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Dynamic Characteristics Analysis on MHTGR Plant’s Secondary Side Fluid Flow Network 被引量:1
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作者 Maoxuan Song Zhe Dong 《Journal of Power and Energy Engineering》 2016年第7期15-22,共8页
Multipe NSSS (Nuclear Steam Supply System) modules use the common feeding-water system to drive the common turbine power generation set. The SSFFN (secondary side fluid flow network) of MHTGR plant has features i.e. s... Multipe NSSS (Nuclear Steam Supply System) modules use the common feeding-water system to drive the common turbine power generation set. The SSFFN (secondary side fluid flow network) of MHTGR plant has features i.e. strong-coupling and nonlinearity. A wide range of power switching operation will cause unsteady flow, which may destroy the working elements and will be a threat for normal operation. To overcome those problems, a differential-algebraic model and PI controllers are designed for the SSFFN. In MATLAB\SIMULINK environment, a simulation platform is established and used to make a simulation of SSFFN of a MHTGR plant with two NSSS modules, which uses feedwater valves to control the mass flow rate in each module instead of feedwater pump. Results reflect good robustness of controllers. 展开更多
关键词 MHTGR Plant secondary side Fluid Flow Network a Differential-Algebraic Model PI Controllers
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Analysis of secondary flow in shell-side channel of trisection helix heat exchangers 被引量:3
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作者 王伟晗 陈亚平 +1 位作者 操瑞兵 施明恒 《Journal of Southeast University(English Edition)》 EI CAS 2010年第3期426-430,共5页
The flow characteristics of shell-side fluid in the tube-and-shell heat exchangers with trisection helical baffles with 35° inclined angles are numerically analyzed. The secondary flow distribution of the fluid i... The flow characteristics of shell-side fluid in the tube-and-shell heat exchangers with trisection helical baffles with 35° inclined angles are numerically analyzed. The secondary flow distribution of the fluid in the shell-side channel is focused on. The results on meridian planes indicate that in the shell-side channel, the center part of fluid has an outward tendency because of the centrifugal force, and the peripheral region fluid has an inward tendency under the centripetal force. So in a spiral cycle, the fluid is divided into the upper and lower beams of streamlines, at the same time the Dean vortices are formed near the left baffle, and then the fluid turns to centripetal flow near the right baffle. Finally the two beams of streamlines merge in the main flow. The results of a number of parallel slices between two parallel baffles with the same sector in a swirl cycle also show the existence of the secondary flow and some backward flows at the V-gaps of the adjacent baffles. The secondary flows have a positive effect on mixing fluid by promoting the momentum and mass exchange between fluid particles near the tube wall and in the main stream, and thus they will enhance the heat transfer of the helix heat exchanger. 展开更多
关键词 trisection helix heat exchangers secondary flow Dean vortices heat transfer enhancement flow field analysis
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Numerical research on adverse effect of muzzle flow formed by muzzle brake considering secondary combustion 被引量:6
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作者 Peng-fei Li Xiao-bing Zhang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2021年第4期1178-1189,共12页
The simulation of the artillery interior and intermediate ballistics problem is performed to investigate the influence of a gas dynamics device,muzzle brake,on the muzzle hazard phenomena,such as flash and blast waves... The simulation of the artillery interior and intermediate ballistics problem is performed to investigate the influence of a gas dynamics device,muzzle brake,on the muzzle hazard phenomena,such as flash and blast waves.The correlation of the chemical reactions with the characteristics of the muzzle flow field is analyzed by the simulation for a further understanding of the secondary combustion phenomenon of the muzzle flow.The novel structure of muzzle flow caused by the muzzle brake is presented by the simultaneous solution of the interior ballistics model and multi-species Navier-Stokes equations in order to analyze the influence of the muzzle brake structure on the chemical reactions.The secondary combustion of the muzzle flow due to the oxygen-supplement chemical reactions is obtained by the chemical reaction kinetic model.The interaction of the blast waves released from the muzzle brake is illustrated in detail and the mechanism of the formation of muzzle flash is analyzed.This research provides a reference for the studies on the suppression of the muzzle flash. 展开更多
关键词 Muzzle flow Muzzle brake secondary combustion Chemical reaction
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Primary and secondary consolidation compression for saturated soil considering coupling effect of loading and heating 被引量:2
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作者 DENG Yue-bao MAO Wei-yun +1 位作者 KONG Gang-qiang HAN Yi-dong 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第8期2514-2526,共13页
Geotechnical engineering that relates to the energy and environmental problem is receiving more and more attention worldwide.It is of great theoretical and practical value to study the properties of soil under thermal... Geotechnical engineering that relates to the energy and environmental problem is receiving more and more attention worldwide.It is of great theoretical and practical value to study the properties of soil under thermal mechanical coupling and its mathematical description.Firstly,based on the general function,a unified primary and secondary consolidation model of saturated soil considering heating temperature is deduced.Combining the existing research achievements,a practical model is obtained which comprehensively reflects the effective stress change,creep and heating effects.After that,a series of thermo-consolidation tests are carried out using a temperature controlled consolidation instrument to study the effects of effective stress,temperature and consolidation duration on saturated soils.The corresponding functional formulas and parameters are obtained thusly.On this basis,the calculation and analysis are carried out to check the reliability and applicability of the newly proposed model.The new model is simple and practical and the parameters are easy to be obtained.And it describes the main law of consolidation compression of saturated soils under the thermal mechanical coupling effect.Therefore,it is suggested for theoretical analysis of thermal geotechnical engineering problems. 展开更多
关键词 soft soil primary consolidation secondary consolidation temperature effect consolidation compression test
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Strigolactones modulate cotton fiber elongation and secondary cell wall thickening 被引量:2
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作者 Yunze Wen Peng He +3 位作者 Xiaohan Bai Huizhi Zhang Yunfeng Zhang Jianing Yu 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第6期1850-1863,共14页
Cotton is one of the most important economic crops in the world,and it is a major source of fiber in the textile industry.Strigolactones(SLs)are a class of carotenoid-derived plant hormones involved in many processes ... Cotton is one of the most important economic crops in the world,and it is a major source of fiber in the textile industry.Strigolactones(SLs)are a class of carotenoid-derived plant hormones involved in many processes of plant growth and development,although the functions of SL in fiber development remain largely unknown.Here,we found that the endogenous SLs were significantly higher in fibers at 20 days post-anthesis(DPA).Exogenous SLs significantly increased fiber length and cell wall thickness.Furthermore,we cloned three key SL biosynthetic genes,namely GhD27,GhMAX3,and GhMAX4,which were highly expressed in fibers,and subcellular localization analyses revealed that GhD27,GhMAX3,and GhMAX4 were localized in the chloroplast.The exogenous expression of GhD27,GhMAX3,and GhMAX4 complemented the physiological phenotypes of d27,max3,and max4 mutations in Arabidopsis,respectively.Knockdown of GhD27,GhMAX3,and GhMAX4 in cotton resulted in increased numbers of axillary buds and leaves,reduced fiber length,and significantly reduced fiber thickness.These findings revealed that SLs participate in plant growth,fiber elongation,and secondary cell wall formation in cotton.These results provide new and effective genetic resources for improving cotton fiber yield and plant architecture. 展开更多
关键词 STRIGOLACTONES fiber elongation secondary cell wall thickening COTTON
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The secondary injury cascade after spinal cord injury:an analysis of local cytokine/chemokine regulation 被引量:1
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作者 Daniel J.Hellenbrand Charles M.Quinn +8 位作者 Zachariah J.Piper Ryan T.Elder Raveena R.Mishra Taylor L.Marti Phoebe M.Omuro Rylie M.Roddick Jae Sung Lee William L.Murphy Amgad S.Hanna 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第6期1308-1317,共10页
After spinal cord injury,there is an extensive infiltration of immune cells,which exacerbates the injury and leads to further neural degeneration.Therefore,a major aim of current research involves targeting the immune... After spinal cord injury,there is an extensive infiltration of immune cells,which exacerbates the injury and leads to further neural degeneration.Therefore,a major aim of current research involves targeting the immune response as a treatment for spinal cord injury.Although much research has been performed analyzing the complex inflammatory process following spinal cord injury,there remain major discrepancies within previous literature regarding the timeline of local cytokine regulation.The objectives of this study were to establish an overview of the timeline of cytokine regulation for 2 weeks after spinal cord injury,identify sexual dimorphisms in terms of cytokine levels,and determine local cytokines that significantly change based on the severity of spinal cord injury.Rats were inflicted with either a mild contusion,moderate contusion,severe contusion,or complete transection,7 mm of spinal cord centered on the injury was harvested at varying times post-injury,and tissue homogenates were analyzed with a Cytokine/Chemokine 27-Plex assay.Results demonstrated pro-inflammatory cytokines including tumor necrosis factorα,interleukin-1β,and interleukin-6 were all upregulated after spinal cord injury,but returned to uninjured levels within approximately 24 hours post-injury,while chemokines including monocyte chemoattractant protein-1 remained upregulated for days post-injury.In contrast,several anti-inflammatory cytokines and growth factors including interleukin-10 and vascular endothelial growth factor were downregulated by 7 days post-injury.After spinal cord injury,tissue inhibitor of metalloproteinase-1,which specifically affects astrocytes involved in glial scar development,increased more than all other cytokines tested,reaching 26.9-fold higher than uninjured rats.After a mild injury,11 cytokines demonstrated sexual dimorphisms;however,after a severe contusion only leptin levels were different between female and male rats.In conclusion,pro-inflammatory cytokines initiate the inflammatory process and return to baseline within hours post-injury,chemokines continue to recruit immune cells for days post-injury,while anti-inflammatory cytokines are downregulated by a week post-injury,and sexual dimorphisms observed after mild injury subsided with more severe injuries.Results from this work define critical chemokines that influence immune cell infiltration and important cytokines involved in glial scar development after spinal cord injury,which are essential for researchers developing treatments targeting secondary damage after spinal cord injury. 展开更多
关键词 ASTROCYTES CHEMOKINES cytokines inflammation macrophages MICROGLIA secondary damage spinal cord injury
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Thrust Characteristics Analysis of Long Primary Double Sided Linear Induction Machine with Plate and Novel Shuttle Secondary Structure
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作者 LIU Huijuan ZHANG Qian MA Jiefang 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2019年第5期693-702,共10页
The air-gap flux density formula and thrust expression of long primary double sided linear induction machine(DLIM)in the secondary motion reference frame are deduced by using the Maxwell equations firstly.Then,by anal... The air-gap flux density formula and thrust expression of long primary double sided linear induction machine(DLIM)in the secondary motion reference frame are deduced by using the Maxwell equations firstly.Then,by analyzing the factors that affect the thrust ripple in the thrust expression,a shuttle type secondary structure of long primary DLIMs is proposed,and its thrust performances of the machine with different shuttle size combinations are simulated and compared with that of plate secondary long primary DLIM.Comparison results show that the new secondary structure can suppress the thrust ripple and improve the stability of system acceleration. 展开更多
关键词 LINEAR induction machine LONG PRIMARY RIPPLE end effect SHUTTLE secondary
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Formation and Development of a Mountain-induced Secondary Center inside Typhoon Morakot(2009)
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作者 Xuwei BAO Leiming MA +2 位作者 Jianyong LIU Jie TANG Jing XU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2018年第9期1160-1176,共17页
The structural evolution of Typhoon Morakot(2009) during its passage across Taiwan was investigated with the WRF model. When Morakot approached eastern Taiwan, the low-level center was gradually filled by the Centra... The structural evolution of Typhoon Morakot(2009) during its passage across Taiwan was investigated with the WRF model. When Morakot approached eastern Taiwan, the low-level center was gradually filled by the Central Mountain Range(CMR), while the outer wind had flowed around the northern tip of the CMR and met the southwesterly monsoon to result in a strong confluent flow over the southern Taiwan Strait. When the confluent flow was blocked by the southern CMR, a secondary center(SC) without a warm core formed over southwestern Taiwan. During the northward movement of the SC along the west slope of the CMR, the warm air produced within the wake flow over the northwestern CMR was continuously advected into the SC, contributing to the generation of a warm core inside the SC. Consequently, a well-defined SC with a warm core, closed circulation and almost symmetric structure was produced over central western Taiwan, and then it coupled with Morakot's mid-level center after crossing the CMR to reestablish a new and vertically stacked typhoon. Therefore, the SC inside Morakot was initially generated by a dynamic interaction among the TC's cyclonic wind, southwesterly wind and orographic effects of the CMR, while the thermodynamic process associated with the downslope adiabatic warming effect documented by previous studies supported its development to be a well-defined SC. In summary, the evolution of the SC in this study is not in contradiction with previous studies, but just a complement, especially in the initial formation stage. 展开更多
关键词 secondary center OROGRAPHY dynamics Typhoon Morakot (2009)
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Secondary diabetes due to different etiologies:Four case reports 被引量:1
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作者 Wen-Rong Song Xiao-Hong Xu +2 位作者 Jia Li Jia Yu Yan-Xiong Li 《World Journal of Clinical Cases》 SCIE 2024年第16期2813-2821,共9页
BACKGROUND As research on diabetes continues to advance,more complex classifications of this disease have emerged,revealing the existence of special types of diabetes,and many of these patients are prone to misdiagnos... BACKGROUND As research on diabetes continues to advance,more complex classifications of this disease have emerged,revealing the existence of special types of diabetes,and many of these patients are prone to misdiagnosis and underdiagnosis,leading to treatment delays and increased health care costs.The purpose of this study was to identify four causes of secondary diabetes.CASE SUMMARY Secondary diabetes can be caused by various factors,some of which are often overlooked.These factors include genetic defects,autoimmune disorders,and diabetes induced by tumours.This paper describes four types of secondary diabetes caused by Williams–Beuren syndrome,Prader–Willi syndrome,pituitary adenoma,and IgG4-related diseases.These cases deviate significantly from the typical progression of the disease due to their low incidence and rarity,often leading to their neglect in clinical practice.In comparison to regular diabetes patients,the four individuals described here exhibited distinct characteristics.Standard hypoglycaemic treatments failed to effectively control the disease.Subsequently,a series of examinations and follow-up history confirmed the diagnosis and underlying cause of diabetes.Upon addressing the primary condition,such as excising a pituitary adenoma,providing glucocorticoid supplementation,and implementing symptomatic treatments,all patients experienced a considerable decrease in blood glucose levels,which were subsequently maintained within a stable range.Furthermore,other accompanying symptoms improved.CONCLUSION Rare diseases causing secondary diabetes are often not considered in the diag-nosis of diabetes.Therefore,it is crucial to conduct genetic tests,antibody detection and other appropriate diagnostic measures when necessary to facilitate early diagnosis and intervention through proactive and efficient management of the underlying condition,ultimately improving patient outcomes. 展开更多
关键词 secondary diabetes IgG4-associated diseases Williams–Beuren syndrome Pituitary adenoma Prader-Willi syndrome Genetic defects Case report
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Consideration of the Self-Care Supporting Program Including Simple Exercise for Patients with Early Stages of Secondary Lower-Limb Lymphedema
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作者 Chitose Arakawa Chiharu Akazawa Sayoko Teraguchi 《Health》 2021年第3期238-252,共15页
<strong>Aim: </strong>We devised a self-care supporting program targeting patients with early stages of secondary lower-limb lymphedema. The program incorporates “Simple exercises to replace lymphatic dra... <strong>Aim: </strong>We devised a self-care supporting program targeting patients with early stages of secondary lower-limb lymphedema. The program incorporates “Simple exercises to replace lymphatic drainage” based on lymphatic flow. The purpose of this study was to consider the feasibility of continuing this program. <strong>Methods:</strong> The participants were patients in the early stages of secondary lower-limb lymphedema after gynecological cancer surgery and lymphedema therapists with more than five years of experience. Patients continued self-care at home after being briefed on the program, and they were analyzed on their self-care continuity status one month later based on a self-administered questionnaire survey and self-care notes. We interviewed the lymphedema therapists about this program to discuss the feasibility of continuing it and obtain feedback. <strong>Results:</strong> The patients who participated in the study were six women who underwent surgery with lymph node dissection for gynecological cancer. The therapists were five nurses and one occupational therapist. The patient understood the importance of all items in the self-care. “Observation,” “Touching,” and “Skin care” were relatively easy to continue. “Lymph drainage” and “Exercise” were continued with “Simple exercises to replace lymphatic drainage”. “Other exercises” were able to continue by adding distance and time to daily activities. Furthermore, “Measurement” and “Recording” became a burden and were difficult to continue. Nonetheless, this program was generally approved by the lymphedema therapists. They also pointed out the content and format of the self-care notes as improvements. <strong>Conclusions: </strong>We found that the self-care supporting program that incorporated “Simple exercises to replace lymphatic drainage” might be feasible to continue self-care for patients with early stages of secondary lower-limb lymphedema. Furthermore, we found that we needed to improve the “Measurement” and “Recording” sections of this program. 展开更多
关键词 secondary Lower-Limb Lymphedema Early Stages Self-Care Supporting Program Lymphatic Drainage Exercises
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Overstory functional groups indicate the legacy of land use in a secondary tropical forest in southwestern China
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作者 Yun Deng Wenfu Zhang +9 位作者 Min Cao Jinlong Dong Hui Chen Xiaobao Deng Jiajia Liu Xiaoyang Song Shangwen Xia Liqing Sha Shengdong Yuan Luxiang Lin 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第5期91-105,共15页
Anthropogenic disturbances are widespread in tropical forests and influence the species composition in the overstory.However,the impacts of historical disturbance on tropical forest overstory recovery are unclear due ... Anthropogenic disturbances are widespread in tropical forests and influence the species composition in the overstory.However,the impacts of historical disturbance on tropical forest overstory recovery are unclear due to a lack of disturbance data,and previous studies have focused on understory species.In this study,the purpose was to deter-mine the influence of historical disturbance on the diver-sity,composition and regeneration of overstory species in present forests.In the 20-ha Xishuangbanna tropical sea-sonal rainforest dynamics plot in southwestern China,the historical disturbance boundaries were delineated based on panchromatic photographs from 1965.Factors that drove species clustering in the overstory layer(DBH≥40 cm)were analyzed and the abundance,richness and composition of these species were compared among different tree groups based on multiple regression tree analysis.The coefficient of variation of the brightness value in historical panchro-matic photographs from 1965 was the primary driver of spe-cies clustering in the overstory layer.The abundance and richness of overstory species throughout the regeneration process were similar,but species composition was always different.Although the proportion of large-seeded and vigorous-sprouting species showed no significant differ-ence between disturbed and undisturbed forests in the tree-let layer(DBH<20 cm),the difference became significant when DBH increased.The findings highlight that historical disturbances have strong legacy effects on functional group composition in the overstory and the recovery of overstory species was multidimensional.Functional group composi-tion can better indicate the dynamics of overstory species replacement during secondary succession. 展开更多
关键词 Historical disturbance Legacy effects secondary forests Overstory species Functional groups
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Contrast in Secondary Organic Aerosols between the Present Day and the Preindustrial Period:The Importance of Nontraditional Sources and the Changed Atmospheric Oxidation Capability
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作者 Yingchuan YANG Wenyi YANG +13 位作者 Xueshun CHEN Jiawen ZHU Huansheng CHEN Yuanlin WANG Wending WANG Lianfang WEI Ying WEI Qian YE Huiyun DU Zichen WU Zhe WANG Jie LI Xiaodong ZENG Zifa WANG 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第10期1936-1952,I0002-I0010,共26页
Quantifying differences in secondary organic aerosols(SOAs)between the preindustrial period and the present day is crucial to assess climate forcing and environmental effects resulting from anthropogenic activities.Th... Quantifying differences in secondary organic aerosols(SOAs)between the preindustrial period and the present day is crucial to assess climate forcing and environmental effects resulting from anthropogenic activities.The lack of vegetation information for the preindustrial period and the uncertainties in describing SOA formation are two leading factors preventing simulation of SOA.This study calculated the online emissions of biogenic volatile organic compounds(VOCs)in the Aerosol and Atmospheric Chemistry Model of the Institute of Atmospheric Physics(IAP-AACM)by coupling the Model of Emissions of Gases and Aerosols from Nature(MEGAN),where the input vegetation parameters were simulated by the IAP Dynamic Global Vegetation Model(IAP-DGVM).The volatility basis set(VBS)approach was adopted to simulate SOA formation from the nontraditional pathways,i.e.,the oxidation of intermediate VOCs and aging of primary organic aerosol.Although biogenic SOAs(BSOAs)were dominant in SOAs globally in the preindustrial period,the contribution of nontraditional anthropogenic SOAs(ASOAs)to the total SOAs was up to 35.7%.In the present day,the contribution of ASOAs was 2.8 times larger than that in the preindustrial period.The contribution of nontraditional sources of SOAs to SOA was as high as 53.1%.The influence of increased anthropogenic emissions in the present day on BSOA concentrations was greater than that of increased biogenic emission changes.The response of BSOA concentrations to anthropogenic emission changes in the present day was more sensitive than that in the preindustrial period.The nontraditional sources and the atmospheric oxidation capability greatly affect the global SOA change. 展开更多
关键词 IAP-AACM VBS MEGAN secondary organic aerosol anthropogenic and biogenic emissions
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Upregulation of the glycine-rich protein-encoding gene GhGRPL enhances plant tolerance to abiotic and biotic stressors by promoting secondary cell wall development
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作者 Wanting Yu Yonglu Dai +17 位作者 Junmin Chen Aimin Liang Yiping Wu Qingwei Suo Zhong Chen Xingying Yan Chuannan Wang Hanyan Lai Fanlong Wang Jingyi Zhang Qinzhao Liu Yi Wang Yaohua Li Lingfang Ran Jie Xiang Zhiwu Pei Yuehua Xiao Jianyan Zeng 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第10期3311-3327,共17页
Abiotic and biotic stressors adversely affect plant survival,biomass generation,and crop yields.As the global availability of arable land declines and the impacts of global warming intensify,such stressors may have in... Abiotic and biotic stressors adversely affect plant survival,biomass generation,and crop yields.As the global availability of arable land declines and the impacts of global warming intensify,such stressors may have increasingly pronounced effects on agricultural productivity.Currently,researchers face the overarching challenge of comprehensively enhancing plant resilience to abiotic and biotic stressors.The secondary cell wall plays a crucial role in bolstering the stress resistance of plants.To increase plant resistance to stress through genetic manipulation of the secondary cell wall,we cloned a cell wall protein designated glycine-rich protein-like(GhGRPL)from cotton fibers,and found that it is specifically expressed during the period of secondary cell wall biosynthesis.Notably,this protein differs from its Arabidopsis homolog,AtGRP,since its glycine-rich domain is deficient in glycine residues.GhGRPL is involved in secondary cell wall deposition.Upregulation of GhGRPL enhances lignin accumulation and,consequently,the thickness of the secondary cell walls,thereby increasing the plant’s resistance to abiotic stressors,such as drought and salinity,and biotic threats,including Verticillium dahliae infection.Conversely,interference with GhGRPL expression in cotton reduces lignin accumulation and compromises that resistance.Taken together,our findings elucidate the role of GhGRPL in regulating secondary cell wall development through its influence on lignin deposition,which,in turn,reinforces cell wall robustness and impermeability.These findings highlight the promising near-future prospect of adopting GhGRPL as a viable,effective approach for enhancing plant resilience to abiotic and biotic stress factors. 展开更多
关键词 glycine-rich protein-like secondary cell wall abiotic stress biotic stress stress resistance
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Promoting role of Ru species on Ir-Fe/BN catalyst in 1,2-diols hydrogenolysis to secondary alcohols
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作者 Ben Liu Yoshinao Nakagawa +1 位作者 Mizuho Yabushita Keiichi Tomishige 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第10期89-102,共14页
Noble metal-based-bimetallic catalysts have been highly investigated and applied in wide applications including biomass transformation via regioselective C−O hydrogenolysis while further modification especially with n... Noble metal-based-bimetallic catalysts have been highly investigated and applied in wide applications including biomass transformation via regioselective C−O hydrogenolysis while further modification especially with noble metal is highly promising yet still under investigation.Herein,Ru was found as an effective modifier among the screened noble metals(Ru,Pt,Rh,Pd,Au,and Ag)for Ir-Fe/BN(Ir=5 wt%,Fe/Ir=0.25)catalyst in terminal C−O hydrogenolysis of 1,2-butanediol(1,2-BuD)to 2-butanol(2-BuOH).Only trace amount of Ru(up to 0.5 wt%)was effective in terms of high 2-BuOH selectivity(>60%)and activity(about twice).Larger amount of Ru species(3 wt%)highly enhanced the activity but gave low selectivity to 2-BuOH with by-products of terminal C−C bond scission.Optimized catalyst(Ru(0.5)-Ir-Fe/BN)was reusable at least 4 times and gave moderate 2-BuOH yield(47%)in hydrogenolysis of 1,2-BuD.The promoting effect of Ru addition(0.5 wt%)to Ir-Fe/BN on hydrogenolysis of various alcohols was also confirmed.Combining catalytic tests with various characterizations,the promotion mechanism of Ru species in trimetallic catalysts was clarified.The Ru species in Ru(0.5)-Ir-Fe/BN form alloy with Ir and are enriched at the interface with BN surface,and direct interaction between Ru and Fe was not necessary in Ru-Ir-Fe alloy.The interface of Ir and Fe on the surface of Ir-Fe alloy may work as active sites for 1,2-diols to secondary alcohols via direct C−O hydrogenolysis,in which Ru-modified Ir activates H_(2) to form hydride-like species.The activity of Ru species in C−C bond cleavage was highly suppressed due to the direct interaction with Ir species and less exposed to substrate.Larger loading amount of Ru species(3 wt%)led to the formation Ru-rich trimetallic alloy,which further works as active sites for C−C bond scission. 展开更多
关键词 Biomass-based polyols secondary alcohol HYDRODEOXYGENATION Trimetallic alloy Boron nitride
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A spatiotemporal evolution model of a short-circuit arc to a secondary arc based on the improved charge simulation method
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作者 丛浩熹 王宇轩 +2 位作者 乔力盼 苏文晶 李庆民 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第1期62-73,共12页
The initial shape of the secondary arc considerably influences its subsequent shape.To establish the model for the arcing time of the secondary arc and modify the single-phase reclosing sequence,theoretical and experi... The initial shape of the secondary arc considerably influences its subsequent shape.To establish the model for the arcing time of the secondary arc and modify the single-phase reclosing sequence,theoretical and experimental analysis of the evolution process of the short-circuit arc to the secondary arc is critical.In this study,an improved charge simulation method was used to develop the internal-space electric-field model of the short-circuit arc.The intensity of the electric field was used as an independent variable to describe the initial shape of the secondary arc.A secondary arc evolution model was developed based on this model.Moreover,the accuracy of the model was evaluated by comparison with physical experimental results.When the secondary arc current increased,the arcing time and dispersion increased.There is an overall trend of increasing arc length with increasing arcing time.Nevertheless,there is a reduction in arc length during arc ignition due to short circuits between the arc columns.Furthermore,the arcing time decreased in the range of 0°-90°as the angle between the wind direction and the x-axis increased.This work investigated the method by which short-circuit arcs evolve into secondary arcs.The results can be used to develop the secondary arc evolution model and to provide both a technical and theoretical basis for secondary arc suppression. 展开更多
关键词 short-circuit arc secondary arc STOCHASTICITY improved charge simulation method arc time
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Separation of halogens and recovery of heavy metals from secondary copper smelting dust
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作者 Zhi-lou LIU Zhi-kang CHEN +7 位作者 Fu-ze SUN Zhi-heng ZHANG Kang YAN Shui-ping ZHONG Hui LIU Rui-xiang WANG Jia-yuan LI Zhi-feng XU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第8期2686-2701,共16页
The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasib... The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasibility of the phase transformation to metal sulfates and to gaseous HF and HCl.Under the sulfating roasting conditions of the roasting temperature of 250℃ and the sulfuric acid excess coefficient of 1.8,over 74 wt.%of F and 98 wt.%of Cl were volatilized into flue gas.Approximately 98.6 wt.%of Zn and 96.5 wt.%of Cu in the roasting product were dissolved into the leaching solution after the water leaching process,while the leaching efficiencies of Pb and Sn were only 0.12%and 0.22%,respectively.The mechanism studies indicate the pivotal effect of roasting temperature on the sulphation reactions from various metal species to metal sulfates and the salting out reactions from various metal halides to gaseous hydrogen halides. 展开更多
关键词 secondary copper smelting dust sulfating roasting water leaching halogen volatilization heavy metal separation
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Experimental study on secondary air mixing along the bed height in a circulating fluidized bed with a multitracer-gas method
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作者 Qingyu Zhang Leming Cheng +3 位作者 Kun Li Qixun Kang Qiang Guo Chaogang Wu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第6期54-62,共9页
A multitracer-gas method was proposed to study the secondary air(SA)mixing along the bed height in a circulating fluidized bed(CFB)using carbon monoxide(CO),oxygen(O_(2)),and carbon dioxide(CO_(2))as tracer gases.Expe... A multitracer-gas method was proposed to study the secondary air(SA)mixing along the bed height in a circulating fluidized bed(CFB)using carbon monoxide(CO),oxygen(O_(2)),and carbon dioxide(CO_(2))as tracer gases.Experiments were carried out on a cold CFB test rig with a cross-section of 0.42 m×0.73 m and a height of 5.50 m.The effects of superficial velocity,SA ratio,bed inventory,and particle diameter on the SA mixing were investigated.The results indicate that there are some differences in the measurement results obtained using different tracer gases,wherein the deviation between CO and CO_(2) ranges from 42%to 66%and that between O_(2) and CO_(2) ranges from 45%to 71%in the lower part of the fluidized bed.However,these differences became less pronounced as the bed height increased.Besides,the high solid concentration and fine particle diameter in the CFB may weaken the difference.The measurement results of different tracer gases show the same trends under the variation of operating parameters.Increasing superficial velocity and SA ratio and decreasing particle diameter result in better mixing of the SA.The effect of bed inventory on SA mixing is not monotonic. 展开更多
关键词 Circulating fluidized bed secondary air injection Gas mixing Multitracer-gas method
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Roles of Upper-Level Descending Inflow in Moat Development in Simulated Tropical Cyclones with Secondary Eyewall Formation
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作者 Nannan QIN Liguang WU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第6期1100-1114,共15页
This study investigated the effects of upper-level descending inflow(ULDI)associated with inner-eyewall convection on the formation of the moat in tropical cyclones(TCs)with secondary eyewall formation(SEF).In our num... This study investigated the effects of upper-level descending inflow(ULDI)associated with inner-eyewall convection on the formation of the moat in tropical cyclones(TCs)with secondary eyewall formation(SEF).In our numerical experiments,a clear moat with SEF occurred in TCs with a significant ULDI,while no SEF occurred in TCs without a significant ULDI.The eyewall convection developed more vigorously in the control run.A ULDI occurred outside the inner-eyewall convection,where it was symmetrically unstable.The ULDI was initially triggered by the diabatic warming released by the inner eyewall and later enhanced by the cooling below the anvil cloud.The ULDI penetrated the outer edge of the inner eyewall with relatively dry air and prevented excessive solid-phase hydrometeors from being advected further outward.It produced extensive sublimation cooling of falling hydrometeors between the eyewall and the outer convection.The sublimation cooling resulted in negative buoyancy and further induced strong subsidence between the eyewall and the outer convection.As a result,a clear moat was generated.Development of the moat in the ongoing SEF prevented the outer rainband from moving farther inward,helping the outer rainband to symmetrize into an outer eyewall.In the sensitivity experiment,no significant ULDI formed since the eyewall convection was weaker,and the eyewall anvil developed relatively lower,meaning the formation of a moat and thus an outer eyewall was less likely.This study suggests that a better-represented simulation of inner-eyewall convective structures and distribution of the solid-phase hydrometeors is important to the prediction of SEF. 展开更多
关键词 tropical cyclone secondary eyewall formation upper-level descending inflow eyewall convection
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Highly divergent sympatric lineages of Leptotila verreauxi(Aves:Columbidae)suggest a secondary contact area in the Isthmus of Tehuantepec,Mexico
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作者 Orlando J.Espinosa-Chávez Adolfo G.Navarro-Sigüenza +1 位作者 Hernando Rodríguez-Correa Luis A.Sánchez-González 《Avian Research》 SCIE CSCD 2024年第1期12-21,共10页
Due to a complex geological and biotic history,the Isthmus of Tehuantepec(IT),has been long recognized as a driver for the evolutionary divergence of numerous lowland and highland taxa.Widely distributed in the lowlan... Due to a complex geological and biotic history,the Isthmus of Tehuantepec(IT),has been long recognized as a driver for the evolutionary divergence of numerous lowland and highland taxa.Widely distributed in the lowlands of the American continent,the White-Tipped Dove(Leptotila verreauxi)is a polytypic species with 13 recognized subspecies.Four of these have been recorded in Mexico,and the distribution of three abuts at the IT,suggesting a contact zone.To estimate phylogenetic patterns,divergence times and genetic differentiation,we examined two mt DNA(ND2 and COI)and one n DNA(β-fibint 7)markers.We also used correlative ecological niche models(ENM)to assess whether ecological differences across the IT may have acted as a biogeographical boundary.We estimated paleodistributions during the Middle Holocene,Last Glacial Maximum and Last Interglacial,to evaluate the influence of climate changes on the distribution and demographic changes.Our results showed genetically distinct lineages that diverged approximately 2.5 million years ago.Climatic and ecological factors may have played a dual role in promoting differentiation,but also in the formation of a secondary contact zone in the southern IT.Our ecological niche comparisons indicated that the ecological niche of sympatric lineages at the IT are not identical,suggesting niches divergence;in addition,environmental niche models across the region indicated no abrupt biogeographic barriers,but the presence of regions with low suitability.These results suggest that genetic differentiation originated by a vicariant event probably related to environmental factors,favored the evolution of different ecological niches.Also,the absence of a biogeographic barrier but the presence of less suitable areas in the contact regions,suggest that secondary contact zones may be also maintained by climatic factors for the eastern group,but also by biotic interactions for the western group. 展开更多
关键词 Biogeographical boundary Humid and dry forests Isthmus of Tehuantepec PHYLOGEOGRAPHY secondary contact
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Optimal Cooperative Secondary Control for Islanded DC Microgrids via a Fully Actuated Approach
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作者 Yi Yu Guo-Ping Liu +1 位作者 Yi Huang Peng Shi 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第2期405-417,共13页
DC-DC converter-based multi-bus DC microgrids(MGs) in series have received much attention, where the conflict between voltage recovery and current balancing has been a hot topic. The lack of models that accurately por... DC-DC converter-based multi-bus DC microgrids(MGs) in series have received much attention, where the conflict between voltage recovery and current balancing has been a hot topic. The lack of models that accurately portray the electrical characteristics of actual MGs while is controller design-friendly has kept the issue active. To this end, this paper establishes a large-signal model containing the comprehensive dynamical behavior of the DC MGs based on the theory of high-order fully actuated systems, and proposes distributed optimal control based on this. The proposed secondary control method can achieve the two goals of voltage recovery and current sharing for multi-bus DC MGs. Additionally, the simple structure of the proposed approach is similar to one based on droop control, which allows this control technique to be easily implemented in a variety of modern microgrids with different configurations. In contrast to existing studies, the process of controller design in this paper is closely tied to the actual dynamics of the MGs. It is a prominent feature that enables engineers to customize the performance metrics of the system. In addition, the analysis of the stability of the closed-loop DC microgrid system, as well as the optimality and consensus of current sharing are given. Finally, a scaled-down solar and battery-based microgrid prototype with maximum power point tracking controller is developed in the laboratory to experimentally test the efficacy of the proposed control method. 展开更多
关键词 DC microgrids distributed control high-order fully actuated system approach linear quadratic regulator microgrid modeling secondary control
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