The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these i...The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these issues,based on Rock-Eval pyrolysis,kerogen macerals,H/C and O/C ratios,GC-MS,major and trace elements,the Dongying Formation Member(Mbr)3(E_(3)d_(3)),the Shahejie Formation mbrs 1 and 2(E_(2)s_(1+2)),and the Shahejie Mbr 3(E_(2)s_(3))source rocks in the western Bozhong Sag were studied.The above methods were used to reveal their geochemical properties,OM origins and depositional environments,all of which indicate that E_(2)s_(1+2)and E_(2)s_(3)are excellent source rocks,and that E_(3)d_(3)is of the second good quality.E_(3)d_(3)source rocks were formed under a warm and humid climate,mainly belong to fluvial/delta facies,the E_(3)d_(3)sediments formed under weakly oxidizing and freshwater conditions.Comparatively,the depositional environments of E_(2)s_(1+2)source rocks were arid and cold climate,representing saline or freshwater lacustrine facies,and the sediments of E_(2)s_(1+2)belong to anoxic or suboxic settings with large evaporation and salinity.During the period of E_(2)s_(3),the climate became warm and humid,indicating the freshwater lacustrine facies,and E_(2)s_(3)was characterized by freshwater and abundant algae.Moreover,compared with other intervals,the OM origin of E_(3)d_(3)source rocks has noticeable terrestrial input.The OM origin of the E_(2)s_(1+2)and E_(2)s_(3)are mainly plankton and bacteria.Tectonic subsidence and climate change have affected the changes of the depositional environment in the western Bozhong Sag,thus controlling the distribution of the source rocks,the geochemical characteristics in the three intervals of lacustrine source rocks have distinct differences.Overall,these factors are effective to evaluate the paleoenvironmental characteristics of source rocks by biomarkers,major and trace elements.The established models may have positive implications for research of lacustrine source rocks in offshore areas with few drillings.展开更多
The coal-measure source rock in the Chinese sea area plays a significant role as a hydrocarbon source rock,with its genetic environment,development and distribution,and hydrocarbon generation potential serving as esse...The coal-measure source rock in the Chinese sea area plays a significant role as a hydrocarbon source rock,with its genetic environment,development and distribution,and hydrocarbon generation potential serving as essential factors for the exploration of coal-type oil and gas fields.This study focuses on the coal-measure source rock of the Paleogene Enping Formation in the ZhuⅠDepression,located in the northern South China Sea.The main geological insights obtained are as follows.The coal measures of the Enping Formation are developed in a warm and wet tropical-subtropical climate.The development environment of the coal-measure source rock in the Enping Formation includes the braided river delta upper plain peat swamp,characterized by dry forest swamp coal facies with relatively thick coal seams and a small number of layers.The braided river delta lower plain swamp-interdistributary bay of braided river delta front represents a forest edge-wetland herbaceous swamp coal facies with numerous layers of thin coal seams and poor stability.The shore swamp corresponds to an open water swamp coal facies with multiple layers of thin coal seams and poor stability.The organic matter abundance in the braided river delta upper plain is the highest,followed by the braided river delta lower plain-braided river delta front,and the shore-shallow lake.The organic matter type is predominantly typeⅡ1.Thermal evolution analysis suggests that the organic matter has progressed into a substantial oil generation stage.The hydrocarbon generation potential of the coal-measure source rock in the Enping Formation is the highest in the braided river delta upper plain,followed by the braided river delta lower plain-braided river delta front and the shore-shallow lake.Overall,this study proposes three organic facies in the coal-measure source rock of the Enping Formation:upper-plain swamp-dry forest swamp facies,lower plain-interdistributary bay-forest-herbaceous swamp facies,and lake swamp-herbaceous swamp facies.展开更多
With the increasing scarcity of Earth’s resources and the development of space science and technology,the exploration, development, and utilization of deep space-specific material resources(minerals, water ice, volat...With the increasing scarcity of Earth’s resources and the development of space science and technology,the exploration, development, and utilization of deep space-specific material resources(minerals, water ice, volatile compounds, etc.) are not only important to supplement the resources and reserves on Earth but also provide a material foundation for establishing extraterrestrial research bases. To achieve large depth in-situ condition-preserved coring(ICP-Coring) in the extreme lunar environment, first, lunar rock simulant was selected(SZU-1), which has a material composition, element distribution, and physical and mechanical properties that are approximately equivalent to those of lunar mare basalt. Second, the influence of the lunar-based in-situ environment on the phase, microstructure, and thermal physical properties(specific heat capacity, thermal conductivity, thermal diffusivity, and thermal expansion coefficient)of SZU-1 was explored and compared with the measured lunar rock data. It was found that in an air atmosphere, low temperature has a more pronounced effect on the relative content of olivine than other temperatures, while in a vacuum atmosphere, the relative contents of olivine and anorthite are significantly affected only at temperatures of approximately-20 and 200 ℃. When the vacuum level is less than100 Pa, the contribution of air conduction can be almost neglected, whereas it becomes dominant above this threshold. Additionally, as the testing temperature increases, the surface of SZU-1 exhibits increased microcracking, fracture opening, and unevenness, while the specific heat capacity, thermal conductivity,and thermal expansion coefficient show nonlinear increases. Conversely, the thermal diffusivity exhibits a nonlinear decreasing trend. The relationship between thermal conductivity, thermal diffusivity, and temperature can be effectively described by an exponential function(R^(2)>0.98). The research results are consistent with previous studies on real lunar rocks. These research findings are expected to be applied in the development of the test and analysis systems of ICP-Coring in a lunar environment and the exploration of the mechanism of machine-rock interaction in the in-situ drilling and coring process.展开更多
In the Hunan-Guizhou-Guangxi area there have developed very thick bedded siliceous rocks of the late Sinian. The rocks have a fairly pure composition, with an average content of siliceous minerals exceeding 95%. They ...In the Hunan-Guizhou-Guangxi area there have developed very thick bedded siliceous rocks of the late Sinian. The rocks have a fairly pure composition, with an average content of siliceous minerals exceeding 95%. They are relatively rich in Fe and Mn, and poor in Al, Ti and Mg. The Fe/Ti, (Fe+Mn)/Ti, Al/(Al+Fe+Mn) and U/Th ratios and the Al-Fe-Mn and Fe-Mn-(Ni+Co+Cu)×10 triangle diagrams all show that they are hydrothermal sedimentary siliceous rocks. In the rocks the total amount of REEs is low, the δCe shows an obvious negative anomaly and the δEu a weak anomaly, and LREE>HREE, all indicating that they are products of hydrothermal processes. The δ30Si and δ18O values, as well as the formation temperature of the rocks all clearly show that the silica forming the rocks comes from hot water. Besides, analyses of the depositional environment of the rocks using the MnO/TiO2 ratio and the δCe and δ30Si values yield the same conclusion that they are formed in environments from continental marginal slopes of a bathyal environment to oceanic basins of a deep-sea environment.展开更多
The Paleocene mudrocks in Ghana’s Tano Basin have received limited attention despite ongoing efforts to explore hydrocarbon resources.A thorough geochemical analysis is imperative to assess these mudrocks’petroleum ...The Paleocene mudrocks in Ghana’s Tano Basin have received limited attention despite ongoing efforts to explore hydrocarbon resources.A thorough geochemical analysis is imperative to assess these mudrocks’petroleum generation potential and formulate effective exploration strategies.In this study,a comprehensive geochemical analysis was carried out on ten Paleocene rock cuttings extracted from TP-1,a discovery well within the Tano Basin.Various analytical techniques,including total organic carbon(TOC)analysis,Rock–Eval pyrolysis,gas chromatography-mass spectrometry,and isotope ratio-mass spectrometry,were employed to elucidate their hydrocar-bon potential and organic facies.Thefindings in this study were subsequently compared to existing geochemical data on Paleocene source rocks in the South Atlantic marginal basins.The results indicated that the Paleocene samples have TOC content ranging from 0.68 to 2.93 wt%.The prevalent kerogen types identified in these samples were Type Ⅱ and Type Ⅲ.Molecular and isotope data suggest that the organic matter found in the Paleocene mudrocks can be traced back to land plants and lower aquatic organisms.These mudrocks were deposited in a transi-tional environment withfluctuating water salinity,charac-terized by sub-oxic redox conditions.Maturity indices,both bulk and molecular,indicated a spectrum of maturity levels within the Paleocene mudrocks,spanning from immature to marginally mature,with increasing maturity observed with greater depth.In comparison,the organic composition and depositional environments of Paleocene source rocks in the Tano Basin closely resemble those found in the Niger Delta Basin,Douala,and Kribi-Campo Basins,the Kwanza Formation in Angola,and certain Brazilian marginal basins.However,it is worth noting that Paleocene source rocks in some of the basins,such as the Niger Delta and Brazilian marginal basins,exhibit rela-tively higher thermal maturity levels compared to those observed in the current Paleocene samples from the Tano Basin.In conclusion,the comprehensive geochemical analysis of Paleocene mudrocks within Ghana’s Tano Basin has unveiled their marginal hydrocarbon generation potential.The shared geochemical characteristics between the Paleocene mudrocks in the Tano Basin and those in the nearby South Atlantic marginal basins offer valuable insights into source rock quality,which is crucial for shaping future strategies in petroleum exploration in this region.展开更多
Deep in-situ rock mechanics considers the influence of the in-situ environment on mechanical properties,differentiating it from traditional rock mechanics.To investigate the effect of in-situ stress,pore pressure pres...Deep in-situ rock mechanics considers the influence of the in-situ environment on mechanical properties,differentiating it from traditional rock mechanics.To investigate the effect of in-situ stress,pore pressure preserved environment on the mechanical difference of sandstone,four tests are numerically modeled by COMSOL:conventional triaxial test,conventional pore pressure test,in-situ stress restoration and reconstruction test,and in-situ pore pressure-preserved test(not yet realized in the laboratory).The in-situ stress restoration parameter is introduced to characterize the recovery effect of in-situ stress on elastic modulus and heterogeneous distribution of sandstone at different depths.A random function and nonuniform pore pressure coefficient are employed to describe the non-uniform distribution of pore pressure in the in-situ environment.Numerical results are compared with existing experimental data to validate the models and calibrate the numerical parameters.By extracting mechanical parameters from numerical cores,the stress-strain curves of the four tests under different depths,in-situ stress and pore pressure are compared.The influence of non-uniform pore pressure coefficient and depth on the peak strength of sandstone is analyzed.The results show a strong linear relationship between the in-situ stress restoration parameter and depth,effectively characterizing the enhanced effect of stress restoration and reconstruction methods on the elastic modulus of conventional cores at different depths.The in-situ pore pressurepreserved test exhibits lower peak stress and peak strain compared to the other three tests,and sandstone subjected to non-uniform pore pressure is more prone to plastic damage and failure.Moreover,the influence of non-uniform pore pressure on peak strength gradually diminished with increasing depth.展开更多
Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatograph...Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry.The bulk carbon isotopic values of the whole rock extracts,saturate and aromatic fractions range from–28.7‰to–26.8‰,–29.2‰to–27.2‰and–28.5‰to–26.7‰,respectively while the bulk carbon isotopic values of the whole oils,saturate and aromatic fractions range from–25.4‰to–27.8‰,–25.9‰to–28.4‰and–23.5‰to–26.9‰,respectively.The average carbon isotopic compositions of individual alkanes(nC12-nC33)in the rock samples range from–34.9‰to–28.2‰whereas the average isotopic values of individual n-alkanes in the oils range from–31.1‰to–23.8‰.Theδ13C isotope ratios of pristane and phytane in the rock samples range from–29.2‰to–28.2‰and–30.2‰to–27.4‰respectively while the pristane and phytane isotopic values range from–32.1‰to–21.9‰and–30.5‰to–26.9‰,respectively.The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments.The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.展开更多
The Songliao Basin, one of the biggest continental petroliferous basins in eastern China, is a Mesozoic- Cenozoic fault-depressed and fault-subsided basin developed on the Hercynian fold basement. Generally, rearrange...The Songliao Basin, one of the biggest continental petroliferous basins in eastern China, is a Mesozoic- Cenozoic fault-depressed and fault-subsided basin developed on the Hercynian fold basement. Generally, rearranged hopanes are considered to be formed by clay- mediated acidic catalysis under oxic or suboxic environment, whereas high abundance of rearranged hopanes were found in hydrocarbon source rocks and crude oils that are derived from salty environment in the Songliao Basin. This phenomenon rarely happens all over the world.展开更多
Objective The distribution of rearranged hopanes in hydrocarbon source rocks is influenced by thermal maturity and original source input, and is also controlled by depositional conditions. Through comparison of lacus...Objective The distribution of rearranged hopanes in hydrocarbon source rocks is influenced by thermal maturity and original source input, and is also controlled by depositional conditions. Through comparison of lacustrine and coal-bearing source rocks, this work attempted to analyze the composition and origin of rearranged hopanes in hydrocarbon source rocks. Taken the source rocks from the Songliao Basin, Ordos Basin and Kuqa Depression as examples, we aimed to investigate the effect of the redox conditions, water salinity and oxygen content of the source-rock depositional environment on the formation of rearranged hopanes to provide theoretical basis for the genesis of rearranged hopanes.展开更多
Granitoids,volcanic rocks and cherts,mainly of early Paleozoic,in northern Altyn Tagh(Fig.1) are analyzed here for the purpose of the determination of the tectonic environments and their development since Early Paleoz...Granitoids,volcanic rocks and cherts,mainly of early Paleozoic,in northern Altyn Tagh(Fig.1) are analyzed here for the purpose of the determination of the tectonic environments and their development since Early Paleozoic.(1) Granitoids\ The collection of 128 main\|element petrochemical data from North Altyn Tagh area shows that most of the granitoids here are granites and granodiorites of calc\|alkaline series.They consist mainly of metaluminous and peraluminous in Shand’s index,and only one of them,which belongs to Mesozoic,is peralkaline.Most of the granitoids plot in the IAG+CAG+CCG fields in the Maniar and Piccoli’s diagrams (1989) for tectonic discrimination of granitoids.IAG (Island arc granitoids)and CAG (Continental arc granitoids) can be distinguished for Early and Late Paleozoic granitoids,and maybe some CCG (Continental collision granitoids) for Early Paleozoic.Granitoids of Mesozoic and Cenozoic inherited the characteristics of those of Paleozoic.Destructive active plate margin (pre\|plate collision)and Anatectic magmatism(syn\|orogenic,S\|type granites)are distinguished (Fig.2)for Paleozoic granitoids using de la Roche R 1\| R 2 multicationic diagram (Batchelor and Bowden,1985).Mesozoic and Cenozoic granitoids inherited the characteristics of Anatectic magmatism (syn\|orogenic)of these early ones,and post\|orogenic(A\|type)granites occurred in Mesozoic.The mechanism for magma formation is mainly partial melting.展开更多
Se-rich black rock series of the Middle and Late Permian system is widely distributed in Enshi Prefecture with an exposed area of 850 km~2,among which the unique Yutangba black rock series independent selenium deposit...Se-rich black rock series of the Middle and Late Permian system is widely distributed in Enshi Prefecture with an exposed area of 850 km~2,among which the unique Yutangba black rock series independent selenium deposit with industrial mining significance in the world is produced.However,the source and metallogenic mechanisms of Se are still controversial.In general,terrestrial weathering and submarine hydrothermal processes are the main source end members of Si and Se,and the related siliceous rocks record the deposition process of Si and Se from different sources.The study of lithofacies and paleogeography shows that western Hubei belongs to the near eastwest turn of the Yangzi platform in the Middle and Late Permian and becomes an inter-platform basin with nearly north-south direction.Therefore,the comparative study of the Yutangba deposit and the selenium-rich black rock series in the northern Shadi with high selenium content is expected to reveal the provenance evolution of the two sections in space,and further restrict the Se mineralization mechanism in the Enshi basin.From the element geochemistry study,the black rock series in two study areas may have formed in a transitional position of either the continental margin or continental slope,in the process of sedimentary,more terrigenous clastic materials entered.They are rich in lithophile elements V and Cr.δU>1.0,U/Th and V/(V+Ni)ratio indicate that the Se-rich strata of black rock series in the Enshi areas occurred in an anoxic reducing environment and formed in an environment between the ocean basin and the continental margin.From Si-O isotope geochemistry,the original Si source of the study area is thought to relate to a volcanic eruption,which leads to the enrichment of Si in the seawater.The determined values of S isotope in the black rock series of the two study areas both show the characteristics related to organic reduction/biogenic.展开更多
The Douala sedimentary basin in Cameroon is the main gas prospective basin in the country and has witnessed a number of investigations in this regard. The Nkapa Formation is one of the basin’s principal rock units an...The Douala sedimentary basin in Cameroon is the main gas prospective basin in the country and has witnessed a number of investigations in this regard. The Nkapa Formation is one of the basin’s principal rock units and here we analyzed samples from sediments comprising this formation in order to constrain their provenance, tectonic setting and depositional environment using geochemical traits. Major and trace elements were analyzed by inductively coupled plasma mass spectrometry. Elemental ratios provide information on geochemical signatures of Eu/Eu ratios of the sandstones and shales, suggesting the provenance of the sediments was felsic from continental rock protoliths. Calculated K</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O/Na</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O ratios > 1 is reminiscent of quartz-rich sediments deposited in passive margin (PM) environments with significant terrigenous input. The elemental ratios La/Sc, La/Ca, Th/Sc, and Th/Co suggest that the sediment sources are felsic and mafic in nature. </span></span><span style="font-family:Verdana;">The clastic sediments were normalized using North American Shale Composite (NASC). The Ni/Co and V/(V</span><span style="font-family:""> </span><span style="font-family:Verdana;">+</span><span style="font-family:""> </span><span style="font-family:Verdana;">Ni) ratios reveal that the sediments were deposited under variable conditions including euxinic, dysoxic and anoxic.</span><span style="font-family:Verdana;"> Overall, the evidence from discrimination diagrams using major and trace elements suggest</span><span style="font-family:"color:red;"> </span><span style="font-family:Verdana;">that the sediments were derived from mostly Passive margins (PM) and continental island arc (CIA) with minor Oceanic island arch (OIA) sources. Limestones from the studied area at Kompina, rich in calcium carbonate above 98.5% make the</span><span style="font-family:Verdana;">m</span><span style="font-family:Verdana;"> suitable for use in the chemical industries. In addition the felsic and mafic source rocks can lead to formation of light and dark colored minerals which can be of economic value.展开更多
In order to reveal the sedimentary environment of carbonate rocks in Nanfen Formation of Qingbaikou System in Tonghua,Jilin Province,the mineral composition and petrochemistry of carbonate rocks in Nanfen Formation we...In order to reveal the sedimentary environment of carbonate rocks in Nanfen Formation of Qingbaikou System in Tonghua,Jilin Province,the mineral composition and petrochemistry of carbonate rocks in Nanfen Formation were analyzed.The mineral compositions of five carbonate rock samples in Nanfen Formation mainly consist of calcite,with minor clay minerals and quartz,and the rock type is siliceous marlite.The Mn/Sr va-lues range from 1.52 to 4.08,with an average of 2.64,indicating that the carbonate rocks experienced weak diagenesis;the Sr/Ba values range from 1.26 to 2.51,with an average of 1.93,indicating marine environment;the ratio of Mg/Al ranges from 35.33 to 86.34,with an average of 62.95,indicating the seawater environment,which is consistent with the result from Sr/Ba;the MgO/CaO values range from 0.01 to 0.04,with an average of 0.02,indicating humid environment;the values of V/(V+Ni)range from 0.63 to 0.73,with an average of 0.70,indicating anoxic environment.In summary,geochemical analyses show that the Nanfen Formation carbonate rocks are marine deposits,in a warm,humid,anoxic environment with poor flow of seawater,and subsequently underwent weak diagenetic alteration.展开更多
Extensive volcanism is one of the important features of Cenozoic geology in China.Based on temporal-spatial distribution,the volcanism was associated with three major different geological settings:1)the continental ri...Extensive volcanism is one of the important features of Cenozoic geology in China.Based on temporal-spatial distribution,the volcanism was associated with three major different geological settings:1)the continental rift basalts in Northeast and North China;2)the tension-fault basalts on the continental margins of Southeast China; and 3) the collision-zone high-K volcanics in the Qinghai-Xizang Plateau and its vicinities.The characteristics of 'depletion in the south and enrichment in the north'of the China continental mantle are strongly supported by isotopic evidence.The Cenozoic continental cal characters,into the following geochemical provinces:1)the depleted mantle in South China;2)the primary mantle in Northeast and NorthChina; 3)the hybrid and transi-tional mantle in the region of Shandong ,Anhui,Jiangsu and northern Zhejiang;4)the depleted mantle around the Bohai Bay and the Lower Liaohe River;5)the K-metasomatic enriched mantle in the northern part of Northeast China;and 6)the re-cycled enriched mantle in the ancient subduction zone in the Qinghai-Xizang Plateau and its surround-ings.These geochemical characteristics on a regional scale must be a reflection of the nature of lithosphere evolution.展开更多
Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the ...Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the Yangtze paraplatform.There are sporadically magmatic rocks and fold basement made up of upper Archaeozoicmiddle and lower Proterozoic strata.The sedimentary cover consists of Sinian-lower Paleozoic marine sediments,Mesozoic-Cenozoic intercalated marine and nonmarine sediments or nonmarine sediments.展开更多
This paper is aimed to analyze the current situation and problems about land use of various karst environments via field survey,documentation and comparison methods,and to make reasonable recommendations about land us...This paper is aimed to analyze the current situation and problems about land use of various karst environments via field survey,documentation and comparison methods,and to make reasonable recommendations about land use and management for different karst types in a bid to provide theoretical and practical basis for optimization of karst land use and the comprehensive control of karst rock desertification.The results show that,①as the bare karst areas are lack of water and soil and highly vulnerable to droughts and floods,land utilization in such areas should follow the principles of soil and water conservation and ecological restoration,emphasize both the ecological benefit and the economic benefits and reasonably configure the land resources to achieve virtuous circle;②in covered karst areas,the most important task is to take measures to prevent the appearance of secondary karst rock desertification,water exhaustion and karst collapse;③the buried karst areas shall mainly focus on prevention of overlaying sand shale collapse,and possible pollution of deep karst water and the surface land resulted from exploration and exploitation of oil and gas and geothermal water.④The final conclusion is that features and problems of land utilization of the three karst types are different from each other,and that the general principle for land use in karst regions shall be based on the local conditions.展开更多
Guizhou Province is one of the least developed areas with the largest number of counties in poverty and the widest coverage of karst landscape in China. The vulnerability of its karst eco-environment seriously threate...Guizhou Province is one of the least developed areas with the largest number of counties in poverty and the widest coverage of karst landscape in China. The vulnerability of its karst eco-environment seriously threatens the survival of local residents and the development of local economy. Rapid population growth results in higher demand of various resources, which leads to more intensive development activities. For example, the blindfolded development on steep slopes has caused rock desertification of local rare soil in this karst area. It has induced a vicious circle in the poverty→population growth→ecosystem degradation and so on. About 3.13×106 people belong to the absolute impoverished population in Guizhou Province and most of them are living in rock-desertification areas. The essential reasons for destitution are the atrocious eco-environment and the huge population stress. Degradation of mountain ecosystems in southwestern China has continued at unprecedented speed and scale in recent decades. It is necessary to control population growth strictly and prevent further expansion of rock-desertification in order to develop local economy and better living conditions for local people. The only way to ensure a sustainable, stable and harmonious development of human, nature and economy is to restore a good condition of eco-environment and resolve the conflicts between human and land use.展开更多
The molecular organic compounds have been identified by gas chromatography (GC) and GC-mass spectrometry (GC-MS) from Mesoproterozoic rocks in the Xuaniong (宣龙) depression in North China. The main saturated co...The molecular organic compounds have been identified by gas chromatography (GC) and GC-mass spectrometry (GC-MS) from Mesoproterozoic rocks in the Xuaniong (宣龙) depression in North China. The main saturated compounds are n-alkanes, monomethylalkanes, n-alkylcyclohexanes, acyclic isoprenoids, and hopanes. The dominant lower-molecular-weight n-alkanes are indicative of the main contribution of microorganisms, in particular, the chemosynthetic bacteria. The presence of abundant monomethylalkanes (mid- and end-branched) and the long chained (〉C20) acyclic isoprenoids indicates the existence of abundant bacteria and/or archaea in ancient oceans. The low abundance of pristane and phytane is suggestive of the relatively low abundance of photosynthetic autotrophs in comparison with chemosynthetic bacteria in the Mesoproterozoic oceans in North China. The sedimentary environmental condition is suboxic/anoxic, as indicated by the low value of the Pr/Ph ratio as well as the presence of abundant sulfur-bearing organic compounds, consistent with the other geochemical data in North China and elsewhere in the world. Both the composition of the primary producers and the sedimentary environmental conditions are favorable for the formation of hydrocarbon source rocks.展开更多
基金funded by the“Key Scientific Issues and Innovative Technology Research on Oil and Gas Resource Exploration in China Sea Risk Exploration Area”(Grant No.CCL2022RCPS2017XNN)from CNOOC Research Institute,Beijing.
文摘The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these issues,based on Rock-Eval pyrolysis,kerogen macerals,H/C and O/C ratios,GC-MS,major and trace elements,the Dongying Formation Member(Mbr)3(E_(3)d_(3)),the Shahejie Formation mbrs 1 and 2(E_(2)s_(1+2)),and the Shahejie Mbr 3(E_(2)s_(3))source rocks in the western Bozhong Sag were studied.The above methods were used to reveal their geochemical properties,OM origins and depositional environments,all of which indicate that E_(2)s_(1+2)and E_(2)s_(3)are excellent source rocks,and that E_(3)d_(3)is of the second good quality.E_(3)d_(3)source rocks were formed under a warm and humid climate,mainly belong to fluvial/delta facies,the E_(3)d_(3)sediments formed under weakly oxidizing and freshwater conditions.Comparatively,the depositional environments of E_(2)s_(1+2)source rocks were arid and cold climate,representing saline or freshwater lacustrine facies,and the sediments of E_(2)s_(1+2)belong to anoxic or suboxic settings with large evaporation and salinity.During the period of E_(2)s_(3),the climate became warm and humid,indicating the freshwater lacustrine facies,and E_(2)s_(3)was characterized by freshwater and abundant algae.Moreover,compared with other intervals,the OM origin of E_(3)d_(3)source rocks has noticeable terrestrial input.The OM origin of the E_(2)s_(1+2)and E_(2)s_(3)are mainly plankton and bacteria.Tectonic subsidence and climate change have affected the changes of the depositional environment in the western Bozhong Sag,thus controlling the distribution of the source rocks,the geochemical characteristics in the three intervals of lacustrine source rocks have distinct differences.Overall,these factors are effective to evaluate the paleoenvironmental characteristics of source rocks by biomarkers,major and trace elements.The established models may have positive implications for research of lacustrine source rocks in offshore areas with few drillings.
基金The Scientific research project under contract under contract No.CCL2021RCPS172KQNFormation mechanism and distribution prediction of Cenozoic marine source rocks in Qiongdongnan and Pearl River Mouth Basin under contract No.2021KT-YXKY-01+2 种基金the resource potential,accumulation mechanism and breakthrough direction of potential oil-rich sags in offshore basins of China under contract No.2021-KT-YXKY-03the Open Foundation of Hebei Provincial Key Laboratory of Resource Survey and Researchthe National Natural Science Foundation of China(NSFC)under contract Nos 42072188,42272205。
文摘The coal-measure source rock in the Chinese sea area plays a significant role as a hydrocarbon source rock,with its genetic environment,development and distribution,and hydrocarbon generation potential serving as essential factors for the exploration of coal-type oil and gas fields.This study focuses on the coal-measure source rock of the Paleogene Enping Formation in the ZhuⅠDepression,located in the northern South China Sea.The main geological insights obtained are as follows.The coal measures of the Enping Formation are developed in a warm and wet tropical-subtropical climate.The development environment of the coal-measure source rock in the Enping Formation includes the braided river delta upper plain peat swamp,characterized by dry forest swamp coal facies with relatively thick coal seams and a small number of layers.The braided river delta lower plain swamp-interdistributary bay of braided river delta front represents a forest edge-wetland herbaceous swamp coal facies with numerous layers of thin coal seams and poor stability.The shore swamp corresponds to an open water swamp coal facies with multiple layers of thin coal seams and poor stability.The organic matter abundance in the braided river delta upper plain is the highest,followed by the braided river delta lower plain-braided river delta front,and the shore-shallow lake.The organic matter type is predominantly typeⅡ1.Thermal evolution analysis suggests that the organic matter has progressed into a substantial oil generation stage.The hydrocarbon generation potential of the coal-measure source rock in the Enping Formation is the highest in the braided river delta upper plain,followed by the braided river delta lower plain-braided river delta front and the shore-shallow lake.Overall,this study proposes three organic facies in the coal-measure source rock of the Enping Formation:upper-plain swamp-dry forest swamp facies,lower plain-interdistributary bay-forest-herbaceous swamp facies,and lake swamp-herbaceous swamp facies.
基金supported by the National Natural Science Foundation of China(Nos.U2013603 and 52225403)the Program for Guangdong Introducing Innovative and Entrepreneurial Teams(No.2019ZT08G315)the Shenzhen National Science Fund for Distinguished Young Scholars(No.RCJC20210706091948015).
文摘With the increasing scarcity of Earth’s resources and the development of space science and technology,the exploration, development, and utilization of deep space-specific material resources(minerals, water ice, volatile compounds, etc.) are not only important to supplement the resources and reserves on Earth but also provide a material foundation for establishing extraterrestrial research bases. To achieve large depth in-situ condition-preserved coring(ICP-Coring) in the extreme lunar environment, first, lunar rock simulant was selected(SZU-1), which has a material composition, element distribution, and physical and mechanical properties that are approximately equivalent to those of lunar mare basalt. Second, the influence of the lunar-based in-situ environment on the phase, microstructure, and thermal physical properties(specific heat capacity, thermal conductivity, thermal diffusivity, and thermal expansion coefficient)of SZU-1 was explored and compared with the measured lunar rock data. It was found that in an air atmosphere, low temperature has a more pronounced effect on the relative content of olivine than other temperatures, while in a vacuum atmosphere, the relative contents of olivine and anorthite are significantly affected only at temperatures of approximately-20 and 200 ℃. When the vacuum level is less than100 Pa, the contribution of air conduction can be almost neglected, whereas it becomes dominant above this threshold. Additionally, as the testing temperature increases, the surface of SZU-1 exhibits increased microcracking, fracture opening, and unevenness, while the specific heat capacity, thermal conductivity,and thermal expansion coefficient show nonlinear increases. Conversely, the thermal diffusivity exhibits a nonlinear decreasing trend. The relationship between thermal conductivity, thermal diffusivity, and temperature can be effectively described by an exponential function(R^(2)>0.98). The research results are consistent with previous studies on real lunar rocks. These research findings are expected to be applied in the development of the test and analysis systems of ICP-Coring in a lunar environment and the exploration of the mechanism of machine-rock interaction in the in-situ drilling and coring process.
文摘In the Hunan-Guizhou-Guangxi area there have developed very thick bedded siliceous rocks of the late Sinian. The rocks have a fairly pure composition, with an average content of siliceous minerals exceeding 95%. They are relatively rich in Fe and Mn, and poor in Al, Ti and Mg. The Fe/Ti, (Fe+Mn)/Ti, Al/(Al+Fe+Mn) and U/Th ratios and the Al-Fe-Mn and Fe-Mn-(Ni+Co+Cu)×10 triangle diagrams all show that they are hydrothermal sedimentary siliceous rocks. In the rocks the total amount of REEs is low, the δCe shows an obvious negative anomaly and the δEu a weak anomaly, and LREE>HREE, all indicating that they are products of hydrothermal processes. The δ30Si and δ18O values, as well as the formation temperature of the rocks all clearly show that the silica forming the rocks comes from hot water. Besides, analyses of the depositional environment of the rocks using the MnO/TiO2 ratio and the δCe and δ30Si values yield the same conclusion that they are formed in environments from continental marginal slopes of a bathyal environment to oceanic basins of a deep-sea environment.
基金funded by the State Key Petroleum Lab of Petroleum Resources and Prospecting at China University of Petroleum (Beijing)
文摘The Paleocene mudrocks in Ghana’s Tano Basin have received limited attention despite ongoing efforts to explore hydrocarbon resources.A thorough geochemical analysis is imperative to assess these mudrocks’petroleum generation potential and formulate effective exploration strategies.In this study,a comprehensive geochemical analysis was carried out on ten Paleocene rock cuttings extracted from TP-1,a discovery well within the Tano Basin.Various analytical techniques,including total organic carbon(TOC)analysis,Rock–Eval pyrolysis,gas chromatography-mass spectrometry,and isotope ratio-mass spectrometry,were employed to elucidate their hydrocar-bon potential and organic facies.Thefindings in this study were subsequently compared to existing geochemical data on Paleocene source rocks in the South Atlantic marginal basins.The results indicated that the Paleocene samples have TOC content ranging from 0.68 to 2.93 wt%.The prevalent kerogen types identified in these samples were Type Ⅱ and Type Ⅲ.Molecular and isotope data suggest that the organic matter found in the Paleocene mudrocks can be traced back to land plants and lower aquatic organisms.These mudrocks were deposited in a transi-tional environment withfluctuating water salinity,charac-terized by sub-oxic redox conditions.Maturity indices,both bulk and molecular,indicated a spectrum of maturity levels within the Paleocene mudrocks,spanning from immature to marginally mature,with increasing maturity observed with greater depth.In comparison,the organic composition and depositional environments of Paleocene source rocks in the Tano Basin closely resemble those found in the Niger Delta Basin,Douala,and Kribi-Campo Basins,the Kwanza Formation in Angola,and certain Brazilian marginal basins.However,it is worth noting that Paleocene source rocks in some of the basins,such as the Niger Delta and Brazilian marginal basins,exhibit rela-tively higher thermal maturity levels compared to those observed in the current Paleocene samples from the Tano Basin.In conclusion,the comprehensive geochemical analysis of Paleocene mudrocks within Ghana’s Tano Basin has unveiled their marginal hydrocarbon generation potential.The shared geochemical characteristics between the Paleocene mudrocks in the Tano Basin and those in the nearby South Atlantic marginal basins offer valuable insights into source rock quality,which is crucial for shaping future strategies in petroleum exploration in this region.
基金supported by the National Natural Science Foundation of China(Nos.51827901 and 52121003)the 111 Project(No.B14006)+1 种基金the Yueqi Outstanding Scholar Program of CUMTB(No.2017A03)the Fundamental Research Funds for the Central Universities(No.2022YJSNY13).
文摘Deep in-situ rock mechanics considers the influence of the in-situ environment on mechanical properties,differentiating it from traditional rock mechanics.To investigate the effect of in-situ stress,pore pressure preserved environment on the mechanical difference of sandstone,four tests are numerically modeled by COMSOL:conventional triaxial test,conventional pore pressure test,in-situ stress restoration and reconstruction test,and in-situ pore pressure-preserved test(not yet realized in the laboratory).The in-situ stress restoration parameter is introduced to characterize the recovery effect of in-situ stress on elastic modulus and heterogeneous distribution of sandstone at different depths.A random function and nonuniform pore pressure coefficient are employed to describe the non-uniform distribution of pore pressure in the in-situ environment.Numerical results are compared with existing experimental data to validate the models and calibrate the numerical parameters.By extracting mechanical parameters from numerical cores,the stress-strain curves of the four tests under different depths,in-situ stress and pore pressure are compared.The influence of non-uniform pore pressure coefficient and depth on the peak strength of sandstone is analyzed.The results show a strong linear relationship between the in-situ stress restoration parameter and depth,effectively characterizing the enhanced effect of stress restoration and reconstruction methods on the elastic modulus of conventional cores at different depths.The in-situ pore pressurepreserved test exhibits lower peak stress and peak strain compared to the other three tests,and sandstone subjected to non-uniform pore pressure is more prone to plastic damage and failure.Moreover,the influence of non-uniform pore pressure on peak strength gradually diminished with increasing depth.
文摘Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry.The bulk carbon isotopic values of the whole rock extracts,saturate and aromatic fractions range from–28.7‰to–26.8‰,–29.2‰to–27.2‰and–28.5‰to–26.7‰,respectively while the bulk carbon isotopic values of the whole oils,saturate and aromatic fractions range from–25.4‰to–27.8‰,–25.9‰to–28.4‰and–23.5‰to–26.9‰,respectively.The average carbon isotopic compositions of individual alkanes(nC12-nC33)in the rock samples range from–34.9‰to–28.2‰whereas the average isotopic values of individual n-alkanes in the oils range from–31.1‰to–23.8‰.Theδ13C isotope ratios of pristane and phytane in the rock samples range from–29.2‰to–28.2‰and–30.2‰to–27.4‰respectively while the pristane and phytane isotopic values range from–32.1‰to–21.9‰and–30.5‰to–26.9‰,respectively.The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments.The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.
基金supported by the National Natural Science Foundation of China(grant No.41272170)
文摘The Songliao Basin, one of the biggest continental petroliferous basins in eastern China, is a Mesozoic- Cenozoic fault-depressed and fault-subsided basin developed on the Hercynian fold basement. Generally, rearranged hopanes are considered to be formed by clay- mediated acidic catalysis under oxic or suboxic environment, whereas high abundance of rearranged hopanes were found in hydrocarbon source rocks and crude oils that are derived from salty environment in the Songliao Basin. This phenomenon rarely happens all over the world.
基金financed by the National Science Foundation of China(grant No.41272170)the National Oil and Gas Major Project(grant No.2016ZX05007-001)
文摘Objective The distribution of rearranged hopanes in hydrocarbon source rocks is influenced by thermal maturity and original source input, and is also controlled by depositional conditions. Through comparison of lacustrine and coal-bearing source rocks, this work attempted to analyze the composition and origin of rearranged hopanes in hydrocarbon source rocks. Taken the source rocks from the Songliao Basin, Ordos Basin and Kuqa Depression as examples, we aimed to investigate the effect of the redox conditions, water salinity and oxygen content of the source-rock depositional environment on the formation of rearranged hopanes to provide theoretical basis for the genesis of rearranged hopanes.
文摘Granitoids,volcanic rocks and cherts,mainly of early Paleozoic,in northern Altyn Tagh(Fig.1) are analyzed here for the purpose of the determination of the tectonic environments and their development since Early Paleozoic.(1) Granitoids\ The collection of 128 main\|element petrochemical data from North Altyn Tagh area shows that most of the granitoids here are granites and granodiorites of calc\|alkaline series.They consist mainly of metaluminous and peraluminous in Shand’s index,and only one of them,which belongs to Mesozoic,is peralkaline.Most of the granitoids plot in the IAG+CAG+CCG fields in the Maniar and Piccoli’s diagrams (1989) for tectonic discrimination of granitoids.IAG (Island arc granitoids)and CAG (Continental arc granitoids) can be distinguished for Early and Late Paleozoic granitoids,and maybe some CCG (Continental collision granitoids) for Early Paleozoic.Granitoids of Mesozoic and Cenozoic inherited the characteristics of those of Paleozoic.Destructive active plate margin (pre\|plate collision)and Anatectic magmatism(syn\|orogenic,S\|type granites)are distinguished (Fig.2)for Paleozoic granitoids using de la Roche R 1\| R 2 multicationic diagram (Batchelor and Bowden,1985).Mesozoic and Cenozoic granitoids inherited the characteristics of Anatectic magmatism (syn\|orogenic)of these early ones,and post\|orogenic(A\|type)granites occurred in Mesozoic.The mechanism for magma formation is mainly partial melting.
基金supported by the General Project of Natural Science Foundation of Shaanxi Province(2020JM423)。
文摘Se-rich black rock series of the Middle and Late Permian system is widely distributed in Enshi Prefecture with an exposed area of 850 km~2,among which the unique Yutangba black rock series independent selenium deposit with industrial mining significance in the world is produced.However,the source and metallogenic mechanisms of Se are still controversial.In general,terrestrial weathering and submarine hydrothermal processes are the main source end members of Si and Se,and the related siliceous rocks record the deposition process of Si and Se from different sources.The study of lithofacies and paleogeography shows that western Hubei belongs to the near eastwest turn of the Yangzi platform in the Middle and Late Permian and becomes an inter-platform basin with nearly north-south direction.Therefore,the comparative study of the Yutangba deposit and the selenium-rich black rock series in the northern Shadi with high selenium content is expected to reveal the provenance evolution of the two sections in space,and further restrict the Se mineralization mechanism in the Enshi basin.From the element geochemistry study,the black rock series in two study areas may have formed in a transitional position of either the continental margin or continental slope,in the process of sedimentary,more terrigenous clastic materials entered.They are rich in lithophile elements V and Cr.δU>1.0,U/Th and V/(V+Ni)ratio indicate that the Se-rich strata of black rock series in the Enshi areas occurred in an anoxic reducing environment and formed in an environment between the ocean basin and the continental margin.From Si-O isotope geochemistry,the original Si source of the study area is thought to relate to a volcanic eruption,which leads to the enrichment of Si in the seawater.The determined values of S isotope in the black rock series of the two study areas both show the characteristics related to organic reduction/biogenic.
文摘The Douala sedimentary basin in Cameroon is the main gas prospective basin in the country and has witnessed a number of investigations in this regard. The Nkapa Formation is one of the basin’s principal rock units and here we analyzed samples from sediments comprising this formation in order to constrain their provenance, tectonic setting and depositional environment using geochemical traits. Major and trace elements were analyzed by inductively coupled plasma mass spectrometry. Elemental ratios provide information on geochemical signatures of Eu/Eu ratios of the sandstones and shales, suggesting the provenance of the sediments was felsic from continental rock protoliths. Calculated K</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O/Na</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O ratios > 1 is reminiscent of quartz-rich sediments deposited in passive margin (PM) environments with significant terrigenous input. The elemental ratios La/Sc, La/Ca, Th/Sc, and Th/Co suggest that the sediment sources are felsic and mafic in nature. </span></span><span style="font-family:Verdana;">The clastic sediments were normalized using North American Shale Composite (NASC). The Ni/Co and V/(V</span><span style="font-family:""> </span><span style="font-family:Verdana;">+</span><span style="font-family:""> </span><span style="font-family:Verdana;">Ni) ratios reveal that the sediments were deposited under variable conditions including euxinic, dysoxic and anoxic.</span><span style="font-family:Verdana;"> Overall, the evidence from discrimination diagrams using major and trace elements suggest</span><span style="font-family:"color:red;"> </span><span style="font-family:Verdana;">that the sediments were derived from mostly Passive margins (PM) and continental island arc (CIA) with minor Oceanic island arch (OIA) sources. Limestones from the studied area at Kompina, rich in calcium carbonate above 98.5% make the</span><span style="font-family:Verdana;">m</span><span style="font-family:Verdana;"> suitable for use in the chemical industries. In addition the felsic and mafic source rocks can lead to formation of light and dark colored minerals which can be of economic value.
文摘In order to reveal the sedimentary environment of carbonate rocks in Nanfen Formation of Qingbaikou System in Tonghua,Jilin Province,the mineral composition and petrochemistry of carbonate rocks in Nanfen Formation were analyzed.The mineral compositions of five carbonate rock samples in Nanfen Formation mainly consist of calcite,with minor clay minerals and quartz,and the rock type is siliceous marlite.The Mn/Sr va-lues range from 1.52 to 4.08,with an average of 2.64,indicating that the carbonate rocks experienced weak diagenesis;the Sr/Ba values range from 1.26 to 2.51,with an average of 1.93,indicating marine environment;the ratio of Mg/Al ranges from 35.33 to 86.34,with an average of 62.95,indicating the seawater environment,which is consistent with the result from Sr/Ba;the MgO/CaO values range from 0.01 to 0.04,with an average of 0.02,indicating humid environment;the values of V/(V+Ni)range from 0.63 to 0.73,with an average of 0.70,indicating anoxic environment.In summary,geochemical analyses show that the Nanfen Formation carbonate rocks are marine deposits,in a warm,humid,anoxic environment with poor flow of seawater,and subsequently underwent weak diagenetic alteration.
文摘Extensive volcanism is one of the important features of Cenozoic geology in China.Based on temporal-spatial distribution,the volcanism was associated with three major different geological settings:1)the continental rift basalts in Northeast and North China;2)the tension-fault basalts on the continental margins of Southeast China; and 3) the collision-zone high-K volcanics in the Qinghai-Xizang Plateau and its vicinities.The characteristics of 'depletion in the south and enrichment in the north'of the China continental mantle are strongly supported by isotopic evidence.The Cenozoic continental cal characters,into the following geochemical provinces:1)the depleted mantle in South China;2)the primary mantle in Northeast and NorthChina; 3)the hybrid and transi-tional mantle in the region of Shandong ,Anhui,Jiangsu and northern Zhejiang;4)the depleted mantle around the Bohai Bay and the Lower Liaohe River;5)the K-metasomatic enriched mantle in the northern part of Northeast China;and 6)the re-cycled enriched mantle in the ancient subduction zone in the Qinghai-Xizang Plateau and its surround-ings.These geochemical characteristics on a regional scale must be a reflection of the nature of lithosphere evolution.
文摘Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the Yangtze paraplatform.There are sporadically magmatic rocks and fold basement made up of upper Archaeozoicmiddle and lower Proterozoic strata.The sedimentary cover consists of Sinian-lower Paleozoic marine sediments,Mesozoic-Cenozoic intercalated marine and nonmarine sediments or nonmarine sediments.
基金Supported by the Fundamental Research Funds for the Central Universities(XDJK2011C048)
文摘This paper is aimed to analyze the current situation and problems about land use of various karst environments via field survey,documentation and comparison methods,and to make reasonable recommendations about land use and management for different karst types in a bid to provide theoretical and practical basis for optimization of karst land use and the comprehensive control of karst rock desertification.The results show that,①as the bare karst areas are lack of water and soil and highly vulnerable to droughts and floods,land utilization in such areas should follow the principles of soil and water conservation and ecological restoration,emphasize both the ecological benefit and the economic benefits and reasonably configure the land resources to achieve virtuous circle;②in covered karst areas,the most important task is to take measures to prevent the appearance of secondary karst rock desertification,water exhaustion and karst collapse;③the buried karst areas shall mainly focus on prevention of overlaying sand shale collapse,and possible pollution of deep karst water and the surface land resulted from exploration and exploitation of oil and gas and geothermal water.④The final conclusion is that features and problems of land utilization of the three karst types are different from each other,and that the general principle for land use in karst regions shall be based on the local conditions.
基金Important Program of West Development of China(No.2003 BA901A12)
文摘Guizhou Province is one of the least developed areas with the largest number of counties in poverty and the widest coverage of karst landscape in China. The vulnerability of its karst eco-environment seriously threatens the survival of local residents and the development of local economy. Rapid population growth results in higher demand of various resources, which leads to more intensive development activities. For example, the blindfolded development on steep slopes has caused rock desertification of local rare soil in this karst area. It has induced a vicious circle in the poverty→population growth→ecosystem degradation and so on. About 3.13×106 people belong to the absolute impoverished population in Guizhou Province and most of them are living in rock-desertification areas. The essential reasons for destitution are the atrocious eco-environment and the huge population stress. Degradation of mountain ecosystems in southwestern China has continued at unprecedented speed and scale in recent decades. It is necessary to control population growth strictly and prevent further expansion of rock-desertification in order to develop local economy and better living conditions for local people. The only way to ensure a sustainable, stable and harmonious development of human, nature and economy is to restore a good condition of eco-environment and resolve the conflicts between human and land use.
基金supported by the National Natural Science Foundation of China (Nos. 40730209, 40525008, 40621002)the 111 project (B08030)the SINOPEC project (G0800-06-ZS-319)
文摘The molecular organic compounds have been identified by gas chromatography (GC) and GC-mass spectrometry (GC-MS) from Mesoproterozoic rocks in the Xuaniong (宣龙) depression in North China. The main saturated compounds are n-alkanes, monomethylalkanes, n-alkylcyclohexanes, acyclic isoprenoids, and hopanes. The dominant lower-molecular-weight n-alkanes are indicative of the main contribution of microorganisms, in particular, the chemosynthetic bacteria. The presence of abundant monomethylalkanes (mid- and end-branched) and the long chained (〉C20) acyclic isoprenoids indicates the existence of abundant bacteria and/or archaea in ancient oceans. The low abundance of pristane and phytane is suggestive of the relatively low abundance of photosynthetic autotrophs in comparison with chemosynthetic bacteria in the Mesoproterozoic oceans in North China. The sedimentary environmental condition is suboxic/anoxic, as indicated by the low value of the Pr/Ph ratio as well as the presence of abundant sulfur-bearing organic compounds, consistent with the other geochemical data in North China and elsewhere in the world. Both the composition of the primary producers and the sedimentary environmental conditions are favorable for the formation of hydrocarbon source rocks.