The pyrolysis behaviors of Qingdao vacuum residue(QD-VR)and its SARA(saturates,aromatics,reins,and asphaltenes)fractions were evaluated by thermo-gravimetric with mass spectrometer(TG-MS).The pyrolysis kinetics were d...The pyrolysis behaviors of Qingdao vacuum residue(QD-VR)and its SARA(saturates,aromatics,reins,and asphaltenes)fractions were evaluated by thermo-gravimetric with mass spectrometer(TG-MS).The pyrolysis kinetics were determined by Friedman,one-parallel and four-parallel distributed activation energy model(DAEM),respectively.The results indicated that the pyrolysis behavior of QD-VR was similar to that of aromatics.For saturates,the release of H_(2),CH_(4),CO,and CO_(2) occurred in 80-400℃,while the temperature range for QD-VR and other fractions is 200-800℃.The average activation energy(Ea)via Friedman method was 179.72 kJ/mol and increased with the conversion ratio.One-parallel Gaussian DAEM was more suitable to describe the pyrolysis process of the single SARA fractions,while four-parallel Gaussian DAEM was more suitable to describe the pyrolysis process of heavy oil.Furthermore,comparing the weighted E_(a) from one-parallel(227.64 kJ/mol)and four-parallel Gaussian DAEM(204.63 kJ/mol),the results suggested that during pyrolysis process of heavy oil,there was an interaction between the SARA fractions,which could reduce the E_(a) of heavy oil pyrolysis.Specifically,during heavy oil pyrolysis,resins and asphaltenes could increase the E_(a) of saturates and aromatics,while saturates and aromatics could decrease the E_(a) of resins and asphaltenes.展开更多
Sara Kreek工作区位于苏里南中部,在全球构造上属太古-元古界的圭亚那地盾。圭亚那地盾上分布着大小几十个矿床(点),如圭亚那奥迈(Omai)大型金矿床,结合最新的勘查成果,对矿区地质、矿床地质特征进行了分析,总结了矿区地质特征、矿体特...Sara Kreek工作区位于苏里南中部,在全球构造上属太古-元古界的圭亚那地盾。圭亚那地盾上分布着大小几十个矿床(点),如圭亚那奥迈(Omai)大型金矿床,结合最新的勘查成果,对矿区地质、矿床地质特征进行了分析,总结了矿区地质特征、矿体特征、矿石特征及围岩蚀变特征,对本区的矿床成因及前景进行了讨论,本区成矿明显受地层、构造等因素的影响,本区绿岩带的原岩为中基性火山岩系,是矿体的成矿母岩,经剪切作用形成金矿体。蚀变以硅化、黄铁矿化蚀变最强,分布最广,与成矿关系最密切。韧性剪切带则是金矿体的控矿构造。研究认为,本矿区矿床成因类型为变质-沉积绿岩型金矿,Sara Kreek矿区找矿前景较好。展开更多
基金the financial support of the National Natural Science Foundation(22278423,U1862107)Science Foundation of China University of Petroleum,Beijing(2462021QNXZ007).
文摘The pyrolysis behaviors of Qingdao vacuum residue(QD-VR)and its SARA(saturates,aromatics,reins,and asphaltenes)fractions were evaluated by thermo-gravimetric with mass spectrometer(TG-MS).The pyrolysis kinetics were determined by Friedman,one-parallel and four-parallel distributed activation energy model(DAEM),respectively.The results indicated that the pyrolysis behavior of QD-VR was similar to that of aromatics.For saturates,the release of H_(2),CH_(4),CO,and CO_(2) occurred in 80-400℃,while the temperature range for QD-VR and other fractions is 200-800℃.The average activation energy(Ea)via Friedman method was 179.72 kJ/mol and increased with the conversion ratio.One-parallel Gaussian DAEM was more suitable to describe the pyrolysis process of the single SARA fractions,while four-parallel Gaussian DAEM was more suitable to describe the pyrolysis process of heavy oil.Furthermore,comparing the weighted E_(a) from one-parallel(227.64 kJ/mol)and four-parallel Gaussian DAEM(204.63 kJ/mol),the results suggested that during pyrolysis process of heavy oil,there was an interaction between the SARA fractions,which could reduce the E_(a) of heavy oil pyrolysis.Specifically,during heavy oil pyrolysis,resins and asphaltenes could increase the E_(a) of saturates and aromatics,while saturates and aromatics could decrease the E_(a) of resins and asphaltenes.
