Commercial oil flow has been obtained from the sandstone reservoir of the Lower Silurian Kelpintag Formation in the Well Shun-9 prospect area.In the present studies,10 Silurian oil and oil sand samples from six wells ...Commercial oil flow has been obtained from the sandstone reservoir of the Lower Silurian Kelpintag Formation in the Well Shun-9 prospect area.In the present studies,10 Silurian oil and oil sand samples from six wells in the area were analyzed for their molecular and carbon isotopic compositions,oil alteration（biodegradation）,oil source rock correlation and oil reservoir filling direction.All the Silurian oils and oil sands are characterized by low Pr/Ph and C21/C23 tricyclic terpane（〈1.0） ratios,＂V＂-pattern C27-C29 steranes distribution,low C28-sterane and triaromatic dinosterane abundances and light δ13C values,which can be correlated well with the carbonate source rock of the O3 l Lianglitage Formation.Different oil biodegradation levels have also been confirmed for the different oils/oil sands intervals.With the S1k2 seal,oils and oil sands from the S1k1 interval of the Kelpintag Formation have only suffered light biodegradation as confirmed by the presence of ＂UCM＂ and absence of 25-norhopanes,whereas the S1k3-1 oil sands were heavily biodegraded（proved by the presence of 25-norhopanes） due to the lack of the S1k2 seal,which suggests a significant role of the S1k2 seal in the protection of the Silurian oil reservoir.Based on the Ts/（Ts＋Tm） and 4-/1-MDBT ratios as reservoir filling tracers,a general oil filling direction from NW to SE has been also estimated for the Silurian oil reservoir in the Well Shun-9 prospect area.展开更多
The Yong＇an-Meitai area is the focus of the present exploration in the Fushan Depression, Beibuwan Basin, South China Sea. All oils from this area are geochemically characterized by higher Pr/Ph ratio, higher proport...The Yong＇an-Meitai area is the focus of the present exploration in the Fushan Depression, Beibuwan Basin, South China Sea. All oils from this area are geochemically characterized by higher Pr/Ph ratio, higher proportion of heavy molecular weight hydrocarbons, and higher proportion of C29 regular steranes, which indicate that the organic matter of source rocks might have been deposited in an oxidizing palaeoenvironment and be dominated by higher plant organic matter input. The oil from E3w2 （the second member of Weizhou Fro. of the Oligocene） has a much higher density, relatively higher Pr/nC17 and Ph/nC18 ratios, and a ＂UCM--unresolved complex mixture＂ on gas chromatograms, which indicate that it has been slightly biodegraded. CPI and other terpane and sterane isomer ratios suggest they are all mature oils. The timing of oil charging in E3w2 and E2I1 （the first member of the Liushagang Fro. of the Eocene） determined by the homogenization temperatures of fluid inclusions and thermal evolution history are from 9-3 Ma and 8-3 Ma, respectively. Thus, the interpretation of E3w2 as a secondary reservoir is unlikely. The timing of oil charging is later than that of hydrocarbon generating and expulsion of Liushagang Fin. source rocks and trap formation, which is favorable for oil accumulation in this area. All molecular parameters that are used for tracing oil filling direction decrease with shallower burial depth, which suggests vertical oil migration. The widely occurring faults that penetrate through the source rocks of the Liushagang Fro. may serve as a fine oil charging conduit.展开更多
Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types：slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely co...Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types：slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely corroded and replaced secondary calcic karstic rocks. The carbon, oxygen and strontium isotope compositions of the various karst rocks are analyzed systematically and compared to rocks without karst corrosion. The results indicate that（1） the Huanglong Formation in the eastern Sichuan Basin was a restricted bay supplied and controlled by freshwater in which mudmicrite and mud-dolomicrite exhibit low δ13C and δ18O values and high 87Sr/86 Sr ratios;（2） all types of karstic rocks in the paleokarst reservoirs of the Huanglong Formation in the research area are affected by atmospheric freshwater with the δ13C and δ18O values and 87Sr/86 Sr ratios in the original formation approaching those of atmospheric freshwater, which reflects ancient hydrological conditions, fluid properties, isotopic source and the fractionation effect;（3） the intensely corroded and replaced secondary limestone is affected by a variety of diagenetic fluids, often reflected by δ13C and δ18O values, while the 87Sr/86 Sr ratios exhibit the strong degree of the corrosion;（4） after comparing the 87Sr/86 Sr ratios of each type of karst rock, the diagenetic fluids are determined to be mainly atmospheric freshwater, and depending on the strength of corrosion, and the low 87Sr/86 Sr ratio fluids in the layer will participate in the karst process. The carbon, oxygen, and strontium isotopes of different karstic reservoirs can provide meaningful geochemical information for forecasting and evaluating the development and distribution rules of the Huanglong Formation at the margin of the eastern Sichuan Basin in time and space.展开更多
The Upper Cretaceous carbonate successions of the Sarvak Formation host giant oil reservoirs in the Persian Gulf.In this research,a total of 28 oil samples from nine oilfields located in the western,central and easter...The Upper Cretaceous carbonate successions of the Sarvak Formation host giant oil reservoirs in the Persian Gulf.In this research,a total of 28 oil samples from nine oilfields located in the western,central and eastern parts of the Persian Gulf region were studied to determine the genetic relationships of oils,depositional setting of possible source rocks,thermal maturity,and source-rock ages in the Persian Gulf basin.According to the measured geochemical data,the source rocks facies vary from marine carbonates and marl/carbonates in the central and eastern oilfields to shale/carbonates in the western oilfields.The Pr/Ph ratio,steranes and terpanes suggest anoxic to dysoxic conditions of the depositional environments.The depositional environments experienced both low water stratification/low salinity and normal salinity/unstratified conditions.Evaluation of the saturated and aromatic biomarkers shows that all oil samples are mature and most of the source rocks lie within the beginning of the oil-generation window.The thermal maturity of the central oilfields is higher than that of the other samples,and has gone beyond the oil-generation stage.The C2s/C2g steranes ratio suggest that the central oilfelds of the Persian Gulf have Paleozoic and Jurassic source rocks,whereas the Sarvak reservoir in other parts of this region is sourced from Cretaceous carbonate rocks.展开更多
基金the Northwest Branch Company, SINOPEC for access to samples and grant support
文摘Commercial oil flow has been obtained from the sandstone reservoir of the Lower Silurian Kelpintag Formation in the Well Shun-9 prospect area.In the present studies,10 Silurian oil and oil sand samples from six wells in the area were analyzed for their molecular and carbon isotopic compositions,oil alteration（biodegradation）,oil source rock correlation and oil reservoir filling direction.All the Silurian oils and oil sands are characterized by low Pr/Ph and C21/C23 tricyclic terpane（〈1.0） ratios,＂V＂-pattern C27-C29 steranes distribution,low C28-sterane and triaromatic dinosterane abundances and light δ13C values,which can be correlated well with the carbonate source rock of the O3 l Lianglitage Formation.Different oil biodegradation levels have also been confirmed for the different oils/oil sands intervals.With the S1k2 seal,oils and oil sands from the S1k1 interval of the Kelpintag Formation have only suffered light biodegradation as confirmed by the presence of ＂UCM＂ and absence of 25-norhopanes,whereas the S1k3-1 oil sands were heavily biodegraded（proved by the presence of 25-norhopanes） due to the lack of the S1k2 seal,which suggests a significant role of the S1k2 seal in the protection of the Silurian oil reservoir.Based on the Ts/（Ts＋Tm） and 4-/1-MDBT ratios as reservoir filling tracers,a general oil filling direction from NW to SE has been also estimated for the Silurian oil reservoir in the Well Shun-9 prospect area.
基金This research was financially supported by the Natural Science Foundation of China(Grant No.40672093)CNPC Innovation Fund(07El001)the ESS-China Hydrocarborn Geoscience Collaboration Project under Natural Resources Canada's International 0pportunities Program.We extend our thanks to South 0il Exploration and Development Company of PetroChina for samples collection.
文摘The Yong＇an-Meitai area is the focus of the present exploration in the Fushan Depression, Beibuwan Basin, South China Sea. All oils from this area are geochemically characterized by higher Pr/Ph ratio, higher proportion of heavy molecular weight hydrocarbons, and higher proportion of C29 regular steranes, which indicate that the organic matter of source rocks might have been deposited in an oxidizing palaeoenvironment and be dominated by higher plant organic matter input. The oil from E3w2 （the second member of Weizhou Fro. of the Oligocene） has a much higher density, relatively higher Pr/nC17 and Ph/nC18 ratios, and a ＂UCM--unresolved complex mixture＂ on gas chromatograms, which indicate that it has been slightly biodegraded. CPI and other terpane and sterane isomer ratios suggest they are all mature oils. The timing of oil charging in E3w2 and E2I1 （the first member of the Liushagang Fro. of the Eocene） determined by the homogenization temperatures of fluid inclusions and thermal evolution history are from 9-3 Ma and 8-3 Ma, respectively. Thus, the interpretation of E3w2 as a secondary reservoir is unlikely. The timing of oil charging is later than that of hydrocarbon generating and expulsion of Liushagang Fin. source rocks and trap formation, which is favorable for oil accumulation in this area. All molecular parameters that are used for tracing oil filling direction decrease with shallower burial depth, which suggests vertical oil migration. The widely occurring faults that penetrate through the source rocks of the Liushagang Fro. may serve as a fine oil charging conduit.
基金supported by the National Major Science of China (Grant NO. 2011ZX05030-003-002)Natural Science key project of Education Department in Sichuan (NO.13ZA0058)
文摘Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types：slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely corroded and replaced secondary calcic karstic rocks. The carbon, oxygen and strontium isotope compositions of the various karst rocks are analyzed systematically and compared to rocks without karst corrosion. The results indicate that（1） the Huanglong Formation in the eastern Sichuan Basin was a restricted bay supplied and controlled by freshwater in which mudmicrite and mud-dolomicrite exhibit low δ13C and δ18O values and high 87Sr/86 Sr ratios;（2） all types of karstic rocks in the paleokarst reservoirs of the Huanglong Formation in the research area are affected by atmospheric freshwater with the δ13C and δ18O values and 87Sr/86 Sr ratios in the original formation approaching those of atmospheric freshwater, which reflects ancient hydrological conditions, fluid properties, isotopic source and the fractionation effect;（3） the intensely corroded and replaced secondary limestone is affected by a variety of diagenetic fluids, often reflected by δ13C and δ18O values, while the 87Sr/86 Sr ratios exhibit the strong degree of the corrosion;（4） after comparing the 87Sr/86 Sr ratios of each type of karst rock, the diagenetic fluids are determined to be mainly atmospheric freshwater, and depending on the strength of corrosion, and the low 87Sr/86 Sr ratio fluids in the layer will participate in the karst process. The carbon, oxygen, and strontium isotopes of different karstic reservoirs can provide meaningful geochemical information for forecasting and evaluating the development and distribution rules of the Huanglong Formation at the margin of the eastern Sichuan Basin in time and space.
文摘The Upper Cretaceous carbonate successions of the Sarvak Formation host giant oil reservoirs in the Persian Gulf.In this research,a total of 28 oil samples from nine oilfields located in the western,central and eastern parts of the Persian Gulf region were studied to determine the genetic relationships of oils,depositional setting of possible source rocks,thermal maturity,and source-rock ages in the Persian Gulf basin.According to the measured geochemical data,the source rocks facies vary from marine carbonates and marl/carbonates in the central and eastern oilfields to shale/carbonates in the western oilfields.The Pr/Ph ratio,steranes and terpanes suggest anoxic to dysoxic conditions of the depositional environments.The depositional environments experienced both low water stratification/low salinity and normal salinity/unstratified conditions.Evaluation of the saturated and aromatic biomarkers shows that all oil samples are mature and most of the source rocks lie within the beginning of the oil-generation window.The thermal maturity of the central oilfields is higher than that of the other samples,and has gone beyond the oil-generation stage.The C2s/C2g steranes ratio suggest that the central oilfelds of the Persian Gulf have Paleozoic and Jurassic source rocks,whereas the Sarvak reservoir in other parts of this region is sourced from Cretaceous carbonate rocks.
