An experimental study was performed to investigate the impact of low salinity water on wettability alteration in carbonate core samples from southern Iranian reservoirs by spontaneous imbibition. In this paper, the ef...An experimental study was performed to investigate the impact of low salinity water on wettability alteration in carbonate core samples from southern Iranian reservoirs by spontaneous imbibition. In this paper, the effect of temperature, salinity,permeability and connate water were investigated by comparing the produced hydrocarbon curves. Contact angle measurements were taken to confirm the alteration of surface wettability of porous media. Oil recovery was enhanced by increasing the dilution ratio of sea water, and there existed an optimum dilution ratio at which the highest oil recovery was achieved. In addition, temperature had a very significant impact on oil recovery from carbonate rocks. Furthermore, oil recovery from a spontaneous imbibition process was directly proportional to the permeability of the core samples. The presence of connate water saturation inside the porous media facilitated oil production significantly. Also, the oil recovery from porous media was highly dependent on ion repulsion/attraction activity of the rock surface which directly impacts on the wettability conditions. Finally, the highest ion attraction percentage was measured for sodium while there was no significant change in pH for all experiments.展开更多
The low salinity water lenses(LSWLes) in the expansion area of the Changjiang diluted water(CDW) exist in a certain period of time in some years. The impact of realistic river runoff, ocean currents and weather co...The low salinity water lenses(LSWLes) in the expansion area of the Changjiang diluted water(CDW) exist in a certain period of time in some years. The impact of realistic river runoff, ocean currents and weather conditions need to be taken into account in the dynamical analysis of LSWL, which is in need of research. In this paper, the POM-σ-z model is used to set up the numerical model for the expansion of the CDW. Then LSWL in summer 1977 is simulated, and its dynamic mechanism driven by wind, tide, river runoff and the Taiwan Warm Current is also analyzed. The simulated results indicate that the isolated LSWL detaches itself from the CDW near the river mouth, and then moves towards the northeast region outside the Changjiang Estuary. Its maintaining period is from July 26 to August 11. Its formation and development is mainly driven by two factors. One is the strong southeasterly wind lasting for ten days. The other is the vertical tidal mixing during the transition from neap tide to spring tide.展开更多
Combining low salinity water (LSW) with surfactants has an enormous potential for enhancing oil recovery processes. However, there is no consensus about the mechanisms involved, in addition to the fact that several st...Combining low salinity water (LSW) with surfactants has an enormous potential for enhancing oil recovery processes. However, there is no consensus about the mechanisms involved, in addition to the fact that several studies have been conducted in model systems, while experiments with rocks and reservoir fluids are scarce. This study presents a core-flooding experiment of LSW injection, with and without surfactant, using the core and heavy oil samples obtained from a sandstone reservoir in southeastern Mexico. The effluents and the crude oil obtained at each stage were analyzed. The study was complemented by tomographic analysis. The results revealed that LSW injection and hybrid process with surfactants obtained an increase of 11.4 percentage points in recovery factor. Various phenomena were caused by LSW flooding, such as changes in wettability and pH, ion exchange, mineral dissolution, detachment of fines and modification of the hydrocarbon profile. In the surfactant flooding, the reduction of interfacial tension and alteration of wettability were the main mechanisms involved. The findings of this work also showed that the conditions believed to be necessary for enhanced oil recovery with LSW, such as the presence of kaolinite or high acid number oil, are not relevant.展开更多
A study comparative of rearing of the Pacific white shrimp (Litopenaeus vannamei) with the Nile tilapia (Oreochromis niloticus) in three earthen ponds (5,600 m^2) with the salinity ranged from 0.5-1.2 ppt and th...A study comparative of rearing of the Pacific white shrimp (Litopenaeus vannamei) with the Nile tilapia (Oreochromis niloticus) in three earthen ponds (5,600 m^2) with the salinity ranged from 0.5-1.2 ppt and three treatment ponds with salinity of 2-4 ppt by adding brine water into the ponds. Postlarvae 12 (PL12) of L. vannamei were stocked at density of 9 PL/m^2 and after one week the Nile tilapia fingerlings were stocked at density of I fish/m^2. Only pelleted feed were given to the fish during the 196-day rearing period. Shrimps were partially harvested by sieve net at day 80 and 120, and five days later PLI2 were stocked at the rate of 3 PL/m^2. After final harvesting at day 196, the production, body weight and survival from the treatment group were significantly higher (P 〈 0.05) than those of the control group. While the fish production body weight and survival rate from both groups were not significant differences (P 〉 0.051). The ionic concentration of six major ions (CI, SO42, Ca^2+, Na^+, Mg^2+ and K^+), salinity and hardness in the treatment ponds were significantly higher than those of the control ponds (P 〈 0.05). Moreover, the ionic profiles of the treatment ponds were similar to seawater at the salinity of 2 ppt while only 1 ppt in the control ponds. Results from the study indicated that in order to achieve good growth and survival rate of L. vannamei, brine water should be added into grow-out ponds prior to stocking and during the rearing: period to obtain and maintain the salinity not less than 2 ppt.展开更多
In recent years,controlling the salinity and composition of the injected water has become an emerging enhanced oil recovery(EOR)technique,often described as low salinity(LS)waterflooding.This work is done with the int...In recent years,controlling the salinity and composition of the injected water has become an emerging enhanced oil recovery(EOR)technique,often described as low salinity(LS)waterflooding.This work is done with the intention to contribute to the ongoing discussions about LS waterflooding mechanism(s).For this purpose,a series of different experiments were conducted.At first,the effect of salinity on the interfacial tension(IFT)and the contact angle was evaluated with a crude oil sample.Then to achieve more accurate results in observing oil/water interface,similar IFT experiments were also carried out on a synthetic oil containing asphaltenes.Thereafter,microscopic visualization using glass micromodel was performed on the interface of the synthetic oil sample and brines.Four brine solutions including Sea Water(SW),it's dilutions and formation water(FW)were used for various experiments.Finally,to investigate the presented mechanism by other authors,a series of Environmental Scanning Electron Microscopy(ESEM)analysis on the synthetic oil was carried out to understand better the phase behaviour after contacting both synthetic oil and water phases from the micromodel experiment.Based on the existing mechanism,there exists an optimal concentration beyond which dilution is no longer an effective process.展开更多
Chemical enhanced oil recovery(c-EOR)is a conventional and promising strategy to recover oil from reservoir techniques such as low salinity water flooding(LSWF),surfactant flooding,alkaline flooding,polymers flooding,...Chemical enhanced oil recovery(c-EOR)is a conventional and promising strategy to recover oil from reservoir techniques such as low salinity water flooding(LSWF),surfactant flooding,alkaline flooding,polymers flooding,and nanofluid flooding.The use of various types of chemical materials for c-EOR method has recently attracted the attention of the oil and gas industry.The primary objective of this review work is to explore the synergy of low salinity water/surfactant/nanoparticle flooding for effective c-EOR method and investigate the mechanism behind these methods.The advantages of combining these chemical materials for c-EOR methods is also reviewed.Challenges and limitations of this synergy and their economic feasibility for additional oil recovery and potential return on investment are reviewed.Nanoparticles have been successfully used in various applications in several industries and have also shown good application for EOR in terms of wettability alteration.LSWF contributes to wettability alteration,while surfactant contributes to wettability alteration and interfacial tension(IFT)reduction.However,fines migration caused by LSWF and nanoparticle agglomeration can cause formation damage,while excessive surfactant adsorption can lead to cost overrun on surfactant use.Understanding the characteristics of reservoir formation mineralogy and appropriate nanoparticle type,size,and concentration can be used to resolve this challenges.The synergy of LSWF and nanoparticles in alkaline medium can serve as sacrificial agent to reduce excessive surfactant loss.Therefore,the appropriate synergistic formulation of LSFW/surfactant/nanoparticle can improve additional oil recovery and support return on investment for c-EOR projects.展开更多
Although significant amount of H_(2)S(sour gas)rich natural gas is estimated globally,but not much attention has been given to the application of H_(2)S in the oil recovery process.Recent studies on the use of H_(2)S ...Although significant amount of H_(2)S(sour gas)rich natural gas is estimated globally,but not much attention has been given to the application of H_(2)S in the oil recovery process.Recent studies on the use of H_(2)S in oil recovery processes showed that H_(2)S has the potential of improving the oil recovery,and it can be even more effective than using CO_(2) in some processes.H_(2)S can equally dissolve in the water,react with the reservoir rock to change its surface charge,porosity,and permeability.However,previous in-vestigations on H_(2)S oil recovery attributed the improved oil recoveries to the higher miscibility of H_(2)S in the oil,and the reduction in the oil viscosity.Therefore,there is limited understanding on the H_(2)S-oil-brine-rock geochemical interactions,and how they impact the oil recovery process.This study aims to investigate the interactions between H_(2)S,oil,and carbonate formations,and to assess how the combi-nation of H_(2)S and low salinity water can impact the wettability and porosity of the reservoirs.A triple layer surface complexation model was used to understand the influence of key parameters(e.g.,pressure,brine salinity,and composition)on the H_(2)S-brine-oil-rock interactions.Moreover,the effects of mineral content of the carbonate rock on H_(2)S interactions were studied.Thereafter,the results of the H_(2)S-oil-brine-rock interactions were compared with a study where CO_(2) was used as the injected gas.Results of the study showed that the seawater and its diluted forms yielded identicalζ-potential values of about 3.31 mV at a pH of 3.24.This indicates that at very low pH condition,pH controls the ζ-potential of the oil-brine interface regardless of the brine's ionic strength.The study further demonstrated that the presence of other minerals in the carbonate rock greatly reduced the calcite dissolution.For instance,the calcite dissolution was reduced by 4.5%when anhydrite mineral was present in the carbonate rock.Findings from the simulation also indicated that CO_(2) produced negative ζ-potential values for the car-bonate rocks,and these values were reduced by 18.4%-20% when H_(2)S was used as the gas phase.This implies that the H_(2)S shifted the carbonate rockζ-potentials towards positive.The outcomes of this study can be applied when designing CO_(2) flooding and CO_(2) storage where the gas stream contains H_(2)S gas since H_(2)S greatly influences the dissolution of the carbonate mineral.展开更多
The capacitance-resistance model(CRM)has been widely implemented to model and optimise water-flooding and enhanced oil recovery(EOR)techniques.However,there is a gap in the application of CRM to analyse physical pheno...The capacitance-resistance model(CRM)has been widely implemented to model and optimise water-flooding and enhanced oil recovery(EOR)techniques.However,there is a gap in the application of CRM to analyse physical phenomena in porous media as well as the performance of EOR methods,such as low-salinity water(LSW)flooding.The main purposes of this study were to investigate how changes in time constant,as a CRM parameter,can represent physical phenomena in porous media such as wettability alteration.Moreover,to show CRM is a reliable tool to use for interpretation of LSW process as an EOR method.The results of different experimental/modelling studies in this research showed that in CRM model time constant increases when the wettability alters to a water wetness state,whereby the smallest time constant value is observed for the oil wet medium and the highest is observed for the water wet medium.The cases with a gradual alteration in wettability show an increasing trend with the dilution of the injection water.The core flooding data confirms the observed results of the simulation approach.The increment in time constant values indicates the resistance against displacing fluid,which is due to the wettability alteration of the porous medium,resulting in additional oil production.The observations made during this research illustrate that the time constant parameter can be a powerful tool for comparing different EOR techniques,since it is a good indication of the speed of impact of a particular injection fluid on production.展开更多
Investigating the enhanced oil recovery leads to optimal production,protection and reduction of lateral impacts.Low salinity water injection(LSWI)is one of the significantly improved oil recovery(IOR)techniques for ch...Investigating the enhanced oil recovery leads to optimal production,protection and reduction of lateral impacts.Low salinity water injection(LSWI)is one of the significantly improved oil recovery(IOR)techniques for changing the amount of wettability in the carbonate fractured reservoirs.The utilization of this methodology in terms of high efficiency in displacing light crude oils to the medium-gravity crude oils,water sources availability and its sustainability for pushing the oil which leads to appropriate economic occasions,are being compared with other IOR/EOR techniques.In this study,the best injection modelling pattern is based on the highest rate of recovery factor.Comparison of“high and low salinity water injection method”with“pure water injection method”is performed in an oil reservoir.Overall,analyzing the sensitivity on the high and low salinity according to the moderately low recovery factor of high and low salinity among the injection scenarios illustrates the low sensitivity of this parameter on a fractured carbonate reservoir.By reviewing different scenarios,it could be demonstrated that if the water injection could be applied to the reservoir from the preliminary times of production,the recovery factor rate would be increased.Thereby,higher appropriate efficiency and better supplement have resulted.Pure water injection has a high recovery factor than salty water injection.By the way,these two methods have little differences in calculating recovery methods.Besides,this parameter is significantly depended on wellhead equipment properties,safety factor and economic issues(water production).展开更多
Using a crop-water-salinity production function and a soil-water-salinity dynamic model, optimal irrigation scheduling was developed to maximize net return per irrigated area. Plot and field experiments were used to o...Using a crop-water-salinity production function and a soil-water-salinity dynamic model, optimal irrigation scheduling was developed to maximize net return per irrigated area. Plot and field experiments were used to obtain the crop water sensitivity index, the salinity sensitivity index, and other parameters. Using data collected during 35 years to calculate the 10-day mean precipitation and evaporation, the variation in soil salinity concentrations and in the yields of winter wheat and cotton were simulated for 49 irrigation scheduling that were combined from 7 irrigation schemes over 3 irrigation dates and 7 salinity concentrations of saline irrigation water (fresh water and 6 levels of saline water). Comparison of predicted results with irrigation data obtained from a large area of the field showed that the model was valid and reliable. Based on the analysis of the investment cost of the irrigation that employed deep tube wells or shallow tube wells, a saline water irrigation schedule and a corresponding strategy for groundwater development and utilization were proposed. For wheat or cotton, if the salinity concentration was higher than 7.0 g L-1 in groundwater, irrigation was needed with only fresh water; if about 5.0 g L-1, irrigation was required twice with fresh water and once with saline water; and if not higher than 3.0 g L-1, irrigation could be solely with saline water.展开更多
In arid and semi-arid regions, freshwater scarcity and high water salinity are serious and chronic problems for crop production and sustainable agriculture development. We conducted a field experiment to evaluate the ...In arid and semi-arid regions, freshwater scarcity and high water salinity are serious and chronic problems for crop production and sustainable agriculture development. We conducted a field experiment to evaluate the effect of irrigation water salinity and nitrogen(N) application rate on soil salinity and cotton yield under drip irrigation during the 2011 and 2012 growing seasons. The experimental design was a 3×4 factorial with three irrigation water salinity levels(0.35, 4.61 and 8.04 dS/m) and four N application rates(0, 240, 360 and 480 kg N/hm2). Results showed that soil water content increased as the salinity of the irrigation water increased, but decreased as the N application rate increased. Soil salinity increased as the salinity of the irrigation water increased. Specifically, soil salinity measured in 1:5 soil:water extracts was 218% higher in the 4.61 dS/m treatment and 347% higher in the 8.04 dS/m treatment than in the 0.35 dS/m treatment. Nitrogen fertilizer application had relatively little effect on soil salinity, increasing salinity by only 3%–9% compared with the unfertilized treatment. Cotton biomass, cotton yield and evapotranspiration(ET) decreased significantly in both years as the salinity of irrigation water increased, and increased as the N application rate increased regardless of irrigation water salinity; however, the positive effects of N application were reduced when the salinity of the irrigation water was 8.04 dS/m. Water use efficiency(WUE) was significantly higher by 11% in the 0.35 dS/m treatment than in the 8.04 dS/m treatment. There was no significant difference in WUE between the 0.35 dS/m treatment and the 4.61 dS/m treatment. The WUE was also significantly affected by the N application rate. The WUE was highest in the 480 kg N/hm2 treatment, being 31% higher than that in the 0 kg N/hm2 treatment and 12% higher than that in the 240 kg N/hm2 treatment. There was no significant difference between the 360 and 480 kg N/hm2 treatments. The N use efficiency(NUE) was significantly lower in the 8.04 dS/m treatment than in either the 4.61 dS/m or the 0.35 dS/m treatment. There was no significant difference in NUE between the latter two treatments. These results suggest that irrigation water with salinity 〈4.61 dS/m does not have an obvious negative effect on cotton production, WUE or NUE under the experimental conditions. Application of N fertilizer(0–360 kg N/hm2) could alleviate salt damage, promote cotton growth, and increase both cotton yield and water use efficiency.展开更多
Use of saline water in irrigated agriculture has become an important means for alleviating water scarcity in arid and semi-arid regions. The objective of this field experiment was to evaluate the effects of irrigation...Use of saline water in irrigated agriculture has become an important means for alleviating water scarcity in arid and semi-arid regions. The objective of this field experiment was to evaluate the effects of irrigation water salinity and N fertilization on soil physicochemical and biological properties related to nitrification and denitrification. A 3×2 factorial design was used with three levels of irrigation water salinity(0.35, 4.61 and 8.04 d S m-1) and two N rates(0 and 360 kg N ha^(-1)). The results indicated that irrigation water salinity and N fertilization had significant effects on many soil physicochemical properties including water content, salinity, p H, NH_4-N concentration, and NO_3-N concentration. The abundance(i.e., gene copy number) of ammonia-oxidizing archaea(AOA) was greater than that of ammonia-oxidizing bacteria(AOB) in all treatments. Irrigation water salinity had no significant effect on the abundance of AOA or AOB in unfertilized plots. However, saline irrigation water(i.e., the 4.61 and 8.04 d S m-1 treatments) reduced AOA abundance, AOB abundance and potential nitrification rate in N fertilized plots. Regardless of N application rate, saline irrigation water increased urease activity but reduced the activities of both nitrate reductase and nitrite reductase. Irrigation with saline irrigation water significantly reduced cotton biomass, N uptake and yield. Nitrogen application exacerbated the negative effect of saline water. These results suggest that brackish water and saline water irrigation could significantly reduce both the abundance of ammonia oxidizers and potential nitrification rates. The AOA may play a more important role than AOB in nitrification in desert soil.展开更多
In this study, nineteen brine samples from the Qarhan Salt Lake(QSL) in western China were collected and analyzed for boron(B) and chlorine(Cl) concentrations, total dissolved solids(TDS), pH values and stable B isoto...In this study, nineteen brine samples from the Qarhan Salt Lake(QSL) in western China were collected and analyzed for boron(B) and chlorine(Cl) concentrations, total dissolved solids(TDS), pH values and stable B isotopic compositions. The B concentrations and δ^(11) B values of brines in the QSL range from 51.6 mg/L to138.4 mg/L, and from +9.32& to +13.08&, respectively. By comparison of B concentrations and TDS of brines in QSL with evaporation paths of brackish water, we found that B enrichment of brines primarily results from strong evaporation and concentration of Qarhan lake water. Combining with comparisons of B concentrations, TDS, p H values and δ^(11) B values of brines, previously elemental ratios(K/Cl, Mg/Cl, Ca/Cl, B/Cl) and δ^(11) B values of halite from a sediment core(ISL1 A), we observe good correlations between B concentrations and TDS, TDS and pH values, pH and δ^(11) B values of brines, which demonstrate that higher B concentrations and more positive δ^(11) B values of halite indicate higher salinity of the Qarhan paleolake water as well as drier paleoclimatic conditions. Based on this interpretation of the δ^(11) B values of halite in core ISL1 A, higher salinity of the Qarhan paleolake occurred during two intervals, around 46-34 ka and26-9 ka, which are almost coincident with the upper and lower halite-dominated salt layers in core ISL1 A,drier climate phases documented from the δ^(18) O record of carbonate in core ISL1 A and the paleomoisture record in monsoonal central Asia, and a higher solar insolation at 30°N. These results demonstrate that the δ^(11) B values of halite in the arid Qaidam Basin could be regarded as a new proxy for reconstructing the salinity record of paleolake water as well as paleoclimate conditions.展开更多
Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms,originated from the long-term erosion by acidic rainwater.The dissolved salt poses an extra osmotic water pote...Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms,originated from the long-term erosion by acidic rainwater.The dissolved salt poses an extra osmotic water potential being normally neglected in laboratory measurements and numerical analyses.However,ignorance of salinity may result in overestimation of stability,and the design may not be as conservative as thought.Therefore,this research aims to first experimentally examine the influence of pore water salinity on water retention curve and saturated permeability of natural dispersive loess under saline and desalinated conditions.Second,the measured parameters are used for stability analyses of a railway embankment in an area subjected to regional rainfall incident.Eventually,a numerical parametric study is carried out to explore the significance of different rainfall schemes,construction patterns,and anisotropic permeability on the factor of safety.Results reveal that desalinization suppresses the water retention capability,which in turn results in a tremendous declination of unsaturated hydraulic conductivity.Despite the natural saline embankment,rainfall can hardly infiltrate into the desalinated embankment due to the lower conductivity.Therefore,the factor of safety for natural saline conditions drops notably,while only marginal changes occur in the case of the desalinated embankment.展开更多
The effect of NaCl on soil strength was investigated in this project based on salinity concentrations of 0 g/L, 5 g/L, 20 g/L, and 50 g/L as well as varying water contents of 15%-20%. Laser particle size analyzer was ...The effect of NaCl on soil strength was investigated in this project based on salinity concentrations of 0 g/L, 5 g/L, 20 g/L, and 50 g/L as well as varying water contents of 15%-20%. Laser particle size analyzer was also performed to explain possible effects. From particle size analysis and strength tests, it is hypothesized that the strength of the soil is increased with the addition of certain salinity concentrations until there are reversed effects, which is between 20 g/L and 50 g/L from our study. The increase of strength is suggested to be the affect of a greater variety of particle sizes. Since NaCI plays a role in the particle size distribution, it also plays a role in the strength of soils. The degree of the effect of the water content also differs from concentrations, and could be due to the variation of hydration film thickness on particles, which is affected by the ions introduced from water.展开更多
High-entropy materials(HEMs),which are newly manufactured compounds that contain five or more metal cations,can be a platform with desired properties,including improved electrocatalytic performance owing to the inhere...High-entropy materials(HEMs),which are newly manufactured compounds that contain five or more metal cations,can be a platform with desired properties,including improved electrocatalytic performance owing to the inherent complexity.Here,a strain engineering methodology is proposed to design transition-metal-based HEM by Li manipulation(LiTM)with tunable lattice strain,thus tailoring the electronic structure and boosting electrocatalytic performance.As confirmed by the experiments and calculation results,tensile strain in the LiTM after Li manipulation can optimize the d-band center and increase the electrical conductivity.Accordingly,the asprepared LiTM-25 demonstrates optimized oxygen evolution reaction and hydrogen evolution reaction activity in alkaline saline water,requiring ultralow overpotentials of 265 and 42 mV at 10 mA cm−2,respectively.More strikingly,LiTM-25 retains 94.6%activity after 80 h of a durability test when assembled as an anion-exchange membrane water electrolyzer.Finally,in order to show the general efficacy of strain engineering,we incorporate Li into electrocatalysts with higher entropies as well.展开更多
The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific consideration...The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific considerations and limitations. One way to decrease undesirable effects of sodic waters on the physical and chemical properties of soils is to apply organic and chemical amendments within the soil. This study aimed to assess the effectiveness of saline water on soil acidity, alkalinity and nutrients leaching in sandy loamy soil at Bella flower farm, in Rwamagana District, Rwanda. The water used was from the Muhazi Lake which is classified as Class I (Saline water quality). Column leaching experiments using treated soils were then conducted under saturated conditions. The soil under experimental was first analyzed for its textural classification, soil properties and is classified as sandy loamy soil. The t-test was taken at 1%, 5% and 10% levels of statistical significance compared to control soil. The results indicated that the application of saline water to soils caused an increase in some soil nutrients like increase of Phosphorus (P), Potassium (K<sup>+</sup>), Magnesium (Mg2<sup>+</sup>), Sulphur (S), CN ratio and Sodium (Na<sup>+</sup>) and decreased soil texture, physical and chemical properties and remained soil nutrients. Consequently, the intensive addition of saline water leachates to soil in PVC pipes led to decreased of soil EC through leaching and a raiser Soluble Sodium Percentage (SSP). The rate of saline water application affected the increase accumulation of SAR and Na% in the top soil layers. The study indicated that saline water is an inefficient amendment for sandy soil with saline water irrigation. The study recommends further studies with similar topic with saline water irrigation, as it accentuated the alkalinity levels.展开更多
The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the...The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the long-term changes in the intermediate water in the SCS have not been thoroughly studied due to limited data,particularly in relation to its thermodynamic variations.This study utilized reanalysis data products to identify a 60-year trend of freshening in the intermediate waters of the northern South China Sea(NSCS),accompanied by an expansion of low-salinity water.The study also constructed salinity budget terms,including advection and entrainment processes,and conducted an analysis of the salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of the intermediate water in the NSCS.The analysis revealed that the freshening in the northwest Pacific Ocean and the intensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes in the NSCS.Additionally,a weakened trend in the intensity of vertical entrainment also contributes to the freshening in the NSCS.This study offers new insights into the understanding of regional deep sea changes in response to variations in both thermodynamics and oceanic dynamic processes.展开更多
Field experiments were conducted in 2008 and 2009 to study the effects of deficit irrigation with saline water on spring wheat growth and yield in an arid region of Northwest China. Nine treatments included three sali...Field experiments were conducted in 2008 and 2009 to study the effects of deficit irrigation with saline water on spring wheat growth and yield in an arid region of Northwest China. Nine treatments included three salinity levels sl, s2 and s3 (0.65, 3.2, and 6.1 dS/m) in combination with three water levels wl, w2 and w3 (375, 300, and 225 mm). In 2008, for most treatments, deficit irrigation showed adverse effects on wheat growth; meanwhile, the effect of saline irrigation was not apparent. In 2009, growth parameters of wl treatments were not always optimal under saline irrigation. At 3.2 and 6.1 dS/m in 2008, the highest yield was obtained by wl treatments, however, in 2009, the weight of 1,000 grains and wheat yield both followed the order w2 〉 wl 〉 w3. In this study, spring wheat was sensitive to water deficit, especially at the booting to grain-filling stages, but was not significantly affected by saline irrigation and the combination of the two factors. The results demonstrated that 300-mm irrigation water with a salinity of less than 3.2 dS/m is suitable for wheat fields in the study area.展开更多
Furrow irrigation when combined with plastic mulch on ridge is one of the current uppermost wa- ter-saving irrigation technologies for arid regions. The present paper studies the dynamics of soil water-salt trans- por...Furrow irrigation when combined with plastic mulch on ridge is one of the current uppermost wa- ter-saving irrigation technologies for arid regions. The present paper studies the dynamics of soil water-salt trans- portation and its spatial distribution characteristics under irrigation with saline water in a maize field experiment. The mathematical relationships for soil salinity, irrigation amount and water salinity are also established to evaluate the contribution of the irrigation amount and the salinity of saline water to soil salt accumulation. The result showed that irrigation with water of high salinity could effectively increase soil water content, but the increment is limited com- paring with the influence from irrigation amount. The soil water content in furrows was higher than that in ridges at the same soil layers, with increments of 12.87% and 13.70% for MMF9 (the treatment with the highest water salinity and the largest amount of irrigation water) and MMF1 (the treatment with the lowest water salinity and the least amount of irrigation water) on 27 June, respectively. The increment for MMF9 was gradually reduced while that for MMF1 increased along with growth stages, the values for 17 August being 2.40% and 19.92%, respectively. Soil water content in the ridge for MMF9 reduced gradually from the surface layer to deeper layers while the surface soil water content for MMF1 was smaller than the contents below 20 cm at the early growing stage. Soil salinities for the treatments with the same amount of irrigation water but different water salinity increased with the water salinity. When water salinity was 6.04 dS/m, the less water resulted in more salt accumulation in topsoil and less in deep layers. When water salinity was 2.89 dS/m, however, the less water resulted in less salt accumulation in topsoil and salinity remained basically stable in deep layers. The salt accumulation in the ridge surface was much smaller than that in the furrow bottom under this technology, which was quite different from traditional furrow irrigation. The soil salinities for MMF7, MMF8 and MMF9 in the ridge surface were 0.191, 0.355 and 0.427 dS/m, respectively, whereas those in the furrow bottom were 0.316, 0.521 and 0.631 dS/m, respectively. The result of correlation analysis indicated that compared with irrigation amount, the irrigation water salinity was still the main factor influ- encing soil salinity in furrow irrigation with plastic mulch on ridge.展开更多
基金the National Iranian South Oil Company (NISOC) for generously funding the project
文摘An experimental study was performed to investigate the impact of low salinity water on wettability alteration in carbonate core samples from southern Iranian reservoirs by spontaneous imbibition. In this paper, the effect of temperature, salinity,permeability and connate water were investigated by comparing the produced hydrocarbon curves. Contact angle measurements were taken to confirm the alteration of surface wettability of porous media. Oil recovery was enhanced by increasing the dilution ratio of sea water, and there existed an optimum dilution ratio at which the highest oil recovery was achieved. In addition, temperature had a very significant impact on oil recovery from carbonate rocks. Furthermore, oil recovery from a spontaneous imbibition process was directly proportional to the permeability of the core samples. The presence of connate water saturation inside the porous media facilitated oil production significantly. Also, the oil recovery from porous media was highly dependent on ion repulsion/attraction activity of the rock surface which directly impacts on the wettability conditions. Finally, the highest ion attraction percentage was measured for sodium while there was no significant change in pH for all experiments.
基金supported by the National Natural Science Foundation of China(Grant Nos.40906044,41076048 and 41376012)the Fundamental Research Funds for the Central Universities(Grant No.2011B05714)the Doctoral Starting up Foundation of College of Meteorology and Oceanography of the PLA University of Science and Technology,China
文摘The low salinity water lenses(LSWLes) in the expansion area of the Changjiang diluted water(CDW) exist in a certain period of time in some years. The impact of realistic river runoff, ocean currents and weather conditions need to be taken into account in the dynamical analysis of LSWL, which is in need of research. In this paper, the POM-σ-z model is used to set up the numerical model for the expansion of the CDW. Then LSWL in summer 1977 is simulated, and its dynamic mechanism driven by wind, tide, river runoff and the Taiwan Warm Current is also analyzed. The simulated results indicate that the isolated LSWL detaches itself from the CDW near the river mouth, and then moves towards the northeast region outside the Changjiang Estuary. Its maintaining period is from July 26 to August 11. Its formation and development is mainly driven by two factors. One is the strong southeasterly wind lasting for ten days. The other is the vertical tidal mixing during the transition from neap tide to spring tide.
文摘Combining low salinity water (LSW) with surfactants has an enormous potential for enhancing oil recovery processes. However, there is no consensus about the mechanisms involved, in addition to the fact that several studies have been conducted in model systems, while experiments with rocks and reservoir fluids are scarce. This study presents a core-flooding experiment of LSW injection, with and without surfactant, using the core and heavy oil samples obtained from a sandstone reservoir in southeastern Mexico. The effluents and the crude oil obtained at each stage were analyzed. The study was complemented by tomographic analysis. The results revealed that LSW injection and hybrid process with surfactants obtained an increase of 11.4 percentage points in recovery factor. Various phenomena were caused by LSW flooding, such as changes in wettability and pH, ion exchange, mineral dissolution, detachment of fines and modification of the hydrocarbon profile. In the surfactant flooding, the reduction of interfacial tension and alteration of wettability were the main mechanisms involved. The findings of this work also showed that the conditions believed to be necessary for enhanced oil recovery with LSW, such as the presence of kaolinite or high acid number oil, are not relevant.
文摘A study comparative of rearing of the Pacific white shrimp (Litopenaeus vannamei) with the Nile tilapia (Oreochromis niloticus) in three earthen ponds (5,600 m^2) with the salinity ranged from 0.5-1.2 ppt and three treatment ponds with salinity of 2-4 ppt by adding brine water into the ponds. Postlarvae 12 (PL12) of L. vannamei were stocked at density of 9 PL/m^2 and after one week the Nile tilapia fingerlings were stocked at density of I fish/m^2. Only pelleted feed were given to the fish during the 196-day rearing period. Shrimps were partially harvested by sieve net at day 80 and 120, and five days later PLI2 were stocked at the rate of 3 PL/m^2. After final harvesting at day 196, the production, body weight and survival from the treatment group were significantly higher (P 〈 0.05) than those of the control group. While the fish production body weight and survival rate from both groups were not significant differences (P 〉 0.051). The ionic concentration of six major ions (CI, SO42, Ca^2+, Na^+, Mg^2+ and K^+), salinity and hardness in the treatment ponds were significantly higher than those of the control ponds (P 〈 0.05). Moreover, the ionic profiles of the treatment ponds were similar to seawater at the salinity of 2 ppt while only 1 ppt in the control ponds. Results from the study indicated that in order to achieve good growth and survival rate of L. vannamei, brine water should be added into grow-out ponds prior to stocking and during the rearing: period to obtain and maintain the salinity not less than 2 ppt.
文摘In recent years,controlling the salinity and composition of the injected water has become an emerging enhanced oil recovery(EOR)technique,often described as low salinity(LS)waterflooding.This work is done with the intention to contribute to the ongoing discussions about LS waterflooding mechanism(s).For this purpose,a series of different experiments were conducted.At first,the effect of salinity on the interfacial tension(IFT)and the contact angle was evaluated with a crude oil sample.Then to achieve more accurate results in observing oil/water interface,similar IFT experiments were also carried out on a synthetic oil containing asphaltenes.Thereafter,microscopic visualization using glass micromodel was performed on the interface of the synthetic oil sample and brines.Four brine solutions including Sea Water(SW),it's dilutions and formation water(FW)were used for various experiments.Finally,to investigate the presented mechanism by other authors,a series of Environmental Scanning Electron Microscopy(ESEM)analysis on the synthetic oil was carried out to understand better the phase behaviour after contacting both synthetic oil and water phases from the micromodel experiment.Based on the existing mechanism,there exists an optimal concentration beyond which dilution is no longer an effective process.
基金supported by the Ministry of Higher Education,Malaysia under the Fundamental Research Grant Scheme:FRGS/1/2020/TK0/CURTIN/03/10.
文摘Chemical enhanced oil recovery(c-EOR)is a conventional and promising strategy to recover oil from reservoir techniques such as low salinity water flooding(LSWF),surfactant flooding,alkaline flooding,polymers flooding,and nanofluid flooding.The use of various types of chemical materials for c-EOR method has recently attracted the attention of the oil and gas industry.The primary objective of this review work is to explore the synergy of low salinity water/surfactant/nanoparticle flooding for effective c-EOR method and investigate the mechanism behind these methods.The advantages of combining these chemical materials for c-EOR methods is also reviewed.Challenges and limitations of this synergy and their economic feasibility for additional oil recovery and potential return on investment are reviewed.Nanoparticles have been successfully used in various applications in several industries and have also shown good application for EOR in terms of wettability alteration.LSWF contributes to wettability alteration,while surfactant contributes to wettability alteration and interfacial tension(IFT)reduction.However,fines migration caused by LSWF and nanoparticle agglomeration can cause formation damage,while excessive surfactant adsorption can lead to cost overrun on surfactant use.Understanding the characteristics of reservoir formation mineralogy and appropriate nanoparticle type,size,and concentration can be used to resolve this challenges.The synergy of LSWF and nanoparticles in alkaline medium can serve as sacrificial agent to reduce excessive surfactant loss.Therefore,the appropriate synergistic formulation of LSFW/surfactant/nanoparticle can improve additional oil recovery and support return on investment for c-EOR projects.
文摘Although significant amount of H_(2)S(sour gas)rich natural gas is estimated globally,but not much attention has been given to the application of H_(2)S in the oil recovery process.Recent studies on the use of H_(2)S in oil recovery processes showed that H_(2)S has the potential of improving the oil recovery,and it can be even more effective than using CO_(2) in some processes.H_(2)S can equally dissolve in the water,react with the reservoir rock to change its surface charge,porosity,and permeability.However,previous in-vestigations on H_(2)S oil recovery attributed the improved oil recoveries to the higher miscibility of H_(2)S in the oil,and the reduction in the oil viscosity.Therefore,there is limited understanding on the H_(2)S-oil-brine-rock geochemical interactions,and how they impact the oil recovery process.This study aims to investigate the interactions between H_(2)S,oil,and carbonate formations,and to assess how the combi-nation of H_(2)S and low salinity water can impact the wettability and porosity of the reservoirs.A triple layer surface complexation model was used to understand the influence of key parameters(e.g.,pressure,brine salinity,and composition)on the H_(2)S-brine-oil-rock interactions.Moreover,the effects of mineral content of the carbonate rock on H_(2)S interactions were studied.Thereafter,the results of the H_(2)S-oil-brine-rock interactions were compared with a study where CO_(2) was used as the injected gas.Results of the study showed that the seawater and its diluted forms yielded identicalζ-potential values of about 3.31 mV at a pH of 3.24.This indicates that at very low pH condition,pH controls the ζ-potential of the oil-brine interface regardless of the brine's ionic strength.The study further demonstrated that the presence of other minerals in the carbonate rock greatly reduced the calcite dissolution.For instance,the calcite dissolution was reduced by 4.5%when anhydrite mineral was present in the carbonate rock.Findings from the simulation also indicated that CO_(2) produced negative ζ-potential values for the car-bonate rocks,and these values were reduced by 18.4%-20% when H_(2)S was used as the gas phase.This implies that the H_(2)S shifted the carbonate rockζ-potentials towards positive.The outcomes of this study can be applied when designing CO_(2) flooding and CO_(2) storage where the gas stream contains H_(2)S gas since H_(2)S greatly influences the dissolution of the carbonate mineral.
基金would like to thank Nazarbayev University for supporting this research through the NU Faculty Development Competitive Research Grants program(Award number:110119FD4541).
文摘The capacitance-resistance model(CRM)has been widely implemented to model and optimise water-flooding and enhanced oil recovery(EOR)techniques.However,there is a gap in the application of CRM to analyse physical phenomena in porous media as well as the performance of EOR methods,such as low-salinity water(LSW)flooding.The main purposes of this study were to investigate how changes in time constant,as a CRM parameter,can represent physical phenomena in porous media such as wettability alteration.Moreover,to show CRM is a reliable tool to use for interpretation of LSW process as an EOR method.The results of different experimental/modelling studies in this research showed that in CRM model time constant increases when the wettability alters to a water wetness state,whereby the smallest time constant value is observed for the oil wet medium and the highest is observed for the water wet medium.The cases with a gradual alteration in wettability show an increasing trend with the dilution of the injection water.The core flooding data confirms the observed results of the simulation approach.The increment in time constant values indicates the resistance against displacing fluid,which is due to the wettability alteration of the porous medium,resulting in additional oil production.The observations made during this research illustrate that the time constant parameter can be a powerful tool for comparing different EOR techniques,since it is a good indication of the speed of impact of a particular injection fluid on production.
文摘Investigating the enhanced oil recovery leads to optimal production,protection and reduction of lateral impacts.Low salinity water injection(LSWI)is one of the significantly improved oil recovery(IOR)techniques for changing the amount of wettability in the carbonate fractured reservoirs.The utilization of this methodology in terms of high efficiency in displacing light crude oils to the medium-gravity crude oils,water sources availability and its sustainability for pushing the oil which leads to appropriate economic occasions,are being compared with other IOR/EOR techniques.In this study,the best injection modelling pattern is based on the highest rate of recovery factor.Comparison of“high and low salinity water injection method”with“pure water injection method”is performed in an oil reservoir.Overall,analyzing the sensitivity on the high and low salinity according to the moderately low recovery factor of high and low salinity among the injection scenarios illustrates the low sensitivity of this parameter on a fractured carbonate reservoir.By reviewing different scenarios,it could be demonstrated that if the water injection could be applied to the reservoir from the preliminary times of production,the recovery factor rate would be increased.Thereby,higher appropriate efficiency and better supplement have resulted.Pure water injection has a high recovery factor than salty water injection.By the way,these two methods have little differences in calculating recovery methods.Besides,this parameter is significantly depended on wellhead equipment properties,safety factor and economic issues(water production).
基金Project supported by the National Natural Science Foundation of China (Nos. 50339030 and 90202001).
文摘Using a crop-water-salinity production function and a soil-water-salinity dynamic model, optimal irrigation scheduling was developed to maximize net return per irrigated area. Plot and field experiments were used to obtain the crop water sensitivity index, the salinity sensitivity index, and other parameters. Using data collected during 35 years to calculate the 10-day mean precipitation and evaporation, the variation in soil salinity concentrations and in the yields of winter wheat and cotton were simulated for 49 irrigation scheduling that were combined from 7 irrigation schemes over 3 irrigation dates and 7 salinity concentrations of saline irrigation water (fresh water and 6 levels of saline water). Comparison of predicted results with irrigation data obtained from a large area of the field showed that the model was valid and reliable. Based on the analysis of the investment cost of the irrigation that employed deep tube wells or shallow tube wells, a saline water irrigation schedule and a corresponding strategy for groundwater development and utilization were proposed. For wheat or cotton, if the salinity concentration was higher than 7.0 g L-1 in groundwater, irrigation was needed with only fresh water; if about 5.0 g L-1, irrigation was required twice with fresh water and once with saline water; and if not higher than 3.0 g L-1, irrigation could be solely with saline water.
基金funded by the National Basic Research Program of China (2009CB825101)the National Natural Science Foundation of China (30960210)
文摘In arid and semi-arid regions, freshwater scarcity and high water salinity are serious and chronic problems for crop production and sustainable agriculture development. We conducted a field experiment to evaluate the effect of irrigation water salinity and nitrogen(N) application rate on soil salinity and cotton yield under drip irrigation during the 2011 and 2012 growing seasons. The experimental design was a 3×4 factorial with three irrigation water salinity levels(0.35, 4.61 and 8.04 dS/m) and four N application rates(0, 240, 360 and 480 kg N/hm2). Results showed that soil water content increased as the salinity of the irrigation water increased, but decreased as the N application rate increased. Soil salinity increased as the salinity of the irrigation water increased. Specifically, soil salinity measured in 1:5 soil:water extracts was 218% higher in the 4.61 dS/m treatment and 347% higher in the 8.04 dS/m treatment than in the 0.35 dS/m treatment. Nitrogen fertilizer application had relatively little effect on soil salinity, increasing salinity by only 3%–9% compared with the unfertilized treatment. Cotton biomass, cotton yield and evapotranspiration(ET) decreased significantly in both years as the salinity of irrigation water increased, and increased as the N application rate increased regardless of irrigation water salinity; however, the positive effects of N application were reduced when the salinity of the irrigation water was 8.04 dS/m. Water use efficiency(WUE) was significantly higher by 11% in the 0.35 dS/m treatment than in the 8.04 dS/m treatment. There was no significant difference in WUE between the 0.35 dS/m treatment and the 4.61 dS/m treatment. The WUE was also significantly affected by the N application rate. The WUE was highest in the 480 kg N/hm2 treatment, being 31% higher than that in the 0 kg N/hm2 treatment and 12% higher than that in the 240 kg N/hm2 treatment. There was no significant difference between the 360 and 480 kg N/hm2 treatments. The N use efficiency(NUE) was significantly lower in the 8.04 dS/m treatment than in either the 4.61 dS/m or the 0.35 dS/m treatment. There was no significant difference in NUE between the latter two treatments. These results suggest that irrigation water with salinity 〈4.61 dS/m does not have an obvious negative effect on cotton production, WUE or NUE under the experimental conditions. Application of N fertilizer(0–360 kg N/hm2) could alleviate salt damage, promote cotton growth, and increase both cotton yield and water use efficiency.
基金funded by the National Natural Science Foundation of China (31360504)the Innovative Research Foundation for Excellent Young Scientists of Xinjiang Production and Construction Crops, China (2014CD002)
文摘Use of saline water in irrigated agriculture has become an important means for alleviating water scarcity in arid and semi-arid regions. The objective of this field experiment was to evaluate the effects of irrigation water salinity and N fertilization on soil physicochemical and biological properties related to nitrification and denitrification. A 3×2 factorial design was used with three levels of irrigation water salinity(0.35, 4.61 and 8.04 d S m-1) and two N rates(0 and 360 kg N ha^(-1)). The results indicated that irrigation water salinity and N fertilization had significant effects on many soil physicochemical properties including water content, salinity, p H, NH_4-N concentration, and NO_3-N concentration. The abundance(i.e., gene copy number) of ammonia-oxidizing archaea(AOA) was greater than that of ammonia-oxidizing bacteria(AOB) in all treatments. Irrigation water salinity had no significant effect on the abundance of AOA or AOB in unfertilized plots. However, saline irrigation water(i.e., the 4.61 and 8.04 d S m-1 treatments) reduced AOA abundance, AOB abundance and potential nitrification rate in N fertilized plots. Regardless of N application rate, saline irrigation water increased urease activity but reduced the activities of both nitrate reductase and nitrite reductase. Irrigation with saline irrigation water significantly reduced cotton biomass, N uptake and yield. Nitrogen application exacerbated the negative effect of saline water. These results suggest that brackish water and saline water irrigation could significantly reduce both the abundance of ammonia oxidizers and potential nitrification rates. The AOA may play a more important role than AOB in nitrification in desert soil.
基金financially supported by the National Natural Science Foundation of China(Grant Nos. 41872093, 41502096) Foundation of Qinghai Science & Technology Department (2016-ZJ-715) One-Thousand InnovativeTalent Project of Qinghai Province (Grant to QS Fan)
文摘In this study, nineteen brine samples from the Qarhan Salt Lake(QSL) in western China were collected and analyzed for boron(B) and chlorine(Cl) concentrations, total dissolved solids(TDS), pH values and stable B isotopic compositions. The B concentrations and δ^(11) B values of brines in the QSL range from 51.6 mg/L to138.4 mg/L, and from +9.32& to +13.08&, respectively. By comparison of B concentrations and TDS of brines in QSL with evaporation paths of brackish water, we found that B enrichment of brines primarily results from strong evaporation and concentration of Qarhan lake water. Combining with comparisons of B concentrations, TDS, p H values and δ^(11) B values of brines, previously elemental ratios(K/Cl, Mg/Cl, Ca/Cl, B/Cl) and δ^(11) B values of halite from a sediment core(ISL1 A), we observe good correlations between B concentrations and TDS, TDS and pH values, pH and δ^(11) B values of brines, which demonstrate that higher B concentrations and more positive δ^(11) B values of halite indicate higher salinity of the Qarhan paleolake water as well as drier paleoclimatic conditions. Based on this interpretation of the δ^(11) B values of halite in core ISL1 A, higher salinity of the Qarhan paleolake occurred during two intervals, around 46-34 ka and26-9 ka, which are almost coincident with the upper and lower halite-dominated salt layers in core ISL1 A,drier climate phases documented from the δ^(18) O record of carbonate in core ISL1 A and the paleomoisture record in monsoonal central Asia, and a higher solar insolation at 30°N. These results demonstrate that the δ^(11) B values of halite in the arid Qaidam Basin could be regarded as a new proxy for reconstructing the salinity record of paleolake water as well as paleoclimate conditions.
基金the Iran’s National Elites Foundation and the Research Grant Office at Sharif University Technology for supporting this research by way of “Dr Kazemi-Ashtiani Award” and grant “G970902”,respectively。
文摘Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms,originated from the long-term erosion by acidic rainwater.The dissolved salt poses an extra osmotic water potential being normally neglected in laboratory measurements and numerical analyses.However,ignorance of salinity may result in overestimation of stability,and the design may not be as conservative as thought.Therefore,this research aims to first experimentally examine the influence of pore water salinity on water retention curve and saturated permeability of natural dispersive loess under saline and desalinated conditions.Second,the measured parameters are used for stability analyses of a railway embankment in an area subjected to regional rainfall incident.Eventually,a numerical parametric study is carried out to explore the significance of different rainfall schemes,construction patterns,and anisotropic permeability on the factor of safety.Results reveal that desalinization suppresses the water retention capability,which in turn results in a tremendous declination of unsaturated hydraulic conductivity.Despite the natural saline embankment,rainfall can hardly infiltrate into the desalinated embankment due to the lower conductivity.Therefore,the factor of safety for natural saline conditions drops notably,while only marginal changes occur in the case of the desalinated embankment.
基金Acknowledgements: This work was supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, SEM, China, and also supported by the United States National Science Foundation. The authors thank Prof. SHEN H. H. and Prof. SHEN H. T. from Clarkson University for their unconditional support to this work.
文摘The effect of NaCl on soil strength was investigated in this project based on salinity concentrations of 0 g/L, 5 g/L, 20 g/L, and 50 g/L as well as varying water contents of 15%-20%. Laser particle size analyzer was also performed to explain possible effects. From particle size analysis and strength tests, it is hypothesized that the strength of the soil is increased with the addition of certain salinity concentrations until there are reversed effects, which is between 20 g/L and 50 g/L from our study. The increase of strength is suggested to be the affect of a greater variety of particle sizes. Since NaCI plays a role in the particle size distribution, it also plays a role in the strength of soils. The degree of the effect of the water content also differs from concentrations, and could be due to the variation of hydration film thickness on particles, which is affected by the ions introduced from water.
基金support provided by the National Natural Science Foundation of China(Grant Nos.51972048,U23A20605)support provided by the Performance subsidy fund for Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province(Grant No.22567627H)the additional data in the revised manuscriptsupported by the National Key Research and Development Program of China(No.2022YFB3706300).
文摘High-entropy materials(HEMs),which are newly manufactured compounds that contain five or more metal cations,can be a platform with desired properties,including improved electrocatalytic performance owing to the inherent complexity.Here,a strain engineering methodology is proposed to design transition-metal-based HEM by Li manipulation(LiTM)with tunable lattice strain,thus tailoring the electronic structure and boosting electrocatalytic performance.As confirmed by the experiments and calculation results,tensile strain in the LiTM after Li manipulation can optimize the d-band center and increase the electrical conductivity.Accordingly,the asprepared LiTM-25 demonstrates optimized oxygen evolution reaction and hydrogen evolution reaction activity in alkaline saline water,requiring ultralow overpotentials of 265 and 42 mV at 10 mA cm−2,respectively.More strikingly,LiTM-25 retains 94.6%activity after 80 h of a durability test when assembled as an anion-exchange membrane water electrolyzer.Finally,in order to show the general efficacy of strain engineering,we incorporate Li into electrocatalysts with higher entropies as well.
文摘The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific considerations and limitations. One way to decrease undesirable effects of sodic waters on the physical and chemical properties of soils is to apply organic and chemical amendments within the soil. This study aimed to assess the effectiveness of saline water on soil acidity, alkalinity and nutrients leaching in sandy loamy soil at Bella flower farm, in Rwamagana District, Rwanda. The water used was from the Muhazi Lake which is classified as Class I (Saline water quality). Column leaching experiments using treated soils were then conducted under saturated conditions. The soil under experimental was first analyzed for its textural classification, soil properties and is classified as sandy loamy soil. The t-test was taken at 1%, 5% and 10% levels of statistical significance compared to control soil. The results indicated that the application of saline water to soils caused an increase in some soil nutrients like increase of Phosphorus (P), Potassium (K<sup>+</sup>), Magnesium (Mg2<sup>+</sup>), Sulphur (S), CN ratio and Sodium (Na<sup>+</sup>) and decreased soil texture, physical and chemical properties and remained soil nutrients. Consequently, the intensive addition of saline water leachates to soil in PVC pipes led to decreased of soil EC through leaching and a raiser Soluble Sodium Percentage (SSP). The rate of saline water application affected the increase accumulation of SAR and Na% in the top soil layers. The study indicated that saline water is an inefficient amendment for sandy soil with saline water irrigation. The study recommends further studies with similar topic with saline water irrigation, as it accentuated the alkalinity levels.
基金National Natural Science Foundation of China(92158204,42076019)Innovation Group Project of the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(31020004)Open Project of the State Key Laboratory of Tropical Oceanography(LTOZZ2001)。
文摘The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the long-term changes in the intermediate water in the SCS have not been thoroughly studied due to limited data,particularly in relation to its thermodynamic variations.This study utilized reanalysis data products to identify a 60-year trend of freshening in the intermediate waters of the northern South China Sea(NSCS),accompanied by an expansion of low-salinity water.The study also constructed salinity budget terms,including advection and entrainment processes,and conducted an analysis of the salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of the intermediate water in the NSCS.The analysis revealed that the freshening in the northwest Pacific Ocean and the intensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes in the NSCS.Additionally,a weakened trend in the intensity of vertical entrainment also contributes to the freshening in the NSCS.This study offers new insights into the understanding of regional deep sea changes in response to variations in both thermodynamics and oceanic dynamic processes.
基金supported by the National Basic Research Program of China (2011CB403406)the National Natural Science Foundation of China (51179166)the Youth Foundation of Taiyuan University of Technology (2012L077)
文摘Field experiments were conducted in 2008 and 2009 to study the effects of deficit irrigation with saline water on spring wheat growth and yield in an arid region of Northwest China. Nine treatments included three salinity levels sl, s2 and s3 (0.65, 3.2, and 6.1 dS/m) in combination with three water levels wl, w2 and w3 (375, 300, and 225 mm). In 2008, for most treatments, deficit irrigation showed adverse effects on wheat growth; meanwhile, the effect of saline irrigation was not apparent. In 2009, growth parameters of wl treatments were not always optimal under saline irrigation. At 3.2 and 6.1 dS/m in 2008, the highest yield was obtained by wl treatments, however, in 2009, the weight of 1,000 grains and wheat yield both followed the order w2 〉 wl 〉 w3. In this study, spring wheat was sensitive to water deficit, especially at the booting to grain-filling stages, but was not significantly affected by saline irrigation and the combination of the two factors. The results demonstrated that 300-mm irrigation water with a salinity of less than 3.2 dS/m is suitable for wheat fields in the study area.
基金supported by the National Natural Science Foundation of China (91025002,30970492)the National Key Technology R & D Program (2012BAC08B05)
文摘Furrow irrigation when combined with plastic mulch on ridge is one of the current uppermost wa- ter-saving irrigation technologies for arid regions. The present paper studies the dynamics of soil water-salt trans- portation and its spatial distribution characteristics under irrigation with saline water in a maize field experiment. The mathematical relationships for soil salinity, irrigation amount and water salinity are also established to evaluate the contribution of the irrigation amount and the salinity of saline water to soil salt accumulation. The result showed that irrigation with water of high salinity could effectively increase soil water content, but the increment is limited com- paring with the influence from irrigation amount. The soil water content in furrows was higher than that in ridges at the same soil layers, with increments of 12.87% and 13.70% for MMF9 (the treatment with the highest water salinity and the largest amount of irrigation water) and MMF1 (the treatment with the lowest water salinity and the least amount of irrigation water) on 27 June, respectively. The increment for MMF9 was gradually reduced while that for MMF1 increased along with growth stages, the values for 17 August being 2.40% and 19.92%, respectively. Soil water content in the ridge for MMF9 reduced gradually from the surface layer to deeper layers while the surface soil water content for MMF1 was smaller than the contents below 20 cm at the early growing stage. Soil salinities for the treatments with the same amount of irrigation water but different water salinity increased with the water salinity. When water salinity was 6.04 dS/m, the less water resulted in more salt accumulation in topsoil and less in deep layers. When water salinity was 2.89 dS/m, however, the less water resulted in less salt accumulation in topsoil and salinity remained basically stable in deep layers. The salt accumulation in the ridge surface was much smaller than that in the furrow bottom under this technology, which was quite different from traditional furrow irrigation. The soil salinities for MMF7, MMF8 and MMF9 in the ridge surface were 0.191, 0.355 and 0.427 dS/m, respectively, whereas those in the furrow bottom were 0.316, 0.521 and 0.631 dS/m, respectively. The result of correlation analysis indicated that compared with irrigation amount, the irrigation water salinity was still the main factor influ- encing soil salinity in furrow irrigation with plastic mulch on ridge.