Considering current space debris situation in outer space environment,different methods for debris removal missions are proposed.In addition,advanced technologies are needed to be demonstrated for future human space e...Considering current space debris situation in outer space environment,different methods for debris removal missions are proposed.In addition,advanced technologies are needed to be demonstrated for future human space exploration programs.The main issue regarding to these missions is high mission cost for both debris removal missions and space environmental tests to achieve high maturity level for new space-usable technologies.Since,these missions are unavoidable for future of human space activities,a solution which can tackle these challenges is necessary.This paper will address to an idea which has the possibility to give a solution for facilitating technology readiness level(TRL)maturity tests by debris removal mission platform consideration.展开更多
Color filters are produced using semiconductor production techniques although problems with low yield remain to be addressed. This study presents a new means of selective removal using excimer irradiation, chemical et...Color filters are produced using semiconductor production techniques although problems with low yield remain to be addressed. This study presents a new means of selective removal using excimer irradiation, chemical etching, or electrochemical machining on the fifth generation TFT LCDs. The selective removal of microstructure layers from the color filter surface of an optoelectronic flat panel display, as well as complete removal of the ITO thin-films, RGB layer, or resin black matrix (BM) layer from the substrate is possible. Individual defective film layers can be removed, or all films down to the Cr layer or bare glass can be completely eliminated. Experimental results demonstrate that defective ITO thin-films, RGB layers, or the resin BM layer can now be recycled with a great precision. When the ITO or RGB layer proves difficult to remove, excimer light can be used to help with removal. During this recycling process, the use of 225 nm excimer irradiation before chemical etching, or electrochemical machining, makes removal of stubborn film residues easy, effectively improving the quality of recycled color filters and reducing fabrication cost.展开更多
The pollution of iron,manganese and nitrate in groundwater is a huge threat to human beings.In this study,column experiments of ceramic,manganese sand,ceramic sand,volcanic rock,quartz sand were conducted.Iron and man...The pollution of iron,manganese and nitrate in groundwater is a huge threat to human beings.In this study,column experiments of ceramic,manganese sand,ceramic sand,volcanic rock,quartz sand were conducted.Iron and manganese contents of influent were 3.3 mg/L and 2.1 mg/L.When the biofilm became mature,the highest iron and manganese removal rate achieved by manganese sand as a filter material.Quartz did a little worse than manganese sand,but other three filter material could not reach展开更多
Most fault-block reservoirs in Xinmu oilfield belong to heterogeneous sandstone in characters which has low permeability, and reservoir pollution is a common phenomenon in this area. Acidizing deplugging in oil wells ...Most fault-block reservoirs in Xinmu oilfield belong to heterogeneous sandstone in characters which has low permeability, and reservoir pollution is a common phenomenon in this area. Acidizing deplugging in oil wells has become one of the major measures to improve production efficiency in the field. A compound deplug- ging technology in high efficiency low corrosion is developed for this kind of low permeability sandstone reser- voir. On the basis of profoundly understanding of the reservoir's physical properties and sensitivity, along with comprehensive analysis of the cause for jams in oil wells, a series of experiments are carried out in order to in- vestigate the dissolution reaction among samples and deplugging inhibitor, sample dissolving speed, formation fluid compatibility, reduction of secondary pollution, etc. Considered reservoir condition in nearby wells the op- timized compositional deplugging liquid formula is selected for this reservoir. It is featured by reducing the de- plugging reaction speed, extending solution for processing radius, preventing secondary damage in dissolution processing, and removing plug pollution effectively. To implement this high efficiency low corrosion deplugging measure based on reservoir condition in the borehole and nearby wells, a relatively better result of deplugging and production increasing is achieved, which enriches the measures to increase production in Xinmu oilfield, and this method can be applied to other similar oiffields for the purpose of maintaining the crude oil production and providing assistant for increasing the production significantly.展开更多
In order to remove gas-phase mercury and NOx from flue gas, experimental studies on flue gas mercury oxidation removal and denitration of Guizhou anthracite combustion with NH4Br addition were carried out. The influen...In order to remove gas-phase mercury and NOx from flue gas, experimental studies on flue gas mercury oxidation removal and denitration of Guizhou anthracite combustion with NH4Br addition were carried out. The influence of NH4Br addition on the ignition temperature and combustion characteristics was studied using a thermogravimetric analyzer. The effects of the NHaBr addition amount on gas-phase mercury oxidation and removal were investigated in a bench scale of 6 kW fluidized bed combustor (FBC). Mercury concentrations in flue gas were determined by the Ontario hydro method (OHM) and the mercury mass balance was obtained. Results show that the NH4Br addition has little influence on the ignition temperature of Guizhou anthracite. With the mercury mass balance of 95.47%, the proportion of particulate mercury Hg^p, gaseous mercury Hg^0 and Hg^2+ are 75.28%, 11.60% and 13. 12%, respectively, as raw coal combustion. The high particulate mercury Hg^p in flue gas is caused by the high unburned carbon content in fly ash. When the NH4Br addition amount increases from 0 to 0. 3%, the concentration of gaseous Hg^0 and Hg^2+ in flue gas decreases continuously, leading to the Hg^p increase accordingly. The oxidation rate of Hg^0 is positively correlated to the Br addition amount. It demonstrates that coal combustion with NH4Br addition can promote Hg^0 oxidation and removal. NOx concentration in flue gas exhibits a descending trend with the NHaBr addition and the removal rate reaches 17.31% with the addition amount of 0.3%. Adding NH4Br to coal also plays a synergistic role in denitration.展开更多
Air pollution control devices (APCDs) are installed at coal-fired power plants for air pollutant regulation. Selective catalytic reduction (SCR) and wet flue gas desulftLrization (FGD) systems have the co-benefi...Air pollution control devices (APCDs) are installed at coal-fired power plants for air pollutant regulation. Selective catalytic reduction (SCR) and wet flue gas desulftLrization (FGD) systems have the co-benefits of air pollutant and mercury removal. Configuration and operational conditions of APCDs and mercury speciation affect mercury removal efficiently at coal-fired utilities. The Ontario Hydro Method (OHM) recommended by the U.S. Environmental Protection Agency (EPA) was used to determine mercury speciation simultaneously at five sampling locations through SCR-ESP-FGD at a 190 MW unit. Chlorine in coal had been suggested as a factor affecting the mercury speciation in flue gas; and low-chlorine coal was purported to produce less oxidized mercury (Hg^2+) and more elemental mercury (Hg^0) at the SCR inlet compared to higher chlorine coal. SCR could oxidize elemental mercury into oxidized mercury when SCR was in service, and oxidation efficiency reached 71.0%. Therefore, oxidized mercury removal efficiency was enhanced through a wet FGD system. In the non-ozone season, about 89.5%-96.8% of oxidized mercury was controlled, but only 54.9%-68.8% of the total mercury was captured through wet FGD. Oxidized mercury removal efficiency was 95.9%-98.0%, and there was a big difference in the total mercury removal efficiencies from 78.0% to 90.2% in the ozone season. Mercury mass balance was evaluated to validate reliability of OHM testing data, and the ratio of mercury input in the coal to mercury output at the stack was from 0.84 to 1.08.展开更多
The Ontario Hydro Method (OHM) recommended by the United States Environmental Protection Agency (EPA) was used to determine mercury speciation in the combustion flue gas across wet FGD systems. Four coal-fired uni...The Ontario Hydro Method (OHM) recommended by the United States Environmental Protection Agency (EPA) was used to determine mercury speciation in the combustion flue gas across wet FGD systems. Four coal-fired units with wet FGD systems were chosen to evaluate mercury speciation and mercury removal efficiencies through these wet FGD systems. Chlorine content in coal had been suggested as a main factor that affects mercury speciation in flue gas. It is shown that the higher the chlorine concentration in coal is, the higher the percentage of oxidized mercury (Hg2+) is removed in wet FGD systems, which can increase overall mercury removal efficiencies through wet FGD systems. The selective catalyst reduction (SCR) system has a function of oxidizing ele- mental mercury (Hg0) to oxidized mercury. A higher percentage of oxidized mercury in the total vapor mercury at the FGD inlet is observed when SCR is in service. Therefore, higher overall mercury removal efficiencies through wet FGD are attained. Because of different wet FGD operating conditions, there are different mercury removal efficiencies in different units. Elemental mercury reemission took place when a fraction of oxidized mercury absorbed in the slurry is reduced to elemental mercury, and Hg2+ is reemitted from stack, which results in decreases in mercury removal efficiencies through wet FGD systems.展开更多
Baseline of mercury in mangrove swamp The mercury content in sediments in the Jiulong Estuary was determined in 1984 and 1985(Table 1). The highest content of mercury in sediments (300×10) was found in Ditou, con...Baseline of mercury in mangrove swamp The mercury content in sediments in the Jiulong Estuary was determined in 1984 and 1985(Table 1). The highest content of mercury in sediments (300×10) was found in Ditou, contrast-ing strongly with the low content of 36×10in Port Dongzhai in the Hainan Island. Tab1e 1 showsthat the average content of mercury in sediments in the Jiulong Estuary is 140×10and the averageof four areas is 72×10. This value means that these areas have not been heavily contaminated by展开更多
One of the suitable methods for removing heavy metals from water is by using surface adsorption process. In this paper, the preparation of polypyrrole and its composites as adsorbents are discussed and the capability ...One of the suitable methods for removing heavy metals from water is by using surface adsorption process. In this paper, the preparation of polypyrrole and its composites as adsorbents are discussed and the capability of separating mercury from water is investigated. The results indicated that the polypyrrole and its composites are able to remove mercury from aqueous media. Furthermore the adsorption percentage is related to the surface morphology, type of additives and its concentration.展开更多
In this work,response surface methodology(RSM)was employed to model and optimize electrodialysis process for mercury(Hg(II))removal from seaweed extracts.Box-Behnken design(BBD)was utilized to evaluate the effects and...In this work,response surface methodology(RSM)was employed to model and optimize electrodialysis process for mercury(Hg(II))removal from seaweed extracts.Box-Behnken design(BBD)was utilized to evaluate the effects and the interaction of influential variables such as operating voltage,influent flow rate,initial concentration of Hg(II)on the removal rate of Hg(II).The developed regression model for removal rate response was validated by analysis of variance,and presented a good agreement of the experimental data with the quadratic equation with high value coefficient of determination value(R2=0.9913,RAdj 2=0.9678).The optimum operating parameters were determined as 7.17V operating voltage,72.54L h−1 influent flow rate and 5.04mgL−1 initial concentration of mercury.Hg(II)removal rate of 76.45%was acquired under the optimum conditions,which showed good agreement with model-predicted(75.81%)result.The results revealed that electrodialysis can be considered as a promising strategy for removal of Hg(II)from seaweed extracts.展开更多
Due to the restriction such as the Minamata Convention as well as the IED of the European Commission,mercury removal from flue gases of coal-fired power plants(CPP)is an increasingly important environmental issue.This...Due to the restriction such as the Minamata Convention as well as the IED of the European Commission,mercury removal from flue gases of coal-fired power plants(CPP)is an increasingly important environmental issue.This makes this topic very crucial for both the energy industry and scientists.This paper shows how mercury arises from natural resources,i.e.,coals,through their combustion processes in CPP and considers the issue of mercury content in flue gases and solid-state coal combustion by-products.The main part of this paper presents a review of the solid sorbents available for elemental mercury control and removal processes,tested on a laboratory scale.The described solutions have a potential for wider usage in exhaust gas treatment processes in the energy production sector.These solutions represent the latest developments in the field of elemental mercury removal from gases.The authors present an overview of the wide range of solid sorbents and their modifications intended to increase affinity for Hg^(0).Among the presented sorbents are the wellknown activated carbon solutions but also novel modifications to these and other innovative sorbent proposals based on,e.g.,zeolites,biochars,other carbon-based materials,metal-organic frameworks.The paper presents a wide range of characteristics of the described sorbents,as well as the conditions for the Hg^(0) removal experiments summarizing the compendium of novel solid sorbent solutions dedicated to the removal of elemental mercury from gases.展开更多
Firstly, physical and chemical properties of dust removed from BOF gas are analyzed, and then the cold banding technology of dust removed from BOF gas and its application are introduced. Tests have proved that using c...Firstly, physical and chemical properties of dust removed from BOF gas are analyzed, and then the cold banding technology of dust removed from BOF gas and its application are introduced. Tests have proved that using cooled agglomerated pellets made of the dust removed from BOF gas and small amounts of modified starch as a coolant and slagging agent in steel production can bring about considerable economic, social and environmental benefits.展开更多
A bench-scale cyclic activated sludge technology (CAST) was operated to study the biological phosphorus removal performance and a series of batch tests was carried out to demonstrate the accumulation of denitrifying...A bench-scale cyclic activated sludge technology (CAST) was operated to study the biological phosphorus removal performance and a series of batch tests was carried out to demonstrate the accumulation of denitrifying polyphosphate-accumulating organisms (DNPAOs) in CAST system. Under all operating conditions, step-feed CAST with enough carbon sources in influent had the highest nitrogen and phosphorus removal efficiency as well as good sludge settling performance. The average removal rate of COD, NH4^+-N, PO4^3--P and total nitrogen (TN) was 88.2%, 98.7%, 97.5% and 92.1%, respectively. The average sludge volume index (SVI) was 133 mL/g. The optimum anaerobic/aerobic/anoxic (AOA) conditions for the cultivation of DNPAOs could be achieved by alternating anoxic/oxic operational strategy, thus a significant denitrifying phosphorus removal occurred in step-feed CAST. The denitrification of NO^x--N completed quickly due to step-feed operation and enough carbon sources, which could enhance phosphorus release and further phosphorus uptake capability of the system. Batch tests also proved that polyphosphate-accumulating organisms (PAOs) in the step-feed process had strong denitrifying phosphorus removal capacity. Both nitrate and nitrite could be used as electron acceptors in denitrifying phosphorus removal. Low COD supply with step-feed operation strategy would favor DNPAOs accumulation.展开更多
The presence of Hg in the aqueous media is known to cause severe health issues in both humans and animals.Many technologies and especially adsorbents have been applied for its removal. In this study, a graphene oxide...The presence of Hg in the aqueous media is known to cause severe health issues in both humans and animals.Many technologies and especially adsorbents have been applied for its removal. In this study, a graphene oxide–carbon composite(GO–CC) as a new adsorbent was prepared by sol gel procedure and characterized using field emission scanning electron microscopy, BET and EDX. The effects of different variables including solution p H, contact time, adsorbent dose and GO ratio in adsorbent matrix on the removal capacity of Hg were studied. The isotherm data correlated well with the Langmuir isotherm model. Further analysis recommended that the Hg^(2+) adsorption process is governed by the intra-particle and external mass transfer, in which the film diffusion was the rate restrictive step. The presented composite has maximum absorption capacity, q_(max) of 68.8 mg·g^(-1), which is comparable with carbon based adsorbent reported in the previous publications.展开更多
A bench-scale reactor(72 L) red with domestic sewage, was operated more than 3 months with three operation modes: traditional mode, modified mode and real-time control mode, so as to evaluate effects of the operati...A bench-scale reactor(72 L) red with domestic sewage, was operated more than 3 months with three operation modes: traditional mode, modified mode and real-time control mode, so as to evaluate effects of the operation mode on the system performance and to develop a feasible control strategy. Results obtained from fixed-time control study indicate that the variations of the pH and oxidation-reduction potential(ORP) profiles can represent dynamic characteristics of system and the cycle sequences can be controlled and optimized by the control points on the pH and ORP profiles. A control strategy was, therefore, developed and applied to real-time control mode. Compared with traditional mode, the total nitrogen(TN) removal can be increased by approximately 16% in modified mode and a mean TN removal of 92% was achieved in real-time control mode. Moreover, approximately 12.5% aeration energy was saved in real- time control mode. The result of this study shows that the performance of nitrogen removal was enhanced in modified operation mode. Moreover, the real-time control made it possible to optimize process operation and save aeration energy.展开更多
In this study, the enclosure system exhibited perfect nitrogen removal performance with in situ oxygen-enhanced indigenous aerobic denitrifying bacteria in an enclosure experiment. We explored changes in the microbial...In this study, the enclosure system exhibited perfect nitrogen removal performance with in situ oxygen-enhanced indigenous aerobic denitrifying bacteria in an enclosure experiment. We explored changes in the microbial community during the nitrogen removal process using the MiSeq high-throughput sequencing technology. The results revealed a total of 7974 and 33653 operational taxonomic units(OTUs) for water and sediment systems, respectively, with 97% similarity. The OTUs were found to be affiliated with eight main phyla(Proteobacteria, Actinobacteria, Cyanobacteria, Bacteroidetes, Planctomycetes, Chloroflexi, Firmicutes, and Actinobacteria). The diversity of the enhanced system was found to be higher than that of the control system. Principal component analysis(PCA) revealed that significant spatial and temporal differences were exhibited in the microbial community during nitrogen removal in the enclosure experiment. Redundancy analysis(RDA)indicated that physical parameters(temperature, dissolved oxygen, and pH), nitrogen(total nitrogen and nitrate), functional genes(nirK and nirS), and dissolved organic carbon(DOC) were the most important factors affecting bacterial community function and composition. Lastly, the results suggested that the variation in the microbial community could be analyzed through the MiSeq high-throughput sequencing technology,which may provide technical support for future field tests.展开更多
From rapid growth of cement industry in China there is serious pollution of powdered dust. After general analysis on factors influencing adoption of environmentally sound technology(EST) as well as economic benefit ...From rapid growth of cement industry in China there is serious pollution of powdered dust. After general analysis on factors influencing adoption of environmentally sound technology(EST) as well as economic benefit from adoption of dust removing technology and capital ability of cement firms to invest, the conclusion that the obstacles to EST in China cement sector are different from ones in other sectors was drawn. And then, hindrances to diffusion and adoption of EST in China cement were discussion by empirical study.展开更多
Coal-fired power generation is the main source of CO_(2)emission in China.To solve the problems of declined efficiency and increased costs caused by CO_(2)capture in coal-fired power systems,an integrated gasification...Coal-fired power generation is the main source of CO_(2)emission in China.To solve the problems of declined efficiency and increased costs caused by CO_(2)capture in coal-fired power systems,an integrated gasification fuel cell(IGFC)power generation technology was developed.The interaction mechanisms among coal gasification and purification,fuel cell and other components were further studied for IGFCs.Towards the direction of coal gasification and purification,we studied gasification reaction characteristics of ultrafine coal particles,ash melting characteristics and their effects on coal gasification reactions,the formation mechanism of pollutants.We further develop an elevated temperature/pressure swing adsorption rig for simultaneous H_(2)S and CO_(2)removals.The results show the validity of the Miura-Maki model to describe the gasification of Shenhua bituminous coal with a good fit between the predicted DTG curves and experimental data.The designed 8–6–1 cycle procedure can effectively remove CO_(2)and H_(2)S simultaneously with removal rate over 99.9%.In addition,transition metal oxides used as mercury removal adsorbents in coal gasified syngas were shown with great potential.The techniques presented in this paper can improve the gasification efficiency and reduce the formation of pollutants in IGFCs.展开更多
A semi-continuous technology combines the merits of discontinuous and continuous technologies. Compared with the discontinuous technology, the semi-continuous technology can be used to decrease haulage costs in mines ...A semi-continuous technology combines the merits of discontinuous and continuous technologies. Compared with the discontinuous technology, the semi-continuous technology can be used to decrease haulage costs in mines be- cause of the use of a belt conveyor instead of trucks. The method may improve efficiency by using shovels instead of BWE. This paper discusses the removal distance of a crushing station based on the Buzhaoba surface mine.展开更多
基金Supported by the National Natural Science Foundation of China(11572037)
文摘Considering current space debris situation in outer space environment,different methods for debris removal missions are proposed.In addition,advanced technologies are needed to be demonstrated for future human space exploration programs.The main issue regarding to these missions is high mission cost for both debris removal missions and space environmental tests to achieve high maturity level for new space-usable technologies.Since,these missions are unavoidable for future of human space activities,a solution which can tackle these challenges is necessary.This paper will address to an idea which has the possibility to give a solution for facilitating technology readiness level(TRL)maturity tests by debris removal mission platform consideration.
基金supported by the BEN TEN CO., and National Science Council contracts 98-2221-E-152-001 and 99-2221-E-152-001
文摘Color filters are produced using semiconductor production techniques although problems with low yield remain to be addressed. This study presents a new means of selective removal using excimer irradiation, chemical etching, or electrochemical machining on the fifth generation TFT LCDs. The selective removal of microstructure layers from the color filter surface of an optoelectronic flat panel display, as well as complete removal of the ITO thin-films, RGB layer, or resin black matrix (BM) layer from the substrate is possible. Individual defective film layers can be removed, or all films down to the Cr layer or bare glass can be completely eliminated. Experimental results demonstrate that defective ITO thin-films, RGB layers, or the resin BM layer can now be recycled with a great precision. When the ITO or RGB layer proves difficult to remove, excimer light can be used to help with removal. During this recycling process, the use of 225 nm excimer irradiation before chemical etching, or electrochemical machining, makes removal of stubborn film residues easy, effectively improving the quality of recycled color filters and reducing fabrication cost.
文摘The pollution of iron,manganese and nitrate in groundwater is a huge threat to human beings.In this study,column experiments of ceramic,manganese sand,ceramic sand,volcanic rock,quartz sand were conducted.Iron and manganese contents of influent were 3.3 mg/L and 2.1 mg/L.When the biofilm became mature,the highest iron and manganese removal rate achieved by manganese sand as a filter material.Quartz did a little worse than manganese sand,but other three filter material could not reach
文摘Most fault-block reservoirs in Xinmu oilfield belong to heterogeneous sandstone in characters which has low permeability, and reservoir pollution is a common phenomenon in this area. Acidizing deplugging in oil wells has become one of the major measures to improve production efficiency in the field. A compound deplug- ging technology in high efficiency low corrosion is developed for this kind of low permeability sandstone reser- voir. On the basis of profoundly understanding of the reservoir's physical properties and sensitivity, along with comprehensive analysis of the cause for jams in oil wells, a series of experiments are carried out in order to in- vestigate the dissolution reaction among samples and deplugging inhibitor, sample dissolving speed, formation fluid compatibility, reduction of secondary pollution, etc. Considered reservoir condition in nearby wells the op- timized compositional deplugging liquid formula is selected for this reservoir. It is featured by reducing the de- plugging reaction speed, extending solution for processing radius, preventing secondary damage in dissolution processing, and removing plug pollution effectively. To implement this high efficiency low corrosion deplugging measure based on reservoir condition in the borehole and nearby wells, a relatively better result of deplugging and production increasing is achieved, which enriches the measures to increase production in Xinmu oilfield, and this method can be applied to other similar oiffields for the purpose of maintaining the crude oil production and providing assistant for increasing the production significantly.
基金The National Natural Science Foundation of China(No.51376046,51076030)the National Key Technology R&D Program of China during the 12th Five-Year Plan Period(No.2012BAA02B01)+2 种基金the United Creative Foundation of Jiangsu Province(No.BY2013073-10)the Fundamental Research Funds for the Central Universitiesthe Scientific Innovation Research of College Graduates in Jiangsu Province(CXZZ13_0093,KYLX_0115,KYLX_0184)
文摘In order to remove gas-phase mercury and NOx from flue gas, experimental studies on flue gas mercury oxidation removal and denitration of Guizhou anthracite combustion with NH4Br addition were carried out. The influence of NH4Br addition on the ignition temperature and combustion characteristics was studied using a thermogravimetric analyzer. The effects of the NHaBr addition amount on gas-phase mercury oxidation and removal were investigated in a bench scale of 6 kW fluidized bed combustor (FBC). Mercury concentrations in flue gas were determined by the Ontario hydro method (OHM) and the mercury mass balance was obtained. Results show that the NH4Br addition has little influence on the ignition temperature of Guizhou anthracite. With the mercury mass balance of 95.47%, the proportion of particulate mercury Hg^p, gaseous mercury Hg^0 and Hg^2+ are 75.28%, 11.60% and 13. 12%, respectively, as raw coal combustion. The high particulate mercury Hg^p in flue gas is caused by the high unburned carbon content in fly ash. When the NH4Br addition amount increases from 0 to 0. 3%, the concentration of gaseous Hg^0 and Hg^2+ in flue gas decreases continuously, leading to the Hg^p increase accordingly. The oxidation rate of Hg^0 is positively correlated to the Br addition amount. It demonstrates that coal combustion with NH4Br addition can promote Hg^0 oxidation and removal. NOx concentration in flue gas exhibits a descending trend with the NHaBr addition and the removal rate reaches 17.31% with the addition amount of 0.3%. Adding NH4Br to coal also plays a synergistic role in denitration.
基金supported by the U.S.Agency for International Development (USAID) cooperation agreement(No.486-A-00-06-000140-00)
文摘Air pollution control devices (APCDs) are installed at coal-fired power plants for air pollutant regulation. Selective catalytic reduction (SCR) and wet flue gas desulftLrization (FGD) systems have the co-benefits of air pollutant and mercury removal. Configuration and operational conditions of APCDs and mercury speciation affect mercury removal efficiently at coal-fired utilities. The Ontario Hydro Method (OHM) recommended by the U.S. Environmental Protection Agency (EPA) was used to determine mercury speciation simultaneously at five sampling locations through SCR-ESP-FGD at a 190 MW unit. Chlorine in coal had been suggested as a factor affecting the mercury speciation in flue gas; and low-chlorine coal was purported to produce less oxidized mercury (Hg^2+) and more elemental mercury (Hg^0) at the SCR inlet compared to higher chlorine coal. SCR could oxidize elemental mercury into oxidized mercury when SCR was in service, and oxidation efficiency reached 71.0%. Therefore, oxidized mercury removal efficiency was enhanced through a wet FGD system. In the non-ozone season, about 89.5%-96.8% of oxidized mercury was controlled, but only 54.9%-68.8% of the total mercury was captured through wet FGD. Oxidized mercury removal efficiency was 95.9%-98.0%, and there was a big difference in the total mercury removal efficiencies from 78.0% to 90.2% in the ozone season. Mercury mass balance was evaluated to validate reliability of OHM testing data, and the ratio of mercury input in the coal to mercury output at the stack was from 0.84 to 1.08.
文摘The Ontario Hydro Method (OHM) recommended by the United States Environmental Protection Agency (EPA) was used to determine mercury speciation in the combustion flue gas across wet FGD systems. Four coal-fired units with wet FGD systems were chosen to evaluate mercury speciation and mercury removal efficiencies through these wet FGD systems. Chlorine content in coal had been suggested as a main factor that affects mercury speciation in flue gas. It is shown that the higher the chlorine concentration in coal is, the higher the percentage of oxidized mercury (Hg2+) is removed in wet FGD systems, which can increase overall mercury removal efficiencies through wet FGD systems. The selective catalyst reduction (SCR) system has a function of oxidizing ele- mental mercury (Hg0) to oxidized mercury. A higher percentage of oxidized mercury in the total vapor mercury at the FGD inlet is observed when SCR is in service. Therefore, higher overall mercury removal efficiencies through wet FGD are attained. Because of different wet FGD operating conditions, there are different mercury removal efficiencies in different units. Elemental mercury reemission took place when a fraction of oxidized mercury absorbed in the slurry is reduced to elemental mercury, and Hg2+ is reemitted from stack, which results in decreases in mercury removal efficiencies through wet FGD systems.
文摘Baseline of mercury in mangrove swamp The mercury content in sediments in the Jiulong Estuary was determined in 1984 and 1985(Table 1). The highest content of mercury in sediments (300×10) was found in Ditou, contrast-ing strongly with the low content of 36×10in Port Dongzhai in the Hainan Island. Tab1e 1 showsthat the average content of mercury in sediments in the Jiulong Estuary is 140×10and the averageof four areas is 72×10. This value means that these areas have not been heavily contaminated by
文摘One of the suitable methods for removing heavy metals from water is by using surface adsorption process. In this paper, the preparation of polypyrrole and its composites as adsorbents are discussed and the capability of separating mercury from water is investigated. The results indicated that the polypyrrole and its composites are able to remove mercury from aqueous media. Furthermore the adsorption percentage is related to the surface morphology, type of additives and its concentration.
基金financially supported by the Key Research Project of Shandong Province (No. 2017CXGC 1004)the National Natural Science Foundation of China (No. 21878178)+1 种基金the Shandong Science and Technology Development Plan (No. 2018GGX107001)the Young Tai- shan Scholars Program of Shandong Province
文摘In this work,response surface methodology(RSM)was employed to model and optimize electrodialysis process for mercury(Hg(II))removal from seaweed extracts.Box-Behnken design(BBD)was utilized to evaluate the effects and the interaction of influential variables such as operating voltage,influent flow rate,initial concentration of Hg(II)on the removal rate of Hg(II).The developed regression model for removal rate response was validated by analysis of variance,and presented a good agreement of the experimental data with the quadratic equation with high value coefficient of determination value(R2=0.9913,RAdj 2=0.9678).The optimum operating parameters were determined as 7.17V operating voltage,72.54L h−1 influent flow rate and 5.04mgL−1 initial concentration of mercury.Hg(II)removal rate of 76.45%was acquired under the optimum conditions,which showed good agreement with model-predicted(75.81%)result.The results revealed that electrodialysis can be considered as a promising strategy for removal of Hg(II)from seaweed extracts.
基金This work was supported by the National Centre for Research and Development project LIDER,Contract Number LIDER/384/L-6/14/NCBR/2015.
文摘Due to the restriction such as the Minamata Convention as well as the IED of the European Commission,mercury removal from flue gases of coal-fired power plants(CPP)is an increasingly important environmental issue.This makes this topic very crucial for both the energy industry and scientists.This paper shows how mercury arises from natural resources,i.e.,coals,through their combustion processes in CPP and considers the issue of mercury content in flue gases and solid-state coal combustion by-products.The main part of this paper presents a review of the solid sorbents available for elemental mercury control and removal processes,tested on a laboratory scale.The described solutions have a potential for wider usage in exhaust gas treatment processes in the energy production sector.These solutions represent the latest developments in the field of elemental mercury removal from gases.The authors present an overview of the wide range of solid sorbents and their modifications intended to increase affinity for Hg^(0).Among the presented sorbents are the wellknown activated carbon solutions but also novel modifications to these and other innovative sorbent proposals based on,e.g.,zeolites,biochars,other carbon-based materials,metal-organic frameworks.The paper presents a wide range of characteristics of the described sorbents,as well as the conditions for the Hg^(0) removal experiments summarizing the compendium of novel solid sorbent solutions dedicated to the removal of elemental mercury from gases.
文摘Firstly, physical and chemical properties of dust removed from BOF gas are analyzed, and then the cold banding technology of dust removed from BOF gas and its application are introduced. Tests have proved that using cooled agglomerated pellets made of the dust removed from BOF gas and small amounts of modified starch as a coolant and slagging agent in steel production can bring about considerable economic, social and environmental benefits.
基金supported by the Environment and Water Industry Development Scheme of Singapore-The Process Control and Enhanced Biological Nutrient Removal of CSBR Process (No. EDB S07/1-53974082)the National Key Technologies R&D Program of China during the Eleventh Five-year Plan Period (No. 2006BAC19B03)+1 种基金the Project of Scientific Research Base and Scientific Innovation Platform of Beijing Municipal Education Commission (No. PXM2008-014204-050843)the Funding Project by Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality (No. PHR20090502)
文摘A bench-scale cyclic activated sludge technology (CAST) was operated to study the biological phosphorus removal performance and a series of batch tests was carried out to demonstrate the accumulation of denitrifying polyphosphate-accumulating organisms (DNPAOs) in CAST system. Under all operating conditions, step-feed CAST with enough carbon sources in influent had the highest nitrogen and phosphorus removal efficiency as well as good sludge settling performance. The average removal rate of COD, NH4^+-N, PO4^3--P and total nitrogen (TN) was 88.2%, 98.7%, 97.5% and 92.1%, respectively. The average sludge volume index (SVI) was 133 mL/g. The optimum anaerobic/aerobic/anoxic (AOA) conditions for the cultivation of DNPAOs could be achieved by alternating anoxic/oxic operational strategy, thus a significant denitrifying phosphorus removal occurred in step-feed CAST. The denitrification of NO^x--N completed quickly due to step-feed operation and enough carbon sources, which could enhance phosphorus release and further phosphorus uptake capability of the system. Batch tests also proved that polyphosphate-accumulating organisms (PAOs) in the step-feed process had strong denitrifying phosphorus removal capacity. Both nitrate and nitrite could be used as electron acceptors in denitrifying phosphorus removal. Low COD supply with step-feed operation strategy would favor DNPAOs accumulation.
文摘The presence of Hg in the aqueous media is known to cause severe health issues in both humans and animals.Many technologies and especially adsorbents have been applied for its removal. In this study, a graphene oxide–carbon composite(GO–CC) as a new adsorbent was prepared by sol gel procedure and characterized using field emission scanning electron microscopy, BET and EDX. The effects of different variables including solution p H, contact time, adsorbent dose and GO ratio in adsorbent matrix on the removal capacity of Hg were studied. The isotherm data correlated well with the Langmuir isotherm model. Further analysis recommended that the Hg^(2+) adsorption process is governed by the intra-particle and external mass transfer, in which the film diffusion was the rate restrictive step. The presented composite has maximum absorption capacity, q_(max) of 68.8 mg·g^(-1), which is comparable with carbon based adsorbent reported in the previous publications.
基金The Project of Beijing Science and Technology Committee (No.020620010120) ,the Hi_Tech Research and Development Program(863) of China (No.2004AA601020) ,the Project under Key International Cooperative Programs of NSFC(No.50521140075) and the Project of Key Laboratory of Beiing
文摘A bench-scale reactor(72 L) red with domestic sewage, was operated more than 3 months with three operation modes: traditional mode, modified mode and real-time control mode, so as to evaluate effects of the operation mode on the system performance and to develop a feasible control strategy. Results obtained from fixed-time control study indicate that the variations of the pH and oxidation-reduction potential(ORP) profiles can represent dynamic characteristics of system and the cycle sequences can be controlled and optimized by the control points on the pH and ORP profiles. A control strategy was, therefore, developed and applied to real-time control mode. Compared with traditional mode, the total nitrogen(TN) removal can be increased by approximately 16% in modified mode and a mean TN removal of 92% was achieved in real-time control mode. Moreover, approximately 12.5% aeration energy was saved in real- time control mode. The result of this study shows that the performance of nitrogen removal was enhanced in modified operation mode. Moreover, the real-time control made it possible to optimize process operation and save aeration energy.
基金supported by the National Science and Technology Pillar Program(Grant No.2012BAC04B02)the National Natural Science Foundation of China(Grant No.51478378)
文摘In this study, the enclosure system exhibited perfect nitrogen removal performance with in situ oxygen-enhanced indigenous aerobic denitrifying bacteria in an enclosure experiment. We explored changes in the microbial community during the nitrogen removal process using the MiSeq high-throughput sequencing technology. The results revealed a total of 7974 and 33653 operational taxonomic units(OTUs) for water and sediment systems, respectively, with 97% similarity. The OTUs were found to be affiliated with eight main phyla(Proteobacteria, Actinobacteria, Cyanobacteria, Bacteroidetes, Planctomycetes, Chloroflexi, Firmicutes, and Actinobacteria). The diversity of the enhanced system was found to be higher than that of the control system. Principal component analysis(PCA) revealed that significant spatial and temporal differences were exhibited in the microbial community during nitrogen removal in the enclosure experiment. Redundancy analysis(RDA)indicated that physical parameters(temperature, dissolved oxygen, and pH), nitrogen(total nitrogen and nitrate), functional genes(nirK and nirS), and dissolved organic carbon(DOC) were the most important factors affecting bacterial community function and composition. Lastly, the results suggested that the variation in the microbial community could be analyzed through the MiSeq high-throughput sequencing technology,which may provide technical support for future field tests.
文摘From rapid growth of cement industry in China there is serious pollution of powdered dust. After general analysis on factors influencing adoption of environmentally sound technology(EST) as well as economic benefit from adoption of dust removing technology and capital ability of cement firms to invest, the conclusion that the obstacles to EST in China cement sector are different from ones in other sectors was drawn. And then, hindrances to diffusion and adoption of EST in China cement were discussion by empirical study.
基金This work was financially supported by National Key R&D Program of China(2017YFB0601900).
文摘Coal-fired power generation is the main source of CO_(2)emission in China.To solve the problems of declined efficiency and increased costs caused by CO_(2)capture in coal-fired power systems,an integrated gasification fuel cell(IGFC)power generation technology was developed.The interaction mechanisms among coal gasification and purification,fuel cell and other components were further studied for IGFCs.Towards the direction of coal gasification and purification,we studied gasification reaction characteristics of ultrafine coal particles,ash melting characteristics and their effects on coal gasification reactions,the formation mechanism of pollutants.We further develop an elevated temperature/pressure swing adsorption rig for simultaneous H_(2)S and CO_(2)removals.The results show the validity of the Miura-Maki model to describe the gasification of Shenhua bituminous coal with a good fit between the predicted DTG curves and experimental data.The designed 8–6–1 cycle procedure can effectively remove CO_(2)and H_(2)S simultaneously with removal rate over 99.9%.In addition,transition metal oxides used as mercury removal adsorbents in coal gasified syngas were shown with great potential.The techniques presented in this paper can improve the gasification efficiency and reduce the formation of pollutants in IGFCs.
文摘A semi-continuous technology combines the merits of discontinuous and continuous technologies. Compared with the discontinuous technology, the semi-continuous technology can be used to decrease haulage costs in mines be- cause of the use of a belt conveyor instead of trucks. The method may improve efficiency by using shovels instead of BWE. This paper discusses the removal distance of a crushing station based on the Buzhaoba surface mine.