Synthesis,characterization,and phase transition of an inorganic-organic hybrid compound,[(3-nitroanilinium^＋)(18-crown-6)][IO4^-](CH3OH)

A novel inorganic-organic hybrid supramolecular compound,[（3-nitroanilinium^＋）（18-crown-6）][IO4]（CH3OH）（1）,was discovered as phase-transition materials displaying dielectric anomalous behaviors.The yellow block crystal formed by N-H…O hydrogen bonding that made contact through the cavity of 18-crown-6 was characterized by single-crystal X-ray diffraction,elemental analysis,infrared analysis,thermogravimetric analysis,differential scanning calorimetry,and potential-energy calculations.Differential scanning calorimetry measurements indicate that the compound experiences a reversible phase transition at around 220 K.Temperature-dependent dielectric measurements further confirm the phase transitions.Potential-energy calculations demonstrate that the phase transition occurs due to the molecular order-disorder rotation of CH3OH,whereas the space grouping of the crystal remains unchanged.

Structural relaxation and glass transition behavior of binary hard-ellipse mixtures

Structural relaxation and glass transition in binary hard-spherical particle mixtures have been reported to exhibit unusual features depending on the size disparity and composition. However, the mechanism by which the mixing effects lead to these features and whether these features are universal for particles with anisotropic geometries remains unclear. Here, we employ event-driven molecular dynamics simulation to investigate the dynamical and structural properties of binary two-dimensional hard-ellipse mixtures. We find that the relaxation dynamics for translational degrees of freedom exhibit equivalent trends as those observed in binary hard-spherical mixtures. However, the glass transition densities for translational and rotational degrees of freedom present different dependencies on size disparity and composition. Furthermore,we propose a mechanism based on structural properties that explain the observed mixing effects and decoupling behavior between translational and rotational motions in binary hard-ellipse systems.

Systematic dependence of SFE＊B(E2)↑ and ROTE＊B(E2)↑on N_pN_n in the framework of shape fluctuation model

A systematic dependence of shape fluctuation energy product SFE ＊ B（E2）↑ and rotational energy product ROTE ＊ B（E2）↑ on the valence nucleon product Np Nn is carried out in the Z = 50-82,N = 82-126 major shell space.For the shape transitional nuclei,the product SFE＊B（E2）↑ drops to zero and becomes negative,indicating direct dependence on N_pN_n.A relative rise,on the other hand,is observed in the product ROTE＊B（E2） ↑plotted against N_pN_n for all the nuclei in Z = 50-82 and N = 82-126.In the N 〉 104 region,large positive values of the product SFE ＊ B（E2） ↑ are observed for the Pt nucleus,which indicates sphericity.A systematic study of the product SFE ＊ B（E2）↑ and ROTE ＊ B（E2） ↑ with atomic number Z is also discussed.The products SFE ＊ B（E2） ↑and ROTE ＊ B（E2） ↑ vary sharply with Z for the N = 88 isotones.We discuss here for the first time the correlation between SFE ＊ B（E2） ↑ and ROTE ＊ B（E2） ↑ with valence nucleon product N_pN_n.

Ultra-narrow parametric magnetic resonances in a miniature vapor cell

Multi-photon parametric magnetic resonance in a miniature vapor cell is demonstrated. Much more multi-photon magnetic resonance can be observed when the radio frequency field becomes stronger. The linewidth of the n photons magnetic resonance equals that of the first-order resonance divided by n, which means that the uncertainty of the magnetic sublevel is reduced by the factor n. The signal-to-noise ratio can be improved when the low-frequency multi-photon resonance takes place, which finds a possible application in precision magnetic field measurement.