The rheological properties of nanocellulose aqueous suspensions play a critical role in the development of nanocellulose-based bulk materials.High-crystalline,high-aspect ratio,and slender nanofibrillated cellulose(NF...The rheological properties of nanocellulose aqueous suspensions play a critical role in the development of nanocellulose-based bulk materials.High-crystalline,high-aspect ratio,and slender nanofibrillated cellulose(NFC)were extracted from four biomass resources.The cellulose nanofibrils and nanofibril bundles formed inter-connected networks in the NFC aqueous suspensions.The storage moduli of the suspensions with different concentrations were higher than their corresponding loss moduli.As the concentration increased,the storage and loss modulus of NFC dispersion increased.When the shear rate increased to a certain value,there were differences in the changing trend of the rheological behavior of NFC aqueous suspensions derived from different biomass resources and the suspensions with different solid concentrations.NFC dispersion’s storage and loss modulus increased when the temperature rose to nearly 80℃.We hope this study can deepen the understanding of the rheological properties of NFC colloids derived from different biomass resources.展开更多
Herein the biowaste by-product spent coffee grounds(SCGs)from coffee industry were incorporated into asphalt binders for performance enhancement.From the analysis of Fourier transform infrared spectroscopy(FTIR),diffe...Herein the biowaste by-product spent coffee grounds(SCGs)from coffee industry were incorporated into asphalt binders for performance enhancement.From the analysis of Fourier transform infrared spectroscopy(FTIR),differential scanning calorimetry(DSC),dynamic shear rheometer(DSR),and Brookfield viscosity rheometer,it is confirmed that SCGs have potential prospects as bio-waste modifiers in the application of sustainable pavements.Results demonstrated that the modification process was mainly based on physical reinforcement.Compared with that of the neat asphalt,the shearing stress-resistant ability and high-temperature performance of the SCGs modified binders with the appropriate addition presented a bit of improvement;whereas the binders with 1%and 3%SCGs exhibited remarkably enhanced low-temperature stability.However,notable weaknesses of practical performance were shown for the binder with excessive content of SCGs,indicating the necessity of proportion selecting before application.展开更多
基金supported in part by the Fundamental Research Funds for the Central Universities(2572019BB03 and 2572021CG01)the Startup Fund and the Catalyst Fund from Rowan University and the Research Grant(PC 20-22)from the New Jersey Health Foundation from USAthe Grant(DMR-2116353)from the National Science Foundation.
文摘The rheological properties of nanocellulose aqueous suspensions play a critical role in the development of nanocellulose-based bulk materials.High-crystalline,high-aspect ratio,and slender nanofibrillated cellulose(NFC)were extracted from four biomass resources.The cellulose nanofibrils and nanofibril bundles formed inter-connected networks in the NFC aqueous suspensions.The storage moduli of the suspensions with different concentrations were higher than their corresponding loss moduli.As the concentration increased,the storage and loss modulus of NFC dispersion increased.When the shear rate increased to a certain value,there were differences in the changing trend of the rheological behavior of NFC aqueous suspensions derived from different biomass resources and the suspensions with different solid concentrations.NFC dispersion’s storage and loss modulus increased when the temperature rose to nearly 80℃.We hope this study can deepen the understanding of the rheological properties of NFC colloids derived from different biomass resources.
文摘Herein the biowaste by-product spent coffee grounds(SCGs)from coffee industry were incorporated into asphalt binders for performance enhancement.From the analysis of Fourier transform infrared spectroscopy(FTIR),differential scanning calorimetry(DSC),dynamic shear rheometer(DSR),and Brookfield viscosity rheometer,it is confirmed that SCGs have potential prospects as bio-waste modifiers in the application of sustainable pavements.Results demonstrated that the modification process was mainly based on physical reinforcement.Compared with that of the neat asphalt,the shearing stress-resistant ability and high-temperature performance of the SCGs modified binders with the appropriate addition presented a bit of improvement;whereas the binders with 1%and 3%SCGs exhibited remarkably enhanced low-temperature stability.However,notable weaknesses of practical performance were shown for the binder with excessive content of SCGs,indicating the necessity of proportion selecting before application.
