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H_∞ ROBUST PERFORMANCE DESIGN FOR UNCERTAIN SYSTEMS
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作者 Weng Zhengxin Shi Songjiao(Dept. of Automatic Control, Shanghai Jiaotong University, Shanghai, 200030)Wang Guangxiong(Dept. of Control Engineering, Harbin Institute of Technology, Harbin, 150001) 《Journal of Shanghai Jiaotong university(Science)》 EI 1996年第2期42-48,共7页
This paper considers the robust per formance design problem of the linear systems with both unmodelled dynamics and real parametric uncertainties. We suggest for the first time that the problem can besolved by the H∞... This paper considers the robust per formance design problem of the linear systems with both unmodelled dynamics and real parametric uncertainties. We suggest for the first time that the problem can besolved by the H∞ mixed sensitivity method. The main idea is as follows: Firstly, the original problem istransformed into the robust per formance design problem for a pure parameter uncertain system. Then, theresulting problem is reduced to a standard H∞ control problem which can be solved by the H∞ state feedbacksynthesis method or Doyle’s "DGKF" algorithm. 展开更多
关键词 h_∞ control robust performance PARAMETRIC UNCERTAINTY unmodelled dynamics MIXED sensitivity
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Randomized Algorithms for Probabilistic Optimal Robust Performance Controller Design 被引量:1
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作者 宋春雷 谢玲 《Journal of Beijing Institute of Technology》 EI CAS 2004年第1期15-19,共5页
Polynomial-time randomized algorithms were constructed to approximately solve optimal robust performance controller design problems in probabilistic sense and the rigorous mathematical justification of the approach wa... Polynomial-time randomized algorithms were constructed to approximately solve optimal robust performance controller design problems in probabilistic sense and the rigorous mathematical justification of the approach was given. The randomized algorithms here were based on a property from statistical learning theory known as (uniform) convergence of empirical means (UCEM). It is argued that in order to assess the performance of a controller as the plant varies over a pre-specified family, it is better to use the average performance of the controller as the objective function to be optimized, rather than its worst-case performance. The approach is illustrated to be efficient through an example. 展开更多
关键词 randomized algorithms statistical learning theory uniform convergence of empirical means (UCEM) probabilistic optimal robust performance controller design
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Robust Optimization of Performance Scheduling Problem under Accepting Strategy
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作者 Hui Ding Yuqiang Fan Weiya Zhong 《Open Journal of Optimization》 2018年第4期65-78,共14页
In this paper, the problem of program performance scheduling with accepting strategy is studied. Considering the uncertainty of actual situation, the duration of a program is expressed as a bounded interval. Firstly, ... In this paper, the problem of program performance scheduling with accepting strategy is studied. Considering the uncertainty of actual situation, the duration of a program is expressed as a bounded interval. Firstly, we decide which programs are accepted. Secondly, the risk preference coefficient of the decision maker is introduced. Thirdly, the min-max robust optimization model of the uncertain program show scheduling is built to minimize the performance cost and determine the sequence of these programs. Based on the above model, an effective algorithm for the original problem is proposed. The computational experiment shows that the performance’s cost (revenue) will increase (decrease) with decision maker’s risk aversion. 展开更多
关键词 performance SChEDULING robust Optimization DUALITY Theory 0 - 1 MIXED Linear PROGRAMMING
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Robust output regulation problem with prescribed performance for nonlinear strict feedback systems
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作者 ZHU Haichao LAN Weiyao 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2023年第4期1033-1041,共9页
This paper investigates the problem of robust output regulation control with prospected transient property for strict feedback systems.By employing the internal model principle,the robust output regulation problem wit... This paper investigates the problem of robust output regulation control with prospected transient property for strict feedback systems.By employing the internal model principle,the robust output regulation problem with a prospected property can be transformed to a robust stabilization problem with a new output constraint.Then,by constructing the speed function and adopting barrier Lyapunov function technique,the dynamic feedback controller can be designed not only to drive error output of the closed-loop system entering into a prescribed performance bound within a given finite time,but also to achieve that the error output converges to zero asymptotically.The effectiveness of the results is illustrated by a simulation example. 展开更多
关键词 robust output regulation nonlinear system prescribed performance bound speed function finite time
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Robust Performance of AlGaN-Channel Metal-Insulator-Semiconductor High-Electron-Mobility Transistors at High Temperatures
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作者 张力 张金风 +4 位作者 张苇杭 张涛 徐雷 张进成 郝跃 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第12期75-78,共4页
Superior characteristics of Al Ga N-channel metal-insulator-semiconductor(MIS) high electron mobility transistors(HEMTs) at high temperatures are demonstrated in detail. The temperature coefficient of the maximum ... Superior characteristics of Al Ga N-channel metal-insulator-semiconductor(MIS) high electron mobility transistors(HEMTs) at high temperatures are demonstrated in detail. The temperature coefficient of the maximum saturation drain current for the Al GaN-channel MIS HEMT can be reduced by 50% compared with the Ga N-channel HEMT. Moreover, benefiting from the better suppression of gate current and reduced leakage current in the buffer layer, the Al Ga N-channel MIS HEMT demonstrates an average breakdown electric field of 1.83 MV/cm at25℃ and 1.06 MV/cm at 300℃, which is almost 2 times and 3 times respectively larger than that of the reference Ga N-channel HEMT. Pulsed mode analyses suggest that the proposed device suffers from smaller current collapse when the temperature reaches as high as 300℃. 展开更多
关键词 robust performance of AlGaN-Channel Metal-Insulator-Semiconductor high-Electron-Mobility Transistors at high Temperatures GAN AL
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Robust Performance of Scene Matching Algorithm
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作者 Zhaohui Xia Xiaogang Yang +1 位作者 Fei Meng Shicheng Wang 《Journal of Software Engineering and Applications》 2013年第5期6-10,共5页
Performance analysis is very important in the study and design of scene matching algorithm. Based on the analysis of the common performance parameters, robustness of scene matching algorithm is defined, including the ... Performance analysis is very important in the study and design of scene matching algorithm. Based on the analysis of the common performance parameters, robustness of scene matching algorithm is defined, including the definitions of robust stability and robust performance, and the corresponding evaluation parameters matching margin and matching adaptability are given. With application of these robustness parameters on 8 scene matching algorithms, quantitative analysis results of algorithm robustness are obtained. The paper provides an important theoretical reference to the performance evaluation of scene matching algorithm. 展开更多
关键词 SCENE MATChING MATChING ALGORIThM performance PARAMETERS robustNESS performance Evaluation
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Comparative Thermal Performance in SiO_(2)–H_(2)O and (MoS_(2)–SiO_(2))–H_(2)O Over a Curved Stretching Semi-Infinite Region: A Numerical Investigation
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作者 Basharat Ullah Umar Khan +3 位作者 Hafiz Abdul Wahab Ilyas Khan Dumitru Baleanu Kottakkaran Sooppy Nisar 《Computers, Materials & Continua》 SCIE EI 2021年第1期947-960,共14页
The investigation of Thermal performance in nanofluids and hybrid nanofluids over a curved stretching infinite region strengthens its roots in engineering and industry.Therefore,the comparative thermal analysis in SiO... The investigation of Thermal performance in nanofluids and hybrid nanofluids over a curved stretching infinite region strengthens its roots in engineering and industry.Therefore,the comparative thermal analysis in SiO_(2)–H_(2)O and(MoS_(2)–SiO_(2))–H_(2)O is conducted over curved stretching surface.The model is reduced in the dimensional version via similarity transformation and then treated numerically.The velocity and thermal behavior for both the fluids is decorated against the preeminent parameters.From the analysis,it is examined that the motion of under consideration fluids declines against Fr and.The thermal performance enhances for higher volumetric fraction and.Further,it is noticed that thermal performance prevailed in(MoS_(2)–SiO_(2))–H_(2)O throughout the analysis.Therefore,(MoS_(2)–SiO_(2))–H_(2)O is better for industrial and engineering uses where high heat transfer is required to accomplished different processes of production. 展开更多
关键词 Thermal performance curved surface SiO_(2)–h_(2)O and(MoS_(2)–SiO_(2))–h_(2)O shear stresses Nusselt number numerical scheme
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重放攻击下多智能体系统H_(∞)一致性PID控制
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作者 宋金波 董宏丽 +1 位作者 申雨轩 侯男 《控制理论与应用》 EI CAS CSCD 北大核心 2024年第4期658-666,共9页
本文针对一类带有加性噪声和乘性噪声的离散多智能体系统,研究重放攻击下多智能体系统的H_(∞)一致性比例-积分-微分(PID)控制问题.首先,根据智能体的测量输出设计状态观测器,对智能体的状态进行有效估计,观测器设计过程中考虑了系统测... 本文针对一类带有加性噪声和乘性噪声的离散多智能体系统,研究重放攻击下多智能体系统的H_(∞)一致性比例-积分-微分(PID)控制问题.首先,根据智能体的测量输出设计状态观测器,对智能体的状态进行有效估计,观测器设计过程中考虑了系统测量输出从传感器传输到观测器过程中受到重放网络攻击的影响.然后,利用智能体与其邻居智能体的估计状态差设计PID控制器.利用李雅普诺夫稳定性理论和代数图论,证明在该控制策略下,多智能体系统在重放攻击存在的情况下达到预期的H_(∞)性能指标.最后,利用线性矩阵不等式(LMI)方法求解观测器和控制器增益,利用数值仿真验证了所设计的观测器和PID控制器的有效性. 展开更多
关键词 多智能体 重放攻击 PID控制 h_(∞)性能 观测器
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非线性系统无需初始条件预设性能有界H_(∞)容错控制
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作者 李小华 程鸿展 刘辉 《控制理论与应用》 EI CAS CSCD 北大核心 2024年第2期273-282,共10页
针对一类具有外部扰动和传感器故障的非线性系统,本文研究了其自适应预设性能有界H_(∞) 容错控制问题.本文提出一种新的预设性能控制设计方法,使得预设性能函数的选择与系统被约束变量的初始状态完全无关,用一种全新的方式解决了传统... 针对一类具有外部扰动和传感器故障的非线性系统,本文研究了其自适应预设性能有界H_(∞) 容错控制问题.本文提出一种新的预设性能控制设计方法,使得预设性能函数的选择与系统被约束变量的初始状态完全无关,用一种全新的方式解决了传统预设性能方法的控制效果依赖被约束变量初始条件的问题.基于该设计方法和有界H_(∞) 控制方法,在未知系统初始条件的情况下获得了系统的自适应预设性能有界H_(∞) 控制器.本文所设计的控制器能够保证系统中的所有信号都是有界稳定的,系统的输出变量能够被预设性能函数约束,并且对于外部干扰具有很好的抑制作用.最后,仿真结果验证了该控制器的可行性及有效性. 展开更多
关键词 非线性系统 传感器故障 预设性能控制 无需初始条件 有界h_(∞)控制 容错控制
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Robust H_∞ control for neutral stochastic uncertain systems with time-varying delay 被引量:3
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作者 Guici Chen Xiaoping Wang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2010年第4期658-665,共8页
The problem of robust H_∞ control for uncertain neutral stochastic systems with time-varying delay is discussed.The parameter uncertaintie is assumed to be time varying norm-bounded.First,the stochastic robust stabil... The problem of robust H_∞ control for uncertain neutral stochastic systems with time-varying delay is discussed.The parameter uncertaintie is assumed to be time varying norm-bounded.First,the stochastic robust stabilization of the stochastic system without disturbance input is investigated by nonlinear matrix inequality method.Then,a full-order stochastic dynamic output feedback controller is designed by solving a bilinear matrix inequality(BMI),which ensures a prescribed stochastic robust H_∞ performance level for the resulting closed-loop system with nonzero disturbance input and for all admissible uncertainties.An illustrative example is provided to show the feasibility of the controller and the potential of the proposed technique. 展开更多
关键词 stochastic robust h_∞ control neutral stochastic system uncertain system stochastic dynamic output feedback controller bilinear matrix inequality(BMI).
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具有H_(∞)性能的输入受限三级倒立摆控制器设计
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作者 韩光信 张保葵 《河南科技》 2024年第17期4-9,共6页
【目的】针对直线三级倒立摆控制输入受限下的稳摆控制问题,设计了具有H_(∞)性能的输入受限三级倒立摆控制器。【方法】利用线性矩阵不等式(LMI)方法,将控制输入约束问题转化为利用线性矩阵不等式求解优化值的优化问题,经Lyapunov稳定... 【目的】针对直线三级倒立摆控制输入受限下的稳摆控制问题,设计了具有H_(∞)性能的输入受限三级倒立摆控制器。【方法】利用线性矩阵不等式(LMI)方法,将控制输入约束问题转化为利用线性矩阵不等式求解优化值的优化问题,经Lyapunov稳定性推导出符合条件的LMI,利用MATLAB中的LMI工具箱求解得到有效的K。进一步在控制输入受限下引入H_(∞)性能指标,使所设计的控制输入受限下的算法具有H_(∞)性能。【结果】仿真结果表明,该控制器对于控制输入受限下的复杂高阶次不稳定系统具有很好的控制效果。【结论】控制输入信号在给定的受限范围内实现了三级倒立摆的稳摆要求,且引入H_(∞)性能指标后控制输入和摆杆波动更小。 展开更多
关键词 直线三级倒立摆 控制输入受限 线性矩阵不等式(LMI) h_(∞)性能指标
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Robust H_∞ output feedback controller design for uncertain discrete-time switched systems via switched Lyapunov functions 被引量:3
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作者 Du Dongsheng Jiang Bin 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2007年第3期584-590,共7页
The H∞ output feedback control problem for uncertain discrete-time switched systems is reasearclled. A new characterization of stability and H∞ performance for the switched system under arbitrary switching is obtain... The H∞ output feedback control problem for uncertain discrete-time switched systems is reasearclled. A new characterization of stability and H∞ performance for the switched system under arbitrary switching is obtained by using switched Lyapunov function. Then, based on the characterization, a linear matrix inequality (LMI) approach is developed to design a switched output feedback controller which guarantees the stability and H∞ performance of the closed-loop system. A numerical example is presented to demonstrate the application of the proposed method. 展开更多
关键词 h performance LMI output feedback robustly stable.
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Robustness-tracking control based on sliding mode and H_∞ theory for linear servo system 被引量:1
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作者 田艳丰 郭庆鼎 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2005年第2期213-217,共5页
A robustness-tracking control scheme based on combining H_∞ robust control and sliding mode control is proposed for a direct drive AC permanent-magnet linear motor servo system to solve the conflict between tracking ... A robustness-tracking control scheme based on combining H_∞ robust control and sliding mode control is proposed for a direct drive AC permanent-magnet linear motor servo system to solve the conflict between tracking and robustness of the linear servo system. The sliding mode tracking controller is designed to ensure the system has a fast tracking characteristic to the command, and the H_∞ robustness controller suppresses the disturbances well within the close loop(including the load and the end effect force of linear motor etc.) and effectively minimizes the chattering of sliding mode control which influences the steady state performance of the system. Simulation results show that this control scheme enhances the track-command-ability and the robustness of the linear servo system, and in addition, it has a strong robustness to parameter variations and resistance disturbances. 展开更多
关键词 permanent-magnet linear synchronous motor sliding mode control h_∞ robust control DIRECT-DRIVE end-effect
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Highly reinforce the interface stability using 2-Phenyl-1H-imidazole-1-sulfonate electrolyte additive to enhance the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries 被引量:1
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作者 Xin He Yiting Li +8 位作者 Wenlian Wang Xueyi Zeng Huilin Hu Haijia Li Weizhen Fan Chaojun Fan Jian Cai Zhen Ma Junmin Nan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第5期10-22,I0001,共14页
This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_... This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries.After 450 cycles at room temperature(25℃),the discharge capacity retentions of batteries with blank and PHIS-containing electrolyte are 56.03%and 94.92%respectively.After 230 cycles at high temperatures(45℃),their values are 75.30%and 88.38%respectively.The enhanced electrochemical performance of the batteries with PHIS-containing electrolyte is supported by the spectroscopic characterization and theoretical calculations.It is demonstrated that this PHIS electrolyte additive can facilitate the construction of the electrode interface films,remove the H2O/HF in the electrolyte,and improve the electrochemical performance of the batteries.This work not only develops a sulfonate-based electrolyte but also can stimulate new ideas of functional additives to improve the battery performance. 展开更多
关键词 LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite battery high temperature performance h_(2)O/hF scavenger 2-Phenyl-1h-imidazole-1-sulfonate Electrolyte additive
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Robust State Feedback H_∞Control for Dynamic Biped Robot Based on T-S Fuzzy Model
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作者 HUAI Chuangfeng FANG Yuefa (Department of Mechanical Engineering,Beijing Jiaotong University,Beijing 10044,E-mall: hcf811225@163.com) 《武汉理工大学学报》 CAS CSCD 北大核心 2006年第S3期951-955,共5页
T-S fuzzy model was applied to describe nonlinear system and global fuzzy model was expressed by the form of uncertain system.Based on robust state feedback H_∞control strategy,designed a global asymptotic steady fuz... T-S fuzzy model was applied to describe nonlinear system and global fuzzy model was expressed by the form of uncertain system.Based on robust state feedback H_∞control strategy,designed a global asymptotic steady fuzzy model.This control system can use the experimental input-output data pairs for the biped robot learning and walking with dynamic balance.It is proved by simulation result that robust state feedback H_∞control method based on T-S fuzzy model can effectively restrain the effect of model uncertainties and external disturbance acting on biped robot.From these works,we showed the satisfactory performance of joint tracking without any chattering. 展开更多
关键词 robust h_∞control state feedback T-S FUZZY model BIPED walking robot FUZZY system
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Robust H_∞/LTR State-Feedback Synthesis Method
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作者 翁正新 王广雄 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 1994年第2期30-33,共4页
This paper focuses on the H_ mixed sensitivity problems of the system with input multiplicative uncertainty, and proposes a new robust H_ /LTR synthesis method. The design procedure consists of two steps. First, an H_... This paper focuses on the H_ mixed sensitivity problems of the system with input multiplicative uncertainty, and proposes a new robust H_ /LTR synthesis method. The design procedure consists of two steps. First, an H_ full state feedback control is designed to satisfy the robust stability and performance specifications. Subsequently, the properties of the state feedback are reobtained by designing full state observers. 展开更多
关键词 ss: h_ /LTR CONTROL h_ state feedback robust CONTROL
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基于H_(∞)控制器的阀控非对称缸位置伺服系统控制
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作者 李虎山 孙淼 +3 位作者 王猛 高有山 席浩 郝建楠 《机床与液压》 北大核心 2024年第14期7-13,共7页
以阀控非对称缸位置伺服系统为研究对象,建立其数学模型;针对负载突变及油液弹性模量变化提出了H∞鲁棒控制方法,从频域上分析了控制器对系统动态性能和稳态性能的影响。采用AMESim和MATLAB/Simulink搭建了阀控非对称缸位置伺服系统的... 以阀控非对称缸位置伺服系统为研究对象,建立其数学模型;针对负载突变及油液弹性模量变化提出了H∞鲁棒控制方法,从频域上分析了控制器对系统动态性能和稳态性能的影响。采用AMESim和MATLAB/Simulink搭建了阀控非对称缸位置伺服系统的联合仿真模型,对不同工况下控制器的跟踪精度及抗扰能力进行仿真研究。最后,通过油缸加载实验测试平台对仿真结果进行进一步验证。结果表明:所设计的H∞控制器提高了系统的快速性和鲁棒性,相比于PID控制下系统正弦响应结果,H∞控制器的最大跟踪误差在无负载工况下降低了48.8%,在负载突变工况下降低了56.25%;同时阶跃响应时间缩短了7.5%。 展开更多
关键词 位置伺服系统 h∞控制器 非对称缸控制
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Output Feedback Robust H_(∞) Control for Discrete 2D Switched Systems
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作者 Wenjun Gao Yang Yang +3 位作者 Hongtao Duan Mingsheng Li Jinrong Ma Songwei Jin 《Computer Systems Science & Engineering》 SCIE EI 2021年第10期69-85,共17页
The two-dimensional(2-D)system has a wide range of applications in different fields,including satellite meteorological maps,process control,and digital filtering.Therefore,the research on the stability of 2-D systems ... The two-dimensional(2-D)system has a wide range of applications in different fields,including satellite meteorological maps,process control,and digital filtering.Therefore,the research on the stability of 2-D systems is of great significance.Considering that multiple systems exist in switching and alternating work in the actual production process,but the system itself often has external perturbation and interference.To solve the above problems,this paper investigates the output feedback robust H_(∞)stabilization for a class of discrete-time 2-D switched systems,which the Roesser model with uncertainties represents.First,sufficient conditions for exponential stability are derived via the average dwell time method,when the system’s interference and external input are zero.Furthermore,in the case of introducing the external interference,the weighted robust H_(∞)disturbance attenuation performance of the underlying system is further analyzed.An output feedback controller is then proposed to guarantee that the resulting closed-loop system is exponentially stable and has a prescribed disturbance attenuation levelγ.All theorems mentioned in the article will also be given in the form of linear matrix inequalities(LMI).Finally,a numerical example is given,which takes two uncertain values respectively and solves the output feedback controller’s parameters by the theorem proposed in the paper.According to the required controller parameter values,the validity of the theorem proposed in the article is compared and verified by simulation. 展开更多
关键词 2-D systems robust h_(∞)control LMI output feedback switched systems Roesser model
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外源H_(2)O_(2)对盐胁迫下棉花幼苗生理特性的影响
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作者 肖陈耀东 刘涛 +1 位作者 刘仕志 张淑英 《华北农学报》 CSCD 北大核心 2024年第5期93-101,共9页
为探明外源H_(2)O_(2)对NaCl胁迫下棉花幼苗的生理调节机制,以棉花品种新陆早48号为供试材料,使用室外盆栽法,设置盐胁迫(NaCl,浓度梯度0,100,200 mmol/L)和H_(2)O_(2)(浓度梯度0,0.005,0.010,0.020,0.050 mmol/L)两因素随机组合,探究... 为探明外源H_(2)O_(2)对NaCl胁迫下棉花幼苗的生理调节机制,以棉花品种新陆早48号为供试材料,使用室外盆栽法,设置盐胁迫(NaCl,浓度梯度0,100,200 mmol/L)和H_(2)O_(2)(浓度梯度0,0.005,0.010,0.020,0.050 mmol/L)两因素随机组合,探究棉花幼苗鲜质量、干质量、叶绿素含量、叶绿素荧光参数、光合气体参数、抗氧化酶活性和渗透调节系统的变化规律。结果表明,外源H_(2)O_(2)有效缓解盐胁迫对棉花幼苗生长的抑制效应,提高棉花幼苗叶绿素含量、光合气体参数、叶绿素荧光参数,维持棉花幼苗光合作用正常运行,保证了干物质的积累;同时,外源H_(2)O_(2)提高抗氧化酶(POD、APX、CAT)活性,加速清除棉花幼苗体内ROS,降低了电解质渗出率、MDA含量及Pro、游离氨基酸、SS等渗透调节物质含量,提高棉苗抗盐性。其中0.020 mmol/L外源H_(2)O_(2)对棉花幼苗所受盐胁迫缓解作用最佳。综上,外源H_(2)O_(2)通过提高盐胁迫棉花幼苗光合性能,保持棉花幼苗稳定的光合作用,维持棉花幼苗体内ROS产生与消除的动态平衡,从而提高棉花幼苗对盐胁迫的适应性。 展开更多
关键词 棉花幼苗 盐胁迫 外源h_(2)O_(2) 光合特性 抗氧化酶系
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Eliminating H_(2)O/HF and regulating interphase with bifunctional tolylene-2,4-diisocyanate(TDI)additive for long life Li-ion battery 被引量:2
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作者 Xueyi Zeng Xiang Gao +8 位作者 Peiqi Zhou Haijia Li Xin He Weizhen Fan Chaojun Fan Tianxiang Yang Zhen Ma Xiaoyang Zhao Junmin Nan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期519-528,I0011,共11页
Lithium-ion batteries(LIBs)featuring a Ni-rich cathode exhibit increased specific capacity,but the establishment of a stable interphase through the implementation of a functional electrolyte strategy remains challengi... Lithium-ion batteries(LIBs)featuring a Ni-rich cathode exhibit increased specific capacity,but the establishment of a stable interphase through the implementation of a functional electrolyte strategy remains challenging.Especially when the battery is operated under high temperature,the trace water present in the electrolyte will accelerate the hydrolysis of the electrolyte and the resulting HF will further erode the interphase.In order to enhance the long-term cycling performance of graphite/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)LIBs,herein,Tolylene-2,4-diisocyanate(TDI)additive containing lone-pair electrons is employed to formulate a novel bifunctional electrolyte aimed at eliminating H_(2)O/HF generated at elevated temperature.After 1000 cycles at 25℃,the battery incorporating the TDI-containing electrolyte exhibits an impressive capacity retention of 94%at 1 C.In contrast,the battery utilizing the blank electrolyte has a lower capacity retention of only 78%.Furthermore,after undergoing 550 cycles at 1 C under45℃,the inclusion of TDI results in a notable enhancement of capacity,increasing it from 68%to 80%.This indicates TDI has a favorable influence on the cycling performance of LIBs,especially at elevated temperatures.The analysis of the film formation mechanism suggests that the lone pair of electrons of the isocyanate group in TDI play a crucial role in inhibiting the generation of H_(2)O and HF,which leads to the formation of a thin and dense interphase.The existence of this interphase is thought to substantially enhance the cycling performance of the LIBs.This work not only improves the performance of graphite/NCM811 batteries at room temperature and high temperature by eliminating H_(2)O/HF but also presents a novel strategy for advancing functional electrolyte development. 展开更多
关键词 Graphite/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)battery Tolylene-2 4-diisocyanate Long-cycling performance h_(2)O/hF eliminated additive
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