Density, ρ, ultrasonic speed, u, and viscosity, η, of binary mixtures of 2-methyl-2-propanol (2M2P) with acetonitrile (AN), propionitrile (PN) and butyronitrile (BN) including those of pure liquids are measured over...Density, ρ, ultrasonic speed, u, and viscosity, η, of binary mixtures of 2-methyl-2-propanol (2M2P) with acetonitrile (AN), propionitrile (PN) and butyronitrile (BN) including those of pure liquids are measured over the entire composition range at temperatures 298.15, 303.15 and 308.15 K. From these experimental data, the excess available volume, E a V , excess free volume, E f V , excess isothermal compressibility, E T β , excess thermal expansion coefficient, E α , and excess internal pressure, E i π , are calculated. The variation of these properties with composition and temperature are discussed in terms of molecular interactions between unlike molecules of the mixtures. It is found that the values of E a V , E f V , E T β and E α are positive and those of E i π are negative for all the mixtures at each temperature studied, indicating the presence of weak interactions between 2M2P and AN/PN/BN molecules. The variations of E a V , E f V , E T β , E α and E i π values with composition indicate that the interactions in these mixtures follow the order: AN<PN<BN, i.e., the 2M2P-nitrile interaction decreases with the increase of alkyl chain length in these nitrile molecules. In addition, the theoretical ultrasonic velocity is calculated using the scaled particle theory and compared with the experimental values.展开更多
为解决沙棘叶茶茶毫离散元仿真中缺乏准确接触参数的问题,利用物理和仿真休止角堆积试验标定茶毫接触参数;将茶毫颗粒简化为软质球形颗粒,通过量纲分析和颗粒缩放理论将茶毫空气动力学当量粒径从231.37μm放大至1.8 mm。利用EDEM软件,...为解决沙棘叶茶茶毫离散元仿真中缺乏准确接触参数的问题,利用物理和仿真休止角堆积试验标定茶毫接触参数;将茶毫颗粒简化为软质球形颗粒,通过量纲分析和颗粒缩放理论将茶毫空气动力学当量粒径从231.37μm放大至1.8 mm。利用EDEM软件,选定“Hertz–Mindlin with JKR”接触模型,以休止角为响应值,通过Plackett-Burman试验筛选出对休止角影响最显著的3个参数:茶毫-茶毫恢复系数、茶毫-茶毫滚动摩擦系数、茶毫-不锈钢滚动摩擦系数;利用最陡爬坡试验,确定各参数最佳取值范围;根据Box-Behnken试验建立并优化3个显著性参数与休止角的二阶回归方程,对回归方程进行寻优求解。得到3个显著性参数的最优组合:茶毫-茶毫恢复系数为0.159,茶毫-茶毫滚动摩擦系数为0.290,茶毫-不锈钢滚动摩擦系数为0.239。通过对比休止角仿真试验值与物理试验值,二者相对误差为1.97%,表明仿真试验预测效果良好。展开更多
More than half a century after its first formulation by Reiss, Frisch and Lebowitz in 1959, scaled particle theory(SPT) has proven its immense usefulness and has become one of the most successful theories in liquid ph...More than half a century after its first formulation by Reiss, Frisch and Lebowitz in 1959, scaled particle theory(SPT) has proven its immense usefulness and has become one of the most successful theories in liquid physics. In recent years, we have strived to extend SPT to fluids confined in a variety of random porous matrices. In this article, we present a timely review of these developments. We have endeavored to present a formulation that is pedagogically more accessible than those presented in various original papers, and we hope this benefits newcomers in their research work. We also use more consistent notations for different cases. In addition, we discuss issues that have been scarcely considered in the literature, e.g., the one-fluid structure of SPT due to the isomorphism between the equation of state for a multicomponent fluid and that for a one-component fluid or the pure-confinement scaling relation that provides a connection between a confined and a bulk fluid.展开更多
文摘Density, ρ, ultrasonic speed, u, and viscosity, η, of binary mixtures of 2-methyl-2-propanol (2M2P) with acetonitrile (AN), propionitrile (PN) and butyronitrile (BN) including those of pure liquids are measured over the entire composition range at temperatures 298.15, 303.15 and 308.15 K. From these experimental data, the excess available volume, E a V , excess free volume, E f V , excess isothermal compressibility, E T β , excess thermal expansion coefficient, E α , and excess internal pressure, E i π , are calculated. The variation of these properties with composition and temperature are discussed in terms of molecular interactions between unlike molecules of the mixtures. It is found that the values of E a V , E f V , E T β and E α are positive and those of E i π are negative for all the mixtures at each temperature studied, indicating the presence of weak interactions between 2M2P and AN/PN/BN molecules. The variations of E a V , E f V , E T β , E α and E i π values with composition indicate that the interactions in these mixtures follow the order: AN<PN<BN, i.e., the 2M2P-nitrile interaction decreases with the increase of alkyl chain length in these nitrile molecules. In addition, the theoretical ultrasonic velocity is calculated using the scaled particle theory and compared with the experimental values.
文摘为解决沙棘叶茶茶毫离散元仿真中缺乏准确接触参数的问题,利用物理和仿真休止角堆积试验标定茶毫接触参数;将茶毫颗粒简化为软质球形颗粒,通过量纲分析和颗粒缩放理论将茶毫空气动力学当量粒径从231.37μm放大至1.8 mm。利用EDEM软件,选定“Hertz–Mindlin with JKR”接触模型,以休止角为响应值,通过Plackett-Burman试验筛选出对休止角影响最显著的3个参数:茶毫-茶毫恢复系数、茶毫-茶毫滚动摩擦系数、茶毫-不锈钢滚动摩擦系数;利用最陡爬坡试验,确定各参数最佳取值范围;根据Box-Behnken试验建立并优化3个显著性参数与休止角的二阶回归方程,对回归方程进行寻优求解。得到3个显著性参数的最优组合:茶毫-茶毫恢复系数为0.159,茶毫-茶毫滚动摩擦系数为0.290,茶毫-不锈钢滚动摩擦系数为0.239。通过对比休止角仿真试验值与物理试验值,二者相对误差为1.97%,表明仿真试验预测效果良好。
文摘More than half a century after its first formulation by Reiss, Frisch and Lebowitz in 1959, scaled particle theory(SPT) has proven its immense usefulness and has become one of the most successful theories in liquid physics. In recent years, we have strived to extend SPT to fluids confined in a variety of random porous matrices. In this article, we present a timely review of these developments. We have endeavored to present a formulation that is pedagogically more accessible than those presented in various original papers, and we hope this benefits newcomers in their research work. We also use more consistent notations for different cases. In addition, we discuss issues that have been scarcely considered in the literature, e.g., the one-fluid structure of SPT due to the isomorphism between the equation of state for a multicomponent fluid and that for a one-component fluid or the pure-confinement scaling relation that provides a connection between a confined and a bulk fluid.
