The surface pressure-Area isotherms of Reversed Duckweed amphiphili polymer were examined in view of their chemical structure and two- dimentional properties of polymer monolayer were studied.
Based on the study of a new type of conducting polymer poly （3,4-ethylenedioxythiophene） （PEDOT）,we focussed on the preparation and characteristics of PEDOT nanoparticles made by reversed micelle method.Moreover,w...Based on the study of a new type of conducting polymer poly （3,4-ethylenedioxythiophene） （PEDOT）,we focussed on the preparation and characteristics of PEDOT nanoparticles made by reversed micelle method.Moreover,we deeply investigated the optical,electrical and the thermal stability of PEDOT nanoparticles.The main results are as follows： the small-sized PEDOT nanoparticles were prepared and utilized by different methods,such as ultraviolet/visible （UV-Vis） spectroscopy,Fourier-transform infrared （FT- IR） spectrum,scanning electron microscopy（SEM） and so on.The results show that the amount of oxidizer,ultrasonic treatment,polymerizing temperature and doping degree can influent morphology,electrical ability and gas sensitivity of PEDOT nanoparticles.The Bragg peaks of nanoparticles at 6.7°,12.7°,25° were observed by XRD and the better orientation of molecular chain was attributed to the effective doping of toluene-p-sulfonic acid,which also resulted in an enhancement of thermal stability of nanoparticles than conventional PEDOT.展开更多
Green and low cost CO_(2) and CaO were used to stimulate amine emulsions to reveal the responsive behavior of amine emulsions.On this basis,oil-based drilling fluids responsive to CO_(2) and CaO were formulated and th...Green and low cost CO_(2) and CaO were used to stimulate amine emulsions to reveal the responsive behavior of amine emulsions.On this basis,oil-based drilling fluids responsive to CO_(2) and CaO were formulated and their properties were evaluated.The results showed that the amine emulsions inversed from water-in-oil state to oil-in-water state readily and their rheological behavior underwent transitions of decreasing,rising again and decreasing again via induction by CO_(2).These CO_(2) responsive behaviors could be reversed by CaO.Oil-based drilling fluids prepared based on the amine emulsions with oil-water volume ratios of 50:50 to 70:30,densities of 1.4-2.0 g/cm^(3) had good rheological and filtration properties at 160℃;and be readily cleaned up using CO_(2) bubbling.The useless solid phase with low density could be removed efficiently via reducing the viscosity of emulsion by CO_(2) and the residual liquid phase could be restored to the original state by CaO and reused to prepare drilling fluid.The mechanisms analysis indicated that CO_(2)/CaO induced the reversible conversion between amine emulsifiers and their salts,which enabled the reversible regulation of both the hydrophilic-lipophilic balance of amine emulsifiers and the emulsion particles’size and finally caused the controllable-reversion of the form and rheology of amine emulsion.展开更多
Magnetic properties and magnetization processes of Co nanowire arrays with various packing densities are investigated by means of object-oriented micromagnetic framework（OOMMF） software package with finite differenc...Magnetic properties and magnetization processes of Co nanowire arrays with various packing densities are investigated by means of object-oriented micromagnetic framework（OOMMF） software package with finite difference micromagnetic simulations. The packing density of nanowires is changed with the diameter, number of nanowires and center-to-center spacing between the wires. The magnetization reversal mechanism and squareness of the hysteresis loops of the nanowire arrays are very sensitive to the packing density of nanowires. Clear steps and plateaux on the demagnetization are visible,which turns out that dipolar interactions among the wires have a significant influence on switching field.展开更多
Two novel compounds {[Cu（IBG）（4,4-bipy）（H2O）2]2·11H2O}n（1） and {[Co（IBG）-（μ-H2O）（H2O）2]·2H2O}n（2） based on isophthaloylbisglycine（H2IBG） have been synthesized and structurally characterize...Two novel compounds {[Cu（IBG）（4,4-bipy）（H2O）2]2·11H2O}n（1） and {[Co（IBG）-（μ-H2O）（H2O）2]·2H2O}n（2） based on isophthaloylbisglycine（H2IBG） have been synthesized and structurally characterized by thermogravimetric analysis, elemental analysis and single-crystal X-ray diffraction. Compound 1 shows a 1D chain sine/cosine chain structure, and compound 2 can be characterized as a 4-connected sql tetragonal planar network with the point symbol of {44·62}. Compound 2 has been characterized by magnetic measurements. In addition, 1 and 2 display an interesting reversible crystal-to-amorphous transformation.展开更多
Channel capacity is a core problem in information theory[1,2].The capacity of a classical channel is essentially characterized by maximum transmission rate of classical information[1].However,in quantum information th...Channel capacity is a core problem in information theory[1,2].The capacity of a classical channel is essentially characterized by maximum transmission rate of classical information[1].However,in quantum information theory,several capacities can be defined for a quantum channel based on the type of information being sent.Currently,classical capacity[3,4],entanglement-assisted classical capacity[5],quantum capacity[6,7],and private capacity[7]are used to展开更多
文摘The surface pressure-Area isotherms of Reversed Duckweed amphiphili polymer were examined in view of their chemical structure and two- dimentional properties of polymer monolayer were studied.
基金Funded by the National Natural Science Foundation of China (No. 60372002)
文摘Based on the study of a new type of conducting polymer poly （3,4-ethylenedioxythiophene） （PEDOT）,we focussed on the preparation and characteristics of PEDOT nanoparticles made by reversed micelle method.Moreover,we deeply investigated the optical,electrical and the thermal stability of PEDOT nanoparticles.The main results are as follows： the small-sized PEDOT nanoparticles were prepared and utilized by different methods,such as ultraviolet/visible （UV-Vis） spectroscopy,Fourier-transform infrared （FT- IR） spectrum,scanning electron microscopy（SEM） and so on.The results show that the amount of oxidizer,ultrasonic treatment,polymerizing temperature and doping degree can influent morphology,electrical ability and gas sensitivity of PEDOT nanoparticles.The Bragg peaks of nanoparticles at 6.7°,12.7°,25° were observed by XRD and the better orientation of molecular chain was attributed to the effective doping of toluene-p-sulfonic acid,which also resulted in an enhancement of thermal stability of nanoparticles than conventional PEDOT.
基金Suppported by National Natural Science Foundation of China(NO.51804263)Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(NO.2020CX040102,NO.2020CX040201)。
文摘Green and low cost CO_(2) and CaO were used to stimulate amine emulsions to reveal the responsive behavior of amine emulsions.On this basis,oil-based drilling fluids responsive to CO_(2) and CaO were formulated and their properties were evaluated.The results showed that the amine emulsions inversed from water-in-oil state to oil-in-water state readily and their rheological behavior underwent transitions of decreasing,rising again and decreasing again via induction by CO_(2).These CO_(2) responsive behaviors could be reversed by CaO.Oil-based drilling fluids prepared based on the amine emulsions with oil-water volume ratios of 50:50 to 70:30,densities of 1.4-2.0 g/cm^(3) had good rheological and filtration properties at 160℃;and be readily cleaned up using CO_(2) bubbling.The useless solid phase with low density could be removed efficiently via reducing the viscosity of emulsion by CO_(2) and the residual liquid phase could be restored to the original state by CaO and reused to prepare drilling fluid.The mechanisms analysis indicated that CO_(2)/CaO induced the reversible conversion between amine emulsifiers and their salts,which enabled the reversible regulation of both the hydrophilic-lipophilic balance of amine emulsifiers and the emulsion particles’size and finally caused the controllable-reversion of the form and rheology of amine emulsion.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51401001,51371002,and 51331003)the International S&T Cooperation Program of China(Grant No.2015DFG52020)
文摘Magnetic properties and magnetization processes of Co nanowire arrays with various packing densities are investigated by means of object-oriented micromagnetic framework（OOMMF） software package with finite difference micromagnetic simulations. The packing density of nanowires is changed with the diameter, number of nanowires and center-to-center spacing between the wires. The magnetization reversal mechanism and squareness of the hysteresis loops of the nanowire arrays are very sensitive to the packing density of nanowires. Clear steps and plateaux on the demagnetization are visible,which turns out that dipolar interactions among the wires have a significant influence on switching field.
基金supported by the National Natural Science Foundation of China(No.2137109291022011)+1 种基金National Basic Research Program of China(2010CB923303)the Universities Natural Science Research Project of Anhui Province(No.KJHS2017B05)
文摘Two novel compounds {[Cu（IBG）（4,4-bipy）（H2O）2]2·11H2O}n（1） and {[Co（IBG）-（μ-H2O）（H2O）2]·2H2O}n（2） based on isophthaloylbisglycine（H2IBG） have been synthesized and structurally characterized by thermogravimetric analysis, elemental analysis and single-crystal X-ray diffraction. Compound 1 shows a 1D chain sine/cosine chain structure, and compound 2 can be characterized as a 4-connected sql tetragonal planar network with the point symbol of {44·62}. Compound 2 has been characterized by magnetic measurements. In addition, 1 and 2 display an interesting reversible crystal-to-amorphous transformation.
基金supported by the National Natural Science Foundation of China(Grant Nos.61671280,and 11531009)the Natural Science Basic Research Plan in Shaanxi Province of China(Grant No.2017KJXX-92)+1 种基金the Fundamental Research Funds for the Central Universities(Grant No.GK201502004)the Funded Projects for the Academic Leaders and Academic Backbones,Shaanxi Normal University(Grant No.16QNGG013)
文摘Channel capacity is a core problem in information theory[1,2].The capacity of a classical channel is essentially characterized by maximum transmission rate of classical information[1].However,in quantum information theory,several capacities can be defined for a quantum channel based on the type of information being sent.Currently,classical capacity[3,4],entanglement-assisted classical capacity[5],quantum capacity[6,7],and private capacity[7]are used to
