期刊文献+
共找到13,914篇文章
< 1 2 250 >
每页显示 20 50 100
A robust & weak-nucleophilicity electrocatalyst with an inert response for chlorine ion oxidation in large-current seawater electrolysis 被引量:1
1
作者 Junting Dong Chang Yu +5 位作者 Hui Wang Lin Chen Hongling Huang Yingnan Han Qianbing Wei Jieshan Qiu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期486-495,I0011,共11页
Seawater splitting into hydrogen,a promising technology,is seriously limited by the durability and tolerance of electrocatalysts for chlorine ions in seawater at large current densities due to chloride oxidation and c... Seawater splitting into hydrogen,a promising technology,is seriously limited by the durability and tolerance of electrocatalysts for chlorine ions in seawater at large current densities due to chloride oxidation and corrosion.Here,we present a robust and weak-nucleophilicity nickel-iron hydroxide electrocatalyst with excellent selectivity for oxygen evolution and an inert response for chlorine ion oxidation which are key and highly desired for efficient seawater electrolysis.Such a weak-nucleophilicity electrocatalyst can well match with strong-nucleophilicity OH-compared with the weak-nucleophilicity Cl^(-),resultantly,the oxidation of OH-in electrolyte can be more easily achieved relative to chlorine ion oxidation,confirmed by ethylenediaminetetraacetic acid disodium probing test.Further,no strongly corrosive hypochlorite is produced when the operating voltage reaches about 2.1 V vs.RHE,a potential that is far beyond the thermodynamic potential of chlorine ion oxidatio n.This concept and approach to reasonably designing weaknucleophilicity electrocatalysts that can greatly avoid chlorine ion oxidation under alkaline seawater environments can push forward the seawater electrolysis technology and also accelerate the development of green hydrogen technique. 展开更多
关键词 Nickel-iron hydroxide electrocatalysts Highly selective seawater electrolysis Weak nucleophilicity Oxygen evolution reaction Hydrogen
下载PDF
Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping 被引量:1
2
作者 Yongchao Yao Shengjun Sun +14 位作者 Hui Zhang Zixiao Li Chaoxin Yang Zhengwei Cai Xun He Kai Dong Yonglan Luo Yan Wang Yuchun Ren Qian Liu Dongdong Zheng Weihua Zhuang Bo Tang Xuping Sun Wenchuang(Walter)Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期306-312,共7页
Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability cau... Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution. 展开更多
关键词 Ce doping NiFe layered double hydroxide seawater oxidation Electrocatalysis Cl^(-) repulsion
下载PDF
The environmental analysis and site selection of mussel and large yellow croaker aquaculture areas based on high resolution remote sensing
3
作者 Lina Cai Jie Yin +3 位作者 Xiaojun Yan Yongdong Zhou Rong Tang Menghan Yu 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第3期66-86,共21页
Mussel aquaculture and large yellow croaker aquaculture areas and their environmental characteristics in Zhoushan were analyzed using satellite data and in-situ surveys.A new two-step remote sensing method was propose... Mussel aquaculture and large yellow croaker aquaculture areas and their environmental characteristics in Zhoushan were analyzed using satellite data and in-situ surveys.A new two-step remote sensing method was proposed and applied to determine the basic environmental characteristics of the best mussel and large yellow croaker aquaculture areas.This methodology includes the first step of extraction of the location distribution and the second step of the extraction of internal environmental factors.The fishery ranching index(FRI1,FRI2)was established to extract the mussel and the large yellow croaker aquaculture area in Zhoushan,using Gaofen-1(GF-1)and Gaofen-6(GF-6)satellite data with a special resolution of 2 m.In the second step,the environmental factors such as sea surface temperature(SST),chlorophyll a(Chl-a)concentration,current and tide,suspended sediment concentration(SSC)in mussel aquaculture area and large yellow croaker aquaculture area were extracted and analyzed in detail.The results show the following three points.(1)For the extraction of the mussel aquaculture area,FRI1 and FRI2 are complementary,and the combination of FRI1 and FRI2 is suitable to extract the mussel aquaculture area.As for the large yellow croaker aquaculture area extraction,FRI2 is suitable.(2)Mussel aquaculture and the large yellow croaker aquaculture area in Zhoushan are mainly located on the side near the islands that are away from the eastern open waters.The water environment factor template suitable for mussel and large yellow croaker aquaculture was determined.(3)This two-step remote sensing method can be used for the preliminary screening of potential site selection for the mussels and large yellow croaker aquaculture area in the future.the fishery ranching index(FRI1,FRI2)in this paper can be applied to extract the mussel and large yellow croaker aquaculture areas in coastal waters around the world. 展开更多
关键词 mussel aquaculture area large yellow croaker aquaculture area high resolution satellite site selection environmental analysis
下载PDF
Impacts of Integrated Multi-Trophic Aquaculture on Phytoplankton in Sanggou Bay
4
作者 HAN Jichang LIU Xing +5 位作者 PAN Kehou LIU Jiaojiao SUN Yan JIN Guiyong LI Yun LI Yuhang 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期835-843,共9页
Integrated multi-trophic aquaculture(IMTA)has been considered as an ecofriendly culture system providing a potential solution to environmental risks caused by intensive monoculture system.However,the impact of IMTA on... Integrated multi-trophic aquaculture(IMTA)has been considered as an ecofriendly culture system providing a potential solution to environmental risks caused by intensive monoculture system.However,the impact of IMTA on phytoplankton remains unclear.In this study,the spatial and temporal variations of phytoplankton in Sanggou Bay were investigated seasonally based on 21 sampling sites covering three cultivation zones(bivalve zone,IMTA zone,and kelp zone)and one control zone(without aquatic cultivation).In total,128 phytoplankton species,with diatoms and dinoflagellates as the dominant groups,were obtained across the whole year,and the mean Shannon diversity index(H')and species richness(SR)were determined as 1.39 and 9.39,respectively.The maximum chlorophyll a(Chl-a)(6.32μg L^(-1))and plankton diversity(H'of 1.97)occurred in summer and autumn,respectively.Compared to other zones,the bivalve zone displayed significantly higher Chl-a and lower H'in majority of time.Pairwise PERMANOVA analysis indicated that the phytoplankton assemblage in the bivalve zone was significantly different with the control and kelp zones,while the IMTA zone maintained close to other three zones.Based on generalized additive models,temperature,NO_(2)^(-)-N,N/P ratio,SiO_(3)^(2-)-Si,and salinity were determined as the key factors underlying Chl-a and phytoplankton diversity.Addi-tionally,the results of redundancy analysis further indicated that the phytoplankton assemblage in the bivalve zone is positively re-lated with nutrients such as NO_(3)^(-)-N and NH_(4)^(+)-N as well as water depth,while the phytoplankton assemblages in the kelp,control,and IMTA zones are associated with NO_(2)^(-)-N,SiO_(3)^(2-)-Si,and salinity.Taken all observations into consideration together,it can be inferred that IMTA can effectively reduce Chl-a level compared to bivalve monoculture by reducing the nutrients.However,the SR,H’,and species composition of phytoplankton are primarily determined by local environment factors such as temperature,water depth,salinity and SiO_(3)^(2-)-Si. 展开更多
关键词 PHYTOPLANKTON DIVERSITY Sanggou Bay integrated multi-trophic aquaculture
下载PDF
Photoelectrochemical seawater oxidation with metal oxide materials:Challenges and opportunities
5
作者 Miao Kan Hangyu Hu +3 位作者 Weijie Zhuang Meng Tao Shiqun Wu Jinlong Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期767-782,I0016,共17页
Photocatalytic water oxidation is a crucial counter-electrode reaction in the process of photoelectrochemical energy conversion.Despite its importance,challenges remain in effectively and sustainably converting water ... Photocatalytic water oxidation is a crucial counter-electrode reaction in the process of photoelectrochemical energy conversion.Despite its importance,challenges remain in effectively and sustainably converting water to oxygen,particularly with readily available and inexpensive electrolyte solutions such as seawater.While metal oxide materials have demonstrated their advantages in promoting efficiency by reducing overpotential and improving light utilization,stability remains limited by corrosion in multicomponent seawater.In this paper,we reviewed the relationship between four basic concepts including photoelectrochemistry,metal oxide,water oxidation and seawater to better understand the challenges and opportunities in photoelectrochemical(PEC)seawater oxidation.To overcome these challenges,the advances in material design,interfacial modification,local environment control and reactor design have been further reviewed to benefit the industrial PEC seawater oxidation.Noticeably,we demonstrate engineered layered metal oxide electrodes and cell structures that enable powerful and stable seawater oxidation.We also outline and advise on the future direction in this area. 展开更多
关键词 PHOTOELECTROCHEMISTRY ANODE Water oxidation Metal oxide seawater STABILITY
下载PDF
Effect of length-width ratio of rounded rectangle aquaculture tank in dual-diagonal-inlet layout on hydrodynamics
6
作者 Meng LI Xiaozhong REN +4 位作者 Shupeng DU Wei SUN Chenxu ZHAO Hangfei LIU Xianying SHI 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第5期1695-1709,共15页
To adapt to the change of aquaculture workshop site,optimize the shape of aquaculture tanks and improve the utilization rate of breeding space,it is necessary to determine the appropriate length width ratio parameters... To adapt to the change of aquaculture workshop site,optimize the shape of aquaculture tanks and improve the utilization rate of breeding space,it is necessary to determine the appropriate length width ratio parameters of aquaculture tanks.In this paper,computational fluid dynamics(CFD)technology is adopted to study the flow field performance of aquaculture tanks with different L/B ratios(L:the length;B:the width,of aquaculture tank)and different jet direction conditions(lengthways jet and widthways jet).A three-dimensional numerical calculation model of turbulence in rounded rectangle aquaculture tanks in dual-diagonal-inlet layout was established.Jet directions are arranged lengthways and widthways,and the water flow velocity,resistance coefficient change,vorticity,etc.are analyzed under two working conditions.Results show that the flow field performance in aquaculture tank decreases with the increase of the L/B ratio.The flow field performed well when L/B was 1.0-1.3,sharply dropped at 1.4-1.6,and poor at 1.7-1.9.The results provided a theoretical basis for the design and optimization in flow field performance of the industrialized circulating aquaculture tanks. 展开更多
关键词 aquaculture tank length-width ratio computational fluid dynamic hydrodynamic
下载PDF
Distribution and sources of sedimentary organic matter in different aquaculture areas of northeastern Zhanjiang Bay using stable carbon and nitrogen isotopes
7
作者 Fengxia Zhou Shuangling Wang +8 位作者 Han Fang Jiani He Liang Ye Zhaohai Ding Cuiting Li Fajin Chen Xuan Lu Chunqing Chen Yafei Meng 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第6期38-48,共11页
Zhanjiang Bay is a major aquaculture area in China with many types of mariculture products(such as oysters,fish,and shrimp).The culture area and shrimp output in Zhanjiang Bay are ranked first in China.We investigated... Zhanjiang Bay is a major aquaculture area in China with many types of mariculture products(such as oysters,fish,and shrimp).The culture area and shrimp output in Zhanjiang Bay are ranked first in China.We investigated the total organic carbon(TOC),total nitrogen(TN),TOC/TN ratio,and stable isotopes(δ^(13)C and δ^(15)N) of the fish and shrimp feed,fish and shrimp feces,and sedimentary organic matter(SOM) in and around different aquaculture areas of northeastern Zhanjiang B ay to study the impact of aquaculture activities on SOM.The average TOC contents of fish and shrimp feed were 39.20%±0.91% and 39.29%±0.21%,respectively.The average TOC content in the surface sediments of the oyster culture area,the mixed(fish and shrimp) culture area,and the cage fish farm area were 0.66%,0.88%±0.10%,and 0.58%±0.19%,respectively,which may indicate that mixed culture had a greater impact on SOM.The relatively high TOC and TN contents and relatively low TOC/TN ratios,and δ^(15)N values in the upper layer of the core sediment in the mixed culture area could also support the significant influence of mixed culture.The average δ^(13)C and δ^(15)N values of fish and shrimp feed were -20.6‰±2.2‰ and 1.8‰±1.2‰,respectively,which were different from the isotopic values of SOM in the study area.δ^(13)C and δ^(15)N values for SOM in different aquaculture areas were different from those of nearby reference stations,probably reflecting the influence of aquaculture.The δ^(13)C and δ^(15)N values in the oyster culture area(-25.9‰ and6.0‰,respectively) seemed to have reduced δ^(13)C and enriched δ^(15)N relative to those of the reference station(-24.6‰ and 5.8‰,respectively).This may reflect the influence of organic matter on oyster culture.The δ^(15)N value of the station in the mixed culture area(7.1‰±0.4‰) seemed to be relatively enriched in δ^(15)N relative to that of the reference station(6.6‰).Sedimentation and the subsequent degradation of organic matter from mixed cultures may have contributed to this phenomenon.The surface sediment at the cage fish farm area seemed to be affected by fish feces and primary production based on the indication of δ^(13)C and δ^(15)N values.The sediment core at the mixed culture region(NS6) had lower TOC/TN ratios and more positive δ^(13)C and δ^(15)N values than the sediment core at the oyster culture area,suggesting a higher proportionate contribution of marine organic matter in the mixed culture area.In summary,oyster culture,mixed culture,and cage fish culture in northeastern Zhanjiang Bay had a certain degree of impact on SOM,and mixed culture had more significant influences on SOM based on the high TOC contents and the significant vertical variations of TOC/TN ratio and δ^(15)N value in the sediment of this area.This study provides new insights into the impact of aquaculture activities on SOM content. 展开更多
关键词 sedimentary organic matter aquaculture stable isotopes SOURCES Zhanjiang Bay
下载PDF
Evolution of Biofilm and Its Effect on Microstructure of Mortar Surfaces in Simulated Seawater
8
作者 荣辉 YU Chenglong 张颖 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期234-243,共10页
To explore the role of biofilm formation on the corrosion of marine concrete structures, we investigated the attachment of biofilm on mortar surfaces in simulated seawater and the influence of biofilm on the microstru... To explore the role of biofilm formation on the corrosion of marine concrete structures, we investigated the attachment of biofilm on mortar surfaces in simulated seawater and the influence of biofilm on the microstructure of mortar surfaces. The results show that the evolution of biofilm on mortar surfaces in simulated seawater is closely related to the corrosion suffered by the mortar, and the process of biofilm attachment and shedding is continuous and cyclical. It is found that the specimens in the absence of biofilm attachment are more severely eroded internally by the corrosive medium in simulated seawater than those in the presence of biofilm attachment. For the specimens without biofilm attachment, after 60 days, gypsum forms,and after 120 days, the number of pores in the mortar is reduced. In contrast, for the specimens in the presence of biofilm attachment, gypsum could only be detected after 90 days, and fewer pores are filled. Therefore, the formation of biofilm could delay the invasion of the corrosive medium into the interior of mortar during the evolution of biofilm on mortar surfaces, mitigating the corrosion of mortars in seawater. 展开更多
关键词 biofilm attachment MORTAR sulfur-oxidizing bacteria GYPSUM simulated seawater MICROSTRUCTURE
下载PDF
Efficient optimization of electron transfer pathway by constructing phosphide/ceria interface boosts seawater hydrogen production
9
作者 Yifan Zhao Lingfeng Yang +3 位作者 Youyu Long Min Xi Anran Chen Hua Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期490-498,I0011,共10页
Developing efficient and durable hydrogen evolution reaction(HER)electrocatalysts is one of the most important issues for the commercialization of seawater electrolysis,but it remains challenging.Here,we report a CeO_... Developing efficient and durable hydrogen evolution reaction(HER)electrocatalysts is one of the most important issues for the commercialization of seawater electrolysis,but it remains challenging.Here,we report a CeO_(2)-CoP nanoneedle array catalyst loaded on Ti mesh(CeO_(2)-CoP/TM)with workfunction-induced directional charge transport properties.The CeO_(2)-CoP/TM catalyst showed superior HER catalytic activity and stability,with over potentials of 41 and 60 mV to attain 10 mA cm^(-2),in 1 M KOH and 1 M KOH+seawater electrolyte,respectively.Experimental results and theoretical calculations reveal that the work function drives the charge transfer from CeO_(2)to CoP,which effectively balances the electronic density of CoP and CeO_(2),optimizes the d-band center,and accelerates the water activation kinetics,thus enhancing the HER activity.The solar-driven water electrolysis device displays a high and stable solar-to-hydrogen conversion efficiency of 19.6%.This study offers a work function-induced directional charge transport strategy to design efficient and durable catalysts for hydrogen production. 展开更多
关键词 Work function HETEROSTRUCTURE Charge transport seawater splitting Solar-to-hydrogen
下载PDF
A highly stable zinc anode protected by a corrosion inhibitor for seawater-based zinc-ion batteries
10
作者 Bowei Shi Rongwei Meng +7 位作者 Xin Jiang Yingxin Liu Huaiyuan Wang Quanjun Tang Li Wang Chen Zhang Guowei Ling Quan-Hong Yang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期332-341,I0006,共11页
The island-based energy storage is of urgent need for the grid construction combined with renewable energy for offshore operation.The direct use of seawater as a substitute of deionized water shows its great promise f... The island-based energy storage is of urgent need for the grid construction combined with renewable energy for offshore operation.The direct use of seawater as a substitute of deionized water shows its great promise for aqueous zinc-ion batteries in such a specific situation.However,the metal corrosion,dendrite growth,and hydrogen evolution stand out in the harsh seawater environment.To address these challenges,we proposed a corrosion inhibitor that was effective in the field of metal anti-corrosion,2-phosphonobutane-1,2,4-tricarboxylic acid(PBTCA),to inhibit anode corrosion caused by Cl-and active H_(2)O molecules by forming a stable solid electrolyte interphase(SEI)film in the seawater-based electrolyte.Besides,PBTCA can chelate with other cations present in seawater,such as Ca^(2+)and Mg^(2+),thereby preventing the aggregation and precipitation of sparingly soluble species.Under a current density of5 mA cm^(-2),the seawater-based zinc-ion battery exhibited an exceptional cycle life exceeding 2000 h and maintained a Coulombic efficiency of over 99.6%after 2000 cycles.Additionally,the performance of the Zn||ZVO full battery was significantly enhanced with the addition of PBTCA.This study provides a simple,low-cost,and efficient approach for making the seawater-based zinc-ion batteries useable. 展开更多
关键词 Zinc-ion batteries ANTI-CORROSION seawater Solid electrolyte interphase
下载PDF
A bulk extraction method to determine the stable isotope ratios of iron,nickel,copper,zinc,and cadmium in seawater using multi-collector inductively coupled plasma mass spectrometry
11
作者 Zhan Shen Yuncong Ge +3 位作者 Jiahui Liu Wenkai Guan Wenfeng Hu Ruifeng Zhang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第7期125-137,共13页
The oceanic trace metals iron(Fe),nickel(Ni),copper(Cu),zinc(Zn),and cadmium(Cd)are crucial to marine phytoplankton growth and global carbon cycle,and the analysis of their stable isotopes can provide valuable insight... The oceanic trace metals iron(Fe),nickel(Ni),copper(Cu),zinc(Zn),and cadmium(Cd)are crucial to marine phytoplankton growth and global carbon cycle,and the analysis of their stable isotopes can provide valuable insights into their biogeochemical cycles within the ocean.However,the simultaneous isotopic analysis of multiple elements present in seawater is challenging because of their low concentrations,limited volumes of the test samples,and high salt matrix.In this study,we present the novel method developed for the simultaneous analysis of five isotope systems by 1 L seawater sample.In the developed method,the NOBIAS Chelate-PA1 resin was used to extract metals from seawater,the AG MP-1M anion-exchange resin to purify Cu,Fe,Zn,Cd,and the NOBIAS Chelate-PA1 resin to further extract Ni from the matrix elements.Finally,a multi-collector inductively coupled plasma mass spectroscope(MC-ICPMS)was employed for the isotopic measurements using a doublespike technique or sample-standard bracketing combined with internal normalization.This method exhibited low total procedural blanks(0.04 pg,0.04 pg,0.21 pg,0.15 pg,and 3 pg for Ni,Cu,Fe,Zn,and Cd,respectively)and high extraction efficiencies(100.5%±0.3%,100.2%±0.5%,97.8%±1.4%,99.9%±0.8%,and 100.1%±0.2%for Ni,Cu,Fe,Zn,and Cd,respectively).The external errors and external precisions of this method could be considered negligible.The proposed method was further tested on the seawater samples obtained from the whole vertical profile of a water column during the Chinese GEOTRACES GP09 cruise in the Northwest Pacific,and the results showed good agreement with previous related data.This innovative method will contribute to the advancement of isotope research and enhance our understanding of the marine biogeochemical cycling of Fe,Ni,Cu,Zn,and Cd. 展开更多
关键词 trace metal stable isotopes seawater bulk extraction
下载PDF
Research on the generation method of seawater sound velocity model based on Perlin noise
12
作者 Zhimiao Chang Fuxing Han +2 位作者 Zhangqing Sun Zhenghui Gao Xueqiu Wang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第1期99-111,共13页
In the processing of conventional marine seismic data,seawater is often assumed to have a constant velocity model.However,due to static pressure,temperature difference and other factors,random disturbances may often f... In the processing of conventional marine seismic data,seawater is often assumed to have a constant velocity model.However,due to static pressure,temperature difference and other factors,random disturbances may often frequently in seawater bodies.The impact of such disturbances on data processing results is a topic of theoretical research.Since seawater sound velocity is a difficult physical quantity to measure,there is a need for a method that can generate models conforming to seawater characteristics.This article will combine the Munk model and Perlin noise to propose a two-dimensional dynamic seawater sound velocity model generation method,a method that can generate a dynamic,continuous,random seawater sound velocity model with some regularity at large scales.Moreover,the paper discusses the influence of the inhomogeneity characteristics of seawater on wave field propagation and imaging.The results show that the seawater sound velocity model with random disturbance will have a significant influence on the wave field simulation and imaging results. 展开更多
关键词 Munk model Perlin noise seawater inhomogeneity
下载PDF
Environmental characteristics of trace metals in seawater from the Ninety East Ridge in the Indian Ocean
13
作者 Jingxi LI Di ZHANG +3 位作者 Fenghua JIANG Hong CHEN Wei CAO Chengjun SUN 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第4期1119-1129,共11页
The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East ... The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East Ridge in the Indian Ocean were investigated.Results show that the average concentrations of different trace metals in all the collected seawater samples were 1.134μg/L for V,0.158μg/L for Cr,0.489μg/L for Mn,0.427μg/L for Fe,0.011μg/L for Co,0.395μg/L for Ni,0.403μg/L for Cu,0.097μg/L for Cd,0.139μg/L for Pb,and 3.470μg/L for U.Differences in the horizontal and vertical distributions of all measured trace metals were revealed,and the occurrence of high concentrations was nonuniform.In addition,the significant differences in the concentration distribution of different trace metals in seawater on both sides of the Ninety East Ridge present regional segmentation in the area for various trace metals in deep sea water.This study provided basic data for future investigations on the environmental and ecological impact of trace metals in the Indian Ocean and the potential water mass transport mechanism. 展开更多
关键词 trace metal environmental characteristic Ninety East Ridge seawater Indian Ocean
下载PDF
In situ generation of oxyanions-decorated cobalt(nickel)oxyhydroxide catalyst with high corrosion resistance for stable and efficient seawater oxidation
14
作者 Fengting Luo Pei Yu +2 位作者 Jueting Xiang Junjie Jiang Shijian Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期508-516,共9页
The development of efficient and robust anode materials for stable alkaline seawater electrolysis is severely limited by chlorine evolution reaction and chloride corrosion.Here,the sulfur-doped cobalt-nickel bimetalli... The development of efficient and robust anode materials for stable alkaline seawater electrolysis is severely limited by chlorine evolution reaction and chloride corrosion.Here,the sulfur-doped cobalt-nickel bimetallic phosphides(CoNiPS)are specifically designed as a pre-catalyst for navigating a surface reconstruction to fabricate the anions(PO^(3-)_(4) and SO^(2-)_(4))-decorated Co(Ni)OOH catalyst(R-CoNiPS)with exceptional durability and high activity for stable alkaline seawater oxidation(ASO).Various experiment techniques together with theoretical simulations both demonstrate that the in situ-generated PO^(3-)_(4) and SO^(2-)_(4) anions on catalyst surface can improve the oxygen evolution reaction(OER)activity,regulating and stabilizing the catalytic active species Co(Ni)OOH,as well as make a critical role in inhibiting the adsorp-tion of chloride ions and extending the service life of electrode.Therefore,this R-CoNiPS electrode exhi-bits superb OER activity toward AsO and stands out among the non-precious ASO electrocatalysts reported recently,requiring low overpotentials of 420 and 440 mV to attain large current densities of 500 and 1000 mA cm^(-2) in an alkaline natural seawater electrolyte,respectively.Particularly,the catalyst displays a negligible chloride corrosion at room temperature during ASO operation(>200 h)at 500 mA cm^(-2).This work opens up a new viewpoint for designing high-activity and durable electrocata-lystsforseawaterelectrolysis. 展开更多
关键词 seawater electrolysis Anions Oxygen evolution reaction Chloride corrosion
下载PDF
Harnessing overlapped temperature-salinity gradient in solar-driven interfacial seawater evaporation for efficient steam and electricity generation
15
作者 Peida Li Dongtong He +2 位作者 Jingchang Sun Jieshan Qiu Zhiyu Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期694-700,I0015,共8页
Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity grad... Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity gradient(TSG)between water-air interface and adjacent seawater,affording opportunities of harnessing electricity.However,the efficiency of conventional SIWE technologies is limited by significant challenges,including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously.Herein,we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG.It enables spontaneous circulation of salt flux upon seawater evaporation,inducing a self-cleaning evaporative interface without salt passivation for stable steam generation.Meanwhile,this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation.These benefits render a remarkable efficiency of90.8%in solar energy utilization,manifesting in co-generation of solar steam at a fast rate of 2.01 kg m^(-2)-h^(-1)and electricity power of 1.91 W m^(-2)with high voltage.Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply.It produces hydrogen at a rapid rate of 1.29 L h^(-1)m^(-2)and freshwater with 22 times lower Na+concentration than the World Health Organization(WHO)threshold. 展开更多
关键词 Solar-driven interfacial water evaporation Steam generation Electricity generation seawater
下载PDF
Effects of inorganic nutrients and environmental factors on the removal of n-propylbenzene and isopropylbenzene in seawater by cryptophytes Rhinomonas reticulata S6A
16
作者 Jiali CUI Shuhao DU +3 位作者 Yumei LI Haiping LI Ping ZHANG Fanping MENG 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第4期1200-1215,共16页
To effectively remove n-propylbenzene(n-PBZ)and isopropylbenzene(i-PBZ)leaked into seawater using Rhinomonas reticulata S6A(a newly isolated marine microalga),the effects of three inorganic nutrients and four environm... To effectively remove n-propylbenzene(n-PBZ)and isopropylbenzene(i-PBZ)leaked into seawater using Rhinomonas reticulata S6A(a newly isolated marine microalga),the effects of three inorganic nutrients and four environmental factors on their degradation were determined after 7 d of inoculation.Results show that NaNO_(3) at 300 mg/L caused a higher removal efficiency of both n-PBZ and i-PBZ(44.79%and 39.26%),while for NaH_(2) PO_(4)·H_(2) O,greater removal rates of two PBZs(47.30%and 42.23%)were achieved at 30 and 20 mg/L,respectively.NaHCO_(3) supplementation(500-750 mg/L)resulted in a large reduction(43.67%-45.04%)in i-PBZ concentration.The change in seawater pH(from 6 to 9)did not affect the elimination of n-PBZ and i-PBZ.The most suitable salinity and temperature were 30 and 25-30℃,respectively,leading to the PBZs removal of~40%.Light intensity exhibited significant influence on elimination of PBZs,and the maximum removal efficiencies of 56.07%(n-PBZ)and 55.00%(i-PBZ)were recorded under 200 and 600μmol/(m^(2)·s),respectively.In addition,the microalga could still remove PBZs when it failed to grow well due to darkness,strong light,low temperature,or low salinity,which might mean that good growth of alga is not always a necessary condition for PBZs removal.Therefore,attention should be paid to the suitability of nutrient levels and environmental conditions(excluding pH)in seawater when using microalgae for bioremediating PBZs-contaminated seawater. 展开更多
关键词 propylbenzene(PBZ) Rhinomonas reticulata seawater inorganic nutrient environmental factor
下载PDF
Generating highly active oxide-phosphide heterostructure through interfacial engineering to break the energy scaling relation toward urea-assisted natural seawater electrolysis
17
作者 Ngoc Quang Tran Nam Hoang Vu +6 位作者 Jianmin Yu Khanh Vy Pham Nguyen Thuy Tien Nguyen Tran Thuy-Kieu Truong Lishan Peng Thi Anh Le Yoshiyuki Kawazoe 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期687-699,I0014,共14页
Urea-assisted natural seawater electrolysis is an emerging technology that is effective for grid-scale carbon-neutral hydrogen mass production yet challenging.Circumventing scaling relations is an effective strategy t... Urea-assisted natural seawater electrolysis is an emerging technology that is effective for grid-scale carbon-neutral hydrogen mass production yet challenging.Circumventing scaling relations is an effective strategy to break through the bottleneck of natural seawater splitting.Herein,by DFT calculation,we demonstrated that the interface boundaries between Ni_(2)P and MoO_(2) play an essential role in the selfrelaxation of the Ni-O interfacial bond,effectively modulating a coordination number of intermediates to control independently their adsorption-free energy,thus circumventing the adsorption-energy scaling relation.Following this conceptual model,a well-defined 3D F-doped Ni_(2)P-MoO_(2) heterostructure microrod array was rationally designed via an interfacial engineering strategy toward urea-assisted natural seawater electrolysis.As a result,the F-Ni_(2)P-MoO_(2) exhibits eminently active and durable bifunctional catalysts for both HER and OER in acid,alkaline,and alkaline sea water-based electrolytes.By in-situ analysis,we found that a thin amorphous layer of NiOOH,which is evolved from the Ni_(2)P during anodic reaction,is real catalytic active sites for the OER and UOR processes.Remarkable,such electrode-assembled urea-assisted natural seawater electrolyzer requires low voltages of 1.29 and 1.75 V to drive 10 and600 mA cm^(-2)and demonstrates superior durability by operating continuously for 100 h at 100 mA cm^(-2),beyond commercial Pt/C||RuO_(2) and most previous reports. 展开更多
关键词 Interfacial engineering Break scaling relationships Doping Natural seawater splitting Urea electrolysis
下载PDF
High-quality Development Path of Graduate Education in Aquaculture Discipline:A Case Study of Guangdong Ocean University
18
作者 Huanying PANG Miao XIE +2 位作者 Shuanghu CAI Yucong HUANG Jichang JIAN 《Asian Agricultural Research》 2024年第9期41-44,共4页
Aquaculture is a discipline system that focuses on exploring the growth,development,reproduction,aquaculture,and resources of aquatic animals and plants,and their complex relationships.Under the tide of the"high-... Aquaculture is a discipline system that focuses on exploring the growth,development,reproduction,aquaculture,and resources of aquatic animals and plants,and their complex relationships.Under the tide of the"high-quality development"strategy,the aquaculture discipline is also facing new opportunities and challenges for transformation,upgrading,and deepening development.Therefore,exploring and practicing an effective path for the high-quality development of graduate education in aquaculture is not only the key to promoting the transformation of graduate education in aquaculture from scale expansion to quality improvement,but also has immeasurable value for implementing the strategy on developing a quality workforce and the strategy of scientific and technological powerhouse.The high-quality development of graduate education in aquaculture can be promoted from the following aspects:optimizing and improving the construction of the graduate education system,focusing on enhancing the quality of high-level talent cultivation,strengthening the overall strength of the graduate supervisor team,actively promoting the adjustment and upgrading of the disciplinary and professional structure,strengthening the construction of resource platforms and deepening the implementation of collaborative education mechanisms,and continuously expanding and deepening the new pattern of international exchange and cooperation.Through the comprehensive promotion of the above paths,the aim is to fully build a model for the improvement and governance of graduate education quality. 展开更多
关键词 aquaculture GRADUATE EDUCATION HIGH-QUALITY development
下载PDF
Numerical simulation of inlet placement on sewage characteristics in the rounded square aquaculture tank with single inlet
19
作者 Xiaozhong REN Yixuan HU +5 位作者 Yinxin ZHOU Shupeng DU Wei SUN Hangfei LIU Chenxu ZHAO Ying LIU 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第4期1359-1382,共24页
To improve the self-cleaning ability of aquaculture tank and the efficiency of circulating water,physical and numerical experiments were conducted on the influence of inlet structure on sewage discharge in a rounded s... To improve the self-cleaning ability of aquaculture tank and the efficiency of circulating water,physical and numerical experiments were conducted on the influence of inlet structure on sewage discharge in a rounded square aquaculture tank with a single inlet.Based on the physical model of the tank,analysis of how inlet structure adjustment affects sewage discharge efficiency and flow field characteristics was conducted to provide suitable flow field conditions for sinkable solid particle discharge.In addition,an internal flow field simulation was conducted using the RNG k-εturbulence model in hydraulic drive mode.Then a solid-fluid multiphase model was created to investigate how the inlet structure affects sewage collection in the rounded square aquaculture tank with single inlet and outlet.The finding revealed that the impact of inlet structure is considerably affecting sewage collection.The conditions of C/B=0.07-0.11(the ratio of horizontal distance between the center of the inlet pipe and the tank wall(C)to length of the tank(B))andα=25°(αis the angle between the direction of the jet and the tangential direction of the arc angle)resulted in optimal sewage collection,which is similar to the flow field experiment in the rounded square aquaculture tank with single inlet and outlet.An excellent correlation was revealed between sewage collection and fluid circulation stability in the aquaculture tank.The present study provided a reference for design and optimization of circulating aquaculture tanks in aquaculture industry. 展开更多
关键词 rounded square aquaculture tank sewage collection characteristic inlet structure computational fluid dynamic
下载PDF
Development and interpretation of ISO 13205:2024,Marine technology-Seawater desalination-Vocabulary
20
作者 Xu Jianmei Wang Min +1 位作者 Xie Chungang Sun Jing 《China Standardization》 2024年第5期62-64,共3页
Vocabulary is the most basic subject of standardization.Despite that individual terms related to seawater desalination have been mentioned in some standards and technical documents of ISO,WHO,and ASTM,the inconsistent... Vocabulary is the most basic subject of standardization.Despite that individual terms related to seawater desalination have been mentioned in some standards and technical documents of ISO,WHO,and ASTM,the inconsistent expression might still induce ambiguity in communications among the participators in this area.Moreover,terms in these documents are not comprehensive.Consequently,ISO 13205:2024 is developed to eliminate the misunderstanding in both the academic and commercial communications.This paper expounds on the specific progress of the research in three aspects:background,drafting of ISO 13205:2024,and interpretation of ISO 13205:2024.The significance of the standard is also discussed. 展开更多
关键词 seawater desalination VOCABULARY ISO STANDARDS
下载PDF
上一页 1 2 250 下一页 到第
使用帮助 返回顶部