Effect of partial pit exhaust ventilation system on ammonia removal ratio and mass transfer coefficients from different emission sources in pig houses

A partial pit exhaust ventilation(PPEV)system installed below the slatted floor has been widely used in fattening pig barns nowadays in Denmark.Experimental tests showed that annually around 50%of ammonia emissions was collected by PPEV system.However,the percent of emissions collected by PPEV system from different emission sources including slurry manure surfaces,top surfaces,bottom surfaces and side surfaces of the slatted floor has not been investigated as well as the mass transfer coefficients.This study applied CFD modeling to investigate the removal ratio of ammonia emissions from four emission surfaces including the top,side,bottom surfaces of the slatted floor and slurry manure surfaces.The CFD model was validated by experimental air speeds measured in a room equipped with two full-scale pigpens.The validated CFD model was further adopted to simulate cases under five ventilation rates(2000-4000 m^(3)/h),four emission sources and two locations of PPEV system exhaust.The results showed that the removal ratios of ammonia emissions by PPEV system from the four emission sources were generally higher for the cases that the PPEV exhaust was installed opposite to the air supplier than the values of those cases that the PPEV exhaust was located at the same side of side wall air supplier.The removal ratios of ammonia emissions were the highest with the emission source of slurry manure surface and generally 30%higher than the values of other cases.The mass transfer coefficients with the emission sources on the side surfaces of the slatted floor were the largest.The results indicated that the airflow patterns and locations of emission sources greatly influenced the removal ratios of ammonia emissions and ammonia mass transfer coefficients.

Efficient Degradation 4-Nitrophenol by Photocatalysis from Modified TiO_2 Doped Copper

In the present study,a film consisting of TiO_2 doped with copper was prepared for efficiently decomposing 4-nitrophenol(4-NP) by photocatalysis.The preparing process of TiO_2 doped with copper includes two procedures:preparing Ti(OH)_4 doped with copper and synthesizing anatase and rutile TiO_2 doped with copper.Ti(OH)_4 doped with copper could be achieved by hydrolyzing TiCl_4in the mixed solution containing deionized water and copper oxalate.The Ti(OH)_4 doped with copper can be gained successfully by the following procedures:rinsing,drying and vacuum drying.The Ti(OH)_4 doped with copper could be converted into anatase TiO_2 doped with copper and rutile TiO_2 doped with copper by incineration for 4.5 h at 723 and 1 073 K,respectively.Characterizations of anatase TiO_2 doped with copper and rutile TiO_2 doped with copper were determined by X-ray diffraction(XRD) and energy dispersion of X-ray(EDX).Anatase and rutile TiO_2 doped with copper were dissolved in a mixed solution containing isopropanol and diethylamine.Stainless electrode was submerged into with the solutions,the film of TiO_2 was formed by drying the thin layer at a ramp rate of 3℃/min until 373 K,and this temperature was held for 1 h.The temperature of the oven was subsequently increased to a final temperature of 823 K at a ramp rate of 3℃/min,and was held at this value for 1 h.The stainless steel covered with modified TiO_2 film was utilized as the anode.The stainless steel mesh was used as the cathode.The cathode and anode were connected with the source and immersed into the solution with 100 mg/L 4-NP.The whole reaction on photocatalysis was perfectly carried out after ultraviolet radiation and aerator were run.The experimental results showed that:cracking ratio of 4-NP ring,the removal ratio of chemical oxygen demand(COD) and total organic carbon(TOC) were respectively more than 90%,80% and 80% within 2 h.Degradation of 4-NP implied its potential application in associated wastewater.

Effect of low basicity refining slag on evolution and removal of oxide inclusions in 55SiCrA spring steel

The laboratory experiments,thermodynamic analysis,dynamic analysis,and industrial trials were carried out to investigate the influence of refining slag on the evolution and removal of oxide inclusions in 55SiCrA spring steel.The reduction in basicity and Al_(2)O_(3) content in refining slag can reduce the[Al]s content in the molten steel,which is conducive to the control of the low melting point of inclusions.However,the refining slag with excessively low basicity transfers the oxygen element to molten steel and increases the Al_(2)O_(3) content in inclusions,which is harmful to the control of inclusions.According to the chemical compositions of inclusions and refining slag in laboratory experiments,their physical parameters were calculated.The maximum separation ratio and the moving time of inclusions to reach the maximum separation ratio(t_(max))of inclusions under different laboratory experimental conditions were studied.The maximum separation ratio of inclusions is positively correlated with the overall wettability(coshIMS)among the slag,steel,and inclusions.The maximum separation ratio of inclusions obtained by laboratory experiments is between 85%and 91%.The t_(max) decreases with the decline in basicity and Al_(2)O_(3) content of refining slag,but excessively low basicity will increase the t_(max).The basicity of refining slag in the range of 0.88–0.97 and the content of Al_(2)O_(3) less than 6%is not only conducive to reducing the content of Al_(2)O_(3) and the melting point of inclusions but also beneficial to removing the inclusions to the slag.The slag system shows good metallurgical results in industrial trials.