Inorganic scale deposits are a major water-related problem encountered in producing oil and gas wells. The harshness of scale deposits is dependent on the field operating conditions. Scale deposits can vary from mild ...Inorganic scale deposits are a major water-related problem encountered in producing oil and gas wells. The harshness of scale deposits is dependent on the field operating conditions. Scale deposits can vary from mild scaling tendencies to extreme. In general, the scale deposit will cause a reduction in formation pores, declining productivity and eventually blockage of the wellbore and hence unexpected downtime if it is allowed to persevere. To overcome this, the productivity of an oil and gas well is ensured by handling scale deposits via removal or prevention methods. Scale prevention is the best and cost-e ective method for handling scale deposits that ensures production continuity. Inhibition through 'threshold' scale inhibitor treatment is the most common method that is proven to prevent or reduce likely deposits. This paper examines the art of synthetic scale inhibitors, in particular, threshold scale inhibitors in oil and gas production. It discusses the chemistry of those inhibitors, inhibition mechanisms, treatment methods and key properties for their applications. It also highlights the chemistry of the synthetic routes often used to produce them in the laboratory and/or industry. Finally, it highlights the environmental concerns for the applicability of threshold scale inhibitors.展开更多
Hydrocarbon source rock obviously controls the formation and distribution of hydrocarbon reservoirs. Based on the geological concept of "source control theory", the concept of a hydrocarbon distribution threshold wa...Hydrocarbon source rock obviously controls the formation and distribution of hydrocarbon reservoirs. Based on the geological concept of "source control theory", the concept of a hydrocarbon distribution threshold was put forward. This means the maximum range for hydrocarbon controlled by the source rock conditions to migrate in the hydrocarbon basins. Three quantitative analysis models are proposed on this basis, namely the hydrocarbon accumulation probability, maximum hydrocarbon scale threshold and reserve distribution probability, which respectively refer to the probability of forming a hydrocarbon reservoir, the possible maximum scale of the hydrocarbon reservoir and the percentage of reserve distribution in a certain area within the hydrocarbon distribution threshold. Statistical analysis on 539 hydrocarbon reservoirs discovered in 28 hydrocarbon source kitchens from seven sedimentary basins and sags of eastern China shows the maximum reservoir scale possibly formed in the hydrocarbon basin, hydrocarbon accumulation probability and oil and gas reserve distribution probability are all controlled by the characteristics of the hydrocarbon source rock. Generally, as the distances from the hydrocarbon source rock center and hydrocarbon discharge boundary get longer and the hydrocarbon discharge intensity of hydrocarbon source rock center gets smaller, there will be lower probability of hydrocarbon accumulation. Corresponding quantitative models are established based on single factor statistics and multivariate analysis. Practical application in the Jiyang Depression shows that the prediction from the quantitative analysis model for the hydrocarbon distribution threshold agree well with the actual exploration results, indicating that the quantitative analysis model is likely to be a feasible tool.展开更多
文摘Inorganic scale deposits are a major water-related problem encountered in producing oil and gas wells. The harshness of scale deposits is dependent on the field operating conditions. Scale deposits can vary from mild scaling tendencies to extreme. In general, the scale deposit will cause a reduction in formation pores, declining productivity and eventually blockage of the wellbore and hence unexpected downtime if it is allowed to persevere. To overcome this, the productivity of an oil and gas well is ensured by handling scale deposits via removal or prevention methods. Scale prevention is the best and cost-e ective method for handling scale deposits that ensures production continuity. Inhibition through 'threshold' scale inhibitor treatment is the most common method that is proven to prevent or reduce likely deposits. This paper examines the art of synthetic scale inhibitors, in particular, threshold scale inhibitors in oil and gas production. It discusses the chemistry of those inhibitors, inhibition mechanisms, treatment methods and key properties for their applications. It also highlights the chemistry of the synthetic routes often used to produce them in the laboratory and/or industry. Finally, it highlights the environmental concerns for the applicability of threshold scale inhibitors.
基金supported by the National Natural Science Foundation Project(Grant No.41102085)the National Key Basic Research and Development 973 Program Project(Grant No.2011CB201105)+1 种基金Supported by Research Fund for the Doctoral Program of Higher Education of China(20110007120001)Supported by Science Foundation of China University of Petroleum, Beijing(No.KYJJ2012-01-08)
文摘Hydrocarbon source rock obviously controls the formation and distribution of hydrocarbon reservoirs. Based on the geological concept of "source control theory", the concept of a hydrocarbon distribution threshold was put forward. This means the maximum range for hydrocarbon controlled by the source rock conditions to migrate in the hydrocarbon basins. Three quantitative analysis models are proposed on this basis, namely the hydrocarbon accumulation probability, maximum hydrocarbon scale threshold and reserve distribution probability, which respectively refer to the probability of forming a hydrocarbon reservoir, the possible maximum scale of the hydrocarbon reservoir and the percentage of reserve distribution in a certain area within the hydrocarbon distribution threshold. Statistical analysis on 539 hydrocarbon reservoirs discovered in 28 hydrocarbon source kitchens from seven sedimentary basins and sags of eastern China shows the maximum reservoir scale possibly formed in the hydrocarbon basin, hydrocarbon accumulation probability and oil and gas reserve distribution probability are all controlled by the characteristics of the hydrocarbon source rock. Generally, as the distances from the hydrocarbon source rock center and hydrocarbon discharge boundary get longer and the hydrocarbon discharge intensity of hydrocarbon source rock center gets smaller, there will be lower probability of hydrocarbon accumulation. Corresponding quantitative models are established based on single factor statistics and multivariate analysis. Practical application in the Jiyang Depression shows that the prediction from the quantitative analysis model for the hydrocarbon distribution threshold agree well with the actual exploration results, indicating that the quantitative analysis model is likely to be a feasible tool.