The role of tungsten-related elements for improving the electrochemical performances of cathode materials in lithium ion batteries

Lithium ion batteries using Ni-Co-Mn ternary oxide materials(NCMs)and Ni-Co-Al materials(NCAs)as the cathode materials are dominantly employed to power the electric vehicles(EVs).Increasing the driving range of EVs necessitates an increase of Ni content to improve the energy densities,which,however,degrades the cycle stability.Here we review the doping/coating of tungsten and related elements to improve the electrochemical performance of these cathodes especially the cycle stability.The selection of tungsten and related elements is based on their special properties including the high valence state,strong bonding with oxygen and the large ionic radius.The improvement of cycle stability mainly results from two features:(1)the enhancement of bulk structure stability upon doping(Mo,W,Ta,Nb)and(2)the resistance of side reactions of electrode/electrolyte by the surficial layer induced by direct coating(V,W,Nb)or bulk doping.For the recent high Ni materials,the formation of Ni2+and its migration to the Li layer induced by these doped/coated tungsten-related elements,and the presence of spinel or rock-salt phase before cycling contributes to improving the cycle stability.The key challenges are the selection of an optimized additive concentration and the fundamental understanding of the reaction mechanism,which will provide insightful guidance for maximizing the electrochemical performance of the state-of-the-art lithium-ion batteries at minimal additional process costs.

A Table That Produces Elements

How do elements originate, how atoms are formed, and what are the laws? According to the unified logic of “Tong Yi Lun Thought”, combined with the elements’ attributes and the atomic composition that have been discovered now, after determining that the mechanism of increasing yang in the atomic system is the increase of proton number, the Bian Zheng relationship among proton, neutron and electron determines that there are only 128 kinds of elements in the atomic system. At the same time, element atoms have corresponding logical relations when they are generated.

COMPARISON OF TWO METHODS IN SATELLITE FORMATION FLYING

Recently, the research of dynamics and control of the satellite formation flying has been attracting a great deal of attentions of the researchers. The theory of the research was mainly based on Clohessy-Wiltshire' s (C-W's) equations, which describe the relative motion between two satellites. But according to some special examples and qualitative analysis , neither the initial parameters nor the period of the solution of C-W' s equations accord with the actual situation, and the conservation of energy is no longer held. A new method developed from orbital element description of single satellite , named relative orbital element method ( ROEM) , was introduced. This new method, with clear physics conception and wide application range, overcomes the limitation of C-W s equation , and the periodic solution is a natural conclusion. The simplified equation of the relative motion is obtained when the eccentricity of the main satellite is small. Finally, the results of the two methods (C-W' s equation and ROEM) are compared and the limitations of C-W s equations are pointed out and explained.

USEFUL RELATIVE MOTION DESCRIPTION METHOD FOR PERTURBATIONS ANALYSIS IN SATELLITEFORMATION FLYING

A set of parameters called relative orbital elements were defined to describe the relative motion of the satellites in the formation flying. With the help of these parameters, the effect of the perturbations on the relative orbit trajectory and geometric properties of satellite formation can be easily analyzed. First, the relative orbital elements are derived, and pointed out： if the eccentricity of the leading satellite is a small value, the relative orbit trajectory is determined by the intersection between an elliptic cylinder and a plane in the leading satellite orbit frame reference; and the parameters that describe the elliptic cylinder and the plane can be used to obtain the relative orbit trajectory and the relative orbital elements. Second, by analyzing the effects of gravitational perturbations on the relative orbit using the relative orbital elements,it is found that the propagation of a relative orbit consists of two parts ： one is the drift of the elliptic cylinder; and the other is the rotation of the plane resulted from the rotation of the normal of the plane. Meanwhile, the analytic formulae for the drift and rotation rates of a relative trajectory under gravitational perturbations are presented. Finally, the relative orbit trajectory and the corresponding changes were analyzed with respect to the J2 perturbation.

NUMERICAL ANALYSIS OF BIFURCATION BUCKLING FOR ROTATIONALLY PERIODIC STRUCTURES UNDER ROTATIONALLY PERIODIC LOADS

By considering the characteristics of deformation of rotationally periodic structures under rotationally periodic loads, the periodic structure is divided into some identical substructures in this study. The degrees-of-freedom (DOFs) of joint nodes between the neighboring substructures are classified as master and slave ones. The stress and strain conditions of the whole structure are obtained by solving the elastic static equations for only one substructure by introducing the displacement constraints between master and slave DOFs. The complex constraint method is used to get the bifurcation buckling load and mode for the whole rotationally periodic structure by solving the eigenvalue problem for only one substructure without introducing any additional approximation. The finite element (FE) formulation of shell element of relative degrees of freedom (SERDF) in the buckling analysis is derived. Different measures of tackling internal degrees of freedom for different kinds of buckling problems and different stages of numerical analysis are presented. Some numerical examples are given to illustrate the high efficiency and validity of this method.

Elliptical formation control based on relative orbit elements

A new set of relative orbit elements（ROEs）is used to derive a new elliptical formation flying model.In-plane and out-of-plane motions can be completely decoupled,which benefts elliptical formation design.The inverse transformation of the state transition matrix is derived to study the relative orbit control strategy.Impulsive feedback control laws are developed for both in-plane and out-of-plane relative motions.Control of in-plane and out-of-plane relative motions can be completely decoupled using the ROE-based feedback control law.A tangential impulsive control method is proposed to study the relationship of fuel consumption and maneuvering positions.An optimal analytical along-track impulsive control strategy is then derived.Different typical orbit maneuvers,including formation establishment,reconfguration,long-distance maneuvers,and formation keeping,are taken as examples to demonstrate the performance of the proposed control laws.The effects of relative measurement errors are also considered to validate the high accuracy of the proposed control method.

Spatial and Temporal Quantitative Analysis of Cell Division and Elongation Rate in Growing Wheat Leaves under Saline Conditions

Leaf growth in grasses is determined by the cell division and elongation rates, with the duration of cell elongation being one of the processes that is the most sensitive to salinity. Our objective was to investigate the distribution profiles of cell production, cell length and the duration of cell elongation in the growing zone of the wheat leaf during the steady growth phase. Plants were grown in loamy soil with or without 120 mmollL NaCI in a growth chamber, and harvested at day 3 after leaf 4 emerged. Results show that the elongation rate of leaf 4 was reduced by t20 mmollL NaCI during the steady growth phase. The distribution profile of the lengths of abaxial epidermal cells of leaf 4 during the steady growth stage shows a sigmoidal pattern along the leaf axis for both treatments. Although salinity did not affect or even increased the length of the epidermal cells in some locations in the growth zone compared to the control treatment, the final length of the epidermal cells was reduced by 14% at 120 mmollL NaCI. Thus, we concluded that the observed reduction in the leaf elongation rate derived in part from the reduced cell division rate and either the shortened cell elongation zone or shortened duration of cell elongation. This suggests that more attention should be paid to the effects of salinity on those properties of cell production and the period of cell maturation that are related to the properties of cell wall.