Diffusion coefficients of chloride ions in four soils of different texture with varying effective moisture content and varying bulk density from 1.1 to 1.6 g cm3 under three different temperatures were determined by t...Diffusion coefficients of chloride ions in four soils of different texture with varying effective moisture content and varying bulk density from 1.1 to 1.6 g cm3 under three different temperatures were determined by the diffusion-cell method using 36Cl-labelled CaCl2 solution. The results showed that activation energy decreased with water content, which indicated that the threshold for diffusion was lower at a higher soil moisture rate. Therefore, the diffusion coefficient (D) of chloride ions in soil increased consistently with soil moisture. Although a near linear increase in the diffusion coefficient with increasing soil moisture or bulk density in all the soils was observed, the increase rate in different soils was not the same. The D value increased with temperature, and with temperature increased by 10℃ in the range from 5 "C to 45℃ theD valve increased by 10%～30%, averaging about 20%.展开更多
Data from July 2006 to June 2008 observed at SACOL （Semi-Arid Climate and Environment Observatory of Lanzhou University, 35.946°N, 104.137°E, elev. 1961 m）, a semi-arid site in Northwest China, are used to...Data from July 2006 to June 2008 observed at SACOL （Semi-Arid Climate and Environment Observatory of Lanzhou University, 35.946°N, 104.137°E, elev. 1961 m）, a semi-arid site in Northwest China, are used to study seasonal variability of soil moisture, along with surface albedo and other soil thermal parameters, such as heat capacity, thermal conductivity and thermal diffusivity, and their relationships to soil moisture content. The results indicate that surface albedo decreases with increases in soil moisture content, showing a typical exponential relation between the surface albedo and the soil moisture. The heat capacity, the soil thermal diffusivity, and soil thermal conductivity show large variations between Julian day 90-212 and 450-578. The soil thermal conductivity is found to increase as a power function of soil moisture. Soil heat capacity and soil thermal diffusivity increase with increases in soil moisture. The SACOL observed soil moisture are also used to validate the AMSR-E/AQUA retrieved soil moisture and there is good agreement between them. The analysis of the relationship between satellite retrieved soil moisture and precipitation suggests that the variability of soil moisture depends on the variation of precipitation over the Loess Plateau.展开更多
Continuous observation data collected over the whole year of 2004 on a cropland surtace m Tongyu, a senti-arid area of northeastern China （44°25＇N, 122°52＇E）, have been used to investigate the variations...Continuous observation data collected over the whole year of 2004 on a cropland surtace m Tongyu, a senti-arid area of northeastern China （44°25＇N, 122°52＇E）, have been used to investigate the variations of surface albedo and soil thermal parameters, including heat capacity, thermal conductivity and thermal diffusivity, and their relationships to soil moisture. The diurnal variation of surface albedo appears as a U shape curve on sunny days. Surface albedo decreases with the increase of solar elevation angle, and it tends to be a constant when solar elevation angle is larger than 40°. So the daily average surface albedo was computed using the data when solar elevation angle is larger than 40° Mean daily surface albedo is found to decrease with the increase of soil moisture, showing an exponential dependence on soil moisture. The variations of soil heat capacity are small during Julian days 90 300. Compared with the heat capacity, soil thermal conductivity has very gentle variations during this period, but the soil thermal diffusivity has wide variations during the same period. The soil thermal conductivity is found to increase as a power function of soil moisture. The soil thermal diffusivity increases firstly and then decreases with the increase of soil moisture.展开更多
文摘Diffusion coefficients of chloride ions in four soils of different texture with varying effective moisture content and varying bulk density from 1.1 to 1.6 g cm3 under three different temperatures were determined by the diffusion-cell method using 36Cl-labelled CaCl2 solution. The results showed that activation energy decreased with water content, which indicated that the threshold for diffusion was lower at a higher soil moisture rate. Therefore, the diffusion coefficient (D) of chloride ions in soil increased consistently with soil moisture. Although a near linear increase in the diffusion coefficient with increasing soil moisture or bulk density in all the soils was observed, the increase rate in different soils was not the same. The D value increased with temperature, and with temperature increased by 10℃ in the range from 5 "C to 45℃ theD valve increased by 10%～30%, averaging about 20%.
基金supported bythe National Natural Science Foundation of China un-der Grants Nos40725015 and 40633017the Na-tional Basic Research Program of China under Grant No2006CB400501
文摘Data from July 2006 to June 2008 observed at SACOL （Semi-Arid Climate and Environment Observatory of Lanzhou University, 35.946°N, 104.137°E, elev. 1961 m）, a semi-arid site in Northwest China, are used to study seasonal variability of soil moisture, along with surface albedo and other soil thermal parameters, such as heat capacity, thermal conductivity and thermal diffusivity, and their relationships to soil moisture content. The results indicate that surface albedo decreases with increases in soil moisture content, showing a typical exponential relation between the surface albedo and the soil moisture. The heat capacity, the soil thermal diffusivity, and soil thermal conductivity show large variations between Julian day 90-212 and 450-578. The soil thermal conductivity is found to increase as a power function of soil moisture. Soil heat capacity and soil thermal diffusivity increase with increases in soil moisture. The SACOL observed soil moisture are also used to validate the AMSR-E/AQUA retrieved soil moisture and there is good agreement between them. The analysis of the relationship between satellite retrieved soil moisture and precipitation suggests that the variability of soil moisture depends on the variation of precipitation over the Loess Plateau.
基金the National Basic Research Program of China (973Program, 2006CB500401).
文摘Continuous observation data collected over the whole year of 2004 on a cropland surtace m Tongyu, a senti-arid area of northeastern China （44°25＇N, 122°52＇E）, have been used to investigate the variations of surface albedo and soil thermal parameters, including heat capacity, thermal conductivity and thermal diffusivity, and their relationships to soil moisture. The diurnal variation of surface albedo appears as a U shape curve on sunny days. Surface albedo decreases with the increase of solar elevation angle, and it tends to be a constant when solar elevation angle is larger than 40°. So the daily average surface albedo was computed using the data when solar elevation angle is larger than 40° Mean daily surface albedo is found to decrease with the increase of soil moisture, showing an exponential dependence on soil moisture. The variations of soil heat capacity are small during Julian days 90 300. Compared with the heat capacity, soil thermal conductivity has very gentle variations during this period, but the soil thermal diffusivity has wide variations during the same period. The soil thermal conductivity is found to increase as a power function of soil moisture. The soil thermal diffusivity increases firstly and then decreases with the increase of soil moisture.
