Gradient cemented carbides with nano-TiN were prepared by the common powder metallurgical procedure. The formation of gradient zone and the microstructure, properties of the alloys were investigated using scanning ele...Gradient cemented carbides with nano-TiN were prepared by the common powder metallurgical procedure. The formation of gradient zone and the microstructure, properties of the alloys were investigated using scanning electron microscope（SEM）, energy dispersive spectroscopy（EDS） and other performance testing apparatus. Moreover, the effect of nano-TiN on the gradient cemented carbide was studied. It is found that gradient zone width increases slightly with nano-TiN introduction. Both cobalt and titanium concentrations reach the maximum near the gradient border. Tungsten concentration shows fluctuation from the surface to the bulk. （Ti ,W）C phase grains are refined for nitrogen introduction. Core-rim structure has been observed under the SEM back-scattered mode. The core appears as dark due to more titanium in it and the rim with more tungsten appears as grey. In addition, the hardness and transverse rupture strength of gradient cemented carbide are enhanced with nano-TiN introduced.展开更多
基金Funded by Research Funds for the Central Universities(No.2011SCU11038)Chengdu Science and Technology Project(Nos.10GGZD080GX-268 and 11DXYB096JH-027)
文摘Gradient cemented carbides with nano-TiN were prepared by the common powder metallurgical procedure. The formation of gradient zone and the microstructure, properties of the alloys were investigated using scanning electron microscope（SEM）, energy dispersive spectroscopy（EDS） and other performance testing apparatus. Moreover, the effect of nano-TiN on the gradient cemented carbide was studied. It is found that gradient zone width increases slightly with nano-TiN introduction. Both cobalt and titanium concentrations reach the maximum near the gradient border. Tungsten concentration shows fluctuation from the surface to the bulk. （Ti ,W）C phase grains are refined for nitrogen introduction. Core-rim structure has been observed under the SEM back-scattered mode. The core appears as dark due to more titanium in it and the rim with more tungsten appears as grey. In addition, the hardness and transverse rupture strength of gradient cemented carbide are enhanced with nano-TiN introduced.
