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RESEARCH ON HOT FORMING PROCESS OF A RETAINING RING OF HIGH-NITROGEN STEEL 被引量:4
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作者 H.Q.Chen J.S.Liu H.G.Guo 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2004年第5期767-770,共4页
Mn18Cr18N, the high-nitrogen steel, is the 2nd generation material for manufacturing the retaining ring of firepower generators. In this paper, the hot deformation behavior of the material was investigated by thermo-m... Mn18Cr18N, the high-nitrogen steel, is the 2nd generation material for manufacturing the retaining ring of firepower generators. In this paper, the hot deformation behavior of the material was investigated by thermo-mechanical modeling tests. And the flow stress curves of the steel were obtained for various combinations of the temperature and strain rate. Based on the results of the tests, the complex forming process of a retaining ring including punching, expanding and extrusion with an enclosure was put forward and simulated by means of numerical simulation method. The results indicate that the process is a novel and force-saved practical technology for manufacturing heavy retaining rings. 展开更多
关键词 Mn18Cr18N high-nitrogen steel a retaining ring the punching with an enclosure process expanding-extrusion complex forming
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Preparation of nucleoside-pyridine hybrids and pyridine attached acylureas from an unexpected uracil ring-opening and pyridine ring-forming sequence
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作者 Xue Sen Fan Xia Wang Xin Ying Zhang Dong Feng Ying Ying Qu 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第10期1161-1165,共5页
Novel pyrimidine nucleoside-3,5-dicyanopyridine hybrids (4) or pyridine attached acylureas (5) were selectively and efficiently prepared from the reaction of 2′-deoxyuddin-5-yl-methylene malononitrile (1), malo... Novel pyrimidine nucleoside-3,5-dicyanopyridine hybrids (4) or pyridine attached acylureas (5) were selectively and efficiently prepared from the reaction of 2′-deoxyuddin-5-yl-methylene malononitrile (1), malononitrile (2) and thiophenol (3) or from an unexpected uracil ring-opening and pyddine ring-forming sequence via the reaction of 1 and 3. It is the first time such a sequence has ever been reported. 展开更多
关键词 Pyrimidine nucleoside PYRIDINE Acylureas ring-opening and -forming reaction
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Wrinkling prediction in rubber forming of Ti-15-3 alloy 被引量:4
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作者 孙永娜 万敏 吴向东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第10期3002-3010,共9页
Wrinkling is a common failure in the sheet metal forming of titanium owing to the relatively poor ability to shrink. It is important to predict wrinkling accurately in the sheet metal forming without costly trials. Th... Wrinkling is a common failure in the sheet metal forming of titanium owing to the relatively poor ability to shrink. It is important to predict wrinkling accurately in the sheet metal forming without costly trials. The ABAQUS/Explicit code was utilized to predict the wrinkling behavior in the sheet metal forming of Ti-15-3 alloy sheets. In terms of the comparison of wrinkling behavior between the simulation and experiment of the Fukui's conical cup tests at room temperature, the sensitivities of wrinkling simulation to various input parameters were evaluated comprehensively and quantitatively. Prediction of wrinkling and influence of rubber hardness on the winkling behavior in the rubber forming of convex flange were investigated quantitatively and validated by the rubber forming experiments. The excellent agreements between the simulations and the experiments conIirmed the accuracy of the prediction. 展开更多
关键词 Ti-15-3 alloy WRINKLING convex flange rubber forming quantitative analysis
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Friction coefficient in rubber forming process of Ti-15-3 alloy 被引量:4
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作者 孙永娜 万敏 吴向东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第12期2952-2959,共8页
The forming limit diagram of Ti-15-3 alloy sheet was constituted at room temperature. The effects of different punch and rubber hardness on the limit principal strain distributions were investigated experimentally. Fi... The forming limit diagram of Ti-15-3 alloy sheet was constituted at room temperature. The effects of different punch and rubber hardness on the limit principal strain distributions were investigated experimentally. Finite element analysis models of the samples with dimensions of 180 mm×180 mm were established to analyze the friction coefficients of different interfaces. Effects of various friction coefficients on the strain distributions were studied in detail. Finally, the friction coefficients in the cold forming were determined by contrasting the strain results between the experimental data and the simulated ones. 展开更多
关键词 Ti-15-3 alloy rubber forming FRICTION BULGING principal strain finite element analysis
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PREDICTION OF MICROSTRUCTURE EVOLUTION DURING HOT EXPANDING-EXTRUSION FORMING OF RESTRAINING RINGS
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作者 Liu, Jiansheng Chen, Huiqin +1 位作者 Guo, Huiguang Wu, Qingpei 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 1998年第2期62-66,72,共5页
A mathematic model for dynamic and static recrystallization of Mn18Cr18N steel is presented.Hot expanding extrusion forming and air cooling process of 600 MW retaining ring has been simulated by the combination of th... A mathematic model for dynamic and static recrystallization of Mn18Cr18N steel is presented.Hot expanding extrusion forming and air cooling process of 600 MW retaining ring has been simulated by the combination of thermos coupled rigid viscoplasitic FEM with this model,and grain size distribution on cross section of ring is shown.The essential results can be provided for use of the new technique. 展开更多
关键词 Retaining ring Hot forming Microstructure evolution Finite element method
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Microstructure and properties of Al-0.70Fe-0.24Cu alloy conductor prepared by horizontal continuous casting and subsequent continuous extrusion forming 被引量:6
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作者 张晓苑 张辉 +1 位作者 孔祥鑫 傅定发 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第6期1763-1769,共7页
A novel process for manufacturing A1-0.70Fe-0.24Cu alloy conductor was proposed, which includes horizontal continuous casting and subsequent continuous extrusion forming (Conform). The mechanical properties, electri... A novel process for manufacturing A1-0.70Fe-0.24Cu alloy conductor was proposed, which includes horizontal continuous casting and subsequent continuous extrusion forming (Conform). The mechanical properties, electrical conductivity and the compressed creep behaviour of the alloy were studied. The results indicate that the Conform process induces obvious grain refinement, strain-induced precipitation of AI7CuzFe phase and the transformation of crystal orientation distribution. The processed alloy has good comprehensive mechanical properties and electrical conductivity. Moreover, a better creep resistance under the conditions of 90 ~C and 76 MPa is shown compared with pure A1 and annealed copper, and the relationship between primary creep strain and time may comply with the logarithmic law. The enhanced properties are attributed to the grain refinement as well as the fine and homogeneously distributed thermally stable A1Fe and A17Cu2Fe precipitation phases. 展开更多
关键词 A1-0.70Fe-0.24Cu alloy horizontal continuous casting continuous extrusion forming MICROSTRUCTURE PROPERTY
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Technology and Experiments of 42CrMo Bearing Ring Forming Based on Casting Ring Blank 被引量:17
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作者 LI Yongtang JU Li +3 位作者 QI Huiping ZHANG Feng CHEN Guozhen WANG Mingli 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2014年第2期418-427,共10页
Bearing ring is the crucial component of bearing. With regard to such problems as material waste, low efficiency and high energy consumption in current process of producing large bearing ring, a new process named "ca... Bearing ring is the crucial component of bearing. With regard to such problems as material waste, low efficiency and high energy consumption in current process of producing large bearing ring, a new process named "casting-rolling compound forming technology" is researched by taking the typical 42CrMo slew bearing as object. Through theoretical analysis, the design criteria of the main casting-rolling forming parameters are put forward at first. Then the constitutive relationship model of as-cast 42CrMo steel and its mathematical model of dynamic recrystallization are obtained according to the results of the hot compression experiment. By a coupled thermal-mechanical finite element model for radial-axial rolling of bearing ring, the fraction of dynamic recrystallization is calculated and recrystallized grains size are predicated. Meanwhile, the effects of the initial rolling temperature and feed rate of idle roll on material microstructure evolution are analyzed. Finally, the industrial rolling experiment is designed and performed, based on the simulation results. In addition, mechanical and metallographic tests are conducted on rolled bearing ring to get the mechanical parameters and metallographic structure. The experimental data and results show that the mechanical properties of bearing ring produced by casting-rolling compound forming technology are up to industrial standard, and a qualified bearing ring can be successfully formed by employing this new technology. Through the study, a process of forming large bearing ring directly by using casting ring blank is obtained, which could provide an effective theoretical guidance for manufacturing large ring parts. It also has an edge in saving material, lowering energy and improving efficiency. 展开更多
关键词 bearing ring 42CrMo casting ring blank casting-rolling compound forming microstructure evolution
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Developments and perspectives on the precision forming processes for ultra-large size integrated components 被引量:23
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作者 Shijian Yuan Xiaobo Fan 《International Journal of Extreme Manufacturing》 2019年第2期34-51,共18页
In order to meet the requirements of high reliability,long-lifetime and lightweight in a new generation of aerospace,aviation,high-speed train,and energy power equipment,integrated components are urgently needed to re... In order to meet the requirements of high reliability,long-lifetime and lightweight in a new generation of aerospace,aviation,high-speed train,and energy power equipment,integrated components are urgently needed to replace traditional multi-piece,welded components.The applications of integrated components involve in a series of large-size,complex-shaped,highperformance components made of difficult-to-deform materials,which present a huge challenge for forming ultra-large size integrated components.In this paper,the developments and perspectives of several extreme forming technologies are reviewed,including the sheet hydroforming of ultra-large curved components,dieless hydroforming of ellipsoidal shells,radial-axial ring rolling of rings,in situ manufacturing process of flanges,and local isothermal forging of titanium alloy components.The principle and processes for controlling deformation are briefly illustrated.The forming of typical ultra-large size integrated components and industrial applications are introduced,such as the high strength aluminum alloy,3m in diameter,integrated tank dome first formed by using a sheet blank with a thickness the same as the final component,and a 16m diameter,integrated steel ring rolled by using a single billet.The trends for extreme forming of ultra-large size integrated components are discussed with a goal of providing ideas and fundamental guidance for the further development of new forming processes for extreme-size integrated components in the future. 展开更多
关键词 ultra-large size integrated components extreme forming HYDROforming radial-axial ring rolling isothermal forging
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Superplastic Forming and Diffusion Bonding for Sandwich Structure of Ti-6Al-4V Alloy
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作者 Wenbo HAN, Kaifeng ZHANG, Guofeng WANG and Xiaojun ZHANGSchool of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, ChinaProf., Ph.D., 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2005年第1期60-62,共3页
Superplastic forming and diffusion bonding (SPF/DB) is a well-established process for the manufacture of components almost exclusively from Ti-6AI-4V sheet material. The sandwich structure of Ti-6AI-4V alloy is invest... Superplastic forming and diffusion bonding (SPF/DB) is a well-established process for the manufacture of components almost exclusively from Ti-6AI-4V sheet material. The sandwich structure of Ti-6AI-4V alloy is investigated. The effects of the microstructure on the SPF/DB process were discussed. The microstructure at the interfaces and the distribution of thickness were researched. 展开更多
关键词 Superplastic forming Diffusion bonding Sandwich structure TI-6A1-4V alloy
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The Evolutionary History of Ore-forming Processes of Metallic Ore Deposits in Northern Guangxi
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作者 Chen Yuchuan, Mao Jinwen and Wang Ping’an Chinese Academy of Geological Sciences, Beijing Fei Zhenbi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1995年第2期155-170,共16页
The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis ... The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian. 展开更多
关键词 metallogenic series evolutionary history of ore - forming processes metallogenic model rare metal- nonferrous metal deposit
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CONTROLLED HOT FORMING OF RETAINING RING OF GENERATOR 被引量:1
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作者 Zhang Qiaoli Chen Huiqin Guo Huiguang Taiyuan Heavy Machinery Institute Guo Yajun Taiyuan Orient Three Stars New Technology Co. Ltd. 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 1999年第2期8-11,共4页
The relevant results of thermodynamics simulation test, recrystallization study and FEM numercal simulation are described. A method is also introduced that the controlled hot forming is carried out by adopting the pro... The relevant results of thermodynamics simulation test, recrystallization study and FEM numercal simulation are described. A method is also introduced that the controlled hot forming is carried out by adopting the program of expansion-extrusion compound forming. 展开更多
关键词 Retaining ring Expansion-extrusion compound forming Controlled hot forming
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The Forming Conditions of and Ore-searching Direction for B, Mg,Pb, Zn and Au Deposits in the Liaoji Proterozoic Rift
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作者 Zhu Yongzheng and Yao Fengliang (College of Earth Sciences,Jilin University, Changchun 130026 P. R. China) 《Global Geology》 2001年第1期20-25,共6页
The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These d... The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These deposits were formed as the result of late mobilization, transportation and concentfation of the previously enriched ore-forming mate- rials in several ore-bearing formations formed during the rift stage. So the metallogeny of these deposits in the rift shows both inheritance and new generation of the ore-forming materials. In future ore-searching practice, attentions should be paid on the studies of the ore-bearing formations in the rift, on the multiple stages of metallogeny and and on multiple derivations of the ore-forming materials. 展开更多
关键词 Liaoji PROTEROZOIC rift B Mg Pb - Zn AU deposits ORE - forming conditions ORE - SEARCHING direction
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Formation of Hybrid Ring Structure of Cyanurate/Isocyanurate in the Reaction be-tween 2,4,6-Tris(4-Phenyl-Phenoxy)-1, 3,5-Triazine and Phenyl Glycidyl Ether
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作者 Daisuke Ohno Kazuya Zenyoji +2 位作者 Youji Kurihara Kazuyoshi Ueda Hitoshi Habuka 《International Journal of Organic Chemistry》 CAS 2016年第2期117-125,共9页
Reaction products of 2,4,6-tris(4-phenyl-phenoxy)-1,3,5-triazine derived from 4-phenylphenol cyanate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound w... Reaction products of 2,4,6-tris(4-phenyl-phenoxy)-1,3,5-triazine derived from 4-phenylphenol cyanate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound which were well known as reaction products of cyanate esters and epoxy resins, compounds with hybrid ring structure of cyanurate/isocyanurate were determined. Gibbs free energies of the compound having hybrid ring structure of cyanurate/isocyanurate with two isocyanurate moiety were found to be lower than that of the compound with cyanurate ring structure through calculations. Calculation data supported the existence of hybrid ring structure of cy-anurate/isocyanurate. It was revealed that isomerization from cyanurate to isocyanurate occurs via hybrid ring structure of cyanurate/isocyanurate in the reaction of aryl cyanurate and epoxy. 展开更多
关键词 Reaction products of 2 4 6-tris(4-phenyl-phenoxy)-1 3 5-triazine derived from 4-phenylphenol cya-nate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound which were well known as reaction products of cyanate esters and epoxy resins compounds with hybrid ring structure of cyanurate/isocyanurate were determined. Gibbs free energies of the compound having hybrid ring structure of cyanurate/isocyanurate with two isocyanurate moiety were found to be lower than that of the compound with cyanurate ring struc-ture through calculations. Calculation data supported the existence of hybrid ring structure of cy-anurate/isocyanurate. It was revealed that isomerization from cyanurate to isocyanurate occurs via hybrid ring structure of cyanurate/isocyanurate in the reaction of aryl cyanurate and epoxy.
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RSM-FORM 的改进与环肋圆柱壳结构的可靠性计算(英文) 被引量:2
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作者 于英霞 刘丰军 +1 位作者 张伟 梁斌 《船舶力学》 EI 北大核心 2012年第3期271-276,共6页
文章在用有限元法对结构进行强度计算和分析的基础上,应用RSM确定了环肋圆柱壳结构强度失效的功能函数;在对相关可靠度理论进行研究的基础上,将RSM与FORM相结合,对FORM进行了改进,解决了当量正态化和参数独立化问题,保留了功能函数的二... 文章在用有限元法对结构进行强度计算和分析的基础上,应用RSM确定了环肋圆柱壳结构强度失效的功能函数;在对相关可靠度理论进行研究的基础上,将RSM与FORM相结合,对FORM进行了改进,解决了当量正态化和参数独立化问题,保留了功能函数的二次项,使计算精度满足实际工程的需要;最后用RSM-FORM对环肋圆柱壳结构强度的可靠性进行了计算分析,计算结果表明,RSM-FORM具有较好的计算精度。 展开更多
关键词 环肋圆柱壳结构 可靠性分析 一次可靠度方法(form) 响应面法(RSM)
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基于Deform-3D的重型汽车新型同步环精密成形过程有限元分析 被引量:1
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作者 陈洁 蔡志武 《制造技术与机床》 CSCD 北大核心 2011年第7期111-114,共4页
重型汽车新型同步环是一种基本对称结构的、带有3个Y型凸台的环形薄壁型零件,主要用于汽车行驶中平稳快速换档。由于新型同步环形状复杂,成形困难,锻造时极易产生填充不满、折叠等情况,因此合理设计锻造工艺与模具结构是一个关键。利用... 重型汽车新型同步环是一种基本对称结构的、带有3个Y型凸台的环形薄壁型零件,主要用于汽车行驶中平稳快速换档。由于新型同步环形状复杂,成形困难,锻造时极易产生填充不满、折叠等情况,因此合理设计锻造工艺与模具结构是一个关键。利用非线形有限元分析软件Deform-3D对重型汽车新型同步环精密成形过程进行仿真,获得成形过程中的应变、应力、材料流动情况,同时对成形过程中的缺陷如折叠、裂纹,进行预测。通过对同步齿环成形过程分析与缺陷预测,可以有效缩短产品开发周期。 展开更多
关键词 新型同步环 有限元 成形工艺 DEform-3D
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A unified analysis of a micro-beam,droplet and CNT ring adhered on a substrate:Calculation of variation with movable boundaries 被引量:3
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作者 Jian-Lin Liu Re Xia 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2013年第1期62-72,共11页
In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube ... In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (CNT) ring on a substrate into one framework, we used the developed line of reasoning to investigate the adhesion behaviors of these systems. Based upon the derived governing equations and transversality conditions, explicit solutions involving the critical parameters and morphologies for the three systems are successfully obtained, and then the parameter analogies and common characteristics of them are thor- oughly investigated. The presented method has been verified via the concept of energy release rate in fracture mechanics. Our analyses provide a new approach for exploring the mechanism of different systems with similarities as well as for understanding the unity of nature. The analysis results may be beneficial for the design of nano-structured materi- als, and hold potential for enhancing their mechanical, chemical, optical and electronic properties. 展开更多
关键词 Variational theory - Transversality condition Beam adhesion Droplet adhesion Carbon nanotube ring adhesion
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Two Classes of Quaternary Codes from Z_4-valued Quadratic Forms
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作者 Zhu Xiaoxing Xu Dazhuan 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2018年第5期896-912,共17页
Let R=GR (4,m)be a Galois ring with Teichmuller set T_m and Tr_m be the trace function fromRto Z_4.In this paper,two classes of quaternary codes C_1 = {c(a,b):a ∈R,b ∈ T_(m/2)},where c(a,b)=(Tr_m(ax)+Tr_(m/2)(2 bx^(... Let R=GR (4,m)be a Galois ring with Teichmuller set T_m and Tr_m be the trace function fromRto Z_4.In this paper,two classes of quaternary codes C_1 = {c(a,b):a ∈R,b ∈ T_(m/2)},where c(a,b)=(Tr_m(ax)+Tr_(m/2)(2 bx^(2 m/2 +1)))_(x∈T_m),and C_2= {c(a,b):a ∈ R,b ∈ T_m}, where c(a,b)=(Tr_m(ax+2 bx^(2 k+1)))_(x∈T_m),and m/gcd(m,k)is even,are investigated,respectively.The Lee weight distributions,Hamming weight distributions and complete weight distributions of the codes are completely given. 展开更多
关键词 GALOIS ring QUATERNARY code Hamming WEIGHT QUADRATIC form LEE WEIGHT
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Novel AC Servo Rotating and Linear Composite Driving Device for Plastic Forming Equipment
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作者 Jin-Tao Liang Sheng-Dun Zhao +1 位作者 Yong-Yi Li Mu-Zhi Zhu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第4期843-853,共11页
The existing plastic forming equipment are mostly driven by traditional AC motors with long trans- mission chains, low efficiency, large size, low precision and poor dynamic response are the common disadvantages. In o... The existing plastic forming equipment are mostly driven by traditional AC motors with long trans- mission chains, low efficiency, large size, low precision and poor dynamic response are the common disadvantages. In order to realize high performance forming processes, the driving device should be improved, especially for com- plicated processing motions. Based on electric servo direct drive technology, a novel AC servo rotating and linear composite driving device is proposed, which features implementing both spindle rotation and feed motion with- out transmission, so that compact structure and precise control can be achieved. Flux switching topology is employed in the rotating drive component for strong robustness, and fractional slot is employed in the linear direct drive component for large force capability. Then the mechanical structure for compositing rotation and linear motion is designed. A device prototype is manufactured, machining of each component and the whole assembly are presented respectively. Commercial servo amplifiers are utilized to construct the control system of the proposed device. To validate the effectiveness of the proposed composite driving device, experimental study on thedynamic test benches are conducted. The results indicate that the output torque can attain to 420 N-m and the dynamic tracking errors are less than about 0.3 rad in the rotating drive, the dynamic tracking errors are less than about 1.6 mm in the linear feed. The proposed research provides a method to construct high efficiency and accu- racy direct driving device in plastic forming equipment. 展开更多
关键词 Plastic forming Direct drive - Permanentmagnet motor Linear feeding Servo control
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Ring-opened Crystal Structure and Photochromism of 2,2-Bis(4-tertiary butyl phenyl)-3H-naphtho[2,1-b]pyran
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作者 谈廷风 庞美丽 吴边鹏 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2009年第2期187-190,共4页
The title compound, 2,2-bis(4-tertial butyl phenyl) naphthopyran, has been prepared and characterized by means of IR, ^1H NMR and elemental analysis, and its crystal structure was determined with X-ray diffraction i... The title compound, 2,2-bis(4-tertial butyl phenyl) naphthopyran, has been prepared and characterized by means of IR, ^1H NMR and elemental analysis, and its crystal structure was determined with X-ray diffraction in the ring-opened form after hydrolyzation. It belongs to monoclinic, space group P21/c, with a = 14.358(3), b = 7.6725(15), c = 24.470(5) А, β= 97.147(4)°, C_33H_36O2, Mr=464.62, V= 2674.8(9)А^3, Z = 4, Dc = 1.154 g/cm^3,μ= 0.070 mm^-1, F(000) = 1000, the final R = 0.0514 and wR = 0.1272 for 5444 observed reflections (I 〉 2σ(I)). X-ray analysis revealed that the C(13)-O(1) bond of the title compound cracks after UV irradiation, the six-membered heterocycles are destroyed, and zwitterionic intermediates come into being. The molecular structure in the ring-opened form is obtained after hydrolyzation. It is infrequent that the single-crystal structure is determined in a ring-opened form. A two-dimensional framework is formed by O-H…O and CAr-H…O hydrogen bonds. The UV-vis spectra show that the title compound exhibits excellent photochromic properties in solutions and polymers. 展开更多
关键词 NAPHTHOPYRAN ring-opened form crystal structure PHOTOCHROMISM
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Unveiling the planar deformation mechanisms for improved formability in pre-twinned AZ31 Mg alloy sheet at warm temperature
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作者 Xiaohuan Pan Lifei Wang +8 位作者 Pengbin Lu Hua Zhang Guangsheng Huang Liuwei Zheng Bin Xing Weili Cheng Hongxia Wang Wei Liang Kwang Seon Shin 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第12期4659-4678,共20页
To investigate the role of pre-twins in Mg alloy sheets during warm planar deformation,the stretch forming is conducted at 200℃.Results suggest the formability of the pre-twinned AZ31 Mg alloy sheet is enhanced to 11... To investigate the role of pre-twins in Mg alloy sheets during warm planar deformation,the stretch forming is conducted at 200℃.Results suggest the formability of the pre-twinned AZ31 Mg alloy sheet is enhanced to 11.30 mm.The mechanisms for the improved formability and the deformation behaviors during the planar stretch forming are systematically investigated based on the planar stress states.The Schmid factor for deformation mechanisms are calculated,the results reveal that planar stress states extremely affect the Schmid factor for{10-12}twinning.The detwinning is activated and the prismatic slip is enhanced in the pre-twinned sheet,especially under the planar extension stress state in the outer region.Consequently,the thickness-direction strain is accommodated better.The dynamic recrystallization(DRX)type is continuous DRX(CDRX)regardless of the planar stress state.However,the CDRX degree is greater under the planar extension stress state.Some twin lattices deviate from the perfect{10-12}twinning relation due to the planar compression stress state and the CDRX.The basal texture is weakened when the planar stress state tends to change the texture components. 展开更多
关键词 AZ31 Mg alloy sheet Planar stretch forming Planar stress states Continuous dynamic recrystallization {10-12}tensile twinning
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