Fatigue Resistance of Filled NR with PMMA-Wrapped and Rare Earth-Doped Alumina-Siloxane Gel

Poly (methyl methacrylate) (PMMA) was used to wrap alumina-siloxane sol which was produced by water glass, aluminum nitrate and α-methacrylic acid, and as a result, alumina-siloxane gel wrapped by PMMA was obtained. Meanwhile, rare earth ions were employed to dope in the course of reaction, and the formed rare earth doped PMMA microcapsule powder was filled into natural rubber (NR). It is found through the analysis of mechanical properties that Young′s modulus universally improves and a remarkable resistance to fatigue is displayed. Retention rate of tensile strength is twice that of the controlled sample after ten thousand times of extension fatigue.

Overall Evaluation of the Effect of Residual Stress Induced by Shot Peening in the Improvement of Fatigue Fracture Resistance for Metallic Materials

Before 1980s,the circular suspension spring in automobile subjected to torsion fatigue load,under the cyclic normal tensile stresses,the majority of fatigue fracture occurred was in normal tensile fracture mode（NTFM）and the fracture surface was under 45°diagonal.Because there exists the interaction between the residual stresses induced by shot peening and the applied cyclic normal tensile stresses in NTFM,which represents as＂stress strengthening mechanism＂,shot peening technology could be used for improving the fatigue fracture resistance（FFR）of springs.However,since 1990s up to date,in addition to regular NTFM,the fatigue fractures occurred of peened springs from time to time are in longitudinal shear fracture mode（LSFM）or transverse shear fracture mode（TSFM）with the increase of applied cyclic shear stresses,which leads to a remarkable decrease of FFR.However,LSFM/TSFM can be avoided effectively by means of shot peening treatment again on the peened springs.The phenomena have been rarely happened before.At present there are few literatures concerning this problem.Based upon the results of force analysis of a spring,there is no interaction between the residual stresses by shot peening and the applied cyclic shear stresses in shear fracture.This;means that the effect of＂stress strengthening mechanism＂for improving the FFR of LSFM/TSFM is disappeared basically.During shot peening,however,both of residual stress and cyclic plastic deformed microstructure are induced synchronously like＂twins＂in the surface layer of a spring.It has been found for the first time by means of force analysis and experimental results that the modified microstructure in the＂twins＂as a＂structure strengthening mechanism＂can improve the FFR of LSFM/TSFM.At the same time,it is;also shown that the optimum technology of shot peening strengthening must have both＂stress strengthening mechanism＂and＂structure strengthening mechanism＂simultaneously so that the FFR of both NTFM and LSFM/TSFM can be improved by shot peening.

Fatigue Resistance and Failure Behavior of Penetration and Non-Penetration Laser Welded Lap Joints

Penetration and non-penetration lap laser welding is the joining method for assembling side facade panels of railway passenger cars,while their fatigue performances and the difference between them are not completely understood.In this study,the fatigue resistance and failure behavior of penetration 1.5+0.8-P and non-penetration 0.8+1.5-N laser welded lap joints prepared with 0.8 mm and 1.5 mm cold-rolled 301L plates were investigated.The weld beads showed a solidification microstructure of primary ferrite with good thermal cracking resistance,and their hardness was lower than that of the plates.The 1.5+0.8-P joint exhibited better fatigue resistance to low stress amplitudes,whereas the 0.8+1.5-N joint showed greater resistance to high stress amplitudes.The failure modes of 0.8+1.5-N and 1.5+0.8-P joints were 1.5 mm and 0.8 mm lower lap plate fracture,respectively,and the primary cracks were initiated at welding fusion lines on the lap surface.There were long plastic ribs on the penetration plate fracture,but not on the non-penetration plate fracture.The fatigue resistance stresses in the crack initiation area of the penetration and non-penetration plates calculated based on the mean fatigue limits are 408 MPa and 326 MPa,respectively,which can be used as reference stress for the fatigue design of the laser welded structures.The main reason for the difference in fatigue performance between the two laser welded joints was that the asymmetrical heating in the non-penetration plate thickness resulted in higher residual stress near the welding fusion line.

A preliminary study on the anti-inflammatory and analgesic effects of two extracts of pine pollen on anoxia and fatigue resistance

Background:To study the anti-inflammatory,analgesic,fatigue resistant and antihypoxia effects of ethanol extract and water extract of pine pollen.Methods:Two different extracts of pine pollen were prepared into there different concentrations,that is 1.5 mg·mL^-1,4.5 mg·mL^-1 and 7.5 mg·mL^-1 respectively.The extract were studied by xylene-induced ear swelling,acetic acid distortion test and hot plate test.The antihypoxia and antifatigue effects were explored by weight-bearing swimming experiment,routine pressure hypoxia tolerance experiment and liver weight coefficient comparison.Results:Through the study of the four pharmacological effects of ethanol extract and water extract,we found that the anti-inflammatory,analgesic,antithyposia and antifatigue effects of ethanol extract were better than that of water extract.Moreover,the experimental effects significantly improved with the increase of the concentration,and the effect of alcohol increased dose group was accurate(P<0.05).Conclusion:Pine pollen has excellent effects of anti-inflammatory,analgesic,antihypoxia and anti-fatigue.Besides,with the increase of drug concentration,effects tend to be more obvious with positive correlation.

Thermal shock fatigue behavior of TiC/Al_2O_3 composite ceramics

The thermal shock fatigue behaviors of pure hot-pressed alumina and 30 wt.% TiC/Al2O3 composites were studied. The effect of TiC and Al2O3 starting particle size on the mechanical properties of the composites was discussed. Indentation-quench test was conducted to evaluate the effect of thermal fatigue temperature difference （ΔT） and number of thermal cycles （Ⅳ） on fatigue crack growth （Δa）. The mechanical properties and thermal fatigue resistance of TiC/Al203 composites are remarkably improved by the addition of TiC. The thermal shock fatigue of monolithic alumina and TiC/Al2O3 composites is due to a ＂true＂ cycling effect （thermal fatigue）. Crack deflection and bridging are the predominant reasons for the improvement of thermal shock fatigue resistance of the composites.

Low Cycle Fatigue and Strengthening Mechanism of Cold Extruded Large Diameter Internal Thread of Q460 Steel

large diameter internal thread of high-strength steel（LDITHSS） manufactured by traditional methods always has the problems of low accuracy and short life. Compared with traditional methods, the cold extrusion process is an effective means to realize higher accuracy and longer life. The low-cycle fatigue properties of LDITHSS are obtained by experiments, and the initiation and propagation of fatigue cracks are observed by scanning electron microscope（SEM）. Based on the mechanical properties, surface microstructure and residual stress, the strengthening mechanism of cold extruded large diameter internal thread（LDIT） is discussed. The results show that new grains or sub-grains can be formed on the surface of LDIT due to grain segmentation and grain refinement during cold extrusion. The fibrous structures appear as elongated and streamlined along the normal direction of the tooth surface which leads to residual compressive stress on the extruded surface. The maximum tension stress of LDIT after cold extrusion is found to be 192.55 k N. Under low stress cycling, the yield stress on thread increases, the propagation rate of crack reduces, the fatigue life is thus improved significantly with decreasing surface grain diameter and the average fatigue life increases to 45.539×10~3 cycle when the maximum applied load decreases to 120 k N. The low cycle fatigue and strengthening mechanism of cold extruded LDIT revealed by this research has significant importance to promote application of internal thread by cold extrusion processing.

A dissipated energy comparison to evaluate fatigue resistance using 2-point bending

Fatigue is the main failure mode in pavement engineering. Typically, micro-cracks originate at the bottom of asphalt concrete layer due to horizontal tensile strains. Micro-cracks start to propagate towards the upper layers under repeated loading which can lead to pavement failure. Different methods are usually used to describe fatigue behavior in asphalt materials such as： phenomenological approach, fracture mechanics approach and dissipated energy ap- proach. This paper presents a comparison of fatigue resistances calculated for different dissipated energy models using 2-point bending （2PB） at IFSTTAR in Nantes. 2PB tests have been undertaken under different loading and environmental conditions in order to evaluate the properties of the mixtures （stiffness, dissipated energy, fatigue life and healing effect）.

An ultrahigh fatigue resistant liquid crystal elastomer-based material enabled by liquid metal

The low crosslink density characteristic of liquid crystal elastomer(LCE)materials causes poor fatigue resistance performance,which has seriously plagued their prospects in industrial applications.Here we report that the introduction of 5 wt%liquid metal nanodroplets(average diameter:ca.195 nm)into the LCE network can dramatically reinforce the corresponding composite’s mechanical properties,in particular ultrahigh fatigue resistance,capable of bearing unprecedented 10,000 tensile cycles within a large range of strain amplitude up to 70%and 2000 times of continuous actuating deformations.Furthermore,this liquid metal-incorporated LCE composite material exhibits large actuation stroke(maximum actuation strain:55%),high actuation stress(blocking stress:1.13 MPa),fully reversible thermal/photo-actuation functions,and self-healing ability at moderate temperatures,which qualifies the composite material for high-load actuators.

Effect of Functional Chemical Admixtures on the Performance of Cement Asphalt Mortar Used in Ballastless Track

Chemical admixtures are of paramount importance to the performance of modern cement based composites. In this paper, we performed a series of tests to investigate the effects of chemical admixtures on the cement asphalt mortar(CA mortar), i e, compressive strength, frost resistance, permeability, fatigue resistance, pore structure and microstructure. In particular, two types of chemical admixtures were tested, i e, defoamer(tributyl phosphate(TBP)) and polycarboxylate superplasticizer(PS). The results indicate that the addition of TBP and PS eliminates big bubbles and promotes small non-connected pores forming in matrix. Besides, an optimum dosage of TBP and PS may be determined with respect to the frost resistance, permeability and fatigue resistance of CA mortar. Further elaborative discussions are presented as well as experimental evidences from mercury intrusion porosimetry, scanning electron microscopy and energy dispersive spectroscopy.

Rheological Evaluation of Polymer Modified Asphalt Binders

The microstructure and dynamic rheological characteristics of asphalt containing different polymer modifiers （crumb rubber, styrene-butadiene-styrene and crumb rubber mix with styrene- butadiene-styrene） at mid and high service temperature levels were investigated by using scanning electron microscopy（SEM）, dynamic shear rheometer（DSR） and repeat creep test. The main objective of the investigation was to rank the modifiers based on their effect on performance characteristics of asphalt under service conditions. To evaluate the effect of different modifiers on the viscoelastic response of asphalt, the temperature and frequency dependences of the dynamic viscoelastic properties were compared. The mid-temperature fatigue resistance and high-temperature rutting resistance of three polymer modified asphalts were evaluated to predict their field performance in roads. Based on the current results, an improved rutting factor was proposed to determine the rutting resistance of asphalt pavements. In addition, the viscous stiffness （Gv）, defined as the reciprocal of viscous compliance, was used to evaluate the high-temperature deformation resistance of asphalt mixtures. The experimental results indicate that the asphalt containing crumb rubber only shows superior performance at mid and high service temperatures in all three modified asphalt binders due to the action of the crumb rubber.

Fatigue‑Resistant and Hysteresis‑Free Composite Fibers with a Heterogeneous Hierarchical Structure

Fatigue-resistant and hysteresis-free composite fibers hold great promise for the next generation of wearable electronic devices.In this study,a novel approach for the fabrication of composite fibers with outstanding elasticity and mechanical stability is proposed.The design incorporates a heterogeneous hierarchical structure(HHS),which mimics the structure of arteries,to achieve enhanced fatigue resistance and hysteresis-free performance.The composite fibers,Ecoflex-polyacrylamide fibers(EPFs),are created through the combination of heterogeneous elastomers and strong interfacial coupling.The results show that the EPFs exhibit exceptional fatigue resistance,being able to withstand up to 10,000 load–unload cycles at strains of 300%without any noticeable changes in their mechanical properties.The potential applications of these EPFs are demonstrated through their use as strain sensors for monitoring human motion in both air and water,as well as in energyharvesting e-textiles.

PHOTOCHROMIC PROPERTIES OF (E)-DICYCLOPROPYLMETHYLENE-(2,5-DIMETHYL-3-FURYLETHYLIDENE)-SUCCINIC ANHYDRIDE DOPED IN POLYSTYRENE THIN FILMS

Fulgide 1-E doped in polystyrene polymer films was heated at various annealing temperatures.Upon irradiation with UV light(366 nm),fulgide 1-E undergoes a conrotatory ring closure to the pink colored closed form 1-C.The later color was switched back to the original color when the films were irradiated with white light.The kinetics of photocoloration and photobleaching processes were followed spectrophotometrically by monitoring the absorbance of the ring closed product 1-C at itsλ_(max) of 525 nm.The first-...

SYNTHESIS AND PHOTOCHROMISM OF ACRYLIC ESTER COPOLYMERS BEARING PENDANT VIOLOGEN GROUPS

A series of acrylic ester copolymers with viologen group as pendant were synthesizedthrough the reaction of MMA-EBA (Ethenyl bromoacetate) copolymer with 4-(4'-pyridyl)-N-alkyl (or arylalkyl) pyridiniums. These viologen copolymers can exchange their anionwith NH_4PF_6 in methanol to improve their solubility in organic solvents such as DMFand acetone. Compared with the corresponding low molecular viologens, these viologencopolymers have relatively lower color development rate under UV light and fade fasterin air due to less affinity to photo-reductant and deficiency of association between theircation radicals. Their photofatigue resistant ability is also slightly better than that of lowmolecular vinlogens.

Stretchable alkaline quasi-solid-state electrolytes created by super-tough, fatigue-resistant and alkali-resistant multi-bond network hydrogels

Hydrogel-based quasi-solid-state electrolytes(Q-SSEs) swollen with electrolyte solutions are important components in stretchable supercapacitors and other wearable devices. This work fabricates a supertough, fatigue-resistant, and alkali-resistant multi-bond network(MBN) hydrogel aiming to be an alkaline Q-SSE. To synthesize the hydrogel, a 2-ureido-4[1H]-pyrimidone(UPy) motif is introduced into a poly(acrylic acid) polymer chain. The obtained MBN hydrogels with 75 wt% water content exhibit tensile strength as high as 2.47 MPa, which is enabled by the large energy dissipation ability originated from the dissociation of UPy dimers due to their high bond association energy. Owing to the high dimerization constant of UPy motifs, the dissociated UPy motifs are able to partially re-associate soon after being released from external forces, resulting in excellent fatigue-resistance. More importantly, the MBN hydrogels exhibit excellent alkali-resistance ability. The UPy Gel-10 swollen with 1 mol/L KOH display a tensile strength as high as ~1.0 MPa with elongation at break of ~550%. At the same time, they show ionic conductivity of ~17 m S/cm, which do not decline even when the hydrogels are stretched to 500% strain.The excellent mechanical property and ionic conductivity of the present hydrogels demonstrate potential application as a stretchable alkaline Q-SSE.

Highly resilient and fatigue-resistant poly(4-methyl-ε-caprolactone)porous scaffold fabricated via thiol-yne photo-crosslinking/salt-templating for soft tissue regeneration

Elastomeric scaffolds, individually customized to mimic the structural and mechanical properties of natural tissues have been used for tissue regeneration. In this regard, polyester elastic scaffolds with tunable mechanical properties and exceptional biological properties have been reported to provide mechanical support and structural integrity for tissue repair. Herein, poly(4-methyl-ε-caprolactone) (PMCL) was first double-terminated by alkynylation (PMCL-DY) as a liquid precursor at room temperature. Subsequently, three-dimensional porous scaffolds with custom shapes were fabricated from PMCL-DY via thiol-yne photocrosslinking using a practical salt template method. By manipulating the Mn of the precursor, the modulus of compression of the scaffold was easily adjusted. As evidenced by the complete recovery from 90% compression, the rapid recovery rate of >500 mm min 1, the extremely low energy loss coefficient of <0.1, and the superior fatigue resistance, the PMCL20-DY porous scaffold was confirmed to harbor excellent elastic properties. In addition, the high resilience of the scaffold was confirmed to endow it with a minimally invasive application potential. In vitro testing revealed that the 3D porous scaffold was biocompatible with rat bone marrow stromal cells (BMSCs), inducing BMSCs to differentiate into chondrogenic cells. In addition, the elastic porous scaffold demonstrated good regenerative efficiency in a 12-week rabbit cartilage defect model. Thus, the novel polyester scaffold with adaptable mechanical properties may have extensive applications in soft tissue regeneration.

Rheological Properties and Microstructure of Printed Circuit Boards Modified Asphalt

The asphalt modifed with different printed circuit boards （PCBs） content （0, 5%, 10%, and 15%） was prepared in this study. The general properties, rheological properties, temperature sensitivity, fatigue resistance, and morphology of the PCBs modifed asphalt were investigated by conventional tests, the Brookfeld viscometry tests, the dynamic shear rheometer （DSR） tests, the bending beam rheometer （BBR） tests, and the fuorescence microscopy tests. And the infuence of PCBs content on the above-mentioned properties was analyzed systematically. The results showed that the addition of PCBs could improve the high temperature performance, the low temperature performance, and the temperature sensitivity property of the modifed asphalt, while compromising with the fatigue resistance of the modifed asphalt. With the increase of PCBs content, the modifed asphalt could have better softening points, viscosity, failure temperature, and temperature sensitivity, while its low temperature performance and fatigue resistance became worse to different degree. And the particle size of PCBs became bigger and non-uniform with an increasing PCBs content. According to the above-mentioned properties, the optimum PCBs content was specifed at less than 10% in the modifed asphalt system.

Fatigue resistance of ProTaper gold exposed to high-concentration sodium hypochlorite in double curvature artificial canal

This study aimed to evaluate and compare the fatigue resistance of ProTaper Gold(PTG)and ProTaper Universal(PTU)in artificial single and double curvature canals in 5%sodium hypochlorite(NaOCl)at body temperature(37℃).PTG and PTU files(size F1)were subjected to fatigue tests in two different artificial ceramic canals.The single curvature model had a 60°curvature angle with a 5mm radius.The double curvature model had a 60°curvature angle with a 5mm radius and a second 30°curvature with a 2mm radius.A file segment was introduced into the artificial canal and immersed in water or 5%NaOCl at 37℃.The total number of cycles to fracture(NCF)was recorded.Data were analyzed using t-test and linear regression analysis.The NCF of all files was significantly influenced by the type of NiTi metal alloy(P<.01),canal curvatures(P<.01),and the environmental conditions(P<.05).PTG had higher fatigue resistance than PTU files in both single and double curvature canals(P<.05).The NCF of PTU files in 5%NaOCl was shorter than that in water(P<.05).The mean length of broken PTG was significantly shorter than those of PTU files in both single and double curvature canals(P<.01).The fatigue performance of PTG is better than that of PTU in both single and double curvature.Environmental conditions may affect the fatigue behavior of PTU files with single curvature.

Mechanic Analysis of the Key Node in Steel Truss Bridge

Steel truss bridges are frequently used in bridge engineering because of their good ability of spanning capacity, construction and light self-weight. Main trusses are the critical component of steel truss bridge and the main truss are made of truss members linked by integral joints. This paper presents the mechanic performance of key joints, and the codified design of joints in steel truss girders according to the latest European norms. The results showed that the fatigue resistance of welded joints evaluation is necessary to predict, detect, and repair the crack in time for the safety service life of the bridge. The stresses of integral joint are greater than that of truss members;the stresses in the center area of the integral joint are greater than the stress at the edge.

American Ginseng Teaand Resist in Fatigue

The fatigue is a main factor to endanger the human health in the 21st century. In the current society, because the rhythm of life is accelerated and overworked for a long time or beared greater psychological pressure for a long time, if not rest reasonable

The Influence of Trans-1,4-poly(butadiene-co-isoprene) Copolymer Rubbers(TBIR) with Different Molecular Weights on the NR/TBIR Blends

The molecular weight of a polymer is of prime importance and greatly influences the processing and mechanical properties of the polymer. Trans-1,4-poly(butadiene-co-isoprene) multi-block copolymer rubbers(TBIR) exhibit outstanding fatigue resistance, low heat build-up and good abrasion resistance, and are expected to be desirable candidate for high performance tire. Study on the influence of TBIR with different molecular weights on the structure and properties of TBIR and natural rubber(NR)/TBIR blends is essential to understand its contribution to the greatly improved dynamic properties of the rubber vulcanizates. TBIR with different molecular weights characterized by 1H-NMR, 13C-NMR, GPC, and DSC were highly trans-1,4-copolymers with similar chain sequence distribution and crystalline trans-1,4-polyisoprene(TPI) blocks. The green strength and modulus of TBIR increased with the increasing molecular weight.The NR/TBIR compounds filled with 40 phr carbon black were chemically cured by sulfur for the preparation of NR/TBIR vulcanizates.The compatibility between NR and TBIR, filler distribution, crosslinking bond and density, and properties of NR/TBIR vulcanizates were studied. The NR/TBIR vulcanizates showed increasing tensile strength, hardness, modulus, rebound, abrasion resistance, and flexural fatigue properties with increasing molecular weight of TBIR. Furthermore, they presented significant improvement in flexural fatigue resistance when compared with that of NR vulcanizate. The contribution mechanism of TBIR on the NR/TBIR blends was discussed. The TBIR with a wide range of molecular weight are ideal rubbers for high performance tires.