The dielectric constant and dielectric loss of Te10Ge10Se80-xSbx (x=3, 6, 12 at. pct) chalcogenide alloys were measured in the temperature range (300 to 453 K) and the frequency range (100 Hz to 100 kHz). The real die...The dielectric constant and dielectric loss of Te10Ge10Se80-xSbx (x=3, 6, 12 at. pct) chalcogenide alloys were measured in the temperature range (300 to 453 K) and the frequency range (100 Hz to 100 kHz). The real dielectric constant ∈′and imaginary dielectric constant ∈' show a decrease with increasing frequency and an increase with increasing temperature. All samples display dielectric dispersion. Both ∈′ and ∈' show a Debye relaxation type. The enthalpy activation energy ΔH and activation energy WH were calculated. Cole-Cole diagram consists of an arc of semicircle shifted from the origin and its center below the real axis at high frequency展开更多
Heat transfer in an Eyring-Powell fluid that conducts electricity and flows past an exponentially growing sheet is considered.As the sheet is stretched in the x direction,the flow develops in the region with y>0.Th...Heat transfer in an Eyring-Powell fluid that conducts electricity and flows past an exponentially growing sheet is considered.As the sheet is stretched in the x direction,the flow develops in the region with y>0.The problem is tackled through a set of partial differential equations accounting for Magnetohydrodynamics(MHD),radiation and Joule heating effects,which are converted into a set of equivalent ordinary differential equations through a similarity transformation.The converted problem is solved in MATLAB in the framework a fourth order accurate integration scheme.It is found that the thermal relaxation period is inversely proportional to the thickness of the thermal boundary layer,whereas the Eckert-number displays the opposite trend.As this characteristic number grows,the temperature within the channel increases.展开更多
The string model for the glass transition can quantitatively describe the universal a-relaxation in glassformers, including the average relaxation time, the distribution function of the relaxation time, and the relaxa...The string model for the glass transition can quantitatively describe the universal a-relaxation in glassformers, including the average relaxation time, the distribution function of the relaxation time, and the relaxation strength as functions of temperature. The string relaxation equation (SRE) of the model, at high enough temperatures, simplifies to the well-known single particle mean-field Debye relaxation equation, and at low enough temperatures to the well-known Rouse-Zimm relaxation equation that describes the relaxation dynamics of linear macromolecules. However, its initial condition, necessary to the further model predictions of glassy dynamics, has not been solved. In this paper, the special initial condition (SIC) of the SRE, i.e. for straight strings and the dielectric spectrum technique that is one of the most common methods to measure the glassy dynamics, was solved exactly. It should be expected that the obtained SIC would benefit the solution of the general initial condition of the SRE of the string model, i.e. for stochastically spatially eonfigurating strings, as will be described in separate publications.展开更多
The string model for the glass transition can quantitatively describe the universal a-relaxation in glassformers. The string relaxation equation (SRE) of the model simplifies the well-known Debye and Rouse-Zimm rela...The string model for the glass transition can quantitatively describe the universal a-relaxation in glassformers. The string relaxation equation (SRE) of the model simplifies the well-known Debye and Rouse-Zimm relaxation equations at high and low enough temperatures, respectively. However, its initial condition, necessary to the further model predictions of glassy dynamics, has not been solved. In this paper, the general initial condition of the SRE for stochastically spatially configurative strings is solved exactly based on the obtained special initial condition of the SRE for straight strings in a previous paper (J. L. Zhang et al. 2010 Chin. Phys. B 19, 056403).展开更多
The various theoretical and experimental models for ion conduction mechanism of fast ion conducting (FIC) glass electrolytes have been reported in the present review paper. Some characterization techniques of FIC gl...The various theoretical and experimental models for ion conduction mechanism of fast ion conducting (FIC) glass electrolytes have been reported in the present review paper. Some characterization techniques of FIC glasses are presented. The experimental methods for determination of some ion transport parameters viz ionic conductivity (σ), ionic mobility (μ), mobile ion concentration (n), ionic drift velocity (Vd), ionic transference number (tion) and activation energies of FIC glasses are explained. The solid state battery fabrication by using some FIC glasses is also reported.展开更多
文摘The dielectric constant and dielectric loss of Te10Ge10Se80-xSbx (x=3, 6, 12 at. pct) chalcogenide alloys were measured in the temperature range (300 to 453 K) and the frequency range (100 Hz to 100 kHz). The real dielectric constant ∈′and imaginary dielectric constant ∈' show a decrease with increasing frequency and an increase with increasing temperature. All samples display dielectric dispersion. Both ∈′ and ∈' show a Debye relaxation type. The enthalpy activation energy ΔH and activation energy WH were calculated. Cole-Cole diagram consists of an arc of semicircle shifted from the origin and its center below the real axis at high frequency
文摘Heat transfer in an Eyring-Powell fluid that conducts electricity and flows past an exponentially growing sheet is considered.As the sheet is stretched in the x direction,the flow develops in the region with y>0.The problem is tackled through a set of partial differential equations accounting for Magnetohydrodynamics(MHD),radiation and Joule heating effects,which are converted into a set of equivalent ordinary differential equations through a similarity transformation.The converted problem is solved in MATLAB in the framework a fourth order accurate integration scheme.It is found that the thermal relaxation period is inversely proportional to the thickness of the thermal boundary layer,whereas the Eckert-number displays the opposite trend.As this characteristic number grows,the temperature within the channel increases.
基金Project supported by the National Natural Science Foundations of China (Grant Nos. 10774064 and 30860076)the Key Foundation of Xinjiang Education Department (Grant No. XJEDU2007137)the Natural Science Foundations of Xinjiang Science and Technology Department of China (Grant Nos. 2008211042 and 200821184)
文摘The string model for the glass transition can quantitatively describe the universal a-relaxation in glassformers, including the average relaxation time, the distribution function of the relaxation time, and the relaxation strength as functions of temperature. The string relaxation equation (SRE) of the model, at high enough temperatures, simplifies to the well-known single particle mean-field Debye relaxation equation, and at low enough temperatures to the well-known Rouse-Zimm relaxation equation that describes the relaxation dynamics of linear macromolecules. However, its initial condition, necessary to the further model predictions of glassy dynamics, has not been solved. In this paper, the special initial condition (SIC) of the SRE, i.e. for straight strings and the dielectric spectrum technique that is one of the most common methods to measure the glassy dynamics, was solved exactly. It should be expected that the obtained SIC would benefit the solution of the general initial condition of the SRE of the string model, i.e. for stochastically spatially eonfigurating strings, as will be described in separate publications.
基金supported by the National Natural Science Foundations of China (Grant Nos. 10774064 and 30860076)the Key Foundation of Xinjiang Education Department (Grant No. XJEDU2007137)the Natural Science Foundations of Xinjiang Science and Technology Department (Grant Nos. 200821104 and 200821184)
文摘The string model for the glass transition can quantitatively describe the universal a-relaxation in glassformers. The string relaxation equation (SRE) of the model simplifies the well-known Debye and Rouse-Zimm relaxation equations at high and low enough temperatures, respectively. However, its initial condition, necessary to the further model predictions of glassy dynamics, has not been solved. In this paper, the general initial condition of the SRE for stochastically spatially configurative strings is solved exactly based on the obtained special initial condition of the SRE for straight strings in a previous paper (J. L. Zhang et al. 2010 Chin. Phys. B 19, 056403).
基金DST,New Delhi for providing financial assistance through the Fast Track Young Scientist Research Project(No.SR/FTP/PS-23/2009)
文摘The various theoretical and experimental models for ion conduction mechanism of fast ion conducting (FIC) glass electrolytes have been reported in the present review paper. Some characterization techniques of FIC glasses are presented. The experimental methods for determination of some ion transport parameters viz ionic conductivity (σ), ionic mobility (μ), mobile ion concentration (n), ionic drift velocity (Vd), ionic transference number (tion) and activation energies of FIC glasses are explained. The solid state battery fabrication by using some FIC glasses is also reported.