Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor alpha-acetamidocinnamic acid and its methyl e...Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor alpha-acetamidocinnamic acid and its methyl ester. With all complexes, D-amino acid is the most abundant product.展开更多
文摘Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor alpha-acetamidocinnamic acid and its methyl ester. With all complexes, D-amino acid is the most abundant product.
