Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expec...Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.展开更多
Using stat ic chamber technique, fluxes of CO 2 , CH 4 and N 2 O were measured in the alpine grassland area from July 2000 to July 2001, d eterminations of mean fluxes showed that CO 2 and N 2 O were gene rally releas...Using stat ic chamber technique, fluxes of CO 2 , CH 4 and N 2 O were measured in the alpine grassland area from July 2000 to July 2001, d eterminations of mean fluxes showed that CO 2 and N 2 O were gene rally released from the soil, while the alpine grassland accounted for a weak CH 4 sink. Fluxes of CO 2 , CH 4 and N 2 O ranged widely. The highest CO 2 emission occurred in August, whereas a lmost 90% of the whole year emission occurred in the growing season. But the variations of CH 4 and N 2 O fluxes did not show any clear patterns over the one-year-experim ent. During a daily variation, the maximum CO 2 emission occurred at 16:00, and then decreased to the minimum emi ssion in the early morning. Daily pattern analyses indicated that the variation in CO 2 fluxes was positively related to air temperatures (R 2 =0.73) and soil temperatures at a depth of 5 cm (R 2 =0.86), whereas daily variations in CH 4 and N 2 O fluxes were poorly explained by soil temperatures and climatic va riables. CO 2 emissions in this area were much lower than other grasslands in plain areas .展开更多
The 3rd Chinese National Arctic Research Expedition （CHINARE-Arctic III） was carried out from July to September in 2008. The partial pressure of CO2 （pCO2） in the atmosphere and in surface seawater were determined...The 3rd Chinese National Arctic Research Expedition （CHINARE-Arctic III） was carried out from July to September in 2008. The partial pressure of CO2 （pCO2） in the atmosphere and in surface seawater were determined in the Bering Sea during luly 11-27, 2008, and a large number of seawater samples were taken for total alkalinity （TA） and total dissolved inorganic carbon （DIC） analysis. The distributions of CO2 parameters in the Bering Sea and their controlling factors were discussed. The pCO2 values in surface seawater presented a drastic variation from 148 to 563 laatm （1 μatm = 1.013 25× 10-1Pa）. The lowest pCOz values were observed near the Bering Sea shelf break while the highest pCO2 existed at the western Bering Strait. The Bering Sea generally acts as a net sink for atmospheric CO2 in summer. The air-sea CO2 fluxes in the Bering Sea shelf, slope, and basin were estimated at -9.4, -16.3, and -5.1 mmol/（m2.d）, respectively. The annual uptake of CO2 was about 34 Tg C in the Bering Sea.展开更多
To accurately evaluate the carbon sequestration potential and better elucidate the relationship between the carbon cycle and regional climate change, using eddy covariance system, we conducted a long-term measurement ...To accurately evaluate the carbon sequestration potential and better elucidate the relationship between the carbon cycle and regional climate change, using eddy covariance system, we conducted a long-term measurement of CO 2 fluxes in the rain-fed winter wheat field of the Chinese Loess Plateau. The results showed that the annual net ecosystem CO 2 exchange （NEE） was （-71.6±5.7） and （-65.3±5.3） g C m-2 y-1 for 2008-2009 and 2009-2010 crop years, respectively, suggesting that the agro-ecosystem was a carbon sink （117.4-126.2 g C m-2 yr-1）. However, after considering the harvested grain, the agro- ecosystem turned into a moderate carbon source. The variations in NEE and ecosystem respiration （R eco ） were sensitive to changes in soil water content （SWC）. When SWC ranged form 0.15 to 0.21 m3 m-3, we found a highly significant relationship between NEE and photosynthetically active radiation （PAR）, and a highly significant relationship between R eco and soil temperature （T s ）. However, the highly significant relationships were not observed when SWC was outside the range of 0.15-0.21 m3 m-3. Further, in spring, the R eco instantly responded to a rapid increase in SWC after effective rainfall events, which could induce 2 to 4-fold increase in daily R eco , whereas the R eco was also inhibited by heavy summer rainfall when soils were saturated. Accumulated R eco in summer fallow period decreased carbon fixed in growing season by 16- 25%, indicating that the period imposed negative impacts on annual carbon sequestration.展开更多
As an important component of ecosystem carbon（C） budgets, soil carbon dioxide（CO2） flux is determined by a combination of a series of biotic and abiotic processes. Although there is evidence showing that the abiot...As an important component of ecosystem carbon（C） budgets, soil carbon dioxide（CO2） flux is determined by a combination of a series of biotic and abiotic processes. Although there is evidence showing that the abiotic component can be important in total soil CO2 flux（R（total））, its relative importance has never been systematically assessed. In this study, after comparative measurements of CO2 fluxes on sterilized and natural soils, the R（total） was partitioned into biotic flux（R（biotic）） and abiotic flux（R（abiotic）） across a broad range of land-cover types（including eight sampling sites： cotton field, hops field, halophyte garden, alkaline land, reservoir edge, native saline desert, dune crest and interdune lowland） in Gurbantunggut Desert, Xinjiang, China. The relative contribution of R（abiotic） to R（total）, as well as the temperature dependency and predominant factors for R（total）, R（biotic） and R（abiotic）, were analyzed. Results showed that R（abiotic） always contributed to R（total） for all of the eight sampling sites, but the degree or magnitude of contribution varied greatly. Specifically, the ratio of R（abiotic） to R（total） was very low in cotton field and hops field and very high in alkaline land and dune crest. Statistically, the ratio of R（abiotic） to R（total） logarithmically increased with decreasing R（biotic）, suggesting that R（abiotic） strongly affected R（total） when R（biotic） was low. This pattern confirms that soil CO2 flux is predominated by biotic processes in most soils, but abiotic processes can also be dominant when biotic processes are weak. On a diurnal basis, R（abiotic） cannot result in net gain or net loss of CO2, but its effect on transient CO2 flux was significant. Temperature dependency of R（total） varied among the eight sampling sites and was determined by the predominant processes（abiotic or biotic） of CO2 flux. Specifically, R（biotic） was driven by soil temperature while R（abiotic） was regulated by the change in soil temperature（ΔT）. Namely, declining temperature（ΔT0） resulted in positive R（abiotic）（i.e., CO2 released from soil）. Without recognition of R（abiotic）, R（biotic） would be overestimated for the daytime and underestimated for the nighttime. Although R（abiotic） may not change the sum or the net value of daily soil CO2 exchange and may not directly constitute a C sink, it can significantly alter the transient apparent soil CO2 flux, either in magnitude or in temperature dependency. Thus, recognizing the fact that abiotic component in R（total） exists widely in soils has widespread consequences for the understanding of C cycling.展开更多
Soil CO 2 emission from an arable soil was measured by closed chamber method to quantify year round soil flux and to develop an equation to predict flux using soil temperature, dissolved organic carbon(DOC) and soil...Soil CO 2 emission from an arable soil was measured by closed chamber method to quantify year round soil flux and to develop an equation to predict flux using soil temperature, dissolved organic carbon(DOC) and soil moisture content. Soil CO 2 flux, soil temperature, DOC and soil moisture content were determined on selected days during the experiment from August 1999 to July 2000, at the Ecological Station of Red Soil, the Chinese Academy of Sciences, in a subtropical region of China. Soil CO 2 fluxes were generally higher in summer and autumn than in winter and spring, and had a seasonal pattern more similar to soil temperature and DOC than soil moisture. The estimation was 2 23 kgCO 2/(m 2·a) for average annual soil CO 2 flux. Regressed separately, the reasons for soil flux variability were 86 6% from soil temperature, 58 8% from DOC, and 26 3% from soil moisture, respectively. Regressed jointly, a multiple equation was developed by the above three variables that explained approximately 85 2% of the flux variance, however by stepwise regression, soil temperature was the dominant affecting soil flux. Based on the exponential equation developed from soil temperature, the predicted annual flux was 2 49 kgCO 2/(m 2·a), and essentially equal to the measured one. It is suggested the exponential relationship between soil flux and soil temperature could be used for accurately predicting soil CO 2 flux from arable soil in subtropical regions of China.展开更多
The Integrated Environmental Monitoring (IEM) project, part of the Asia-Pacific Environmental Innovation Strategy (APEIS) project, developed an integrated environmental monitoring system that can be used to detect, mo...The Integrated Environmental Monitoring (IEM) project, part of the Asia-Pacific Environmental Innovation Strategy (APEIS) project, developed an integrated environmental monitoring system that can be used to detect, monitor, and assess environmental disasters, degradation, and their impacts in the Asia-Pacific region. The system primarily employs data from the moderate resolution imaging spectrometer (MODIS) sensor on the Earth Observation System-(EOS-) Terra/Aqua satellite, as well as those from ground observations at five sites in different ecological systems in China. From the preliminary data analysis on both annual and daily variations of water, heat and CO2 fluxes, we can confirm that this system basically has been working well. The results show that both latent flux and CO2 flux are much greater in the crop field than those in the grassland and the saline desert, whereas the sensible heat flux shows the opposite trend. Different data products from MODIS have very different correspondence, e.g. MODIS-derived land surface temperature has a close correlation with measured ones, but LAI and NPP are quite different from ground measurements, which suggests that the algorithms used to process MODIS data need to be revised by using the local dataset. We are now using the APEIS-FLUX data to develop an integrated model, which can simulate the regional water, heat, and carbon fluxes. Finally, we are expected to use this model to develop more precise high-order MODIS products in Asia-Pacific region.展开更多
The turbidity maximum zone(TMZ) is one of the most important regions in an estuary.However,the high concentration of suspended material makes it difficult to measure the partial pressure of CO_2(pCO_2) in these region...The turbidity maximum zone(TMZ) is one of the most important regions in an estuary.However,the high concentration of suspended material makes it difficult to measure the partial pressure of CO_2(pCO_2) in these regions.Therefore,very little data is available on the pCO_2 levels in TMZs.To relatively accurately evaluate the CO_2 flux in an example estuary,we studied the TMZ and surrounding area in the Changjiang(Yangtze) River estuary.From seasonal cruises during February,August,November 2010,and May 2012,the pCO_2 in the TMZ and surrounding area was calculated from pH and total alkalinity(TA)measured in situ,from which the CO_2 flux was calculated.Overall,the TMZ and surrounding area acted as a source of atmosphere CO_2 in February and November,and as a sink in May and August.The average FCO_2was-9,-16,5,and 5 mmol/(m^2·d) in May,August,November,and February,respectively.The TMZ's role as a source or sink of atmosphere CO_2 was quite different to the outer estuary.In the TMZ and surrounding area,suspended matter,phytoplankton,and pH were the main factors controlling the FCO_2,but here the influence of temperature,salinity,and total alkalinity on the FCO_2 was weak.Organic carbon decomposition in suspended matter was the main reason for the region acting as a CO_2 source in winter,and phytoplankton production was the main reason the region was a CO_2 sink in summer.展开更多
A multilayer study of pCO2 for the Yellow and South China Seas in the surface waters was conducted based on data from four cruises sponsored by the China SOLAS Project in 2005 and 2006,including data for the surface m...A multilayer study of pCO2 for the Yellow and South China Seas in the surface waters was conducted based on data from four cruises sponsored by the China SOLAS Project in 2005 and 2006,including data for the surface microlayer(SML) ,subsurface layer(SSL) and surface layer(SL) . The carbon fluxes across the air-sea interface were calculated. The results showed that the pCO2 values in the surface waters of the study area decreased in the following order:pCO2 SML> pCO2 SSL> pCO2 SL. The highest values were found in March for all SML,SSL and SL,followed by those in April,and the lowest were in May. The pCO2 values had a significant positive correlation with temperature or salinity. While there was no relationship between pCO2 and longitude,there was a significant negative correlation between it and latitude,i.e.,'high latitude low pCO2'. By using four calculation models,the carbon dioxide fluxes(FC O2) in spring in the Yellow and South China Seas,which were found to act as a 'sink' of atmospheric CO2,were preliminarily estimated on the basis of the pCO2 data in the SML to be -7.00×106 t C and -22.35×106 t C,respectively. It is suggested that the FC O2calculated on the basis of pCO2 data in the SML is more reliable than that calculated on the basis of those in the SL.展开更多
Mold flux serves the crucial metallurgical function of absorbing inclusions, directly impacting the smoothness of the casting process as well as the cast slab quality. In this study, the dissolution behavior and mecha...Mold flux serves the crucial metallurgical function of absorbing inclusions, directly impacting the smoothness of the casting process as well as the cast slab quality. In this study, the dissolution behavior and mechanism of Ti O_(2)and Ti N inclusions in molten Ca O–Si O_(2)–B_(2)O_(3)-based fluorine-free mold flux were explored by in situ single hot thermocouple technology combined with X-ray photoelectron spectroscopy.The results showed that Ti O_(2) inclusions are effectively dissolved by the molten slag within 76 s, during which the original octahedral [Ti O_(6)]^(8-)structures are destroyed and convert to the networker tetrahedral [Ti O_(4)]^(4-)structures. However, the dissolution rate is much lower for Ti N inclusions than for Ti O_(2)inclusions. This can be attributed to the fact that the Ti N particles need to be oxidized and then dissolved in the molten slag to form tetrahedral [Ti O4]4-and octahedral [Ti O_(6)]^(8-)structures during the Ti N inclusion dissolution process, which is accompanied by the generation of a large amount of N_(2)gas. Moreover, Ca Ti O_(3)crystals tend to nucleate and grow on bubble surfaces with sufficient octahedral [Ti O_(6)]^(8-)structures and Ca^(2+)ions, eventually resulting in the molten slag being in a solid–liquid mixed state.展开更多
The CO_2 released from respiring cells in woody tissues of trees can contribute to one of three fluxes:efflux to the atmosphere(E_A),internal xylem sap transport flux(F_T),and storage flux(DS).Adding those fluxes toge...The CO_2 released from respiring cells in woody tissues of trees can contribute to one of three fluxes:efflux to the atmosphere(E_A),internal xylem sap transport flux(F_T),and storage flux(DS).Adding those fluxes together provides an estimate of actual stem respiration(R_S).We know that the relative proportion of CO_2 in those fluxes varies greatly among tree species,but we do not yet have a clear understanding of the causes for this variation.One possible explanation is that species differ in stem radial CO_2 conductance(g_c).A high g_c would favor the E_A pathway and a low g_cwould favor the F_Tpathway.However,g_chas only been measured once in situ and only in a single tree species.We measured g_cusing two methods in stems of Fraxinus mandshurica Rupr.(ash)and Betula platyphylla Suk.(birch)trees in situ,along with R_S,E_A,F_T and DS.Stem radial CO_2 conductance was substantially greater in ash trees than in birch trees.Corresponding to that finding,in ash trees over 24 h,E_Aconstituted the entire flux of respired CO_2 ,and F_Twas negative,indicating that additional CO_2 ,probably transported from the root system via the xylem,was also diffusing into the atmosphere.In ash trees,F_T was negative over the entire 24 h,and this study represents the first time that has been reported.The addition of xylem-transported CO_2 to E_A caused E_Ato be 9% higher than the actual R_Sover the diel measurement period.Birch trees,which had lower g_c,also had a more commonly seen pattern,with E_A accounting for about 80% of the CO_2 released from local cell respiration and F_T accounting for the remainder.The inorganic carbon concentration in xylem sap was also lower in ash trees than in birch trees:2.7 versus 5.3 mmol L^(-1),respectively.Our results indicate that stem CO_2 conductance could be a very useful measurement to help explain differences among species in the proportion of respired CO_2 that remains in the xylem or diffuses into the atmosphere.展开更多
A comparison between simulated land surface fluxes and observed eddy covariance （EC） measurements was conducted to validate Integrated Biosphere Simulator （IBIS） at Tongyu field observation station （44°25＇N...A comparison between simulated land surface fluxes and observed eddy covariance （EC） measurements was conducted to validate Integrated Biosphere Simulator （IBIS） at Tongyu field observation station （44°25＇N, 122°52＇E） in Jilin Province, China. Results showed that the IBIS model could reproduce net ecosystem CO2 exchange （NEE）, sensible and latent heat fluxes reasonably, as indicated by correlation coefficients exceeding the significant level of 0.05. It was also evident that the NEE and sensible heat fluxes were characterized by diurnal and seasonal variation both in the grassland and the cropland ecosystems, while the latent heat fluxes correlated with evapotranspiration, only took on the diurnal variation during the growing season. Moreover, both sensible heat fluxes and the latent heat fluxes were larger in the cropland ecosystem than that in the degraded grassland ecosystem. This different characteristic was possibly correlated with vegetation growing situation in the two kinds of ecosystems. A close agreement between observation and simulation on NEE, sensible heat fluxes and latent heat flux was obtained both in the degraded grassland and the cropland ecosystems. In addition, the annual NEE in the model was overestimated by 23.21% at the grassland and 27.43% at the cropland, sensible heat flux with corresponding 9.90% and 11.98%, respectively, and the annual latent heat flux was underestimated by 4.63% and 3.48%, respectively.展开更多
文摘Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.
基金National Key Project for Basic Research,No.G1998040800
文摘Using stat ic chamber technique, fluxes of CO 2 , CH 4 and N 2 O were measured in the alpine grassland area from July 2000 to July 2001, d eterminations of mean fluxes showed that CO 2 and N 2 O were gene rally released from the soil, while the alpine grassland accounted for a weak CH 4 sink. Fluxes of CO 2 , CH 4 and N 2 O ranged widely. The highest CO 2 emission occurred in August, whereas a lmost 90% of the whole year emission occurred in the growing season. But the variations of CH 4 and N 2 O fluxes did not show any clear patterns over the one-year-experim ent. During a daily variation, the maximum CO 2 emission occurred at 16:00, and then decreased to the minimum emi ssion in the early morning. Daily pattern analyses indicated that the variation in CO 2 fluxes was positively related to air temperatures (R 2 =0.73) and soil temperatures at a depth of 5 cm (R 2 =0.86), whereas daily variations in CH 4 and N 2 O fluxes were poorly explained by soil temperatures and climatic va riables. CO 2 emissions in this area were much lower than other grasslands in plain areas .
基金The National Natural Science Foundation of China (NSFC) under contract Nos 40976116 and 40531007the Fujian Science Foundation under contract No.2009J06025+3 种基金the SOA Youth Foundation Grant under contract No.2012538the Chinese Projects for Investigations and Assessments of the Arctic and Antarctic under contract Nos CHINARE2012: 01-04, 02-01, 03-04, 04-03, 04-04, and CHINARE2013: 01-04, 02-01, 03-04, 04-03, 04-04the Chinese International Cooperation Projects under contract Nos IC201114, IC201201, IC201308, and HC120601the Scientific Research Foundation of Third Institute of Oceanography, SOA under contract Nos 2012006 and 2014006
文摘The 3rd Chinese National Arctic Research Expedition （CHINARE-Arctic III） was carried out from July to September in 2008. The partial pressure of CO2 （pCO2） in the atmosphere and in surface seawater were determined in the Bering Sea during luly 11-27, 2008, and a large number of seawater samples were taken for total alkalinity （TA） and total dissolved inorganic carbon （DIC） analysis. The distributions of CO2 parameters in the Bering Sea and their controlling factors were discussed. The pCO2 values in surface seawater presented a drastic variation from 148 to 563 laatm （1 μatm = 1.013 25× 10-1Pa）. The lowest pCOz values were observed near the Bering Sea shelf break while the highest pCO2 existed at the western Bering Strait. The Bering Sea generally acts as a net sink for atmospheric CO2 in summer. The air-sea CO2 fluxes in the Bering Sea shelf, slope, and basin were estimated at -9.4, -16.3, and -5.1 mmol/（m2.d）, respectively. The annual uptake of CO2 was about 34 Tg C in the Bering Sea.
基金supported by the National Natural Science Foundation of China (31171506 and 31071375)
文摘To accurately evaluate the carbon sequestration potential and better elucidate the relationship between the carbon cycle and regional climate change, using eddy covariance system, we conducted a long-term measurement of CO 2 fluxes in the rain-fed winter wheat field of the Chinese Loess Plateau. The results showed that the annual net ecosystem CO 2 exchange （NEE） was （-71.6±5.7） and （-65.3±5.3） g C m-2 y-1 for 2008-2009 and 2009-2010 crop years, respectively, suggesting that the agro-ecosystem was a carbon sink （117.4-126.2 g C m-2 yr-1）. However, after considering the harvested grain, the agro- ecosystem turned into a moderate carbon source. The variations in NEE and ecosystem respiration （R eco ） were sensitive to changes in soil water content （SWC）. When SWC ranged form 0.15 to 0.21 m3 m-3, we found a highly significant relationship between NEE and photosynthetically active radiation （PAR）, and a highly significant relationship between R eco and soil temperature （T s ）. However, the highly significant relationships were not observed when SWC was outside the range of 0.15-0.21 m3 m-3. Further, in spring, the R eco instantly responded to a rapid increase in SWC after effective rainfall events, which could induce 2 to 4-fold increase in daily R eco , whereas the R eco was also inhibited by heavy summer rainfall when soils were saturated. Accumulated R eco in summer fallow period decreased carbon fixed in growing season by 16- 25%, indicating that the period imposed negative impacts on annual carbon sequestration.
基金supported by the National Natural Science Foundation of China (41301279, 41201041)the International Science & Technology Cooperation Program of China (2010DFA92720)the Knowledge Innovation Project of the Chinese Academy of Sciences (KZCX2-YW-T09)
文摘As an important component of ecosystem carbon（C） budgets, soil carbon dioxide（CO2） flux is determined by a combination of a series of biotic and abiotic processes. Although there is evidence showing that the abiotic component can be important in total soil CO2 flux（R（total））, its relative importance has never been systematically assessed. In this study, after comparative measurements of CO2 fluxes on sterilized and natural soils, the R（total） was partitioned into biotic flux（R（biotic）） and abiotic flux（R（abiotic）） across a broad range of land-cover types（including eight sampling sites： cotton field, hops field, halophyte garden, alkaline land, reservoir edge, native saline desert, dune crest and interdune lowland） in Gurbantunggut Desert, Xinjiang, China. The relative contribution of R（abiotic） to R（total）, as well as the temperature dependency and predominant factors for R（total）, R（biotic） and R（abiotic）, were analyzed. Results showed that R（abiotic） always contributed to R（total） for all of the eight sampling sites, but the degree or magnitude of contribution varied greatly. Specifically, the ratio of R（abiotic） to R（total） was very low in cotton field and hops field and very high in alkaline land and dune crest. Statistically, the ratio of R（abiotic） to R（total） logarithmically increased with decreasing R（biotic）, suggesting that R（abiotic） strongly affected R（total） when R（biotic） was low. This pattern confirms that soil CO2 flux is predominated by biotic processes in most soils, but abiotic processes can also be dominant when biotic processes are weak. On a diurnal basis, R（abiotic） cannot result in net gain or net loss of CO2, but its effect on transient CO2 flux was significant. Temperature dependency of R（total） varied among the eight sampling sites and was determined by the predominant processes（abiotic or biotic） of CO2 flux. Specifically, R（biotic） was driven by soil temperature while R（abiotic） was regulated by the change in soil temperature（ΔT）. Namely, declining temperature（ΔT0） resulted in positive R（abiotic）（i.e., CO2 released from soil）. Without recognition of R（abiotic）, R（biotic） would be overestimated for the daytime and underestimated for the nighttime. Although R（abiotic） may not change the sum or the net value of daily soil CO2 exchange and may not directly constitute a C sink, it can significantly alter the transient apparent soil CO2 flux, either in magnitude or in temperature dependency. Thus, recognizing the fact that abiotic component in R（total） exists widely in soils has widespread consequences for the understanding of C cycling.
文摘Soil CO 2 emission from an arable soil was measured by closed chamber method to quantify year round soil flux and to develop an equation to predict flux using soil temperature, dissolved organic carbon(DOC) and soil moisture content. Soil CO 2 flux, soil temperature, DOC and soil moisture content were determined on selected days during the experiment from August 1999 to July 2000, at the Ecological Station of Red Soil, the Chinese Academy of Sciences, in a subtropical region of China. Soil CO 2 fluxes were generally higher in summer and autumn than in winter and spring, and had a seasonal pattern more similar to soil temperature and DOC than soil moisture. The estimation was 2 23 kgCO 2/(m 2·a) for average annual soil CO 2 flux. Regressed separately, the reasons for soil flux variability were 86 6% from soil temperature, 58 8% from DOC, and 26 3% from soil moisture, respectively. Regressed jointly, a multiple equation was developed by the above three variables that explained approximately 85 2% of the flux variance, however by stepwise regression, soil temperature was the dominant affecting soil flux. Based on the exponential equation developed from soil temperature, the predicted annual flux was 2 49 kgCO 2/(m 2·a), and essentially equal to the measured one. It is suggested the exponential relationship between soil flux and soil temperature could be used for accurately predicting soil CO 2 flux from arable soil in subtropical regions of China.
文摘The Integrated Environmental Monitoring (IEM) project, part of the Asia-Pacific Environmental Innovation Strategy (APEIS) project, developed an integrated environmental monitoring system that can be used to detect, monitor, and assess environmental disasters, degradation, and their impacts in the Asia-Pacific region. The system primarily employs data from the moderate resolution imaging spectrometer (MODIS) sensor on the Earth Observation System-(EOS-) Terra/Aqua satellite, as well as those from ground observations at five sites in different ecological systems in China. From the preliminary data analysis on both annual and daily variations of water, heat and CO2 fluxes, we can confirm that this system basically has been working well. The results show that both latent flux and CO2 flux are much greater in the crop field than those in the grassland and the saline desert, whereas the sensible heat flux shows the opposite trend. Different data products from MODIS have very different correspondence, e.g. MODIS-derived land surface temperature has a close correlation with measured ones, but LAI and NPP are quite different from ground measurements, which suggests that the algorithms used to process MODIS data need to be revised by using the local dataset. We are now using the APEIS-FLUX data to develop an integrated model, which can simulate the regional water, heat, and carbon fluxes. Finally, we are expected to use this model to develop more precise high-order MODIS products in Asia-Pacific region.
基金Supported by the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA05030402)the National Natural Science Foundation of China(Nos.U1406403,41121064,41376092)the Public Science and Technology Research Funds Projects of Ocean(No.200905012-9)
文摘The turbidity maximum zone(TMZ) is one of the most important regions in an estuary.However,the high concentration of suspended material makes it difficult to measure the partial pressure of CO_2(pCO_2) in these regions.Therefore,very little data is available on the pCO_2 levels in TMZs.To relatively accurately evaluate the CO_2 flux in an example estuary,we studied the TMZ and surrounding area in the Changjiang(Yangtze) River estuary.From seasonal cruises during February,August,November 2010,and May 2012,the pCO_2 in the TMZ and surrounding area was calculated from pH and total alkalinity(TA)measured in situ,from which the CO_2 flux was calculated.Overall,the TMZ and surrounding area acted as a source of atmosphere CO_2 in February and November,and as a sink in May and August.The average FCO_2was-9,-16,5,and 5 mmol/(m^2·d) in May,August,November,and February,respectively.The TMZ's role as a source or sink of atmosphere CO_2 was quite different to the outer estuary.In the TMZ and surrounding area,suspended matter,phytoplankton,and pH were the main factors controlling the FCO_2,but here the influence of temperature,salinity,and total alkalinity on the FCO_2 was weak.Organic carbon decomposition in suspended matter was the main reason for the region acting as a CO_2 source in winter,and phytoplankton production was the main reason the region was a CO_2 sink in summer.
基金This work was supported by the Key Project of the National Natural Science Foundation of China(No.40490263)the National Natural Science Foundation of China(Nos.40706040,40376022 and 40606023)+1 种基金the Doctoral Program for Higher Education(20030423007)Scientific Research Promotional fund for Middle-age and Young Scientist of Shandong Province(2007BS08015).
文摘A multilayer study of pCO2 for the Yellow and South China Seas in the surface waters was conducted based on data from four cruises sponsored by the China SOLAS Project in 2005 and 2006,including data for the surface microlayer(SML) ,subsurface layer(SSL) and surface layer(SL) . The carbon fluxes across the air-sea interface were calculated. The results showed that the pCO2 values in the surface waters of the study area decreased in the following order:pCO2 SML> pCO2 SSL> pCO2 SL. The highest values were found in March for all SML,SSL and SL,followed by those in April,and the lowest were in May. The pCO2 values had a significant positive correlation with temperature or salinity. While there was no relationship between pCO2 and longitude,there was a significant negative correlation between it and latitude,i.e.,'high latitude low pCO2'. By using four calculation models,the carbon dioxide fluxes(FC O2) in spring in the Yellow and South China Seas,which were found to act as a 'sink' of atmospheric CO2,were preliminarily estimated on the basis of the pCO2 data in the SML to be -7.00×106 t C and -22.35×106 t C,respectively. It is suggested that the FC O2calculated on the basis of pCO2 data in the SML is more reliable than that calculated on the basis of those in the SL.
基金financially supported by the Fellowship of China National Postdoctoral Program for Innovative Talents(No.BX20220357)the National Science Foundation of China (No.52130408)。
文摘Mold flux serves the crucial metallurgical function of absorbing inclusions, directly impacting the smoothness of the casting process as well as the cast slab quality. In this study, the dissolution behavior and mechanism of Ti O_(2)and Ti N inclusions in molten Ca O–Si O_(2)–B_(2)O_(3)-based fluorine-free mold flux were explored by in situ single hot thermocouple technology combined with X-ray photoelectron spectroscopy.The results showed that Ti O_(2) inclusions are effectively dissolved by the molten slag within 76 s, during which the original octahedral [Ti O_(6)]^(8-)structures are destroyed and convert to the networker tetrahedral [Ti O_(4)]^(4-)structures. However, the dissolution rate is much lower for Ti N inclusions than for Ti O_(2)inclusions. This can be attributed to the fact that the Ti N particles need to be oxidized and then dissolved in the molten slag to form tetrahedral [Ti O4]4-and octahedral [Ti O_(6)]^(8-)structures during the Ti N inclusion dissolution process, which is accompanied by the generation of a large amount of N_(2)gas. Moreover, Ca Ti O_(3)crystals tend to nucleate and grow on bubble surfaces with sufficient octahedral [Ti O_(6)]^(8-)structures and Ca^(2+)ions, eventually resulting in the molten slag being in a solid–liquid mixed state.
基金supported by the National Natural Science Foundation of China(31670476 and 31100284)the Fundamental Research Funds for the Central Universities(2572016CA02)
文摘The CO_2 released from respiring cells in woody tissues of trees can contribute to one of three fluxes:efflux to the atmosphere(E_A),internal xylem sap transport flux(F_T),and storage flux(DS).Adding those fluxes together provides an estimate of actual stem respiration(R_S).We know that the relative proportion of CO_2 in those fluxes varies greatly among tree species,but we do not yet have a clear understanding of the causes for this variation.One possible explanation is that species differ in stem radial CO_2 conductance(g_c).A high g_c would favor the E_A pathway and a low g_cwould favor the F_Tpathway.However,g_chas only been measured once in situ and only in a single tree species.We measured g_cusing two methods in stems of Fraxinus mandshurica Rupr.(ash)and Betula platyphylla Suk.(birch)trees in situ,along with R_S,E_A,F_T and DS.Stem radial CO_2 conductance was substantially greater in ash trees than in birch trees.Corresponding to that finding,in ash trees over 24 h,E_Aconstituted the entire flux of respired CO_2 ,and F_Twas negative,indicating that additional CO_2 ,probably transported from the root system via the xylem,was also diffusing into the atmosphere.In ash trees,F_T was negative over the entire 24 h,and this study represents the first time that has been reported.The addition of xylem-transported CO_2 to E_A caused E_Ato be 9% higher than the actual R_Sover the diel measurement period.Birch trees,which had lower g_c,also had a more commonly seen pattern,with E_A accounting for about 80% of the CO_2 released from local cell respiration and F_T accounting for the remainder.The inorganic carbon concentration in xylem sap was also lower in ash trees than in birch trees:2.7 versus 5.3 mmol L^(-1),respectively.Our results indicate that stem CO_2 conductance could be a very useful measurement to help explain differences among species in the proportion of respired CO_2 that remains in the xylem or diffuses into the atmosphere.
基金This paper was supported by the National Basic Research Program of China (2006CB400506).
文摘A comparison between simulated land surface fluxes and observed eddy covariance （EC） measurements was conducted to validate Integrated Biosphere Simulator （IBIS） at Tongyu field observation station （44°25＇N, 122°52＇E） in Jilin Province, China. Results showed that the IBIS model could reproduce net ecosystem CO2 exchange （NEE）, sensible and latent heat fluxes reasonably, as indicated by correlation coefficients exceeding the significant level of 0.05. It was also evident that the NEE and sensible heat fluxes were characterized by diurnal and seasonal variation both in the grassland and the cropland ecosystems, while the latent heat fluxes correlated with evapotranspiration, only took on the diurnal variation during the growing season. Moreover, both sensible heat fluxes and the latent heat fluxes were larger in the cropland ecosystem than that in the degraded grassland ecosystem. This different characteristic was possibly correlated with vegetation growing situation in the two kinds of ecosystems. A close agreement between observation and simulation on NEE, sensible heat fluxes and latent heat flux was obtained both in the degraded grassland and the cropland ecosystems. In addition, the annual NEE in the model was overestimated by 23.21% at the grassland and 27.43% at the cropland, sensible heat flux with corresponding 9.90% and 11.98%, respectively, and the annual latent heat flux was underestimated by 4.63% and 3.48%, respectively.
