Application of vertically integrated sampling approach to study of new production via ^(234)Th -^(238)U disequilibria

The spatial and temporal distributions of new production vary largely in different sea areas. To understand the level of new production in the sea area studied better, an estimate of new production must be obtained in large spatial and temporal scales. The ~234Th/ ~238U disequilibrium is an effective method for the study of new production. Two sampling strategies, vertically integrated sampling ap proach based on trapezoidal integration principle and discrete layer sampling approach, were compared in the studies of the xiamen Bay and the northern South China Sea. The scavenging fluxes and removal fluxes of ~234Th and the residence times for dissolved and particulate ~234Th were calculated. The coinci dent results from two Sampling approach suggest that vertically integrated sampling approach is not only effective and reliable, but also significantly reduces the number and volume of samples. It allows us to study new production by ba ^(234)Th - ^(238)U disequilibria in large spatial scale.

Multiwavelength generation using an add-drop microring resonator integrated with an InGaAsP/InP sampled grating distributed feedback

A system of an add-drop microring resonator integrated with a sampled grating distributed feedback （SG-DFB） is investigated via modeling and simulation with the time-domain traveling wave （TDTW） method. The proposed microring resonator comprises a SiO2 waveguide integrated with an InGaAsP/InP SG-DFB, and the SiO2 waveguide consists of a silicon core having a refractive index of 3.48 and Kerr co- efficient of 4.5 × 10^-18 m2/W. The SG-DFB consists of a series of grating bursts that are constructed using a periodic apodization function with a burst spacing in the grating of 45 μm, a burst length of 5 μm, and I0 bursts across the total length of the SG-DBR. Transmission results of the through and drop port of the microring resonator show the significant capacity enhancement of the generated center wavelengths. The Q-factor of the microring resonator system, defined as the center wavelength （λ0） divided by 3 dB FWHM, without and with integration with the SG-DFB is calculated as 1.93 × 10^5 and 2.87 × 10^5, respectively. Analysis of the dispersion of the system reveals that increasing the wavelength results in a decrease of the dispersion. The higher capacity and efficiency are the advantages of integrating the microring resonator and the InGaAsP/InP SG-DFB.

Unfolded Frequency Response and Model of a Multi-Tap Direct Sampling Mixer

A transform method was used to model a discrete time multi-tap direct sampling mixer. The method transforms the mixed filtering and down-sampling stages to separate cascade filtering and sampling stages to determine the unfolded frequency response which shows the anti-aliasing ability of the mixer. The trans-formation can also be applied to other mixed signal and multi-rate receiver systems to analyze their unfolded frequency responses. The transformed system architecture was used to calculate the unfolded frequency response of the multi-tap direct sampling mixer and compared with the mixer model without noise in the advanced design system 2005A environment to further evaluate the frequency response. The simulations show that the -3 dB bandwidth is 3.0 MHz and the voltage gain is attenuated by 1.5 dB within a 1-MHz baseband bandwidth.

Enhanced Sampling Simulations on Transition-Metal-Catalyzed Organic Reactions:Zirconocene-Catalyzed Propylene Polymerization and Sharpless Epoxidation

The bond breaking and forming in chemical reactions is a typical rare event,which is one of the difficult problems in molecular dynamics simulations.Numerous enhanced sampling methods have been developed to extend the time scale covered by molecular simulations.However,the difficulties of obtaining appropriate collective variables from complicated reaction pathways and a controlled sampling over the desired phase space remain as challenges.Herein,we use MetaITS,which combines metadynamics and integrated tempered sampling,to increase the sampling efficiency for chemical reactions.Metadynamics with collective variables obtained by harmonic linear discriminant analysis can efficiently decrease the main energy barrier of chemical reaction.Meanwhile,integrated tempered sampling can enhance the exploration of other degrees of freedom.In this study,we applied the MetaITS method to two transition-metal-catalyzed organic reactions with complicated reaction coordinates.We simulated here a zirconocene-catalyzed propylene polymerization to investigate the regioselectivity and temperature effects.We also studied a Sharpless epoxidation reaction,for which both chiral products are observed through simulation.