A RHEOLOGICAL MODEL FOR POLYMER MELTS WITH INTERNAL STRUCTURE IN FLOW FIELDS

Conceptually, an imagined conformation ellipsoid is supposed to represent the shape of a polymer chain for polymer melts in flow fields and to be equivalent to the volume element in a mathematical sense in continuum mechanics. A power law dependence of shear modulus of polymer melts on detC, referred to as envelope volume, is proposed. Based on those assumptions and the non-linear relation of shear modulus, a phenomenological viscoelastic model is derived. The model is tested in simple shear flow, simple elongational flow, oscillatory shear flow, and relaxation process after flow suddenly stopped. The results show that the model works well to predict the change of internal structure and viscoelastic performance of polymer melts in flow fields.

A Nonlinear Rheological Model of Soft Clay and Its Application in Settlement of Sunk Ship

A one-dimensional consolidation-creep model test on the creep deformation of soft muddy clay in the littoral area of Tianjin is performed. A nonlinear rheologic model is established and the model coefficients are determined, in consideration of the characteristics of soft muddy clay. Furthermore, a settlement equation is deduced from the theologic model and verified by the field settlement measurements of Beitang Reservoir dam in Tianjin littoral area. Finally, the settlement e- quation is applied in calculating the settlement of ＂FAIRWAY-＂ suction dredger, which sunk in the external channel of Tianjin Port, induced by the soft clay consolidation of seabed. These results provide useful information for the decision of salvage plan.

ON THE RHEOLOGICAL MODEL OF STEELS AT ELEVATED TEMPERATURES

Mechanical properties of steels ZG15CrMoV and 35 in the temperature range of 500 to 1400℃ have been experimently researched by means of Gleeble-1500.The experi- mental results is used as input-output responses,a rhelological model with five elements of the mechanical behaviour of steels ZG15CrMoV and 35 at elevated temperatures, i.e[M]=[H_1]-[H_2/[N_2]-[S/N_3],is determined by a system identification method,and the parameters of the model in the temperature range are also identified.

High temperature and high pressure rheological properties of high-density water-based drilling fluids for deep wells

To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids （fresh water-based and brine-based） under high temperature and high pressure （HTHP） with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site.

Rheological Behavior of Basalt Fiber Reinforced Asphalt Mastic

The characters of basalt fiber are analyzed and compared with commonly used fibers. The rheological behaviors of the basalt fiber reinforced asphalt mastic are investigated by the dynamic shear rheological tests and the repeated creep tests. The results show that basalt fiber has excellent reinforced performances, such as high asphalt absorption ratio, low water absorption ratio, high tensile strength, high elastic modulus and high temperature stability. The rutting factor of the fiber reinforced asphalt mastic is higher than the plain asphalt mastic and the reinforced effects are more remarkable under high temperature. The rheological performances of the asphalt mastic demonstrate a good linear relationship between different temperature and loading frequency. The creep stiffness modulus of the asphalt mastic at different loading time can be expressed by power function. Improved Burgers model is used to represent the rheological behaviors of the asphalt mastic with basalt fiber and the model parameters are estimated.

Theoretical analysis of the spatio-temporal evolution of the bulk-strain field based on a rheologic inclusion model

Based on the theoretical expression of the three-dimension rheologic inclusion model, we analyze in detail the spatio-temporal changes on the ground of the bulk-strain produced by a spherical rheologic inclusion in a semi-infinite rheologic medium. The results show that the spatio-temporal change of bulk-strain produced by the hard inclusion has three stages of different characteristics, which are similar to most of those geodetic deformation curves, but those by a soft inclusion do not. The α-stage is a long stage in which the precursors in both the near source region and the far field develop from the focal region to the periphery. The β-stage indicates a very rapid propagation of the precursors, so that they almost appear everywhere. During the γ-stage, the precursors in the far-field converge from the periphery, and the precursors in the near source region develop outwards. The theoretical results have been used to explain tentatively the stage characteristics of the spatio-temporal change of earthquake precursors.

Investigation into the effect of silica nanoparticles on the rheological characteristics of water-in-heavy oil emulsions

The effect of silica nanoparticles on the rheological characteristics of water-in-heavy oil emulsions has been investigated.Enhanced oil recovery methods for heavy oil production(most especially,thermal fluid injection)usually result in the formation of water-in-oil(W/O)emulsion.In reality,the emulsion produced also contains some fine solid mineral particles such as silica,which,depending on its quantity,may alter the viscosity and/or rheological properties of the fluid.A series of binary-component emulsions were separately prepared by dispersing silica nanoparticles[phase fraction,βs,=0.5%–5.75%(wt/v)]in heavy oil(S/O suspension)and by dispersing water[water cut,θw=10%–53%(v/v)]in heavy oil(W/O emulsion).Ternary-component emulsions comprising heavy oil,water droplets and suspended silica nanoparticles(S/W/O)were also prepared with similar ranges ofθw andβs.The viscosity was measured at different shear rates(5.1–1021.4 s-1)and temperatures(30–70°C).Both binary-component and ternary-component emulsion systems were observed to exhibit nonNewtonian shear thinning behaviour.The viscosity of the heavy oil and W/O emulsions increased in the presence of silica nanoparticles.The effect was,however,less signifi cant belowβs=2%(wt/v).Moreover,a generalized correlation has been proposed to predict the viscosity of both binary-component and ternary-component emulsions.

Numerical Modeling of Water Wave Interaction with A Soft Mud Bed

A vertical 2-D numerical model is presented for simulating the interaction between water waves and a soft mud bed. Taking into account nonlinear rheology, a semi-empirical rheological model is applied to this water-mud model, reflecting the combined visco-elasto-plastic properties of soft mud under such oscillatory external forces as water waves. In order to increase the resolution of the flow in the neighborhood of both sides of the inter-surface, a logarithmic grid in the vertical direction is employed for numerical treatment. Model verifications are given through comparisons between the calculated and the measured mud mass transport velocities as well as wave height changes.

Numerical analysis of submarine landslides using a smoothed particle hydrodynamics depth integral model

Submarine landslides can cause severe damage to marine engineering structures. Their sliding velocity and runout distance are two major parameters for quantifying and analyzing the risk of submarine landslides.Currently, commercial calculation programs such as BING have limitations in simulating underwater soil movements. All of these processes can be consistently simulated through a smoothed particle hydrodynamics（SPH） depth integrated model. The basis of the model is a control equation that was developed to take into account the effects of soil consolidation and erosion. In this work, the frictional rheological mode has been used to perform a simulation study of submarine landslides. Time-history curves of the sliding body＇s velocity, height,and length under various conditions of water depth, slope gradient, contact friction coefficient, and erosion rate are compared; the maximum sliding distance and velocity are calculated; and patterns of variation are discussed.The findings of this study can provide a reference for disaster warnings and pipeline route selection.

Utilization of Bitter Orange Seed as a Novel Pectin Source:Compositional and Rheological Characterization

The seeds from bitter orange,the by-product of juice making units,hold the potential to facilitate novel,easy yet high-quality pectin extraction.To test this hypothesis,orange seed pectin(OSP)was extracted by distilled water and its compositional parameters and rheological behavior were then evaluated.Results showed that galacturonic acid was the major component of OSP(∼425 mg/g)confirming the purity of the extracted pectin,followed by glucose and some minor neutral sugars.The Mw(weight-average molar mass),Rn(number average molar mass),and Rz(z-average molar mass)values for the OSP were 4511.8 kDa,61 nm,and 61.1 nm,respectively.Rheological measurements showed a shear-thinning behavior for OSP so that the viscosity of the gum decreased by increasing the temperature from 5 to 45℃.The Power-law model fitted as the best rheological model describing the flow behavior of OSP.The strain sweep dynamic rheological measurements confirmed an entangled network structure for OSP and the NaCl addition to the gum dispersion decreased the consistency coefficient from 35.6 to 23.18 Pa.sn,while the flow behavior index remained unchanged.These results demonstrate that the OSP can be used as a new source of pectin,with likely a wide range of applications in the food industry.

Rheological Behaviour of Steel ZG15CrMoV and Carbon Steel 35 at High Temperatures

1.IntroductionModeling of metallic materials pro-cesses has been developed rapidly during thelast quarter century to meet the needs forbetter components to provide higher stand-ards of performance and reliability inservice.But,up to now,design and mod-

Study on Rheological Characteristics of a Grease Used in High Speed Bearing

On a self-made super-high shear strain rate rheometer, the rheological characteristics and apparent viscosity curves of a high-speed bearing grease were obtained under different working conditions. A new grease rheological model suited to a shear strain rate range of 0—3.5×10~6s^(-1) was presented. The results showed that the shear stress increased linearly at first and then increased nonlinearly with the increase in shear strain rate up to 1.5×10~6s^(-1), and finally the shear stress decreased slightly with the successive increase in shear strain rate. The shear stress increased with a decreasing rolling speed and an increasing contact pressure. The apparent viscosity decreased rapidly with the increase of shear strain rate at beginning and could approach the viscosity of the base oil if the shear strain rate surpassed 1.5×10~6s^(-1). The fits between the test data and the predicted values by the new model were fairly good.

Dynamic properties of structures with dampers modelled using fractional order derivatives

The focus of this paper is on determination of the dynamic parameters of structural systems with viscoelastic (VE) dampers described by Maxwell rheological models. Such parameters could be obtained after solving the appropriately defined nonlinear eigenvalue problem for frames with VE dampers. The solution to the nonlinear eigenvalue problem is obtained by equating to zero the determinant of the considered system of equations. Apart from complex conjugate eigenvalues, the real ones occurred when dampers that are described by the classic Maxwell model, are also determined.

Numerical investigation into pillar failure induced by time-dependent skin degradation

This paper focuses on the instability mechanism of an isolated pillar, caused by time-dependent skin degradation and strength heterogeneity. The time-dependent skin degradation is simulated with a non-linear rheological model capable of simulating tertiary creep, whereby two different pillar failure cases are investigated. The first case is of an isolated pillar in a deep hard rock underground mine and subjected to high stresses. The results show that pillar degradation is limited to the regions near the surface or the skin until two months after ore extraction. Afterwards degradation starts to extend deeper into the pillar, eventually leaving a highly-stressed pillar core due to stress transfer from the failed skin.Rockburst potential indices show that the risk increases exponentially at the core as time goes by. It is then demonstrated that the progressive skin degradation cannot be simulated with conventional strain-softening model assuming brittle failure. The parametric study with respect to the degree of heterogeneity reveals that heterogeneity is key to the occurrence of progressive skin degradation. The second case investigated in this study is pillar failure taking place in a very long period. Such failure becomes significantly important when assessing the risk for ground subsidence caused by pillar collapse in an abandoned mine. The analysis results demonstrate that the employed non-linear rheological model can simulate gradual skin degradation taking place over several hundred years. The percentage of damage zone volume within the pillar is merely 1% after a lapse of one days and increases to 50% after one hundred years, indicating a high risk for pillar collapse in the long term. The vertical displacements within the pillar also indicate the risk of subsidence. The proposed method is suitable for evaluating the risk of ground surface subsidence above an abandoned mine.

Methods for Calculation of Geogenetic Depth

Some current methods for the calculation of the geogenetic depth are based on the hydrostatic model, it is induced that the depth in certain underground place is equal to the pressure divided by the specific weight of rock, on the assumption that the rock is hydrostatic and overlain by no other force but gravity. However, most of rock is in a deformation environment and non hydrostatic state, especially in an orogenic belt, so that the calculated depth may be exaggerated in comparison with the actual depth according to the hydrostatic formula. In the finite slight deformation and elastic model, the relative actual depth value from the 3 axis strain data was obtained with the measurement of strain including that of superimposed tectonic forces but excluding that of time factor for the strain. If some data on the strain speed are obtained, the depth would be more realistically calculated according to the rheological model because the geological body often experiences long term creep strains.

Time-dependent squeezing deformation mechanism of tunnels in layered soft-rock stratum under high geo-stress

Large squeezing deformation of layered soft rock tunnel under high geo-stress has a significant time-dependent deformation behavior.In this paper,we studied the deformation mechanism during the construction period of deep-buried softrock tunnel by means of a combination of field observations and a numerical method.First,a new classification criterion for large deformations based on the power exponent variation law between the deformation and the strength-stress ratio is proposed.Then,the initial damage tensor reflecting the bedding plane(joint)distribution and an equivalent damage evolution equation derived from the viscoplastic strain are introduced based on the geometric research method,i.e.,a new rheological damage model(RDL model)of layered soft rock is established consisting of elastic,viscous,viscoelastic,viscoplastic and plastic elements.A field test was conducted on the Maoxian tunnel in Sichuan province,southwestern China,which is in broken phyllite(layered soft rock)under high geo-stress.The tunnel has experienced large deformation due to serious squeezing pressure,thus we adopted double primary support method to overcome the supporting structure failure problems.The rheological parameters of phyllite in the Maoxian tunnel were recognized by using SA-PSO optimization,and the RDL model does a good job in describing the time-dependent deformation behavior of a layered soft-rock tunnel under high geo-stress.Thus,the RDL model was used to investigate the supporting effect and bearing mechanism of the double primary support method.Compared with the single primary support method,the surrounding rock pressure,secondary lining force,surrounding rock deformation,and the depth of the damage to the rock mass was reduced by 40%-60%after the double primary support method was used.

Recycled materials in railroad substructure: an energy perspective

Given that the current ballasted tracks in Australia may not be able to support faster and significantly heavier freight trains as planned for the future,the imminent need for innovative and sustainable ballasted tracks for transport infrastructure is crucial.Over the past two decades,a number of studies have been conducted by the researchers of Transport Research Centre(TRC)at the University of Technology Sydney(UTS)to investigate the ability of recycled rubber mats,as well as waste tyre cells and granulated rubber to improve the stability of track substructure including ballast and subballast layers.This paper reviews four applications of these novel methods,including using recycled rubber products such as CWRC mixtures(i.e.,mixtures of coal wash(CW)and rubber crumbs(RC))and SEAL mixtures(i.e.,mixtures of steel furnace slag,CW and RC)to replace subballast/capping materials,tyre cells reinforcements for subballast/capping layer and under ballast mats;and investigates the energy dissipation capacity for each application based on smallscale cyclic triaxial tests and large-scale track model tests.It has been found that the inclusion of these rubber products increases the energy dissipation effect of the track,hence reducing the ballast degradation efficiently and increasing the track stability.Moreover,a rheological model is also proposed to investigate the effect of different rubber inclusions on their efficiency to reduce the transient motion of rail track under dynamic loading.The outcomes elucidated in this paper will lead to a better understanding of the performance of ballast tracks upgraded with resilient rubber products,while promoting environmentally sustainable and more affordable ballasted tracks for greater passenger comfort and increased safety.

Application of a weakly compressible smoothed particle hydrodynamics multi-phase model to non-cohesive embankment breaching due to flow overtopping

The subject of present study is the application of mesh free Lagrangian two-dimensional non-cohesive sediment transport model applied to a two-phase flow over an initially trapezoidal-shaped sediment embankment. The governing equations of the present model are the Navier-Stocks equations solved using Weakly Compressible Smoothed Particle Hydrodynamics （WCSPH） method. To simulate the movement of sediment particles, the model considers a powerful two-part technique; when the sediment phase has rigid behavior, only the force term due to shear stress in the Navier-Stokes equations is used for simulation of sediment particles＇ movement. Otherwise, all the Navier-Stokes force terms are used for transport simulation of sediment particles. In the present model, the interactions between different phases are calculated automatically, even with considerable difference between the density and viscosity of phases. Validation of the model is performed using simulation of available laboratory experiments, and the comparison between computational results and experimental data shows that the model generally predicts well the flow propagation over movable beds, the induced sediment transport and bed changes, and temporal evolution of embankment breaching.

Performance prediction of magnetorheological fluid‐based liquid gating membrane by kriging machine learning method

Smart liquid gating membrane is a responsive structural material as a pressure-driven system that consists of solid membrane and dynamic liquid,responding to the external field.An accurate prediction of rheological and mechanical properties is important for the designs of liquid gating membranes for various applications.However,high predicted accuracy by the traditional sequential method requires a large amount of experimental data,which is not practical in some situations.To conquer these problems,artificial intelligence has promoted the rapid development of material science in recent years,bringing hope to solve these challenges.Here we propose a Kriging machine learning model with an active candidate region,which can be smartly updated by an expected improvement probability method to increase the local accuracy near the most sensitive search region,to predict the mechanical and rheolo-gical performance of liquid gating system with an active minimal size of ex-perimental data.Besides this,this new machine learning model can instruct our experiments with optimal size.The methods are then verified by liquid gating membrane with magnetorheological fluids,which would be of wide interest for the design of potential liquid gating applications in drug release,microfluidic logic,dynamic fluid control,and beyond.

Serrated Flow Model for Metallic Glasses under Compressive Loading

A rheological model is proposed that incorporates the serrated flow nature of metallic glasses. It involves the process of the nucleation, propagation and the arrest of a shear bands in the samples subjected to compressive deformation at room temperature. Numerical resolution of the constitutive equations resulting from the model is compared with the stress-strain curve obtained from in-situ nano-compression test in SEM of Zrbased metallic glass. Parametric identification method was applied and enabled us to release the physical parameters of the model. The obtained results showed that the model is adequately valid to describe the experimental data and the almost adjustable model parameters are physically meaningful and comparable to literature.