Based on the data of outcrop,core,logging,gas testing,and experiments,the natural gas accumulation and aluminous rock mineralization integrated research was adopted to analyze the controlling factors of aluminous rock...Based on the data of outcrop,core,logging,gas testing,and experiments,the natural gas accumulation and aluminous rock mineralization integrated research was adopted to analyze the controlling factors of aluminous rock series effective reservoirs in the Ordos Basin,NW China,as well as the configuration of coal-measure source rocks and aluminous rock series reservoirs.A natural gas accumulation model was constructed to evaluate the gas exploration potential of aluminous rock series under coal seam in the basin.The effective reservoirs of aluminous rock series in the Ordos Basin are composed of honeycomb-shaped bauxites with porous residual pisolitic and detrital structures,with the diasporite content of greater than 80%and dissolved pores as the main storage space.The bauxite reservoirs are formed under a model that planation controls the material supply,karst paleogeomorphology controls diagenesis,and land surface leaching improves reservoir quality.The hot humid climate and sea level changes in the Late Carboniferous–Early Permian dominated the development of a typical coal-aluminum-iron three-stage stratigraphic structure.The natural gas generated by the extensive hydrocarbon generation of coal-measure source rocks was accumulated in aluminous rock series under the coal seam,indicating a model of hydrocarbon accumulation under the source.During the Upper Carboniferous–Lower Permian,the relatively low-lying area on the edge of an ancient land or island in the North China landmass was developed.The gas reservoirs of aluminous rock series,which are clustered at multiple points in lenticular shape,are important new natural gas exploration fields with great potential in the Upper Paleozoic of North China Craton.展开更多
In Northern China, sandstone-type uranium (U) deposits are mostly developed in Mesozoic-Cenozoic basins. These U deposits are usually hosted in unvarying horizons within the basins and exhibit typical U-forming sedi...In Northern China, sandstone-type uranium (U) deposits are mostly developed in Mesozoic-Cenozoic basins. These U deposits are usually hosted in unvarying horizons within the basins and exhibit typical U-forming sedimentary associations, which is referred to as U-bearing rock series. This study describes the structural features of U-bearing rock series within the main Mesozoic-Cenozoic U-producing continental basins in Kazakhstan, Uzbekistan, and Russia in the western segment of the Central Asian Metallogenic Belt (CAMB), and Northern China in the eastern segment of the CAMB. We analyze the basic structural conditions and sedimentary environments of U-bearing rock series in Northern China and classify their structural styles in typical basins into river valley, basin margin, and intrabasin uplift margin types. The intrabasin uplift margin structural style proposed in this study can be used to indicate directions for the exploration of sandstone-type U deposits hosted in the center of a basin. At the same time, the study of structural style provides a new idea for exploring sandstone-type U deposits in Mesozoic-Cenozoic basins and it is of great significance to prospecting of sandstone-type uranium deposits.展开更多
The molybdenum-nickel deposits in Shuidong District of Nayong County (Guizhou Province, Southwest China) are found mainly in black shale series of Lower Cambrian Niutitang Formation, which is another Mo-Ni-rich regi...The molybdenum-nickel deposits in Shuidong District of Nayong County (Guizhou Province, Southwest China) are found mainly in black shale series of Lower Cambrian Niutitang Formation, which is another Mo-Ni-rich region besides Zunyi District (Guizhou province). Our systematic study on the Mo-Ni deposits in Tangjiaba of Nayong reveals that layered coarse-grained limestones, spherical beaded limestones concretions are hosted at the lower seam of the Mo-Ni deposits. Its strong negative carbon isotope anomaly (the carbon isotope value of the coarse-grained limestones varies from -2.148‰ to 8.223‰) is similar to that in the modern submarine black smoker chimney. The carbon in the coarse-grained limestones from black rock series of Nayong County might be deep source inorganic carbon. The seams, coarse-grained limestones, ore-bearing coarse-grained limestones and the roof and floor of the deposits are characterized by co-variation on the trace element spider diagram, showing good homology. The extraordinary enrichment of Ag, As and Sb resembles hydrothermal sedimentation. Pro-Earth's core elements Se is strongly enriched in Ni-Mo ore-bearing coarse-grained limestones. The ore-bearing rock series has an extremely low Th/U value (0.012-0.19); in the logU-logTh Cartesian Coordinates, the samples of the roof and floor of the deposits and ore-bearing coarse-grained limestones are found in the East Pacific tise; and the samples of coarse-grained limestones are found between the paleo-hydrothermal dedimentary area and the East Pacific tise. The chondrite-normalized rare earth element patterns of the Ni-Mo deposits show LREE enrichment, Ce negative anomaly, and Eu negative anomaly (which is supposed to be influenced by the deep magmatic processes in an extensional environment) resembles the rare earth element distribution patterns of the fluid and its sediments in modern submarine hydrothermal system. It proves that coarse-grained limestones is characterized by typical hydrothermal limestones, being closely related with the genesis of Mo-Ni deposits in Nayong County, which provides new evidence for hydrothermal sedimentary genesis of Mo-Ni deposit and negative carbon anomaly in the basal Cambrian on a global scale.展开更多
A systematic geological and geochemical study was conducted for the granitoids of different periods in the western Kunlun orogenic belt. The study indicates that the granitoids belong to tholeiitic, calc-alkaline, hig...A systematic geological and geochemical study was conducted for the granitoids of different periods in the western Kunlun orogenic belt. The study indicates that the granitoids belong to tholeiitic, calc-alkaline, high-K calc-alkaline, alkaline and shoshonitic series, and that there are 5 genetic types, i.e., I-, S-, M-, A- and SH-type, of which SH-type is first put forward in this paper, which corresponds to shoshonitic granitoids.展开更多
Abstract: A great amount of black rock series has been found in the Upper Sinian Members 2 and 4 of the Jinjiadong Formation, middle-upper Liuchapo Formation and the Lower Cambrian Xiaoyanxi Formation in West Hunan, w...Abstract: A great amount of black rock series has been found in the Upper Sinian Members 2 and 4 of the Jinjiadong Formation, middle-upper Liuchapo Formation and the Lower Cambrian Xiaoyanxi Formation in West Hunan, which is associated with periodic sea-level changes. By the studies of relationships between the distribution and development of the biota and the abundance of Au, Ag, U, V, Ni, Mo and Cu in the Upper Sinian and Early Cambrian black rock series in Cili, Dayong, Yuanling, Xupu and Qianyang of West Hunan, central China, it has been revealed that the enrichment of Ag, V, and Mo is related with the development of multi-cell plants and vendotaenides, and that of Cu and Ni is related to flourishing of bacteria and shelly fossils. The black rock series in the study area contains abundant organic matter, among which the siliceous shale contains the highest TOC, amounting to 4.51–13.4%. All the values of the equivalent vitrinite reflectance (medium values) determinated with the IR-spectroscopic method in the area are over 2.65%, indicating that the organic evolution was at an overmature stage. Due to the effect of enhancement of organic maturation by hydrothermal fluids, the Upper Sinian and Lower Cambrian had a reverse organic maturity profile in most areas of West Hunan. The enrichment of Ag, V, Ni, Mo and U is a result of organic absorption, and that of Au might be attributed to the migration by hydrothermal fluids.展开更多
This paper discusses the late Yanshanian-Himalayan igneous rock series and minerogenetic series (Cheng et al., 1979, 1982) related to tin polymetallic deposits in the Tengchong area. The multi-stage differentiation an...This paper discusses the late Yanshanian-Himalayan igneous rock series and minerogenetic series (Cheng et al., 1979, 1982) related to tin polymetallic deposits in the Tengchong area. The multi-stage differentiation and evolution of the igneous rock series led to the concentration of metal and ore-forming elements in a cupola of a granite body formed in the late stage. The minerogenetic series shows a zoning of Nb-Ta-W-Sn, Sn-Fe and Sn around the cupola in space and a multi-stage regularity in time. Finally a minerogenetic model and three key factors of tin minerogenesis are put forward for tin polymetallic deposits in the area.展开更多
Some extraditional types—black rock series types of platinum group element (PGE), gold and silver mineralization occurrences were found in the Lower Cambrian in Guizhou and Hunan provinces of southwest China where PG...Some extraditional types—black rock series types of platinum group element (PGE), gold and silver mineralization occurrences were found in the Lower Cambrian in Guizhou and Hunan provinces of southwest China where PGE concentration reaches more than 800×10 -6. Sea floor hydrothermal fluid eruption was suggested to have been the main origin of the ore-forming materials. The whole process from the sedimentation to the redistribution of the ore-forming elements occurred on the conditions of intermediate to weak alkaline, weak reduction to weak oxidation. The temperature for the sedimentation and redistribution of the ore-forming elements was lower than 210 ℃. At such a low temperature, inert elements such as PGE, Au and Ag could quite easily be remobilized.展开更多
Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the ...Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the Yangtze paraplatform.There are sporadically magmatic rocks and fold basement made up of upper Archaeozoicmiddle and lower Proterozoic strata.The sedimentary cover consists of Sinian-lower Paleozoic marine sediments,Mesozoic-Cenozoic intercalated marine and nonmarine sediments or nonmarine sediments.展开更多
The change of the primary productivity across the Permian-Triassic boundary (PTB) remains controversial. In this study, records from two deep-water sections in South China (Xiakou and Xinmin sections) show the pri...The change of the primary productivity across the Permian-Triassic boundary (PTB) remains controversial. In this study, records from two deep-water sections in South China (Xiakou and Xinmin sections) show the primary productivity decreased gradually from the latest Permian to the earliest Triassic, and five evolutionary stages Increase-Decrease-Recovery-Recession- Stagnation) can be observed from Clarkina changxingensis-C, deflecta to Hindeodus parvus-lsarcicella isarcica zones. Pri- mary productivity decreased abruptly from the base of C. meishanensis zone. Besides, for adjusting to the deterioration of the oceanic environment, the primary producers in the oceanic surface had changed to acritarch and cyanobacteria, which were more tolerant of stressful environment. Then the producers were under huge stagnation in the H. parvus-L isarcica zone. The values of quantitative calculation of the primary productivity from the black rock series in the Dalong Formation were very high, corresponding to that of an upwelling area in modern ocean, which shows that the strata of the Dalong Formation in the study region are potential hydrocarbon source-rocks. This result may come from the fact that South China craton was located at the equatorial upwelling area during the Permian-Triassic transitions. But organic matter contents were different in various sections because they could be affected by redox conditions and diagenesis process after burial.展开更多
With further exploration and research,the gypsum-salts rock series as good caprocks attracted a lot of attention.The gypsum-salt rock series played an important role during migration,preservation and trapping of hydro...With further exploration and research,the gypsum-salts rock series as good caprocks attracted a lot of attention.The gypsum-salt rock series played an important role during migration,preservation and trapping of hydrocarbons.Recently,major breakthroughs have been continuously made in marine petroleum exploration of gypsum-salt rock series in the eastern Ordos Basin,the central Tarim Basin and the western Sichuan Basin in China,and the high-evolution and low-abundance gypsum-salt rock series as hydrocarbon source rocks become possible.Besides research advances in the reservoirecaprock assemblage of gypsum-salt rock series,development and hydrocarbon-generation potential of source rocks in the gypsum-salt rock series were well studied in terms of source-rock development environment and hydrocarbon generation mechanism.Results showed that the gypsum-salt rock series,including high-evolution and low-TOC gypsum-salt rock series in China,could be regarded as good source rocks.This understanding was a breakthrough to previous traditional viewpoint that low-TOC gypsum-salt rock series could not act as effective hydrocarbon sources.The key to understand hydrocarbon-generation mechanism was that abundant and high-quality hydrocarbon-generation materials,large amount of hydrocarbon generation and conversion in geological history,and hydrocarbongeneration materials occurred in the form of carboxylates,were developed in the high-evolution and low-TOC gypsum-salt rock series.展开更多
The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential...The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential to elucidate the evolutionary path of marine redox states and the biogeochemical nitrogen cycle within the water column of the Early Cambrian ocean.While existing research on this topic has predominantly focused on South China,the exploration of other continental margins has been limited,leaving contradictory hypotheses untested.In this study,pairedδ^(15)N andδ^(13)C org analyses were performed on the Lower Cambrian successions from the Shiairike section(inner ramp)and Well Tadong 2(deep shelf/basin)in the northwestern and eastern Tarim Basin,respectively.Our data from the Shiairike section reveal a discernible shift in the operation of different nitrogen cycles for the black chert-shale unit,also referred to as the black rock series in Chinese literature,of the Yurtus Formation(Fortunian stage to lower Stage 3).Oscillatingδ^(15)N values for its lower part are suggestive of alternating anaerobic assimilation of NH 4+and denitrification/anammox.This is likely attributed to a shallow,unstable chemocline consistent with the upwelling and incursion of deep,anoxic waters during a major transgression.In contrast,aerobic nitrogen cycling,indicated by positiveδ^(15)N values of>2‰,dominated the upper part alongside a reduction in upwelling intensity.On the other hand,theδ^(15)N signatures of Xishanbulake and Xidashan Formations of Well Tadong 2,which encompass a time interval from the Cambrian Fortunian Age to Age 4,are indicative of N_(2)fixation by diazotrophs as the major nitrogen source.The two studied intervals,although not time-equivalent,exhibit separated states of nitrogen cycling at least during the deposition of the Yurtus black rock series.The spatially different nitrogen cycling of the studied sections is compatible with a redox-stratified ocean during the deposition of the Yurtus black rock series.The build-up of a NO_(3)−reservoir and aerobic nitrogen cycling in seawater was largely restricted to near-shore settings whereas anaerobic nitrogen cycling dominated by N_(2)fixation served as the main nitrogen uptake pathway in off-shore settings.展开更多
The late Paleozoic adakitic rocks are closely associated with the shoshonitic volcanic rocks in the western Tianshan Mountains, China, both spatially and temporally. The magmatic rocks were formed during the period fr...The late Paleozoic adakitic rocks are closely associated with the shoshonitic volcanic rocks in the western Tianshan Mountains, China, both spatially and temporally. The magmatic rocks were formed during the period from the middle to the late Permian with isotopic ages of 248-268 Ma. The 87Sr/86Sr initial ratios of the rocks are low in a narrow variation range (-0.7050). The 143Nd/144Nd initial ratios are high (-0.51240) with positive εND(t) values (+1.28-+4.92). In the εNd(t)-(87Sr/86Sr)i diagram they fall in the first quadrant. The association of the shoshonitic and adakitic rocks can be interpreted by a two-stage model: the shoshonitic volcanic rocks were formed through long-term fractional crystallization of underplated basaltic magma, while the following partial melting of the residual phases formed the adakitic rocks.展开更多
Zhijin County in Western Guizhou is one of the most important production areas of phosphorites in China. In order to investigate genesis of the phosphorites, their REE compositions were analyzed by using inductively c...Zhijin County in Western Guizhou is one of the most important production areas of phosphorites in China. In order to investigate genesis of the phosphorites, their REE compositions were analyzed by using inductively coupled plasma emission mass spectrometry (ICP-MS) method. For comparison, phosphorites from the Lower Cambrian black rock series in Southern China, such as Zunyi in Guizhou and Zhangjiajie in Hunan Province, were also analyzed. The analytical data show that: (1) Xinhua phosphorites possess a quite high and greatly varied total rare earth elements (ΣREE), which varying between 164.23×10-6 and 1395.01×10-6 with average of 642.54×10-6, remarkable differentiation between light (LREE) and heavy rare earth elements (HREE), and the ΣLREE/ΣHREE ratios varying between 5.04 and 6.52. The ΣREE and ΣLREE/ΣHREE ratios of the Zunyi and Zhangjiajie phosphorites are 156.69×10-6~637.41×10-6 with average of 431 75×10-6 and 3.17~6.95 with average of 4.37 respectively; (2) All the phosphorites from Xinhua, Zunyi and Zhangjiajie show remarkable negative Ce anomalies. Besides, the Xinhua phosphorites possess lower δCe, which varying between 0.26 and 0.53 with average of 0.35, while δCe of the Zunyi and Zhangjiajie phosphorites are 0.30~0.66 with average of 0.47, suggesting that all of the phosphorites are typical marine sediments deposited mainly in ancient peri-continental seas, and the depositional position of the Xinhua phosphorite might be deeper; (3) Most phosphorites from Xinhua, Zunyi and Zhangjiajie possess unremarkable positive Eu anomaly, and only a few of samples show obvious ones. The δEu varies between 0.98 and 2.4, suggesting that hot (>200 ℃) and strong reductive hydrothermal fluids might have been involved in genesis of the phosphorites; (4) The Xinhua phosphorite is relatively depleted in HREE, and LaN/NdN and δY of most samples are >1 and >1.5 respectively. Besides, there exists no correlation between δY and δCe, suggesting that the phosphorite was subjected to quite strong weathering and leaching processes, and catagenesis do not greatly modify its REE compositions.展开更多
The sedimentary sequence of the Lower Cambrian is a key interval to reveal the early evolution history of the Earth and there occur widespread cherts worldwide. These cherts possibly carry important information to dec...The sedimentary sequence of the Lower Cambrian is a key interval to reveal the early evolution history of the Earth and there occur widespread cherts worldwide. These cherts possibly carry important information to decipher the breakup process of the Rodinia Continent. Black rock series at the bottom of the Lower Cambrian in the Northern Tarim Basin, China, is composed of black shales interbedded with thin-bedded cherts. Ten chert samples were systematically collected from two outcrops at Xiaoerbulak and Sogatbulak, 8.8 and 7.5 m thick respectively. The cherts were crushed, and were analyzed for trace element and rare earth concentrations. Trace elements such as V, Cu, Zn, U, Pb, Ba, Cd, Ag, Mo, As and Sb are highly enriched, and others such as Rb, Zr, Cs, Hf, Ta, W, Tl, Bi and Th are highly depleted in the cherts. These trace element patterns suggest that the cherts may be of deep crustal origin. The low ratios of Th/U and Rb/Sr further suggest that the cherts are of earth interior sources or received hydrothermal input during their deposition. Chondrite- normalized Eu/Eu* value markedly decreases upward in the section from 5.54 at the lowermost to 0.73 at the top, and NASC-normalized Eu/Eu* value decreases from 8.05 to 1.03. The relatively high Eu/Eu* ratio for the cherts from the northern Tarim Basin is most likely due to a hydrothermal input (e.g., Eu/Eu* ~10). The systematic decrease of Eu/Eu* ratio from the bottom to the top of the section reflects that the hydrothermal input is the largest in the lowermost portion of the section and gradually decreases upward. The chondrite-normalized Ce/Ce* ratio ranges from 0.42 to 0.83, with an average of 0.60. North American Shale Composite (NASC)-normalized Ce/Ce* ratio ranges from 0.42 to 0.79, with an average of 0.57. Negative Ce anomalies are distinct. ΣREEs in the cherts generally increase from 10.50 ppm at the bottom to 35.97 ppm at the top of the sampled section. NASC-normalized (La/Lu) N ratio decreases from 2.72 at the bottom to 0.67 at the top. NASC-normalized (La/Ce) N ratio increases from 1.36 at the bottom to 3.13 at the top. These REE patterns are very similar to those for the cherts deposited in the pelagic ocean-basin floor in the Franciscan Complex exposed at Marin Headlands, California (F-MH chert) (Murray et al., 1991). These geochemical signatures are inconsistent with our previous sedimentological data, which suggests a continental shelf setting. Based on multiple lines of evidence including high TOC content in the concomitant black shales, phosphorite at the bottom of black rock series, regional rise of sea level, and beginning of the southern Tianshan Ocean geotectonic cycle, the authors infer that the hydrothermal fluid was carried to the continental shelf by upwelling from a divergent pelagic ocean floor setting.展开更多
The Xigaze ophiolite is located in the middle section of the Yarlung Zangbo River ophiolite belt and includes a well-preserved sequence section of seven ophiolite blocks. The relatively complete ophiolitic sequence se...The Xigaze ophiolite is located in the middle section of the Yarlung Zangbo River ophiolite belt and includes a well-preserved sequence section of seven ophiolite blocks. The relatively complete ophiolitic sequence sections are represented by Jiding, Dejixiang, Baigang, and Dazhuqu ophiolites and consist of three-four units. The complete ophiolite sequence in order from the bottom to top consists of mantle peridotite, cumulates, sheeted sill dike swarms, and basic lavas±radiolarian chert. These cumulates are absent in the remaining blocks of Dejixiang and Luqu. The age of radiolaria in the radiolarian chert is Late Jurassic-Cretaceous. The basalt and ultramafic rock of the ophiolite also are overlaid by Tertiary Liuqu conglomerate, which contains numerous pebble components of ophiolite, indicating that the Tethys Ocean began to close at the end of Cretaceous Period. The isotopic data of gabbro, diabase, and albite granite in the Xigaze ophiolite are approximately 126-139 Ma, which indicates that the ophiolite formed in the Early Cretaceous. The K-Ar age of amphibole in garnet amphibolite in the ophiolite melange is 81 Ma, indicating that tectonic ophiolite emplacement occurred at the end of Late Cretaceous. Research in petrology, petrological chemistry, mineralogy, and geochemistry of volcanic rocks and dikes of the Xigaze ophiolite indicate the following characteristics: (1) They are mainly composed of basalt, basaltic andesite, dolerite, and diabase and are characterized by high TiO2 (0.7-1.47%), low MgO (mostly less than 8%), and low SiO2 (mostly less than 53%). (2) The volcanic rocks and dikes of the Xigaze ophiolite show light rare earth element (LREE)-depleted rare earth element (REE) patterns. (3) The spider diagrams of the volcanic rocks and dikes of the Xigaze ophiolite exhibit LILE depletion relative to high-field-strength element (HFSE) patterns with left oblique features. (4) No protogenetic olivine and clinoenstatite was detected. (5) Some dikes show low TiO2 and high MgO, in which a few of Cr-enriched spinels and a very few pseudomorphs of olivine, orthopyroxene can be seen. They show more distinctive affinity as boninitic rock and canbe classified to boninite series rock. The previously mentioned features of the volcanic rocks and dikes in the Xigaze ophiolite implies that these ophiolites formed in a mid-ocean ridge (MOR) in the earlier stage and than forearc extension of subduction initiation occurred once at the later stage of the evolution of the Xigaze ophiolite. The forearc extention caused further melting of the residue-depleted mantle, resulting in the formation of melts with lower TiO2 and higher MgO. These melts formed as dikes and intruded into the oceanic crust formed in the earlier stage, resulting in a close association of mid-ocean ridge basalt and the boninite rock of the Xigaze ophiolite.展开更多
Gallium(Ga)is a critical mineral that plays an irreplaceable role in consumer electronics,clean energy technologies and the aerospace industry.Nowadays competition for gallium resources at the national strategic level...Gallium(Ga)is a critical mineral that plays an irreplaceable role in consumer electronics,clean energy technologies and the aerospace industry.Nowadays competition for gallium resources at the national strategic level has begun to emerge,but gallium resources are unevenly distributed globally,and their presence is not guaranteed.New discoveries revealed an average gallium concentration of thirty-one samples from M_(1),M_(2),M_(3) and M_(4) stone coal-bearing seams of the Cambrian strata on South Qinling Orogenic Belt in central China is 157 mg/kg(9.98–747 mg/kg),which is 27.6-fold higher than the global hard coal average,as well as the existing association of Mo–V–U–Cd–Zn–Ba–Se–Mg–Ni–Cu enrichment.Ga average of these coal seams are 344 mg/kg(M_(3),44.5–747 mg/kg,n=11),270 mg/kg(M_(4),14.3–270 mg/kg,n=5),53.8 mg/kg(M_(2),22.6–75.4 mg/kg,n=8)and 19.8 mg/kg(M_(1),9.98–34.9 mg/kg,n=7)respectively,as well as the thickness of approximately 6,12,8,and 20 m,which be close to or exceed to the boundary grade standard(30 mg/kg)and minimum recoverable thickness(0.7 m)of gal-lium resources exploration.These findings indicate that the Cambrian stone coal deposits,especially in the middle and late Cambrian period,should be considered as promising alternative sources of gallium.The anomalous gallium-enriched sediments originated from a complex combination of hydrothermal flu-ids,original biomass and terrigenous materials.For the M_(1) stone coal-bearing seams,gallium most likely occurred in the mode of GaAs,Ga_(x)In_(1-x)As and GaO(OH),while modes of gallium in the M_(2) to M_(4) seams is interrelated with the organic affinity and clay minerals.The crude reserve estimate of gallium resources in central China is approximately 10.06?104 tons,corresponding to a super-large coal-hosted gallium ore deposit.The unique paleogeographic location and geological structure in central China resulted that this newly discovered deposit is a unique type of gallium-enriched deposit that has been discovered worldwide.These discoveries will provide the critical parameters when developing distinctive benefici-ation processes and appropriate extraction procedures,as well as guidance and effective for future prospecting regions of gallium resources around the globe,involving a combination consider the distri-bution of regional deep–large fault zones and the middle to late Cambrian black rock series deposits.展开更多
Due to deep burial of Precambrian in Tarim Basin,no breakthrough in the hydrocarbon exploration has been achieved from these strata,and development of high-quality source rocks is also uncertain.More than 30 explorato...Due to deep burial of Precambrian in Tarim Basin,no breakthrough in the hydrocarbon exploration has been achieved from these strata,and development of high-quality source rocks is also uncertain.More than 30 exploratory wells have been drilled in the southwest Tarim Basin and the pediment region of Kunlun Mountains with a total area of more than 100103 km2.Though some marine oil/gas fields such as Hetianhe,Bashituopu,Yubei and Luosi 2 have been discovered,the Cambrian or Ordovician source rocks have not been drilled,and hydrocarbon source still remain controversial.Recently,a set of thick black shales and mudstones has been found in the southwest Tarim Basin.The total thickness of mudstones is more than 140 m,and the total organic carbon mainly ranges from 0.6%to 1.9%with an average of 1.0%.Tmax is from 490C to 520C,equivalent to Ro from 1.99%to 2.99%.Pyrites are very rich in mudstone.According to stratigraphic contact relationship and isotopic chronology,this mudstone may have the age of more than 517 Ma,and is tentatively named as the“Western Kunlun black rock series”.Through the plate tectonic analysis,this set of thick black mudstones is possibly distributed widely in the southwest Tarim Basin,and its formation may be controlled by the aulacogen.This set of black mudstones may be an important source rocks in the southwest Tarim Basin,which suggest that the Precambrian-Cambrian strata in Tarim Basin has geological conditions for hydrocarbon accumulations.This discovery of the black thick mudstones in the southwest Tarim Basin will promote hydrocarbon exploration in the deep and ultra-deep strata of the Tarim Basin.展开更多
基金Supported by the PetroChina Science and Technology Major Project(2021DJ2101).
文摘Based on the data of outcrop,core,logging,gas testing,and experiments,the natural gas accumulation and aluminous rock mineralization integrated research was adopted to analyze the controlling factors of aluminous rock series effective reservoirs in the Ordos Basin,NW China,as well as the configuration of coal-measure source rocks and aluminous rock series reservoirs.A natural gas accumulation model was constructed to evaluate the gas exploration potential of aluminous rock series under coal seam in the basin.The effective reservoirs of aluminous rock series in the Ordos Basin are composed of honeycomb-shaped bauxites with porous residual pisolitic and detrital structures,with the diasporite content of greater than 80%and dissolved pores as the main storage space.The bauxite reservoirs are formed under a model that planation controls the material supply,karst paleogeomorphology controls diagenesis,and land surface leaching improves reservoir quality.The hot humid climate and sea level changes in the Late Carboniferous–Early Permian dominated the development of a typical coal-aluminum-iron three-stage stratigraphic structure.The natural gas generated by the extensive hydrocarbon generation of coal-measure source rocks was accumulated in aluminous rock series under the coal seam,indicating a model of hydrocarbon accumulation under the source.During the Upper Carboniferous–Lower Permian,the relatively low-lying area on the edge of an ancient land or island in the North China landmass was developed.The gas reservoirs of aluminous rock series,which are clustered at multiple points in lenticular shape,are important new natural gas exploration fields with great potential in the Upper Paleozoic of North China Craton.
基金supported by the undertaken units of subprojects of the Program of Survey on Sandstone-Type Uranium Deposits in Northern Chinathe Ministry of Science and Technology of China(Grant 2015CB453000)the Geological Survey project of China(Grant No.DD20160128)
文摘In Northern China, sandstone-type uranium (U) deposits are mostly developed in Mesozoic-Cenozoic basins. These U deposits are usually hosted in unvarying horizons within the basins and exhibit typical U-forming sedimentary associations, which is referred to as U-bearing rock series. This study describes the structural features of U-bearing rock series within the main Mesozoic-Cenozoic U-producing continental basins in Kazakhstan, Uzbekistan, and Russia in the western segment of the Central Asian Metallogenic Belt (CAMB), and Northern China in the eastern segment of the CAMB. We analyze the basic structural conditions and sedimentary environments of U-bearing rock series in Northern China and classify their structural styles in typical basins into river valley, basin margin, and intrabasin uplift margin types. The intrabasin uplift margin structural style proposed in this study can be used to indicate directions for the exploration of sandstone-type U deposits hosted in the center of a basin. At the same time, the study of structural style provides a new idea for exploring sandstone-type U deposits in Mesozoic-Cenozoic basins and it is of great significance to prospecting of sandstone-type uranium deposits.
基金sponsored by the Doctoral Fund of Ministry of Education of China (Grant no.20105201110002)Research Fund of Guizhou Province and Doctoral Programme Fund of Guizhou University
文摘The molybdenum-nickel deposits in Shuidong District of Nayong County (Guizhou Province, Southwest China) are found mainly in black shale series of Lower Cambrian Niutitang Formation, which is another Mo-Ni-rich region besides Zunyi District (Guizhou province). Our systematic study on the Mo-Ni deposits in Tangjiaba of Nayong reveals that layered coarse-grained limestones, spherical beaded limestones concretions are hosted at the lower seam of the Mo-Ni deposits. Its strong negative carbon isotope anomaly (the carbon isotope value of the coarse-grained limestones varies from -2.148‰ to 8.223‰) is similar to that in the modern submarine black smoker chimney. The carbon in the coarse-grained limestones from black rock series of Nayong County might be deep source inorganic carbon. The seams, coarse-grained limestones, ore-bearing coarse-grained limestones and the roof and floor of the deposits are characterized by co-variation on the trace element spider diagram, showing good homology. The extraordinary enrichment of Ag, As and Sb resembles hydrothermal sedimentation. Pro-Earth's core elements Se is strongly enriched in Ni-Mo ore-bearing coarse-grained limestones. The ore-bearing rock series has an extremely low Th/U value (0.012-0.19); in the logU-logTh Cartesian Coordinates, the samples of the roof and floor of the deposits and ore-bearing coarse-grained limestones are found in the East Pacific tise; and the samples of coarse-grained limestones are found between the paleo-hydrothermal dedimentary area and the East Pacific tise. The chondrite-normalized rare earth element patterns of the Ni-Mo deposits show LREE enrichment, Ce negative anomaly, and Eu negative anomaly (which is supposed to be influenced by the deep magmatic processes in an extensional environment) resembles the rare earth element distribution patterns of the fluid and its sediments in modern submarine hydrothermal system. It proves that coarse-grained limestones is characterized by typical hydrothermal limestones, being closely related with the genesis of Mo-Ni deposits in Nayong County, which provides new evidence for hydrothermal sedimentary genesis of Mo-Ni deposit and negative carbon anomaly in the basal Cambrian on a global scale.
基金supported by the Key Project(No.9502010)of the former Chinese Ministry of Geology and Mineral Resources.
文摘A systematic geological and geochemical study was conducted for the granitoids of different periods in the western Kunlun orogenic belt. The study indicates that the granitoids belong to tholeiitic, calc-alkaline, high-K calc-alkaline, alkaline and shoshonitic series, and that there are 5 genetic types, i.e., I-, S-, M-, A- and SH-type, of which SH-type is first put forward in this paper, which corresponds to shoshonitic granitoids.
基金This study was financially supported by CAGS(Project No:97-8)China National Petroleum Corporation(Project No:GJ9471908-2)
文摘Abstract: A great amount of black rock series has been found in the Upper Sinian Members 2 and 4 of the Jinjiadong Formation, middle-upper Liuchapo Formation and the Lower Cambrian Xiaoyanxi Formation in West Hunan, which is associated with periodic sea-level changes. By the studies of relationships between the distribution and development of the biota and the abundance of Au, Ag, U, V, Ni, Mo and Cu in the Upper Sinian and Early Cambrian black rock series in Cili, Dayong, Yuanling, Xupu and Qianyang of West Hunan, central China, it has been revealed that the enrichment of Ag, V, and Mo is related with the development of multi-cell plants and vendotaenides, and that of Cu and Ni is related to flourishing of bacteria and shelly fossils. The black rock series in the study area contains abundant organic matter, among which the siliceous shale contains the highest TOC, amounting to 4.51–13.4%. All the values of the equivalent vitrinite reflectance (medium values) determinated with the IR-spectroscopic method in the area are over 2.65%, indicating that the organic evolution was at an overmature stage. Due to the effect of enhancement of organic maturation by hydrothermal fluids, the Upper Sinian and Lower Cambrian had a reverse organic maturity profile in most areas of West Hunan. The enrichment of Ag, V, Ni, Mo and U is a result of organic absorption, and that of Au might be attributed to the migration by hydrothermal fluids.
文摘This paper discusses the late Yanshanian-Himalayan igneous rock series and minerogenetic series (Cheng et al., 1979, 1982) related to tin polymetallic deposits in the Tengchong area. The multi-stage differentiation and evolution of the igneous rock series led to the concentration of metal and ore-forming elements in a cupola of a granite body formed in the late stage. The minerogenetic series shows a zoning of Nb-Ta-W-Sn, Sn-Fe and Sn around the cupola in space and a multi-stage regularity in time. Finally a minerogenetic model and three key factors of tin minerogenesis are put forward for tin polymetallic deposits in the area.
文摘Some extraditional types—black rock series types of platinum group element (PGE), gold and silver mineralization occurrences were found in the Lower Cambrian in Guizhou and Hunan provinces of southwest China where PGE concentration reaches more than 800×10 -6. Sea floor hydrothermal fluid eruption was suggested to have been the main origin of the ore-forming materials. The whole process from the sedimentation to the redistribution of the ore-forming elements occurred on the conditions of intermediate to weak alkaline, weak reduction to weak oxidation. The temperature for the sedimentation and redistribution of the ore-forming elements was lower than 210 ℃. At such a low temperature, inert elements such as PGE, Au and Ag could quite easily be remobilized.
文摘Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the Yangtze paraplatform.There are sporadically magmatic rocks and fold basement made up of upper Archaeozoicmiddle and lower Proterozoic strata.The sedimentary cover consists of Sinian-lower Paleozoic marine sediments,Mesozoic-Cenozoic intercalated marine and nonmarine sediments or nonmarine sediments.
基金was supported by National Natural Science Foundation of China (Grant Nos. 41073007 and 41273005)National Basic Research Program of China (Grant No. 2011CB808800)+3 种基金the 111 Project (Grant No. B08030)Research Fund for the Doctoral Program of Higher Education (Grant No. 20110145130001)special funding from the State Key Laboratory of Geological Processes and Mineral Resourcesa contribution to IGCP Project 572 (Grant No. GPMR201301)
文摘The change of the primary productivity across the Permian-Triassic boundary (PTB) remains controversial. In this study, records from two deep-water sections in South China (Xiakou and Xinmin sections) show the primary productivity decreased gradually from the latest Permian to the earliest Triassic, and five evolutionary stages Increase-Decrease-Recovery-Recession- Stagnation) can be observed from Clarkina changxingensis-C, deflecta to Hindeodus parvus-lsarcicella isarcica zones. Pri- mary productivity decreased abruptly from the base of C. meishanensis zone. Besides, for adjusting to the deterioration of the oceanic environment, the primary producers in the oceanic surface had changed to acritarch and cyanobacteria, which were more tolerant of stressful environment. Then the producers were under huge stagnation in the H. parvus-L isarcica zone. The values of quantitative calculation of the primary productivity from the black rock series in the Dalong Formation were very high, corresponding to that of an upwelling area in modern ocean, which shows that the strata of the Dalong Formation in the study region are potential hydrocarbon source-rocks. This result may come from the fact that South China craton was located at the equatorial upwelling area during the Permian-Triassic transitions. But organic matter contents were different in various sections because they could be affected by redox conditions and diagenesis process after burial.
基金The work was supported by the National Key Basic Research Program of China(973 Program)(No.2012CB214801)the National Natural Science Foundation of China(No.U1663201).
文摘With further exploration and research,the gypsum-salts rock series as good caprocks attracted a lot of attention.The gypsum-salt rock series played an important role during migration,preservation and trapping of hydrocarbons.Recently,major breakthroughs have been continuously made in marine petroleum exploration of gypsum-salt rock series in the eastern Ordos Basin,the central Tarim Basin and the western Sichuan Basin in China,and the high-evolution and low-abundance gypsum-salt rock series as hydrocarbon source rocks become possible.Besides research advances in the reservoirecaprock assemblage of gypsum-salt rock series,development and hydrocarbon-generation potential of source rocks in the gypsum-salt rock series were well studied in terms of source-rock development environment and hydrocarbon generation mechanism.Results showed that the gypsum-salt rock series,including high-evolution and low-TOC gypsum-salt rock series in China,could be regarded as good source rocks.This understanding was a breakthrough to previous traditional viewpoint that low-TOC gypsum-salt rock series could not act as effective hydrocarbon sources.The key to understand hydrocarbon-generation mechanism was that abundant and high-quality hydrocarbon-generation materials,large amount of hydrocarbon generation and conversion in geological history,and hydrocarbongeneration materials occurred in the form of carboxylates,were developed in the high-evolution and low-TOC gypsum-salt rock series.
基金supported by the Fundamental Research Funds for the Central Universities(No.B200202009).
文摘The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential to elucidate the evolutionary path of marine redox states and the biogeochemical nitrogen cycle within the water column of the Early Cambrian ocean.While existing research on this topic has predominantly focused on South China,the exploration of other continental margins has been limited,leaving contradictory hypotheses untested.In this study,pairedδ^(15)N andδ^(13)C org analyses were performed on the Lower Cambrian successions from the Shiairike section(inner ramp)and Well Tadong 2(deep shelf/basin)in the northwestern and eastern Tarim Basin,respectively.Our data from the Shiairike section reveal a discernible shift in the operation of different nitrogen cycles for the black chert-shale unit,also referred to as the black rock series in Chinese literature,of the Yurtus Formation(Fortunian stage to lower Stage 3).Oscillatingδ^(15)N values for its lower part are suggestive of alternating anaerobic assimilation of NH 4+and denitrification/anammox.This is likely attributed to a shallow,unstable chemocline consistent with the upwelling and incursion of deep,anoxic waters during a major transgression.In contrast,aerobic nitrogen cycling,indicated by positiveδ^(15)N values of>2‰,dominated the upper part alongside a reduction in upwelling intensity.On the other hand,theδ^(15)N signatures of Xishanbulake and Xidashan Formations of Well Tadong 2,which encompass a time interval from the Cambrian Fortunian Age to Age 4,are indicative of N_(2)fixation by diazotrophs as the major nitrogen source.The two studied intervals,although not time-equivalent,exhibit separated states of nitrogen cycling at least during the deposition of the Yurtus black rock series.The spatially different nitrogen cycling of the studied sections is compatible with a redox-stratified ocean during the deposition of the Yurtus black rock series.The build-up of a NO_(3)−reservoir and aerobic nitrogen cycling in seawater was largely restricted to near-shore settings whereas anaerobic nitrogen cycling dominated by N_(2)fixation served as the main nitrogen uptake pathway in off-shore settings.
基金the State Key Basic Research of China(2001CB409803)the National Natural Science Foundation of China(40373017) National 305 Project of Xinjiang(96-915-03-02).
文摘The late Paleozoic adakitic rocks are closely associated with the shoshonitic volcanic rocks in the western Tianshan Mountains, China, both spatially and temporally. The magmatic rocks were formed during the period from the middle to the late Permian with isotopic ages of 248-268 Ma. The 87Sr/86Sr initial ratios of the rocks are low in a narrow variation range (-0.7050). The 143Nd/144Nd initial ratios are high (-0.51240) with positive εND(t) values (+1.28-+4.92). In the εNd(t)-(87Sr/86Sr)i diagram they fall in the first quadrant. The association of the shoshonitic and adakitic rocks can be interpreted by a two-stage model: the shoshonitic volcanic rocks were formed through long-term fractional crystallization of underplated basaltic magma, while the following partial melting of the residual phases formed the adakitic rocks.
文摘Zhijin County in Western Guizhou is one of the most important production areas of phosphorites in China. In order to investigate genesis of the phosphorites, their REE compositions were analyzed by using inductively coupled plasma emission mass spectrometry (ICP-MS) method. For comparison, phosphorites from the Lower Cambrian black rock series in Southern China, such as Zunyi in Guizhou and Zhangjiajie in Hunan Province, were also analyzed. The analytical data show that: (1) Xinhua phosphorites possess a quite high and greatly varied total rare earth elements (ΣREE), which varying between 164.23×10-6 and 1395.01×10-6 with average of 642.54×10-6, remarkable differentiation between light (LREE) and heavy rare earth elements (HREE), and the ΣLREE/ΣHREE ratios varying between 5.04 and 6.52. The ΣREE and ΣLREE/ΣHREE ratios of the Zunyi and Zhangjiajie phosphorites are 156.69×10-6~637.41×10-6 with average of 431 75×10-6 and 3.17~6.95 with average of 4.37 respectively; (2) All the phosphorites from Xinhua, Zunyi and Zhangjiajie show remarkable negative Ce anomalies. Besides, the Xinhua phosphorites possess lower δCe, which varying between 0.26 and 0.53 with average of 0.35, while δCe of the Zunyi and Zhangjiajie phosphorites are 0.30~0.66 with average of 0.47, suggesting that all of the phosphorites are typical marine sediments deposited mainly in ancient peri-continental seas, and the depositional position of the Xinhua phosphorite might be deeper; (3) Most phosphorites from Xinhua, Zunyi and Zhangjiajie possess unremarkable positive Eu anomaly, and only a few of samples show obvious ones. The δEu varies between 0.98 and 2.4, suggesting that hot (>200 ℃) and strong reductive hydrothermal fluids might have been involved in genesis of the phosphorites; (4) The Xinhua phosphorite is relatively depleted in HREE, and LaN/NdN and δY of most samples are >1 and >1.5 respectively. Besides, there exists no correlation between δY and δCe, suggesting that the phosphorite was subjected to quite strong weathering and leaching processes, and catagenesis do not greatly modify its REE compositions.
基金the National NaturalScience Foundation of China(Project Nos.40172042,40472064 , 40228004)the Ministry of Science and Technology of China(Project No.G1999043304) the Special Foundation for Doctor Subjects in China(Project No.200049107).
文摘The sedimentary sequence of the Lower Cambrian is a key interval to reveal the early evolution history of the Earth and there occur widespread cherts worldwide. These cherts possibly carry important information to decipher the breakup process of the Rodinia Continent. Black rock series at the bottom of the Lower Cambrian in the Northern Tarim Basin, China, is composed of black shales interbedded with thin-bedded cherts. Ten chert samples were systematically collected from two outcrops at Xiaoerbulak and Sogatbulak, 8.8 and 7.5 m thick respectively. The cherts were crushed, and were analyzed for trace element and rare earth concentrations. Trace elements such as V, Cu, Zn, U, Pb, Ba, Cd, Ag, Mo, As and Sb are highly enriched, and others such as Rb, Zr, Cs, Hf, Ta, W, Tl, Bi and Th are highly depleted in the cherts. These trace element patterns suggest that the cherts may be of deep crustal origin. The low ratios of Th/U and Rb/Sr further suggest that the cherts are of earth interior sources or received hydrothermal input during their deposition. Chondrite- normalized Eu/Eu* value markedly decreases upward in the section from 5.54 at the lowermost to 0.73 at the top, and NASC-normalized Eu/Eu* value decreases from 8.05 to 1.03. The relatively high Eu/Eu* ratio for the cherts from the northern Tarim Basin is most likely due to a hydrothermal input (e.g., Eu/Eu* ~10). The systematic decrease of Eu/Eu* ratio from the bottom to the top of the section reflects that the hydrothermal input is the largest in the lowermost portion of the section and gradually decreases upward. The chondrite-normalized Ce/Ce* ratio ranges from 0.42 to 0.83, with an average of 0.60. North American Shale Composite (NASC)-normalized Ce/Ce* ratio ranges from 0.42 to 0.79, with an average of 0.57. Negative Ce anomalies are distinct. ΣREEs in the cherts generally increase from 10.50 ppm at the bottom to 35.97 ppm at the top of the sampled section. NASC-normalized (La/Lu) N ratio decreases from 2.72 at the bottom to 0.67 at the top. NASC-normalized (La/Ce) N ratio increases from 1.36 at the bottom to 3.13 at the top. These REE patterns are very similar to those for the cherts deposited in the pelagic ocean-basin floor in the Franciscan Complex exposed at Marin Headlands, California (F-MH chert) (Murray et al., 1991). These geochemical signatures are inconsistent with our previous sedimentological data, which suggests a continental shelf setting. Based on multiple lines of evidence including high TOC content in the concomitant black shales, phosphorite at the bottom of black rock series, regional rise of sea level, and beginning of the southern Tianshan Ocean geotectonic cycle, the authors infer that the hydrothermal fluid was carried to the continental shelf by upwelling from a divergent pelagic ocean floor setting.
基金jointly supported by the Geological Survey Project of Chinese (Grant No.1212010911070)National Science Foundation of China (Grant No.41072167)Institute of Geology, Chinese Academy of Geological Sciences (Grant No. J1120)
文摘The Xigaze ophiolite is located in the middle section of the Yarlung Zangbo River ophiolite belt and includes a well-preserved sequence section of seven ophiolite blocks. The relatively complete ophiolitic sequence sections are represented by Jiding, Dejixiang, Baigang, and Dazhuqu ophiolites and consist of three-four units. The complete ophiolite sequence in order from the bottom to top consists of mantle peridotite, cumulates, sheeted sill dike swarms, and basic lavas±radiolarian chert. These cumulates are absent in the remaining blocks of Dejixiang and Luqu. The age of radiolaria in the radiolarian chert is Late Jurassic-Cretaceous. The basalt and ultramafic rock of the ophiolite also are overlaid by Tertiary Liuqu conglomerate, which contains numerous pebble components of ophiolite, indicating that the Tethys Ocean began to close at the end of Cretaceous Period. The isotopic data of gabbro, diabase, and albite granite in the Xigaze ophiolite are approximately 126-139 Ma, which indicates that the ophiolite formed in the Early Cretaceous. The K-Ar age of amphibole in garnet amphibolite in the ophiolite melange is 81 Ma, indicating that tectonic ophiolite emplacement occurred at the end of Late Cretaceous. Research in petrology, petrological chemistry, mineralogy, and geochemistry of volcanic rocks and dikes of the Xigaze ophiolite indicate the following characteristics: (1) They are mainly composed of basalt, basaltic andesite, dolerite, and diabase and are characterized by high TiO2 (0.7-1.47%), low MgO (mostly less than 8%), and low SiO2 (mostly less than 53%). (2) The volcanic rocks and dikes of the Xigaze ophiolite show light rare earth element (LREE)-depleted rare earth element (REE) patterns. (3) The spider diagrams of the volcanic rocks and dikes of the Xigaze ophiolite exhibit LILE depletion relative to high-field-strength element (HFSE) patterns with left oblique features. (4) No protogenetic olivine and clinoenstatite was detected. (5) Some dikes show low TiO2 and high MgO, in which a few of Cr-enriched spinels and a very few pseudomorphs of olivine, orthopyroxene can be seen. They show more distinctive affinity as boninitic rock and canbe classified to boninite series rock. The previously mentioned features of the volcanic rocks and dikes in the Xigaze ophiolite implies that these ophiolites formed in a mid-ocean ridge (MOR) in the earlier stage and than forearc extension of subduction initiation occurred once at the later stage of the evolution of the Xigaze ophiolite. The forearc extention caused further melting of the residue-depleted mantle, resulting in the formation of melts with lower TiO2 and higher MgO. These melts formed as dikes and intruded into the oceanic crust formed in the earlier stage, resulting in a close association of mid-ocean ridge basalt and the boninite rock of the Xigaze ophiolite.
基金This paper was supported by the National Basic Research Pro-gram of China(2021YFC2902002)the National Natural Sciences Foundation of China(42272208,41877299 and 41172310).
文摘Gallium(Ga)is a critical mineral that plays an irreplaceable role in consumer electronics,clean energy technologies and the aerospace industry.Nowadays competition for gallium resources at the national strategic level has begun to emerge,but gallium resources are unevenly distributed globally,and their presence is not guaranteed.New discoveries revealed an average gallium concentration of thirty-one samples from M_(1),M_(2),M_(3) and M_(4) stone coal-bearing seams of the Cambrian strata on South Qinling Orogenic Belt in central China is 157 mg/kg(9.98–747 mg/kg),which is 27.6-fold higher than the global hard coal average,as well as the existing association of Mo–V–U–Cd–Zn–Ba–Se–Mg–Ni–Cu enrichment.Ga average of these coal seams are 344 mg/kg(M_(3),44.5–747 mg/kg,n=11),270 mg/kg(M_(4),14.3–270 mg/kg,n=5),53.8 mg/kg(M_(2),22.6–75.4 mg/kg,n=8)and 19.8 mg/kg(M_(1),9.98–34.9 mg/kg,n=7)respectively,as well as the thickness of approximately 6,12,8,and 20 m,which be close to or exceed to the boundary grade standard(30 mg/kg)and minimum recoverable thickness(0.7 m)of gal-lium resources exploration.These findings indicate that the Cambrian stone coal deposits,especially in the middle and late Cambrian period,should be considered as promising alternative sources of gallium.The anomalous gallium-enriched sediments originated from a complex combination of hydrothermal flu-ids,original biomass and terrigenous materials.For the M_(1) stone coal-bearing seams,gallium most likely occurred in the mode of GaAs,Ga_(x)In_(1-x)As and GaO(OH),while modes of gallium in the M_(2) to M_(4) seams is interrelated with the organic affinity and clay minerals.The crude reserve estimate of gallium resources in central China is approximately 10.06?104 tons,corresponding to a super-large coal-hosted gallium ore deposit.The unique paleogeographic location and geological structure in central China resulted that this newly discovered deposit is a unique type of gallium-enriched deposit that has been discovered worldwide.These discoveries will provide the critical parameters when developing distinctive benefici-ation processes and appropriate extraction procedures,as well as guidance and effective for future prospecting regions of gallium resources around the globe,involving a combination consider the distri-bution of regional deep–large fault zones and the middle to late Cambrian black rock series deposits.
基金The work was supported by the National Science and Technology Major Project of China(No.2016ZX05004-004)PetroChina Project(Comprehensive petroleum geology study as well as optimazation of replacement fields and risk target of evaluation in Sinian Cambrian in Tarim Basin).
文摘Due to deep burial of Precambrian in Tarim Basin,no breakthrough in the hydrocarbon exploration has been achieved from these strata,and development of high-quality source rocks is also uncertain.More than 30 exploratory wells have been drilled in the southwest Tarim Basin and the pediment region of Kunlun Mountains with a total area of more than 100103 km2.Though some marine oil/gas fields such as Hetianhe,Bashituopu,Yubei and Luosi 2 have been discovered,the Cambrian or Ordovician source rocks have not been drilled,and hydrocarbon source still remain controversial.Recently,a set of thick black shales and mudstones has been found in the southwest Tarim Basin.The total thickness of mudstones is more than 140 m,and the total organic carbon mainly ranges from 0.6%to 1.9%with an average of 1.0%.Tmax is from 490C to 520C,equivalent to Ro from 1.99%to 2.99%.Pyrites are very rich in mudstone.According to stratigraphic contact relationship and isotopic chronology,this mudstone may have the age of more than 517 Ma,and is tentatively named as the“Western Kunlun black rock series”.Through the plate tectonic analysis,this set of thick black mudstones is possibly distributed widely in the southwest Tarim Basin,and its formation may be controlled by the aulacogen.This set of black mudstones may be an important source rocks in the southwest Tarim Basin,which suggest that the Precambrian-Cambrian strata in Tarim Basin has geological conditions for hydrocarbon accumulations.This discovery of the black thick mudstones in the southwest Tarim Basin will promote hydrocarbon exploration in the deep and ultra-deep strata of the Tarim Basin.