abundance of copiotrophic bacteria and potentially beneficial microorganisms(e.g.,Gemmatimonadetes,Chaetomium,and Aureobasidium).Low N addition increased microbiome network connectivity.Three rare fungi were identified as module hubs under nutrient addition,indicating that low abundance fungi were more sensitive to increased nutrients.The results indicate that the overall composition of microbial communities was stable but not static to long-term N addition.Our findings provide new insights that can aid predictions of the response of soil microbial communities to long-term N addition.展开更多
The effect of addition temperature of MgO particles(MgOp)on their dispersion behavior and the efficiency of grain refinement in AZ31 Mg alloy was investigated.In addition,the grain refinement mechanism was systematica...The effect of addition temperature of MgO particles(MgOp)on their dispersion behavior and the efficiency of grain refinement in AZ31 Mg alloy was investigated.In addition,the grain refinement mechanism was systematically studied by microstructure characterization,thermodynamic calculation,and analysis of solidification curves.The results show that the grain size of AZ31 Mg alloy initially decreases and then increases as the MgOp addition temperature is increased from 720 to 810℃,exhibiting a minimum value of 136μm at 780℃.The improved grain refinement efficiency with increasing MgOp addition temperature can be attributed to the reduced Mg melt viscosity and enhanced wettability between MgOp and Mg melt.Furthermore,a corresponding physical model describing the solidification behavior and grain refinement mechanism was proposed.展开更多
Human activities and industrialization have significantly increased soil nutrients,such as nitrogen(N)and phos-phorus(P),profoundly impacting the composition and structure of plant community,as well as the ecosystem fu...Human activities and industrialization have significantly increased soil nutrients,such as nitrogen(N)and phos-phorus(P),profoundly impacting the composition and structure of plant community,as well as the ecosystem functions,especially in nutrient-limited ecosystems.However,as the key propagule pool of perennial grasslands,how belowground bud bank and its relationship with aboveground vegetation respond to short-term changes in soil nutrients was still unclear.In this study,we conducted a short-term(2021–2022)soil fertilization experiment with N addition(10 g N m^(-2) yr^(-1))and P addition(5 g N m^(-2) yr^(-1))in the meadow steppe of Inner Mongolia,China,to explore the responses of belowground bud bank,aboveground shoot population and their relationships(represented by the ratio of bud to shoot density-meristem limitation index(MLI))for the whole community and three plant functional groups(perennial rhizomatous grasses-PR,perennial bunchgrasses-PB,and perennial forbs-PF)to nutrient addition.The short-term nutrient addition had no significant influences on belowground bud density,aboveground shoot density,and MLI of the whole plant community.Plant functional groups showed different responses to soil fertilization.Specifically,N addition significantly increased the bud density and shoot density of PR,especially in combination with P addition.N addition reduced the shoot density of PF but had no influence on its bud density and MLI.Nutrient addition had significant effects on the three indicators of PB.Our study indicates that the belowground bud bank and its relationship with aboveground vegetation in temperate meadow steppe are insensitive to short-term soil fertilization,but plant functional groups exhibit specific responses in terms of population regeneration,which implies that plant community composition and ecosystem functions will be changed under the ongoing global change.展开更多
Are all prime numbers linked by four simple functions? Can we predict when a prime will appear in a sequence of primes? If we classify primes into two groups, Group 1 for all primes that appear before ζ (such that , ...Are all prime numbers linked by four simple functions? Can we predict when a prime will appear in a sequence of primes? If we classify primes into two groups, Group 1 for all primes that appear before ζ (such that , for instance 5, ), an even number divisible by 3 and 2, and Group 2 for all primes that are after ζ (such that , for instance 7), then we find a simple function: for each prime in each group, , where n is any natural number. If we start a sequence of primes with 5 for Group 1 and 7 for Group 2, we can attribute a μ value for each prime. The μ value can be attributed to every prime greater than 7. Thus for Group 1, and . Using this formula, all the primes appear for , where μ is any natural number.展开更多
●AIM:To explore the clinical efficacy and safety of stromal lenticule addition keratoplasty(SLAK)with corneal crosslinking(CXL)on patients with corneal ectasia secondary to femtosecond laser-assisted in situ keratomi...●AIM:To explore the clinical efficacy and safety of stromal lenticule addition keratoplasty(SLAK)with corneal crosslinking(CXL)on patients with corneal ectasia secondary to femtosecond laser-assisted in situ keratomileusis(FS-LASIK).●METHODS:A series of 5 patients undertaking SLAK with CXL for the treatment of corneal ectasia secondary to FS-LASIK were followed for 4-9mo.The lenticules were collected from patients undertaking small incision lenticule extraction(SMILE)for the correction of myopia.Adding a stromal lenticule was aimed at improving the corneal thickness for the safe application of crosslinking and compensating for the thin cornea to improve its mechanical strength.●RESULTS:All surgeries were conducted successfully with no significant complications.Their best corrected visual acuity(BCVA)ranged from 0.05 to 0.8-2 before surgery.The pre-operational total corneal thickness ranged from 345-404μm and maximum keratometry(Kmax)ranged from 50.8 to 86.3.After the combination surgery,both the corneal keratometry(range 55.9 to 92.8)and total corneal thickness(range 413-482μm)significantly increased.Four out of 5 patients had improvement of corneal biomechanical parameters(reflected by stiffness parameter A1 in Corvis ST).However,3 patients showed decreased BCVA after surgery due to the development of irregular astigmatism and transient haze.Despite the onset of corneal edema right after SLAK,the corneal topography and thickness generally stabilized after 3mo.●CONCLUSION:SLAK with CXL is a potentially beneficial and safe therapy for advanced corneal ectasia.Future work needs to address the poor predictability of corneal refractometry and compare the outcomes of different surgical modes.展开更多
The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully ci...The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.展开更多
The mechanical properties and texture of AM60(Mg-6.0Al-0.3Mn,mass fraction %) and ZXM200(Mg-1.6Zn-0.5Ca-0.2Mn) Mg alloys subjected to multi-pass hot rolling were investigated.The finer recrystallized grains usuall...The mechanical properties and texture of AM60(Mg-6.0Al-0.3Mn,mass fraction %) and ZXM200(Mg-1.6Zn-0.5Ca-0.2Mn) Mg alloys subjected to multi-pass hot rolling were investigated.The finer recrystallized grains usually exhibit particular preferred orientations and then alter the total texture feature of rolled sheets.Ca solid solution into Mg matrix serves to the formation of texture component with c-axis rotated away from normal direction towards transverse direction and then weakens the overall texture intensity,resulting in a similar anisotropic characteristic to RE-containing Mg alloys.展开更多
The effects of nitrogen (N) availability and tree species on the dynamics of carbon and nitrogen at early stage of decomposition of forest litter were studied in a 13-week laboratory incubation experiment. Fresh lit...The effects of nitrogen (N) availability and tree species on the dynamics of carbon and nitrogen at early stage of decomposition of forest litter were studied in a 13-week laboratory incubation experiment. Fresh litter samples including needle litter (Pinus koraiensis) and two types of broadleaf litters (Quercus mongolica and Tilia amurensis) were collected from a broadleaf-korean pine mixed forest in the northern slope of Changbai Mountain (China). Different doses of N (equal to 0, 30 and 50 kg.ha^-1yr^-1, respectively, as NH4NO3) were added to litter during the experiment period. The litter decomposition rate expressed as mass loss and respiration rate increased significantly with increasing N availability. The mass loss and cumulative CO2-C emission were higher in leaf litter compared to that in needle litter. The dis- solved organic Carbon (DOC) concentrations in litter leachate varied widely between the species, but were not greatly affected by N treatments. Regardless of the N addition rate, both N treatments and species had no significant effect on dissolved organic N (DON) concentrations in litter leachate. About 52-78% of added N was retained in the litter. The percentage of N retention was positively correlated (R^2=0.9 1, p〈0.05) with the litter mass loss. This suggested that a forest floor with easily decomposed litter might have higher potential N sink strength than that with more slowly decomposed litter.展开更多
Nineβ‐cyclodextrin derivatives containing an amino group were synthesized via nucleophilic sub‐stitution from mono(6‐O‐p‐tolylsulfonyl)‐β‐cyclodextrin and used in asymmetric biomimetic Mi‐chael addition re...Nineβ‐cyclodextrin derivatives containing an amino group were synthesized via nucleophilic sub‐stitution from mono(6‐O‐p‐tolylsulfonyl)‐β‐cyclodextrin and used in asymmetric biomimetic Mi‐chael addition reactions in water at room temperature. The mechanism responsible for the moder‐ate activity and enantioselectivity of the β‐cyclodextrin derivatives was explored using nuclear magnetic resonance spectroscopy, namely 2D 1H rotating‐frame overhauser effect spectroscopy (ROESY), ultraviolet absorption spectroscopy, and quantum chemical calculations, which provide a useful technique for investigating the formation of inclusion complexes. The effects of the pH of the reaction medium, theβ‐cyclodextrin derivative dosage, the structure of the modifying amino group, and various substrates on the yield and enantioselectivity were investigated. The results indicated that these factors had an important effect on the enantiomeric excess (ee) in the reaction system. Experiments using a competitor for inclusion complex formation showed that a hydrophobic cavity is necessary for enantioselective Michael addition. A comparison of the reactions using 4‐nitro‐β‐nitrostyrene and 2‐nitro‐β‐nitrostyrene showed that steric hindrance improved the enan‐tioselectivity. This was verified by the optimized geometries obtained from quantum chemical cal‐culations. An ee of 71%was obtained in the asymmetric Michael addition of cyclohexanone and 2‐nitro‐β‐nitrostyrene, using (S)‐2‐aminomethylpyrrolidine‐modified β‐CD as the catalyst, in an aqueous buffer solution, i.e., CH3COONa‐HCl (pH 7.5).展开更多
The effects of Y addition on the structural and mechanical properties of CuZrAl bulk metallic glass(BMG) were studied.The results show that the glass forming ability of CuZrAl system is improved by the addition of Y...The effects of Y addition on the structural and mechanical properties of CuZrAl bulk metallic glass(BMG) were studied.The results show that the glass forming ability of CuZrAl system is improved by the addition of Y and the fracture strength decreases with Y addition due to the reduction of binding energy induced by Y.The fracture surface is dominated by vein-like patterns in Cu45Zr48Al7 bulk metallic glass,and changes to smooth regions in Cu46Zr42Al7Y5 BMG.TEM observation shows that Cu45Zr48Al7 BMG has a composite microstructure of nanocrystalline phases dispersed in amorphous matrix.However,the Cu46Zr42Al7Y5 BMG shows a fully amorphous structure.展开更多
The effects of Cu addition on the microstructure and mechanical properties of the as-cast magnesium alloy ZK60 were investigated with optical microscope, SEM, TEM, XRD, EPMA and tensile tester. The mechanism by which ...The effects of Cu addition on the microstructure and mechanical properties of the as-cast magnesium alloy ZK60 were investigated with optical microscope, SEM, TEM, XRD, EPMA and tensile tester. The mechanism by which the mechanical properties are affected by Cu addition was discussed. The results show that Cu can effectively eliminate the intragranular solute segregations in the alloy, and the grain size of the alloy is decreased considerably with increasing the Cu amount. A ternary eutectic phase MgZnCu with a face-centered cubic structure is identified in the Cu-bearing alloys, which predominantly distributes at the grain boundary and acts as the nucleation sites of microcracks during the plastic deformation process. It is also found that the tensile properties of the alloy firstly increase by the trace addition of 0.5%-1%Cu and then decrease by a further addition up to 2.0%.展开更多
The as-cast microstructure of AE42 was of typical dendritic and composed of the a matrix and some needle-shaped interphases Al11RE3. A small mount of Ca addition results in significant microstructural refinement and f...The as-cast microstructure of AE42 was of typical dendritic and composed of the a matrix and some needle-shaped interphases Al11RE3. A small mount of Ca addition results in significant microstructural refinement and formation of a Al2Ca phase, which showed two kinds of morphologies, lamellar and tiny granular. The former distributes on grain boundaries and the later is within the matrix grains. With the increase of Ca addition the volume fraction of Al-RE compound (Al11RE3) decreases, but Al2Ca increases. Addition of Ca causes a significant increase of yield strength of the alloy both at ambient and elevated temperatures, but a little decrease of the ductility. With calcium addition the ultimate strength decreases at ambient temperature and 150°t, but increases at 175°C and 200°C.展开更多
The CuZrAl bulk metallic glass with minor-addition of Fe was prepared by rapid quenching method. The structures were examined by X-ray diffraction (XRD). The effect of Fe on the glass-forming ability was studied by ...The CuZrAl bulk metallic glass with minor-addition of Fe was prepared by rapid quenching method. The structures were examined by X-ray diffraction (XRD). The effect of Fe on the glass-forming ability was studied by differential scanning calorimetry (DSC). The minor-addition of Fe obviously extends the supercooled liquid region ΔTx. The plastic strain of the Cu44Zr48Al7Fe bulk metallic glass is about 1.5%. The microstructures were examined by transmission electron microscopy (TEM). It is found that when 1%-2% Fe (mole fraction) were introduced into the CuZrAl alloy matrix, nanoscale phase separation occurs in the as-prepared Cu44Zr48Al7Fe bulk metallic glass.展开更多
In order to remove gas-phase mercury and NOx from flue gas, experimental studies on flue gas mercury oxidation removal and denitration of Guizhou anthracite combustion with NH4Br addition were carried out. The influen...In order to remove gas-phase mercury and NOx from flue gas, experimental studies on flue gas mercury oxidation removal and denitration of Guizhou anthracite combustion with NH4Br addition were carried out. The influence of NH4Br addition on the ignition temperature and combustion characteristics was studied using a thermogravimetric analyzer. The effects of the NHaBr addition amount on gas-phase mercury oxidation and removal were investigated in a bench scale of 6 kW fluidized bed combustor (FBC). Mercury concentrations in flue gas were determined by the Ontario hydro method (OHM) and the mercury mass balance was obtained. Results show that the NH4Br addition has little influence on the ignition temperature of Guizhou anthracite. With the mercury mass balance of 95.47%, the proportion of particulate mercury Hg^p, gaseous mercury Hg^0 and Hg^2+ are 75.28%, 11.60% and 13. 12%, respectively, as raw coal combustion. The high particulate mercury Hg^p in flue gas is caused by the high unburned carbon content in fly ash. When the NH4Br addition amount increases from 0 to 0. 3%, the concentration of gaseous Hg^0 and Hg^2+ in flue gas decreases continuously, leading to the Hg^p increase accordingly. The oxidation rate of Hg^0 is positively correlated to the Br addition amount. It demonstrates that coal combustion with NH4Br addition can promote Hg^0 oxidation and removal. NOx concentration in flue gas exhibits a descending trend with the NHaBr addition and the removal rate reaches 17.31% with the addition amount of 0.3%. Adding NH4Br to coal also plays a synergistic role in denitration.展开更多
[Objective] By carrying out the anther culture on the monosomic alien addition line MAAL8 of O.officinalis-O.sativa and the back crossing with O.sativa H1493,the genetic characteristics of monosomic alien addition lin...[Objective] By carrying out the anther culture on the monosomic alien addition line MAAL8 of O.officinalis-O.sativa and the back crossing with O.sativa H1493,the genetic characteristics of monosomic alien addition line were studied.[Method] The phenotype analysis was used to study the separation proportion of progeny.Moreover,SSR and the methylation analysis were used to study the transmission behavior of nonhomologous chromosome.[Result] 78 plants of 145 backcross progenies preserved the rolled leaf mark trait of MAAL8.In 32 anther culture plants,five plants had the normal rolled leaves,and two plants had the extremely rolled leaves.The rest had the flat leaves.14 couples of SSR markers were used to analyze,and it indicated that all the rolled-leaf plants could obtain the characteristic band type of O.officinalis,but the flat-leaf plants showed none of them.11 polymorphic RFLP markers were used to carry out Methylation-Sensitive Southern analysis.It showed that the methylation variation manners of eight markers between AA and CC genomes were different.[Conclusion] The nonhomologous chromosome of MAAL8 could pass to the progenies independently and integrally via the meiosis,and the phenotype characteristics didn't change.Moreover,the methylation manner of O.officinalis could inherit stably in the hybrid progeny as the addition of single chromosome.The stability of methylation might have the certain effect on the relatively independent inheritance of nonhomologous chromosome in the genome environment of O.sativa.展开更多
To resist the side chaimel attacks of elliptic curve cryptography, a new fast and secure point multiplication algorithm is proposed. The algorithm is based on a particular kind of addition chains involving only additi...To resist the side chaimel attacks of elliptic curve cryptography, a new fast and secure point multiplication algorithm is proposed. The algorithm is based on a particular kind of addition chains involving only additions, providing a natural protection against side channel attacks. Moreover, the new addition formulae that take into account the specific structure of those chains making point multiplication very efficient are proposed. The point multiplication algorithm only needs 1 719 multiplications for the SAC260 of 160-bit integers. For chains of length from 280 to 260, the proposed method outperforms all the previous methods with a gain of 26% to 31% over double-and add, 16% to22% over NAF, 7% to 13% over4-NAF and 1% to 8% over the present best algorithm--double-base chain.展开更多
基金supported by the Materials and Components Technology Development Program(No.20024843)funded by the Ministry of Trade,Industry,and Energy(MOTIE,South Korea)+1 种基金the National Research Foundation of Korea(NRF)grant(No.RS-2023-00244478)funded by the Ministry of Science,ICT,and Future Planning(MSIP,South Korea).
文摘This study investigated the influence of the addition of Al to a Mg-7Bi(B7,wt%)alloy,particularly its recrystallization behavior during extrusion and its resulting mechanical properties.The addition of 2 wt%Al to the B7 alloy resulted in a lower grain size,a reduction in the number density of fine Mg3Bi2 particles,and a higher area fraction of relatively coarse Mg3Bi2 particles in the extrusion billet.These microstructural changes increased the nucleation sites for recrystallization,reduced the Zener pinning effect,and enhanced particle-stimulated nucleation,all of which promoted dynamic recrystallization behavior during extrusion.As a result,the area fraction of recrystallized grains in the extruded alloy increased from 77%to 94%.The extruded B7 alloy exhibited a strong<10-10>fiber texture,whereas the extruded Mg-7Bi-2Al(BA72)alloy had a weak<10-10>-<2-1-10>texture,which was attributed to the minimal presence of unrecrystallized grains and the dispersed orientation of the recrystallized grains.The tensile yield strength(TYS)of the extruded BA72 alloy was higher than that of the extruded B7 alloy(170 and 124 MPa,respectively),which resulted from the enhanced grain-boundary and solid-solution strengthening effects.The tensile elongation(EL)of the BA72 alloy also exceeded that of the B7 alloy(20.3%and 6.1%,respectively),the result of the uniform formation of fine twins under tension in the former and the formation of a few coarse twins among the unrecrystallized grains in the latter.Consequently,the addition of a small amount of Al to the B7 alloy significantly improved both the strength and ductility of the extruded alloy,resulting in a remarkable increase in the product of the TYS and EL from 756 to 3451 MPa%and expanding its potential range of applications as a lightweight extruded structural component.
文摘Catalysts with varying Fe contents were prepared using a sequential impregnation method to investigate the effects of Fe addition on the physicochemical properties of Pt/Al_(2)O_(3) and their performance in methylcyclohexane(MCH)dehydrogenation.The results demonstrated that the addition of Fe to Pt/Al_(2)O_(3) enhanced the electron density of Pt and improved catalytic activity,while exhibiting negligible influence on the catalytic selectivity for toluene.When the Fe content was 0.057%,the catalyst exhibited the highest MCH consumption rate,which was approximately two times higher than that of the catalyst without Fe.Additionally,the incorporation of Fe inhibited the formation of coke and reduced the quantity of coke deposits on the catalyst,thereby improving its catalytic durability.Overall,Fe shows promise as a prospective secondary element for Pt/Al_(2)O_(3) to enhance the MCH dehydrogenation performance.
基金This study was supported by the National Key Research and Development Program of China(2023YFD2100403)the Agricultural Science and Technology Innovation Program of Chinese Academy of Agricultural Sciences(CAAS-ASTIP-2021-OCRI)+2 种基金the earmarked fund for CARS-14,the Innovation Group Project of Hubei Province(2023AFA042)the Key Research Projects of Hubei Province(2020BBA045)the Knowledge Innovation Program of Wuhan-Basic Research(3562).
文摘The study explored the influence of defatted flaxseed gum powder(DFGP) on the stability and quality of sesame paste by measuring and analyzing its composition, color, texture, particle size, centrifugal oil separation rate,rheological properties, and microstructure. The results showed that the moisture and polysaccharide content of sesame paste was increased as the DFGP increased. Additionally, the hardness, gumminess, and chewiness of the sesame paste was improved, while the presence of particles with small particle size(1–100 μm) was decreased.The rate of oil precipitation was reduced by 28.99% when the amount of DFGP was 6%. The sesame paste samples exhibited pseudoplastic behavior, demonstrating shear thinning. As the shear rate increased, the apparent viscosity of sesame paste gradually decreased. Both the storage modulus(G’) and the loss modulus(G’’) increased as the shear frequency increased. The microstructure observation revealed that protein and oil were evenly distributed in the sesame paste system, and the addition of DFGP enhanced the bonding between oil and protein.This study can provide valuable references for high-quality sesame paste products in the food industry.
基金supported by the National Science Foundation of China(No.31770672 and 3137062)the National Basic Research Program of China(No.2010CB950602)。
文摘Atmospheric nitrogen(N)deposition is predicted to increase,especially in the subtropics.However,the responses of soil microorganisms to long-term N addition at the molecular level in N-rich subtropical forests have not been clarified.A long-term nutrient addition experiment was conducted in a subtropical evergreen old-growth forest in China.The four treatments were:control,low N(50 kg N ha^(-1)a^(-1)),high N(100 kg N ha^(-1)a^(-1)),and combined N and phosphorus(P)(100 kg N ha^(-1)a^(-1)+50 kg P ha^(-1)a^(-1)).Metagenomic sequencing characterized diversity and composition of soil microbial communities and used to construct bacterial/fungal co-occurrence networks.Nutrient-treated soils were more acidic and had higher levels of dissolved organic carbon than controls.There were no significant differences in microbial diversity and community composition across treatments.The addition of nutrients increased the abundance of copiotrophic bacteria and potentially beneficial microorganisms(e.g.,Gemmatimonadetes,Chaetomium,and Aureobasidium).Low N addition increased microbiome network connectivity.Three rare fungi were identified as module hubs under nutrient addition,indicating that low abundance fungi were more sensitive to increased nutrients.The results indicate that the overall composition of microbial communities was stable but not static to long-term N addition.Our findings provide new insights that can aid predictions of the response of soil microbial communities to long-term N addition.
基金the National Natural Science Foundation of China(No.51871155).
文摘The effect of addition temperature of MgO particles(MgOp)on their dispersion behavior and the efficiency of grain refinement in AZ31 Mg alloy was investigated.In addition,the grain refinement mechanism was systematically studied by microstructure characterization,thermodynamic calculation,and analysis of solidification curves.The results show that the grain size of AZ31 Mg alloy initially decreases and then increases as the MgOp addition temperature is increased from 720 to 810℃,exhibiting a minimum value of 136μm at 780℃.The improved grain refinement efficiency with increasing MgOp addition temperature can be attributed to the reduced Mg melt viscosity and enhanced wettability between MgOp and Mg melt.Furthermore,a corresponding physical model describing the solidification behavior and grain refinement mechanism was proposed.
基金support from the National Natural Science Foundation of China(41877542).
文摘Human activities and industrialization have significantly increased soil nutrients,such as nitrogen(N)and phos-phorus(P),profoundly impacting the composition and structure of plant community,as well as the ecosystem functions,especially in nutrient-limited ecosystems.However,as the key propagule pool of perennial grasslands,how belowground bud bank and its relationship with aboveground vegetation respond to short-term changes in soil nutrients was still unclear.In this study,we conducted a short-term(2021–2022)soil fertilization experiment with N addition(10 g N m^(-2) yr^(-1))and P addition(5 g N m^(-2) yr^(-1))in the meadow steppe of Inner Mongolia,China,to explore the responses of belowground bud bank,aboveground shoot population and their relationships(represented by the ratio of bud to shoot density-meristem limitation index(MLI))for the whole community and three plant functional groups(perennial rhizomatous grasses-PR,perennial bunchgrasses-PB,and perennial forbs-PF)to nutrient addition.The short-term nutrient addition had no significant influences on belowground bud density,aboveground shoot density,and MLI of the whole plant community.Plant functional groups showed different responses to soil fertilization.Specifically,N addition significantly increased the bud density and shoot density of PR,especially in combination with P addition.N addition reduced the shoot density of PF but had no influence on its bud density and MLI.Nutrient addition had significant effects on the three indicators of PB.Our study indicates that the belowground bud bank and its relationship with aboveground vegetation in temperate meadow steppe are insensitive to short-term soil fertilization,but plant functional groups exhibit specific responses in terms of population regeneration,which implies that plant community composition and ecosystem functions will be changed under the ongoing global change.
文摘Are all prime numbers linked by four simple functions? Can we predict when a prime will appear in a sequence of primes? If we classify primes into two groups, Group 1 for all primes that appear before ζ (such that , for instance 5, ), an even number divisible by 3 and 2, and Group 2 for all primes that are after ζ (such that , for instance 7), then we find a simple function: for each prime in each group, , where n is any natural number. If we start a sequence of primes with 5 for Group 1 and 7 for Group 2, we can attribute a μ value for each prime. The μ value can be attributed to every prime greater than 7. Thus for Group 1, and . Using this formula, all the primes appear for , where μ is any natural number.
基金Supported by the Science&Technology Department of Sichuan Province(China)Funding Project(No.2021YFS0221,No.2023YFS0179)1.3.5 Project for Disciplines of Excellence,West China Hospital,Sichuan University(No.2022HXFH032,No.ZYJC21058)the Postdoctoral Research Funding of West China Hospital,Sichuan University,China(No.2020HXBH044).
文摘●AIM:To explore the clinical efficacy and safety of stromal lenticule addition keratoplasty(SLAK)with corneal crosslinking(CXL)on patients with corneal ectasia secondary to femtosecond laser-assisted in situ keratomileusis(FS-LASIK).●METHODS:A series of 5 patients undertaking SLAK with CXL for the treatment of corneal ectasia secondary to FS-LASIK were followed for 4-9mo.The lenticules were collected from patients undertaking small incision lenticule extraction(SMILE)for the correction of myopia.Adding a stromal lenticule was aimed at improving the corneal thickness for the safe application of crosslinking and compensating for the thin cornea to improve its mechanical strength.●RESULTS:All surgeries were conducted successfully with no significant complications.Their best corrected visual acuity(BCVA)ranged from 0.05 to 0.8-2 before surgery.The pre-operational total corneal thickness ranged from 345-404μm and maximum keratometry(Kmax)ranged from 50.8 to 86.3.After the combination surgery,both the corneal keratometry(range 55.9 to 92.8)and total corneal thickness(range 413-482μm)significantly increased.Four out of 5 patients had improvement of corneal biomechanical parameters(reflected by stiffness parameter A1 in Corvis ST).However,3 patients showed decreased BCVA after surgery due to the development of irregular astigmatism and transient haze.Despite the onset of corneal edema right after SLAK,the corneal topography and thickness generally stabilized after 3mo.●CONCLUSION:SLAK with CXL is a potentially beneficial and safe therapy for advanced corneal ectasia.Future work needs to address the poor predictability of corneal refractometry and compare the outcomes of different surgical modes.
基金financially supported by the Agency for Science,Technology and Research(A*Star),Republic of Singapore,under the Aerospace Consortium Cycle 12“Characterization of the Effect of Wire and Powder Deposited Materials”(No.A1815a0078)。
文摘The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.
基金Project(51204003)supported by the National Natural Science Foundation of ChinaProject(KJ2011A051)supported by the Scientific Research Foundation of Education Department of Anhui Province,China
文摘The mechanical properties and texture of AM60(Mg-6.0Al-0.3Mn,mass fraction %) and ZXM200(Mg-1.6Zn-0.5Ca-0.2Mn) Mg alloys subjected to multi-pass hot rolling were investigated.The finer recrystallized grains usually exhibit particular preferred orientations and then alter the total texture feature of rolled sheets.Ca solid solution into Mg matrix serves to the formation of texture component with c-axis rotated away from normal direction towards transverse direction and then weakens the overall texture intensity,resulting in a similar anisotropic characteristic to RE-containing Mg alloys.
基金Foundation project: This work was supported by the Knowledge Innova- tion Project of the Chinese Academy of Sciences (KZCX2-YW-416) and the National Natural Science Foundation (90411020)
文摘The effects of nitrogen (N) availability and tree species on the dynamics of carbon and nitrogen at early stage of decomposition of forest litter were studied in a 13-week laboratory incubation experiment. Fresh litter samples including needle litter (Pinus koraiensis) and two types of broadleaf litters (Quercus mongolica and Tilia amurensis) were collected from a broadleaf-korean pine mixed forest in the northern slope of Changbai Mountain (China). Different doses of N (equal to 0, 30 and 50 kg.ha^-1yr^-1, respectively, as NH4NO3) were added to litter during the experiment period. The litter decomposition rate expressed as mass loss and respiration rate increased significantly with increasing N availability. The mass loss and cumulative CO2-C emission were higher in leaf litter compared to that in needle litter. The dis- solved organic Carbon (DOC) concentrations in litter leachate varied widely between the species, but were not greatly affected by N treatments. Regardless of the N addition rate, both N treatments and species had no significant effect on dissolved organic N (DON) concentrations in litter leachate. About 52-78% of added N was retained in the litter. The percentage of N retention was positively correlated (R^2=0.9 1, p〈0.05) with the litter mass loss. This suggested that a forest floor with easily decomposed litter might have higher potential N sink strength than that with more slowly decomposed litter.
基金supported by the National Natural Science Foundation of China (21425627,21376279)~~
文摘Nineβ‐cyclodextrin derivatives containing an amino group were synthesized via nucleophilic sub‐stitution from mono(6‐O‐p‐tolylsulfonyl)‐β‐cyclodextrin and used in asymmetric biomimetic Mi‐chael addition reactions in water at room temperature. The mechanism responsible for the moder‐ate activity and enantioselectivity of the β‐cyclodextrin derivatives was explored using nuclear magnetic resonance spectroscopy, namely 2D 1H rotating‐frame overhauser effect spectroscopy (ROESY), ultraviolet absorption spectroscopy, and quantum chemical calculations, which provide a useful technique for investigating the formation of inclusion complexes. The effects of the pH of the reaction medium, theβ‐cyclodextrin derivative dosage, the structure of the modifying amino group, and various substrates on the yield and enantioselectivity were investigated. The results indicated that these factors had an important effect on the enantiomeric excess (ee) in the reaction system. Experiments using a competitor for inclusion complex formation showed that a hydrophobic cavity is necessary for enantioselective Michael addition. A comparison of the reactions using 4‐nitro‐β‐nitrostyrene and 2‐nitro‐β‐nitrostyrene showed that steric hindrance improved the enan‐tioselectivity. This was verified by the optimized geometries obtained from quantum chemical cal‐culations. An ee of 71%was obtained in the asymmetric Michael addition of cyclohexanone and 2‐nitro‐β‐nitrostyrene, using (S)‐2‐aminomethylpyrrolidine‐modified β‐CD as the catalyst, in an aqueous buffer solution, i.e., CH3COONa‐HCl (pH 7.5).
基金Project (2010ZDJH10) supported by the NUST Research FundingProject (BK2007213) supported by the Natural Science Foundation of Jiangsu Province,China
文摘The effects of Y addition on the structural and mechanical properties of CuZrAl bulk metallic glass(BMG) were studied.The results show that the glass forming ability of CuZrAl system is improved by the addition of Y and the fracture strength decreases with Y addition due to the reduction of binding energy induced by Y.The fracture surface is dominated by vein-like patterns in Cu45Zr48Al7 bulk metallic glass,and changes to smooth regions in Cu46Zr42Al7Y5 BMG.TEM observation shows that Cu45Zr48Al7 BMG has a composite microstructure of nanocrystalline phases dispersed in amorphous matrix.However,the Cu46Zr42Al7Y5 BMG shows a fully amorphous structure.
基金Project(51201088)supported by the National Natural Science Foundation of ChinaProject(12C0324)supported by the Research Foundation of Education Bureau of Hunan Province,China+1 种基金Project(2011XQD26)supported by Doctoral Scientific Research Foundation of University of South,ChinaProject([2011]76)supported by the Construct Program of the Key Discipline in Hunan Province,China
文摘The effects of Cu addition on the microstructure and mechanical properties of the as-cast magnesium alloy ZK60 were investigated with optical microscope, SEM, TEM, XRD, EPMA and tensile tester. The mechanism by which the mechanical properties are affected by Cu addition was discussed. The results show that Cu can effectively eliminate the intragranular solute segregations in the alloy, and the grain size of the alloy is decreased considerably with increasing the Cu amount. A ternary eutectic phase MgZnCu with a face-centered cubic structure is identified in the Cu-bearing alloys, which predominantly distributes at the grain boundary and acts as the nucleation sites of microcracks during the plastic deformation process. It is also found that the tensile properties of the alloy firstly increase by the trace addition of 0.5%-1%Cu and then decrease by a further addition up to 2.0%.
文摘The as-cast microstructure of AE42 was of typical dendritic and composed of the a matrix and some needle-shaped interphases Al11RE3. A small mount of Ca addition results in significant microstructural refinement and formation of a Al2Ca phase, which showed two kinds of morphologies, lamellar and tiny granular. The former distributes on grain boundaries and the later is within the matrix grains. With the increase of Ca addition the volume fraction of Al-RE compound (Al11RE3) decreases, but Al2Ca increases. Addition of Ca causes a significant increase of yield strength of the alloy both at ambient and elevated temperatures, but a little decrease of the ductility. With calcium addition the ultimate strength decreases at ambient temperature and 150°t, but increases at 175°C and 200°C.
基金Project (2010ZDJH10) supported by the Nanjing University of Science and Technology Research Funding, ChinaProject (BK2007213) supported by the Natural Science Foundation of Jiangsu Province, China
文摘The CuZrAl bulk metallic glass with minor-addition of Fe was prepared by rapid quenching method. The structures were examined by X-ray diffraction (XRD). The effect of Fe on the glass-forming ability was studied by differential scanning calorimetry (DSC). The minor-addition of Fe obviously extends the supercooled liquid region ΔTx. The plastic strain of the Cu44Zr48Al7Fe bulk metallic glass is about 1.5%. The microstructures were examined by transmission electron microscopy (TEM). It is found that when 1%-2% Fe (mole fraction) were introduced into the CuZrAl alloy matrix, nanoscale phase separation occurs in the as-prepared Cu44Zr48Al7Fe bulk metallic glass.
基金The National Natural Science Foundation of China(No.51376046,51076030)the National Key Technology R&D Program of China during the 12th Five-Year Plan Period(No.2012BAA02B01)+2 种基金the United Creative Foundation of Jiangsu Province(No.BY2013073-10)the Fundamental Research Funds for the Central Universitiesthe Scientific Innovation Research of College Graduates in Jiangsu Province(CXZZ13_0093,KYLX_0115,KYLX_0184)
文摘In order to remove gas-phase mercury and NOx from flue gas, experimental studies on flue gas mercury oxidation removal and denitration of Guizhou anthracite combustion with NH4Br addition were carried out. The influence of NH4Br addition on the ignition temperature and combustion characteristics was studied using a thermogravimetric analyzer. The effects of the NHaBr addition amount on gas-phase mercury oxidation and removal were investigated in a bench scale of 6 kW fluidized bed combustor (FBC). Mercury concentrations in flue gas were determined by the Ontario hydro method (OHM) and the mercury mass balance was obtained. Results show that the NH4Br addition has little influence on the ignition temperature of Guizhou anthracite. With the mercury mass balance of 95.47%, the proportion of particulate mercury Hg^p, gaseous mercury Hg^0 and Hg^2+ are 75.28%, 11.60% and 13. 12%, respectively, as raw coal combustion. The high particulate mercury Hg^p in flue gas is caused by the high unburned carbon content in fly ash. When the NH4Br addition amount increases from 0 to 0. 3%, the concentration of gaseous Hg^0 and Hg^2+ in flue gas decreases continuously, leading to the Hg^p increase accordingly. The oxidation rate of Hg^0 is positively correlated to the Br addition amount. It demonstrates that coal combustion with NH4Br addition can promote Hg^0 oxidation and removal. NOx concentration in flue gas exhibits a descending trend with the NHaBr addition and the removal rate reaches 17.31% with the addition amount of 0.3%. Adding NH4Br to coal also plays a synergistic role in denitration.
基金Supported by Hubei Natural Science Fund Item(2008CDB392)Natural Science Fund of South-Central University for Nationalities(yzz08005)~~
文摘[Objective] By carrying out the anther culture on the monosomic alien addition line MAAL8 of O.officinalis-O.sativa and the back crossing with O.sativa H1493,the genetic characteristics of monosomic alien addition line were studied.[Method] The phenotype analysis was used to study the separation proportion of progeny.Moreover,SSR and the methylation analysis were used to study the transmission behavior of nonhomologous chromosome.[Result] 78 plants of 145 backcross progenies preserved the rolled leaf mark trait of MAAL8.In 32 anther culture plants,five plants had the normal rolled leaves,and two plants had the extremely rolled leaves.The rest had the flat leaves.14 couples of SSR markers were used to analyze,and it indicated that all the rolled-leaf plants could obtain the characteristic band type of O.officinalis,but the flat-leaf plants showed none of them.11 polymorphic RFLP markers were used to carry out Methylation-Sensitive Southern analysis.It showed that the methylation variation manners of eight markers between AA and CC genomes were different.[Conclusion] The nonhomologous chromosome of MAAL8 could pass to the progenies independently and integrally via the meiosis,and the phenotype characteristics didn't change.Moreover,the methylation manner of O.officinalis could inherit stably in the hybrid progeny as the addition of single chromosome.The stability of methylation might have the certain effect on the relatively independent inheritance of nonhomologous chromosome in the genome environment of O.sativa.
基金The National Natural Science Foundation of China (No.60473029,60673072).
文摘To resist the side chaimel attacks of elliptic curve cryptography, a new fast and secure point multiplication algorithm is proposed. The algorithm is based on a particular kind of addition chains involving only additions, providing a natural protection against side channel attacks. Moreover, the new addition formulae that take into account the specific structure of those chains making point multiplication very efficient are proposed. The point multiplication algorithm only needs 1 719 multiplications for the SAC260 of 160-bit integers. For chains of length from 280 to 260, the proposed method outperforms all the previous methods with a gain of 26% to 31% over double-and add, 16% to22% over NAF, 7% to 13% over4-NAF and 1% to 8% over the present best algorithm--double-base chain.