Backscattered fields from one-dimensional time-varying Gerstners sea surface are calculated utilising the secondorder small slope approximation. It is well known that spectral properties of the backscattered echoes re...Backscattered fields from one-dimensional time-varying Gerstners sea surface are calculated utilising the secondorder small slope approximation. It is well known that spectral properties of the backscattered echoes relate to the velocity of the small elementary scatterers on sea surface profiles. Therefore, modeling Doppler spectra from the ocean requires an accurate description of the sea surface motion. The profile of nonlinear Gerstners sea surface shows verticalskewness of sea waves, it is sharper at the crest and flatter at the trough than linear waves, and its maximum slope position is closer to the crest than to the trough. Furthermore, the horizontal component of the small elementary scatterers orbit velocity on the sea surface, which yields noticeable influence on Doppler spectra, can be obtained conveniently by Gerstners sea surface model. In this study the characteristics of Doppler spectra of backscattered fields from time-varying Gerstners sea surface are investigated and the dependences of the Doppler frequency and the Doppler bandwidth on the parameters, such as the wind speed, the radar frequency, the incident angle, etc. are discussed. It is shown that the Doppler bandwidth of microwave scattered fields from Gerstners sea surface is considerably broadened. For the case of high frequency backscattered fields, the values of the higher-order spectrum peaks are larger than those obtained by linear sea surface.展开更多
A method using group-induced second-order long waves(GSLW) to represent statistical properties of wave groups with double-peaked spectra is put forward in this paper on the basis of the GSLW theory. The GSLW is regard...A method using group-induced second-order long waves(GSLW) to represent statistical properties of wave groups with double-peaked spectra is put forward in this paper on the basis of the GSLW theory. The GSLW is regarded as a weighted linear superimposition of the second-order long Wave induced by the low peak frequency section and that induced by the high peak frequency section. There is a parabolic relationship between the GSLW and the wave envelope. Then the probability density function and the distribution function of the GSLW amplitude are derived. Thus the formulas for the average time duration and the mean length of runs can be derived. Good agreement between theoretical results and measured values was achieved. as verified with the measured double-peaked spectra in different regions.展开更多
UV-VIS spectroscopic investigations of interaction of bovine and human serum albumin with selected chalcones (1) and their cyclic chalcone analogues: (E)-2-(4’-X-benzylidene-1-tetralones (3), benzosuberones (4) with ...UV-VIS spectroscopic investigations of interaction of bovine and human serum albumin with selected chalcones (1) and their cyclic chalcone analogues: (E)-2-(4’-X-benzylidene-1-tetralones (3), benzosuberones (4) with dimethylamino and methoxy substituents and (E)-2-(2’,4’-dimethox- ybenzylidene)-1-indanone (2) were performed in polar respiration medium. Absorption maxima of the tested compounds were investigated in the presence of bovine and human serum albumin at the 0, 10, 30 and 60 minute timepoints of the interaction. The absorbance of all studied compounds in the presence of proteins decreased after one hour of the reaction. Molecule 4a showed the strongest and fastest kinet initial interaction with both albumins.展开更多
AMI semi-empirical method was used to optimize the barbituric acid derivatives substituted with glucosyl B1-5 （series B）, and the thiobarbituric acid derivatives substituted with glucosyl T1-5 （series T）. Based on...AMI semi-empirical method was used to optimize the barbituric acid derivatives substituted with glucosyl B1-5 （series B）, and the thiobarbituric acid derivatives substituted with glucosyl T1-5 （series T）. Based on the optimized structures, INDO/CI method was adopted to calculate the electronic spectra. Meanwhile, the second-order nonlinear optical （NLO） coefficients βμ were calculated with the sum-over-state （SOS） formula. The results show that when the number of glucosyl units was increased, ｜βμ｜ values of the barbituric and thiobarbituric acid derivatives were both enhanced, especially for thiobarbituric acid derivatives. It indicates that non-conjugated substituted group could also improve NLO properties of materials when the number of repeated units was increased. Additionally, the absorption bands appearing in UV area are consistent with the proper change of the number of glucosyl units, and consequently it can be concluded that the high transparencies of all systems were scarcely varied.展开更多
基金Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 40906088)the National Natural Science Foundation of China (Grant No. 60971067)Specialised Research Fund for the Doctoral Program of Higher Education (Grant No. 200804231021)
文摘Backscattered fields from one-dimensional time-varying Gerstners sea surface are calculated utilising the secondorder small slope approximation. It is well known that spectral properties of the backscattered echoes relate to the velocity of the small elementary scatterers on sea surface profiles. Therefore, modeling Doppler spectra from the ocean requires an accurate description of the sea surface motion. The profile of nonlinear Gerstners sea surface shows verticalskewness of sea waves, it is sharper at the crest and flatter at the trough than linear waves, and its maximum slope position is closer to the crest than to the trough. Furthermore, the horizontal component of the small elementary scatterers orbit velocity on the sea surface, which yields noticeable influence on Doppler spectra, can be obtained conveniently by Gerstners sea surface model. In this study the characteristics of Doppler spectra of backscattered fields from time-varying Gerstners sea surface are investigated and the dependences of the Doppler frequency and the Doppler bandwidth on the parameters, such as the wind speed, the radar frequency, the incident angle, etc. are discussed. It is shown that the Doppler bandwidth of microwave scattered fields from Gerstners sea surface is considerably broadened. For the case of high frequency backscattered fields, the values of the higher-order spectrum peaks are larger than those obtained by linear sea surface.
基金This project was funded by the National Natural Science Foundation of China
文摘A method using group-induced second-order long waves(GSLW) to represent statistical properties of wave groups with double-peaked spectra is put forward in this paper on the basis of the GSLW theory. The GSLW is regarded as a weighted linear superimposition of the second-order long Wave induced by the low peak frequency section and that induced by the high peak frequency section. There is a parabolic relationship between the GSLW and the wave envelope. Then the probability density function and the distribution function of the GSLW amplitude are derived. Thus the formulas for the average time duration and the mean length of runs can be derived. Good agreement between theoretical results and measured values was achieved. as verified with the measured double-peaked spectra in different regions.
基金thanks to the Austrian grant(ASO)SK-06/07-14/2007the Faculty of Mediccine Research Fund(University of Pécs)AOK-KA-213/20.
文摘UV-VIS spectroscopic investigations of interaction of bovine and human serum albumin with selected chalcones (1) and their cyclic chalcone analogues: (E)-2-(4’-X-benzylidene-1-tetralones (3), benzosuberones (4) with dimethylamino and methoxy substituents and (E)-2-(2’,4’-dimethox- ybenzylidene)-1-indanone (2) were performed in polar respiration medium. Absorption maxima of the tested compounds were investigated in the presence of bovine and human serum albumin at the 0, 10, 30 and 60 minute timepoints of the interaction. The absorbance of all studied compounds in the presence of proteins decreased after one hour of the reaction. Molecule 4a showed the strongest and fastest kinet initial interaction with both albumins.
基金Project supported bythe National Natural Science Foundation of China （No.20162005）, and the Trans-century Programme Foundation for the Talents by the State Education Commission of China （No. [2001]3）.
文摘AMI semi-empirical method was used to optimize the barbituric acid derivatives substituted with glucosyl B1-5 （series B）, and the thiobarbituric acid derivatives substituted with glucosyl T1-5 （series T）. Based on the optimized structures, INDO/CI method was adopted to calculate the electronic spectra. Meanwhile, the second-order nonlinear optical （NLO） coefficients βμ were calculated with the sum-over-state （SOS） formula. The results show that when the number of glucosyl units was increased, ｜βμ｜ values of the barbituric and thiobarbituric acid derivatives were both enhanced, especially for thiobarbituric acid derivatives. It indicates that non-conjugated substituted group could also improve NLO properties of materials when the number of repeated units was increased. Additionally, the absorption bands appearing in UV area are consistent with the proper change of the number of glucosyl units, and consequently it can be concluded that the high transparencies of all systems were scarcely varied.
