Aeromagnetic data over the Mamfe Basin have been processed. A regional magnetic gridded dataset was obtained from the Total Magnetic Intensity (TMI) data grid using a 3 × 3 convolution (Hanning) filter to remove ...Aeromagnetic data over the Mamfe Basin have been processed. A regional magnetic gridded dataset was obtained from the Total Magnetic Intensity (TMI) data grid using a 3 × 3 convolution (Hanning) filter to remove regional trends. Major similarities in magnetic field orientation and intensities were observed at identical locations on both the regional and TMI data grids. From the regional and TMI gridded datasets, the residual dataset was generated which represents the very shallow geological features of the basin. Processing this residual data grid using the Source Parameter Imaging (SPI) for magnetic depth suggests that the estimated depths to magnetic sources in the basin range from about 271 m to 3552 m. The highest depths are located in two main locations somewhere around the central portion of the study area which correspond to the area with positive magnetic susceptibilities, as well as the areas extending outwards across the eastern boundary of the study area. Shallow magnetic depths are prominent towards the NW portion of the basin and also correspond to areas of negative magnetic susceptibilities. The basin generally exhibits a variation in depth of magnetic sources with high, average and shallow depths. The presence of intrusive igneous rocks was also observed in this basin. This characteristic is a pointer to the existence of geologic resources of interest for exploration in the basin.展开更多
Sediment constitutes the fundamental basis for forming and evolving aeolian geomorphology.The characteristics of sediment particle size offer insights into the development and evolution of sandy terrain,making their s...Sediment constitutes the fundamental basis for forming and evolving aeolian geomorphology.The characteristics of sediment particle size offer insights into the development and evolution of sandy terrain,making their study critical to understanding aeolian geomorphology and sand control.In this study,we combined high-density collection of surface sediments in the Uzhumqin sand dunes and GIS spatial analysis to analyze the particle size parameters and changes in the spatial distribution of surface sediments in this region.In addition,we used an end-member analysis to identify the potential sources of the sediments.The results showed that surface sediments in the Uzhumqin sand dunes had distinct spatial distributions.Medium and coarse grain sands dominated the sediments in the dunes,and the mean grain size and the sorting coefficient generally increased along the prevailing wind direction,with high values in individual areas related to factors such as material sources and vegetation cover.Skewness was strongly influenced by factors such as landform change and human activity,and spatial variability became more complex.Kurtosis and the soil fractal dimension showed generally decreasing trends along the prevailing wind direction.With dune fixation,the contents of clay and powder particles in the soil increased;the mean particle size,the sorting coefficient,and the fractal dimension of the soil gradually increased,and the skewness and kurtosis gradually decreased.The end-member analysis results indicated the existence of five end-members(EM)in the dune sediments.EM 1 was a mixed component of wind-deposited fine sands and nearby fluvial sediments.EM 2 was the main component of sediments in the study area and was the result of sorting lake sediments by wind action and by the local topography.EM 3 may be a product of river flood deposition.EM 4 and EM 5 had coarser grain sizes.EM 4 was a lake-phase sediment product influenced by topographic and vegetation cover factors,and EM 5 was primarily a river and lake sediment product modified by weathering.The sediment particle size results from the study area indicate that the sediment in the sandy region is generally coarse due to multiple factors,including topography,climate,hydrology,and human activity.Sandy material in the study area originated from nearby,with very little sand being transported from long distances.展开更多
Zhanjiang Bay is a major aquaculture area in China with many types of mariculture products(such as oysters,fish,and shrimp).The culture area and shrimp output in Zhanjiang Bay are ranked first in China.We investigated...Zhanjiang Bay is a major aquaculture area in China with many types of mariculture products(such as oysters,fish,and shrimp).The culture area and shrimp output in Zhanjiang Bay are ranked first in China.We investigated the total organic carbon(TOC),total nitrogen(TN),TOC/TN ratio,and stable isotopes(δ^(13)C and δ^(15)N) of the fish and shrimp feed,fish and shrimp feces,and sedimentary organic matter(SOM) in and around different aquaculture areas of northeastern Zhanjiang B ay to study the impact of aquaculture activities on SOM.The average TOC contents of fish and shrimp feed were 39.20%±0.91% and 39.29%±0.21%,respectively.The average TOC content in the surface sediments of the oyster culture area,the mixed(fish and shrimp) culture area,and the cage fish farm area were 0.66%,0.88%±0.10%,and 0.58%±0.19%,respectively,which may indicate that mixed culture had a greater impact on SOM.The relatively high TOC and TN contents and relatively low TOC/TN ratios,and δ^(15)N values in the upper layer of the core sediment in the mixed culture area could also support the significant influence of mixed culture.The average δ^(13)C and δ^(15)N values of fish and shrimp feed were -20.6‰±2.2‰ and 1.8‰±1.2‰,respectively,which were different from the isotopic values of SOM in the study area.δ^(13)C and δ^(15)N values for SOM in different aquaculture areas were different from those of nearby reference stations,probably reflecting the influence of aquaculture.The δ^(13)C and δ^(15)N values in the oyster culture area(-25.9‰ and6.0‰,respectively) seemed to have reduced δ^(13)C and enriched δ^(15)N relative to those of the reference station(-24.6‰ and 5.8‰,respectively).This may reflect the influence of organic matter on oyster culture.The δ^(15)N value of the station in the mixed culture area(7.1‰±0.4‰) seemed to be relatively enriched in δ^(15)N relative to that of the reference station(6.6‰).Sedimentation and the subsequent degradation of organic matter from mixed cultures may have contributed to this phenomenon.The surface sediment at the cage fish farm area seemed to be affected by fish feces and primary production based on the indication of δ^(13)C and δ^(15)N values.The sediment core at the mixed culture region(NS6) had lower TOC/TN ratios and more positive δ^(13)C and δ^(15)N values than the sediment core at the oyster culture area,suggesting a higher proportionate contribution of marine organic matter in the mixed culture area.In summary,oyster culture,mixed culture,and cage fish culture in northeastern Zhanjiang Bay had a certain degree of impact on SOM,and mixed culture had more significant influences on SOM based on the high TOC contents and the significant vertical variations of TOC/TN ratio and δ^(15)N value in the sediment of this area.This study provides new insights into the impact of aquaculture activities on SOM content.展开更多
At present,there is a great demand for building materials in the market,and the market prospect of building materials is relatively considerable.Through studying the composition of river sediment and its resource util...At present,there is a great demand for building materials in the market,and the market prospect of building materials is relatively considerable.Through studying the composition of river sediment and its resource utilization in the field of building materials,this paper expounds the current domestic scholars research on river sediment in building materials,and summarizes the current problems and challenges,so as to provide a reference for the sustainable development of river sediment in the field of building materials.展开更多
XRF and EDX analyses were carried out on 18 batches of representative raw samples to determine the distribution of major chemical elements in the petroleum source rocks of Donga and Yogou formations of Termit sediment...XRF and EDX analyses were carried out on 18 batches of representative raw samples to determine the distribution of major chemical elements in the petroleum source rocks of Donga and Yogou formations of Termit sedimentary basin. The chemical composition of these formations is dominated by silicon (Si), aluminum (Al) and iron (Fe). This is consistent with the oxide composition, which is also dominated by silicon oxide (SiO2), aluminum oxide (Al<sub>2</sub>O<sub>3</sub>) and iron monoxide (FeO). No less important chemical elements are calcium (Ca), potassium (K), sulfur (S), titanium (Ti), magnesium (Mg), manganese (Mn) and barium (Ba), as well as some of their oxides. All these major chemical elements are carried by silicate detrital minerals associated with pyrite and goethite and/or clay minerals such as kaolinite and interstratified illite, smectite and chlorite. This trend is illustrated by the values of the Si/Al and SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratios.展开更多
The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment sourc...The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment source-to-sink process variations of such beaches and their morphological indications.The results show that the clay mineral assemblages of these SMT-Beaches mainly comprise of almost equal illite(~30%),kaolinite(~28%),chlorite(~22%),and smectite(~20%)contents.From the surrounding mountain rivers to the SMT-Beaches,clay mineral assemblages show distinct spatial changes characterized by a large decrease(~40%)in kaolinite,whereas the other three clay minerals present relative increases,especially clear for smectite.The muddy sediment sources of SMT-Beaches inferred from the clay mineralogy are mainly derived from nearby mountain rivers coupled with long-distance transport and penetration of the Changjiang River.The sandy sediments of these beaches are predominantly sourced from nearby mountain rivers,the weathering products of surrounding rocks in both mainland and island environments,and erosion of the“Old Red Sand”and“Red Soil Platform”.However,the sandy sediment sources of the SMT-Beaches are largely reduced because of the remarkable decrease in the river fluvial supply associated with intensive human activities such as dam construction and coastal reclamation.Subsequently,the sandy sections of SMT-Beaches present clear erosion and have revealed by both time series remote sensing images and a compilation of published literature.In contrast,the muddy sediment supply of SMT-Beaches is temporarily stable and relatively constant,resulting in the landward migration of the mudflats with relative transgression or accumulation.These findings highlight that the natural evolution processes of SMT-Beaches have been greatly reshaped by intensive human activities.展开更多
Soil erosion is a major issue in Loess Plateau,China,and quantitative analyses of sediment sources are crucial for soil erosion control.In this study,a combination of flood couplet analysis and composite fingerprint i...Soil erosion is a major issue in Loess Plateau,China,and quantitative analyses of sediment sources are crucial for soil erosion control.In this study,a combination of flood couplet analysis and composite fingerprint identification was used for historical reconstructions of soil erosion in sediment source areas in Loess Plateau.Each flood couplet was constructed based on sediment 137Cs activity,and past soil erosion was calculated using soil bulk density and storage capacity curves.The contribution rates of the sediment sources were calculated using the fingerprinting method,and the amount of erosion in the sediment source areas was estimated.The best fingerprint combination(Cr,Ni,V,and TOC)enabled a 97.2%recognition of sediment sources from 29 flood events(1956–1990)in the Loess Plateau.The contribution rates of gullies,farmland,grassland,and shrubland were 44.89%,26.38%,10.49%,and 18.24%,respectively.These four land use types contributed 1,227,751,512,and 279 tons of sediments,respectively.Re-vegetation decreased soil erosion(1966–1983),whereas deforestation increased soil erosion(1956–1965 and 1984–1990).Rational soil and water conservation measures on slopes and check dam construction in gullies are therefore suggested to mitigate erosion.展开更多
In this study, 30 sediment samples were collected from the lower reaches of the Shichuanhe River in Xi’an, Shaanxi Province, China, to test the distribution of heavy metal elements in this area and for an analysis of...In this study, 30 sediment samples were collected from the lower reaches of the Shichuanhe River in Xi’an, Shaanxi Province, China, to test the distribution of heavy metal elements in this area and for an analysis of the pollution levels of this area, hope to provide guidance on agricultural production activities in this region. The results show that the heavy metal elements in this area are mainly concentrated at the Qinghe River and Shichuanhe River confluences. Furthermore, the element contents are higher than that of the background levels of the continental crust(UCC) and close to the background levels of the soil from Shaanxi Province;the two most enriched elements are Cd and As, with contents of 0.79 and 22.7 mg·kg-1, respectively, and their contents are 3.8 and 1.72 times higher than that of the background values. Herein, the heavy metal pollution assessment methods applied indicated that Cd and As are the two most abundant pollutant elements in the area’s soils. As has a peak geo-accumulation index value of 3, and the pollution level is high, while Cd exhibits high potential ecological risks due to its high toxicity(potential risk index of 143) and an active fraction of more than 64%.In addition, a principal component analysis and hierarchical cluster analysis study showed that there are two sources of the heavy metals in this area. The Zn, As, Ni, Cu, Pb,and Cr are mainly from natural sources, and the Cd likely comes from a discharge of untreated agricultural wastewater in the region. The Cd which poses a high potential risk and mainly results from human activities, needs to be further monitored.展开更多
Polycyclic aromatic hydrocarbons (PAHs) are strongly associated with agricultural, residential, transportation, industrial and petroleum activities. In this study, the presence of PAHs (polycyclic aromatic hydrocarbon...Polycyclic aromatic hydrocarbons (PAHs) are strongly associated with agricultural, residential, transportation, industrial and petroleum activities. In this study, the presence of PAHs (polycyclic aromatic hydrocarbons) was investigated in sediments of the ivory coastal zone (Toukouzou Hozalem-Assinie). The main objectives of this study were to determine the abundance and to predict the source of PAHs in the sediments. Gas chromatography-mass spectrometry (GC-MS) was used to analyze sixteen priority PAHs. Total PAHs concentrations were from 1.31 to 3992.68 mg/kg in sediment with an average concentration of (307.54 ± 16.10) mg/kg. Among all PAHs, Naphthalene (Nap = 332.72 mg/kg) and Phenanthrene (Phe = 41.75 mg/kg) were found in the highest concentration, whereas Benzo (k) Fluoranthene was found in the least concentration in the range of 0 - 0.85 mg/kg (mean 0.24 mg/kg). Bassam-Modeste Lagune (BML) sampling site was the site with the highest concentration of total PAHs (all 16 PAHs) compared to the others due to their location in a highly populated estuary area that receives commercial, tourism, port, petroleum and heavy industrial activities. Diagnostic ratios were used to determine the sources of PAHs and suggested that the PAH profile in the sediments was dominated by 2 and 3 ring PAHs. The patterns of PAH compounds in sediment indicated that contamination is from mixed sources, with a strong indication of petrogenic contamination potentially from spills of fuel, oil and industrial activities.展开更多
Natural radionuclides are powerful tools for understanding the sources and fate of suspended particulate matter(SPM).Particulate matter with different particle sizes behaves differently with respect to adsorption and ...Natural radionuclides are powerful tools for understanding the sources and fate of suspended particulate matter(SPM).Particulate matter with different particle sizes behaves differently with respect to adsorption and desorption.We analyzed the activi-ties and distribution characteristics of multiple natural radionuclides(238U,226Ra,40K,228Ra,7Be and 210Pbex)on size-fractionated SPM at the Lijin Hydrographic Station(Huanghe or Yellow River)every month over a one-year period.Results showed that medium silt(16–32µm)was the main component.As expected,the activity of each radionuclide decreased with an increase of particle size.We examined the sources of SPM with different particle sizes using activity ratios of 226Ra/238U,228Ra/226Ra,40K/238U and 7Be/210Pbex,and concluded that SPM with different particle sizes originated from different sources.Our results indicate that fine SPM(<32µm)was mainly from the erosion of soil along the lower reaches of the Yellow River,while coarse SPM(>32µm)was mainly derived from resuspension of riverbed sediment.During high runoff periods,the concentration of SPM increased significantly,and the pro-portion of fine particles originating upstream increased.Naturally occurring radioactive isotopes,especially on size-fractionated par-ticles,are therefore seen as useful tracers to understand the sources and behaviors of riverine particles transported from land to sea.展开更多
The sandstones of the Late miocene–Pliocene Dibdibba Formation in the Najaf–Karbala Plateau and Basra were examined to determine their source rocks and origin. The rare earth elements(REE) and trace elements(Sc, Co,...The sandstones of the Late miocene–Pliocene Dibdibba Formation in the Najaf–Karbala Plateau and Basra were examined to determine their source rocks and origin. The rare earth elements(REE) and trace elements(Sc, Co, V, and Th) concentrations in these sandstones revealed that they likely derived from a single source. The steep light rare earth elements(LREE) and flat, heavy rare earth element(HREE) patterns, negative Eu anomaly, and high ΣREE contents in sandstones suggest its derivation from a suggests that a passive continental margin environment and originated from felsic source rocks. The average concentration of ΣREE is 93.5 ppm, which is lower than that of the average crustal compositions like Upper Continental Crust and Post Archean Australian Shale. The higher proportion of LREE compared to HREE implies that these sandstones were recycled and derived from a distal source. The Th/Co, Th/Sc, La/Sc, La/Co, Eu/Eu*and(La/Lu)cn elemental ratios indicated that these Late Miocene–Pliocene sandstones were derived from felsic rocks located in the marginal region of the Arabian Shield.展开更多
Several studies have documented that during‘green tide’events,comprising green macroalgae blooms in aquatic ecosystems,dissolved inorganic phosphorus(DIP)levels remain relatively steady despite the absorption of a l...Several studies have documented that during‘green tide’events,comprising green macroalgae blooms in aquatic ecosystems,dissolved inorganic phosphorus(DIP)levels remain relatively steady despite the absorption of a large amount of DIP.In this study,surface sediment samples and a sediment core were extracted using a modified sequential extraction scheme,and water and surface sediment samples were analyzed in April 2017 to better understand phosphorus(P)cycling and replenishment in Subei shoal.We used a simple model on equilibrium of adsorption-desorption to present the buffering capacity of phosphate.The total P(TP)in the surface sediments ranged from 12.2 to 28.4μmol g^(-1)(average 15.5μmol g^(-1))and was dominated by inorganic P.TP,exchangeable P,reactive and reductive Fe/Al bound P,and authigenic apatite P significantly decreased northward and eastward from Subei shoal,contrary to the detrital P and organic P results.Dissolved and particulate inorganic P in the water samples ranged from 0.01 to 0.54μmol L^(-1)(average 0.19μmol L^(-1))and 0.9 to 19.6μmol g^(-1)(average 4.9μmol g^(-1)),respectively.The applied model showed that suspended particulate matter is an important regulator of DIP behavior.Thus,modification of SPM can alter the DIP buffering capacity.The calculated buffering capacity in the surface layer of the sea water was>60 within Subei shoal and always>10 along the path of floating Ulva prolifera,providing a reasonable explanation for the steady concentration of DIP and its replenishment during the blooming of this green macroalgae.展开更多
Condensed and hydrolysable tannins are non-toxic natural polyphenols that are a commercial commodity industrialized for tanning hides to obtain leather and for a growing number of other industrial applications mainly ...Condensed and hydrolysable tannins are non-toxic natural polyphenols that are a commercial commodity industrialized for tanning hides to obtain leather and for a growing number of other industrial applications mainly to substitute petroleum-based products.They are a definite class of sustainable materials of the forestry industry.They have been in operation for hundreds of years to manufacture leather and now for a growing number of applications in a variety of other industries,such as wood adhesives,metal coating,pharmaceutical/medical applications and several others.This review presents the main sources,either already or potentially commercial of this forestry by-materials,their industrial and laboratory extraction systems,their systems of analysis with their advantages and drawbacks,be these methods so simple to even appear primitive but nonetheless of proven effectiveness,or very modern and instrumental.It constitutes a basic but essential summary of what is necessary to know of these sustainable materials.In doing so,the review highlights some of the main challenges that remain to be addressed to deliver the quality and economics of tannin supply necessary to fulfill the industrial production requirements for some materials-based uses.展开更多
The spring atmospheric heat source(AHS)over the Tibetan Plateau(TP)has been suggested to affect the Asian summer monsoon and summer precipitation over South China.However,its influence on the summer precipitation in N...The spring atmospheric heat source(AHS)over the Tibetan Plateau(TP)has been suggested to affect the Asian summer monsoon and summer precipitation over South China.However,its influence on the summer precipitation in Northeast China(NEC)remains unknown.The connection between spring TP AHS and subsequent summer precipitation over NEC from 1961 to 2020 is analyzed in this study.Results illustrate that stronger spring TP AHS can enhance subsequent summer NEC precipitation,and higher soil moisture in the Yellow River Valley-North China region(YRVNC)acts as a bridge.During spring,the strong TP AHS could strengthen the transportation of water vapor to East China and lead to excessive rainfall in the YRVNC.Thus,soil moisture increases,which regulates local thermal conditions by decreasing local surface skin temperature and sensible heat.Owing to the memory of soil moisture,the lower spring sensible heat over the YRVNC can last until mid-summer,decrease the land–sea thermal contrast,and weaken the southerly winds over the East Asia–western Pacific region and convective activities over the South China Sea and tropical western Pacific.This modulates the East Asia–Pacific teleconnection pattern,which leads to a cyclonic anomaly and excessive summer precipitation over NEC.展开更多
Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organ...Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organic carbon(TOC)content,various kerogen types,and a wide range of thermal maturity.Consequently,their hydrocarbon generation potential and resource estimation can be misinterpreted.In this study,geochemical tests,numerical analysis,hydrocarbon generation kinetics,and basin modeling were integrated to investigate the differential effects of kerogen types on the hydrocarbon generation potential of lacustrine source rocks.Optimized hydrocarbon generation and expulsion(HGE)models of different kerogen types were established quantitatively upon abundant Rock-Eval/TOC/vitrinite reflectance(R_(o))datasets.Three sets of good-excellent source rocks deposited in the fourth(Es4),third(Es3),and first(Es1)members of Paleogene Shahejie Formation,are predominantly types I-II_(1),II_(1)-II_(2),and II-III,respectively.The activation energy of types I-II_(2)kerogen is concentrated(180-230 kcal/mol),whereas that of type III kerogen is widely distributed(150-280 kcal/mol).The original hydrocarbon generation potentials of types I,II_(1),II_(2),and III kerogens are 790,510,270,and 85 mg/g TOC,respectively.The Ro values of the hydrocarbon generation threshold for type I-III source rocks gradually increase from 0.42%to 0.74%,and Ro values of the hydrocarbon expulsion threshold increase from 0.49%to 0.87%.Types I and II_(1)source rocks are characterized by earlier hydrocarbon generation,more rapid hydrocarbon expulsion,and narrower hydrocarbon generation windows than types II_(2)and III source rocks.The kerogen types also affect the HGE history and resource potential.Three types(conventional,tight,and shale oil/gas)and three levels(realistic,expected,and prospective)of hydrocarbon resources of different members in the Liaohe Western Depression are evaluated.Findings suggest that the Es3 member has considerable conventional and unconventional hydrocarbon resources.This study can quantitatively characterize the hydrocarbon generation potential of source rocks with different kerogen types,and facilitate a quick and accurate assessment of hydrocarbon resources,providing strategies for future oil and gas exploration.展开更多
Geochemical behaviors of heavy metals are closely related to their chemical state that can be divided by sequential extraction into exchangeable(F1),bound to carbonates(F2),bound to Fe-Mn oxides(F3),bound to organic m...Geochemical behaviors of heavy metals are closely related to their chemical state that can be divided by sequential extraction into exchangeable(F1),bound to carbonates(F2),bound to Fe-Mn oxides(F3),bound to organic matter or sulfide(F4),and residual(F5).Uranium in sediment of the Huanghe(Yellow)River,China,in different chemical states was extracted using the five-step procedure of Tessier and the source and sink were analyzed.Results show that more than 70%of the total uranium was immobile residual F5 in abundance,followed in order of F4>F3>F2>F1,indicating that the main source of uranium in the sediments was from weathered rock in the drainage basin.In addition,the uranium in the sediments presents potential exogenous input in the Lanzhou,Baotou,and Tongguan reach.Fe-Mn oxides are main carriers of unstable uranium,especially those of F1 and F3.Calcite and illite are secondary adsorption minerals of unstable uranium in sediments under natural conditions.Human activities can also produce an obvious impact on uranium speciation.This study provides a reference for the application of sequential extraction in analyzing the source and sink of uranium in river sediments.展开更多
The organic-rich mudstones and dolostones of the Permian Fengcheng Formation(Fm.)are typically alkaline lacustrine source rocks,which are typified by impressively abundantβ-carotane.Abundant β-carotane has been well...The organic-rich mudstones and dolostones of the Permian Fengcheng Formation(Fm.)are typically alkaline lacustrine source rocks,which are typified by impressively abundantβ-carotane.Abundant β-carotane has been well acknowledged as an effective indicator of biological sources or depositional environments.However,the specific biological sources of β-carotane and the coupling control of biological sources and environmental factors on the enrichment of β-carotane in the Fengcheng Fm.remains obscure.Based on a comprehensive investigation of the bulk,molecular geochemistry,and organic petrology of sedimentary rocks and the biochemistry of phytoplankton in modern alkaline lakes,we proposed a new understanding of the biological precursors of β-carotane and elucidated the enrichment mechanism of β-carotane in the Fengcheng Fm.The results show that the biological precursors crucially control the enrichment of β-carotane in the Fengcheng Fm.The haloalkaliphilic cyanobacteria are the primary biological sources of β-carotane,which is suggested by a good positive correlation between the 2-methylhopane index,7-+8-methyl heptadecanes/C_(max),C_(29%),and β-carotane/C_(max)in sedimentary rocks and the predominance of cyanobacteria with abundantβ-carotene in modern alkaline lakes.The enrichment of β-carotane requires the reducing condition,and the paleoredox state that affects the enrichment of β-carotane appears to have a threshold.The paleoclimate conditions do not considerably impact the enrichment of β-carotane,but they have some influence on the water's paleosalinity by affecting evaporation and precipitation.While it does not directly affect the enrichment of β-carotane in the Fengcheng Fm.,paleosalinity does have an impact on the cyanobacterial precursor supply and the preservation conditions.展开更多
Hydrocarbon resources in the Qiongdongnan Basin have become an important exploration target in China.However,the development of high-quality source rocks in this basin,especially in its deep-water areas,are still not ...Hydrocarbon resources in the Qiongdongnan Basin have become an important exploration target in China.However,the development of high-quality source rocks in this basin,especially in its deep-water areas,are still not fully understood.In this study,evolutions of sedimentary facies and palaeoenvironment and their influences on the development of source rocks in diverse tectonic regions of the Qiongdongnan Basin were investigated.The results show that during the Oligocene and to Miocene periods,the sedimentary environment of this basin progressively varied from a semi-closed gulf to an open marine environment,which resulted in significant differences in palaeoenvironmental conditions of the water column for various tectonic regions of the basin.In shallow-water areas,the palaeoproductivity and reducibility successively decrease,and the hydrodynamic intensity gradually increases for the water columns of the Yacheng,Lingshui,and Sanya-Meishan strata.In deep-water areas,the water column of the Yacheng and Lingshui strata has a higher palaeoproductivity and a weaker hydrodynamic intensity than that of the Sanya-Meishan strata,while the reducibility gradually increases for the water columns of the Yacheng,Lingshui,and Sanya-Meishan strata.In general,the palaeoenvironmental conditions of the water column are the most favorable to the development of the Yacheng organic-rich source rocks.Meanwhile,the Miocene marine source rocks in the deep-water areas of the Qiongdongnan Basin may also have a certain hydrocarbon potential.The differences in the development models of source rocks in various tectonic regions of continental margin basins should be fully evaluated in the exploration and development of hydrocarbons.展开更多
With the rapid development of China's social economy and the acceleration of urbanization,a large quantity of production and domestic sewage is discharged into rivers and lakes,and the concentration of pollutants ...With the rapid development of China's social economy and the acceleration of urbanization,a large quantity of production and domestic sewage is discharged into rivers and lakes,and the concentration of pollutants leads to serious excessive heavy metals in sediment,which affects the ecological environment.In this paper,the treatment technology of heavy metal pollution in sediment and its resource utilization in building ceramics in China are systematically analyzed and summarized,in order to provide a reference for the treatment of sediment in rivers and lakes and the sustainable development of building ceramics industry.展开更多
Triassic-Jurassic carbonates widely distributed in Eastern Indonesia are believed as oils source rock. The Mesozoic Tokala Formation exhibit source rock potential, as evidenced by high contents of organic matter. Rece...Triassic-Jurassic carbonates widely distributed in Eastern Indonesia are believed as oils source rock. The Mesozoic Tokala Formation exhibit source rock potential, as evidenced by high contents of organic matter. Recent exploration has been conducted in southeastern Sulawesi, targeting the Mesozoic intervals. Therefore, in this study, we attempted to determine source rock potential of Tokala Formation outcropped in southeastern Sulawesi area and its capability to generate hydrocarbon. Five distinct lithofacies were delineated, emphasizing lithological and mineralogical features: foraminifera wackestone (FW), lime mudstone (LM), massive bioturbated calcareous-argillaceous shale (MBCAS), weakly laminated argillaceous-calcareous shale (WLACS), and strongly laminated calcareous-argillaceous shale (SLCAS). Subsequent analyses showed that carbonate-rich samples (FW and LM facies, >50% CaO) had poor source rock potential. Conversely, shale facies with moderate carbonate content (WLACS, MBCAS, and SLCAS, 15% - 50% CaO) had good to excellent source rock characteristics, qualifying them as preferable source rock. In addition, levels of SiO2 and Al2O3 should not be neglected, as these constituents play important roles in clay mineral adsorption. Laminated shale facies with moderate CaO content tended to be more promising as source rock than bioturbated facies. The shale facies of Tokala Formation indicate prospective source rock horizon.展开更多
文摘Aeromagnetic data over the Mamfe Basin have been processed. A regional magnetic gridded dataset was obtained from the Total Magnetic Intensity (TMI) data grid using a 3 × 3 convolution (Hanning) filter to remove regional trends. Major similarities in magnetic field orientation and intensities were observed at identical locations on both the regional and TMI data grids. From the regional and TMI gridded datasets, the residual dataset was generated which represents the very shallow geological features of the basin. Processing this residual data grid using the Source Parameter Imaging (SPI) for magnetic depth suggests that the estimated depths to magnetic sources in the basin range from about 271 m to 3552 m. The highest depths are located in two main locations somewhere around the central portion of the study area which correspond to the area with positive magnetic susceptibilities, as well as the areas extending outwards across the eastern boundary of the study area. Shallow magnetic depths are prominent towards the NW portion of the basin and also correspond to areas of negative magnetic susceptibilities. The basin generally exhibits a variation in depth of magnetic sources with high, average and shallow depths. The presence of intrusive igneous rocks was also observed in this basin. This characteristic is a pointer to the existence of geologic resources of interest for exploration in the basin.
基金This research was supported by the project"Research on Vegetation Restoration and Reconstruction Technology in the Ecologically Fragile Areas of Uzhumqin Sand Dunes"of the Science and Technology Program of Inner Mongolia Autonomous Region(2020GG0077).We are grateful to the Key Laboratory of Wind and Sand Physics and Sand Control Engineering of Inner Mongolia Autonomous Region for providing us with experimental equipment and space.We thank LetPub(www.letpub.com)for its linguistic assistance during the preparation of this manuscript.
文摘Sediment constitutes the fundamental basis for forming and evolving aeolian geomorphology.The characteristics of sediment particle size offer insights into the development and evolution of sandy terrain,making their study critical to understanding aeolian geomorphology and sand control.In this study,we combined high-density collection of surface sediments in the Uzhumqin sand dunes and GIS spatial analysis to analyze the particle size parameters and changes in the spatial distribution of surface sediments in this region.In addition,we used an end-member analysis to identify the potential sources of the sediments.The results showed that surface sediments in the Uzhumqin sand dunes had distinct spatial distributions.Medium and coarse grain sands dominated the sediments in the dunes,and the mean grain size and the sorting coefficient generally increased along the prevailing wind direction,with high values in individual areas related to factors such as material sources and vegetation cover.Skewness was strongly influenced by factors such as landform change and human activity,and spatial variability became more complex.Kurtosis and the soil fractal dimension showed generally decreasing trends along the prevailing wind direction.With dune fixation,the contents of clay and powder particles in the soil increased;the mean particle size,the sorting coefficient,and the fractal dimension of the soil gradually increased,and the skewness and kurtosis gradually decreased.The end-member analysis results indicated the existence of five end-members(EM)in the dune sediments.EM 1 was a mixed component of wind-deposited fine sands and nearby fluvial sediments.EM 2 was the main component of sediments in the study area and was the result of sorting lake sediments by wind action and by the local topography.EM 3 may be a product of river flood deposition.EM 4 and EM 5 had coarser grain sizes.EM 4 was a lake-phase sediment product influenced by topographic and vegetation cover factors,and EM 5 was primarily a river and lake sediment product modified by weathering.The sediment particle size results from the study area indicate that the sediment in the sandy region is generally coarse due to multiple factors,including topography,climate,hydrology,and human activity.Sandy material in the study area originated from nearby,with very little sand being transported from long distances.
基金The National Natural Science Foundation of China under contract No.42276047the Guangdong Basic and Applied Basic Research Foundation under contract Nos 2023A1515110473 and 2021A1515110172+1 种基金the Program for Scientific Research Start-up Funds of Guangdong Ocean University under contract No.R17058the National College Student Innovation and Entrepreneurship Training Program Project under contract No.202310566007。
文摘Zhanjiang Bay is a major aquaculture area in China with many types of mariculture products(such as oysters,fish,and shrimp).The culture area and shrimp output in Zhanjiang Bay are ranked first in China.We investigated the total organic carbon(TOC),total nitrogen(TN),TOC/TN ratio,and stable isotopes(δ^(13)C and δ^(15)N) of the fish and shrimp feed,fish and shrimp feces,and sedimentary organic matter(SOM) in and around different aquaculture areas of northeastern Zhanjiang B ay to study the impact of aquaculture activities on SOM.The average TOC contents of fish and shrimp feed were 39.20%±0.91% and 39.29%±0.21%,respectively.The average TOC content in the surface sediments of the oyster culture area,the mixed(fish and shrimp) culture area,and the cage fish farm area were 0.66%,0.88%±0.10%,and 0.58%±0.19%,respectively,which may indicate that mixed culture had a greater impact on SOM.The relatively high TOC and TN contents and relatively low TOC/TN ratios,and δ^(15)N values in the upper layer of the core sediment in the mixed culture area could also support the significant influence of mixed culture.The average δ^(13)C and δ^(15)N values of fish and shrimp feed were -20.6‰±2.2‰ and 1.8‰±1.2‰,respectively,which were different from the isotopic values of SOM in the study area.δ^(13)C and δ^(15)N values for SOM in different aquaculture areas were different from those of nearby reference stations,probably reflecting the influence of aquaculture.The δ^(13)C and δ^(15)N values in the oyster culture area(-25.9‰ and6.0‰,respectively) seemed to have reduced δ^(13)C and enriched δ^(15)N relative to those of the reference station(-24.6‰ and 5.8‰,respectively).This may reflect the influence of organic matter on oyster culture.The δ^(15)N value of the station in the mixed culture area(7.1‰±0.4‰) seemed to be relatively enriched in δ^(15)N relative to that of the reference station(6.6‰).Sedimentation and the subsequent degradation of organic matter from mixed cultures may have contributed to this phenomenon.The surface sediment at the cage fish farm area seemed to be affected by fish feces and primary production based on the indication of δ^(13)C and δ^(15)N values.The sediment core at the mixed culture region(NS6) had lower TOC/TN ratios and more positive δ^(13)C and δ^(15)N values than the sediment core at the oyster culture area,suggesting a higher proportionate contribution of marine organic matter in the mixed culture area.In summary,oyster culture,mixed culture,and cage fish culture in northeastern Zhanjiang Bay had a certain degree of impact on SOM,and mixed culture had more significant influences on SOM based on the high TOC contents and the significant vertical variations of TOC/TN ratio and δ^(15)N value in the sediment of this area.This study provides new insights into the impact of aquaculture activities on SOM content.
基金Supported by Undergraduate Training Program for Innovation and Entrepreneurship of Jiangxi Provincial Department of Education(S202310846004&S202310846007).
文摘At present,there is a great demand for building materials in the market,and the market prospect of building materials is relatively considerable.Through studying the composition of river sediment and its resource utilization in the field of building materials,this paper expounds the current domestic scholars research on river sediment in building materials,and summarizes the current problems and challenges,so as to provide a reference for the sustainable development of river sediment in the field of building materials.
文摘XRF and EDX analyses were carried out on 18 batches of representative raw samples to determine the distribution of major chemical elements in the petroleum source rocks of Donga and Yogou formations of Termit sedimentary basin. The chemical composition of these formations is dominated by silicon (Si), aluminum (Al) and iron (Fe). This is consistent with the oxide composition, which is also dominated by silicon oxide (SiO2), aluminum oxide (Al<sub>2</sub>O<sub>3</sub>) and iron monoxide (FeO). No less important chemical elements are calcium (Ca), potassium (K), sulfur (S), titanium (Ti), magnesium (Mg), manganese (Mn) and barium (Ba), as well as some of their oxides. All these major chemical elements are carried by silicate detrital minerals associated with pyrite and goethite and/or clay minerals such as kaolinite and interstratified illite, smectite and chlorite. This trend is illustrated by the values of the Si/Al and SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratios.
基金The National Natural Science Foundation of China under contract Nos 41930538,42076211 and 42076058the Scientific Research Foundation of the Third Institute of Oceanography,Ministry of Natural Resources under contract Nos 2022017 and 2019006the China Postdoctoral Science Foundation under contract No.2019M652248.
文摘The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment source-to-sink process variations of such beaches and their morphological indications.The results show that the clay mineral assemblages of these SMT-Beaches mainly comprise of almost equal illite(~30%),kaolinite(~28%),chlorite(~22%),and smectite(~20%)contents.From the surrounding mountain rivers to the SMT-Beaches,clay mineral assemblages show distinct spatial changes characterized by a large decrease(~40%)in kaolinite,whereas the other three clay minerals present relative increases,especially clear for smectite.The muddy sediment sources of SMT-Beaches inferred from the clay mineralogy are mainly derived from nearby mountain rivers coupled with long-distance transport and penetration of the Changjiang River.The sandy sediments of these beaches are predominantly sourced from nearby mountain rivers,the weathering products of surrounding rocks in both mainland and island environments,and erosion of the“Old Red Sand”and“Red Soil Platform”.However,the sandy sediment sources of the SMT-Beaches are largely reduced because of the remarkable decrease in the river fluvial supply associated with intensive human activities such as dam construction and coastal reclamation.Subsequently,the sandy sections of SMT-Beaches present clear erosion and have revealed by both time series remote sensing images and a compilation of published literature.In contrast,the muddy sediment supply of SMT-Beaches is temporarily stable and relatively constant,resulting in the landward migration of the mudflats with relative transgression or accumulation.These findings highlight that the natural evolution processes of SMT-Beaches have been greatly reshaped by intensive human activities.
基金supported by the Project of Creating Ordos National Sustainable Development Agenda Innovation Demonstration Zone(Grant 2022EEDSKJXM005)Natural Science Foundation of China(Grant 42077073)+3 种基金Natural Science Basic Research Plan in Shaanxi Province of China(2022KJXX-62)the Project of Shaanxi Coal and Chemical Industry Group Co.,Ltd(2022SMHKJ-A-J07-02,2022SMHKJ-B-J-54)the Project of AnHui Water Resources Development Co.,Ltd(KY-2021-13)。
文摘Soil erosion is a major issue in Loess Plateau,China,and quantitative analyses of sediment sources are crucial for soil erosion control.In this study,a combination of flood couplet analysis and composite fingerprint identification was used for historical reconstructions of soil erosion in sediment source areas in Loess Plateau.Each flood couplet was constructed based on sediment 137Cs activity,and past soil erosion was calculated using soil bulk density and storage capacity curves.The contribution rates of the sediment sources were calculated using the fingerprinting method,and the amount of erosion in the sediment source areas was estimated.The best fingerprint combination(Cr,Ni,V,and TOC)enabled a 97.2%recognition of sediment sources from 29 flood events(1956–1990)in the Loess Plateau.The contribution rates of gullies,farmland,grassland,and shrubland were 44.89%,26.38%,10.49%,and 18.24%,respectively.These four land use types contributed 1,227,751,512,and 279 tons of sediments,respectively.Re-vegetation decreased soil erosion(1966–1983),whereas deforestation increased soil erosion(1956–1965 and 1984–1990).Rational soil and water conservation measures on slopes and check dam construction in gullies are therefore suggested to mitigate erosion.
基金financially supported by the Key Project of Shaanxi Provincial Natural Science Basic Research Program(2023-JC-ZD-16).
文摘In this study, 30 sediment samples were collected from the lower reaches of the Shichuanhe River in Xi’an, Shaanxi Province, China, to test the distribution of heavy metal elements in this area and for an analysis of the pollution levels of this area, hope to provide guidance on agricultural production activities in this region. The results show that the heavy metal elements in this area are mainly concentrated at the Qinghe River and Shichuanhe River confluences. Furthermore, the element contents are higher than that of the background levels of the continental crust(UCC) and close to the background levels of the soil from Shaanxi Province;the two most enriched elements are Cd and As, with contents of 0.79 and 22.7 mg·kg-1, respectively, and their contents are 3.8 and 1.72 times higher than that of the background values. Herein, the heavy metal pollution assessment methods applied indicated that Cd and As are the two most abundant pollutant elements in the area’s soils. As has a peak geo-accumulation index value of 3, and the pollution level is high, while Cd exhibits high potential ecological risks due to its high toxicity(potential risk index of 143) and an active fraction of more than 64%.In addition, a principal component analysis and hierarchical cluster analysis study showed that there are two sources of the heavy metals in this area. The Zn, As, Ni, Cu, Pb,and Cr are mainly from natural sources, and the Cd likely comes from a discharge of untreated agricultural wastewater in the region. The Cd which poses a high potential risk and mainly results from human activities, needs to be further monitored.
文摘Polycyclic aromatic hydrocarbons (PAHs) are strongly associated with agricultural, residential, transportation, industrial and petroleum activities. In this study, the presence of PAHs (polycyclic aromatic hydrocarbons) was investigated in sediments of the ivory coastal zone (Toukouzou Hozalem-Assinie). The main objectives of this study were to determine the abundance and to predict the source of PAHs in the sediments. Gas chromatography-mass spectrometry (GC-MS) was used to analyze sixteen priority PAHs. Total PAHs concentrations were from 1.31 to 3992.68 mg/kg in sediment with an average concentration of (307.54 ± 16.10) mg/kg. Among all PAHs, Naphthalene (Nap = 332.72 mg/kg) and Phenanthrene (Phe = 41.75 mg/kg) were found in the highest concentration, whereas Benzo (k) Fluoranthene was found in the least concentration in the range of 0 - 0.85 mg/kg (mean 0.24 mg/kg). Bassam-Modeste Lagune (BML) sampling site was the site with the highest concentration of total PAHs (all 16 PAHs) compared to the others due to their location in a highly populated estuary area that receives commercial, tourism, port, petroleum and heavy industrial activities. Diagnostic ratios were used to determine the sources of PAHs and suggested that the PAH profile in the sediments was dominated by 2 and 3 ring PAHs. The patterns of PAH compounds in sediment indicated that contamination is from mixed sources, with a strong indication of petrogenic contamination potentially from spills of fuel, oil and industrial activities.
基金financially supported by the National Natural Science Foundation of China(Nos.U22A20580,42130410,and U1906210)the Fundamental Research Funds for the Central Universities(No.201962003).
文摘Natural radionuclides are powerful tools for understanding the sources and fate of suspended particulate matter(SPM).Particulate matter with different particle sizes behaves differently with respect to adsorption and desorption.We analyzed the activi-ties and distribution characteristics of multiple natural radionuclides(238U,226Ra,40K,228Ra,7Be and 210Pbex)on size-fractionated SPM at the Lijin Hydrographic Station(Huanghe or Yellow River)every month over a one-year period.Results showed that medium silt(16–32µm)was the main component.As expected,the activity of each radionuclide decreased with an increase of particle size.We examined the sources of SPM with different particle sizes using activity ratios of 226Ra/238U,228Ra/226Ra,40K/238U and 7Be/210Pbex,and concluded that SPM with different particle sizes originated from different sources.Our results indicate that fine SPM(<32µm)was mainly from the erosion of soil along the lower reaches of the Yellow River,while coarse SPM(>32µm)was mainly derived from resuspension of riverbed sediment.During high runoff periods,the concentration of SPM increased significantly,and the pro-portion of fine particles originating upstream increased.Naturally occurring radioactive isotopes,especially on size-fractionated par-ticles,are therefore seen as useful tracers to understand the sources and behaviors of riverine particles transported from land to sea.
文摘The sandstones of the Late miocene–Pliocene Dibdibba Formation in the Najaf–Karbala Plateau and Basra were examined to determine their source rocks and origin. The rare earth elements(REE) and trace elements(Sc, Co, V, and Th) concentrations in these sandstones revealed that they likely derived from a single source. The steep light rare earth elements(LREE) and flat, heavy rare earth element(HREE) patterns, negative Eu anomaly, and high ΣREE contents in sandstones suggest its derivation from a suggests that a passive continental margin environment and originated from felsic source rocks. The average concentration of ΣREE is 93.5 ppm, which is lower than that of the average crustal compositions like Upper Continental Crust and Post Archean Australian Shale. The higher proportion of LREE compared to HREE implies that these sandstones were recycled and derived from a distal source. The Th/Co, Th/Sc, La/Sc, La/Co, Eu/Eu*and(La/Lu)cn elemental ratios indicated that these Late Miocene–Pliocene sandstones were derived from felsic rocks located in the marginal region of the Arabian Shield.
基金supported by the National Natural Science Foundation of China(No.U1901215)the National Key Research and Development Program of China(No.2019YFE0124700)+1 种基金the China National Key Research and Development Program(No.2022YFC3106002)the Startup Foundation for Introducing Talent of NUIST(No.2020r028)。
文摘Several studies have documented that during‘green tide’events,comprising green macroalgae blooms in aquatic ecosystems,dissolved inorganic phosphorus(DIP)levels remain relatively steady despite the absorption of a large amount of DIP.In this study,surface sediment samples and a sediment core were extracted using a modified sequential extraction scheme,and water and surface sediment samples were analyzed in April 2017 to better understand phosphorus(P)cycling and replenishment in Subei shoal.We used a simple model on equilibrium of adsorption-desorption to present the buffering capacity of phosphate.The total P(TP)in the surface sediments ranged from 12.2 to 28.4μmol g^(-1)(average 15.5μmol g^(-1))and was dominated by inorganic P.TP,exchangeable P,reactive and reductive Fe/Al bound P,and authigenic apatite P significantly decreased northward and eastward from Subei shoal,contrary to the detrital P and organic P results.Dissolved and particulate inorganic P in the water samples ranged from 0.01 to 0.54μmol L^(-1)(average 0.19μmol L^(-1))and 0.9 to 19.6μmol g^(-1)(average 4.9μmol g^(-1)),respectively.The applied model showed that suspended particulate matter is an important regulator of DIP behavior.Thus,modification of SPM can alter the DIP buffering capacity.The calculated buffering capacity in the surface layer of the sea water was>60 within Subei shoal and always>10 along the path of floating Ulva prolifera,providing a reasonable explanation for the steady concentration of DIP and its replenishment during the blooming of this green macroalgae.
文摘Condensed and hydrolysable tannins are non-toxic natural polyphenols that are a commercial commodity industrialized for tanning hides to obtain leather and for a growing number of other industrial applications mainly to substitute petroleum-based products.They are a definite class of sustainable materials of the forestry industry.They have been in operation for hundreds of years to manufacture leather and now for a growing number of applications in a variety of other industries,such as wood adhesives,metal coating,pharmaceutical/medical applications and several others.This review presents the main sources,either already or potentially commercial of this forestry by-materials,their industrial and laboratory extraction systems,their systems of analysis with their advantages and drawbacks,be these methods so simple to even appear primitive but nonetheless of proven effectiveness,or very modern and instrumental.It constitutes a basic but essential summary of what is necessary to know of these sustainable materials.In doing so,the review highlights some of the main challenges that remain to be addressed to deliver the quality and economics of tannin supply necessary to fulfill the industrial production requirements for some materials-based uses.
基金supported by the Open Research Fund of TPESER(Grant No.TPESER202205)the Second Tibetan Plateau Scientific Expedition and Research Program(Grant No.2019QZKK0101)。
文摘The spring atmospheric heat source(AHS)over the Tibetan Plateau(TP)has been suggested to affect the Asian summer monsoon and summer precipitation over South China.However,its influence on the summer precipitation in Northeast China(NEC)remains unknown.The connection between spring TP AHS and subsequent summer precipitation over NEC from 1961 to 2020 is analyzed in this study.Results illustrate that stronger spring TP AHS can enhance subsequent summer NEC precipitation,and higher soil moisture in the Yellow River Valley-North China region(YRVNC)acts as a bridge.During spring,the strong TP AHS could strengthen the transportation of water vapor to East China and lead to excessive rainfall in the YRVNC.Thus,soil moisture increases,which regulates local thermal conditions by decreasing local surface skin temperature and sensible heat.Owing to the memory of soil moisture,the lower spring sensible heat over the YRVNC can last until mid-summer,decrease the land–sea thermal contrast,and weaken the southerly winds over the East Asia–western Pacific region and convective activities over the South China Sea and tropical western Pacific.This modulates the East Asia–Pacific teleconnection pattern,which leads to a cyclonic anomaly and excessive summer precipitation over NEC.
基金This research is supported by the Joint Fund of the National Natural Science Foundation of China(grant number U19B6003-02)the Cooperation Program of PetroChina Liaohe Oilfield Company(grant Number HX20180604)the AAPG Foundation Grants-in-Aid Program(grant number 22269437).This study has benefited considerably from PetroChina Liaohe Oilfield Company for data support.We also thank the editor and the anonymous reviewers for their professional suggestions and comments.
文摘Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organic carbon(TOC)content,various kerogen types,and a wide range of thermal maturity.Consequently,their hydrocarbon generation potential and resource estimation can be misinterpreted.In this study,geochemical tests,numerical analysis,hydrocarbon generation kinetics,and basin modeling were integrated to investigate the differential effects of kerogen types on the hydrocarbon generation potential of lacustrine source rocks.Optimized hydrocarbon generation and expulsion(HGE)models of different kerogen types were established quantitatively upon abundant Rock-Eval/TOC/vitrinite reflectance(R_(o))datasets.Three sets of good-excellent source rocks deposited in the fourth(Es4),third(Es3),and first(Es1)members of Paleogene Shahejie Formation,are predominantly types I-II_(1),II_(1)-II_(2),and II-III,respectively.The activation energy of types I-II_(2)kerogen is concentrated(180-230 kcal/mol),whereas that of type III kerogen is widely distributed(150-280 kcal/mol).The original hydrocarbon generation potentials of types I,II_(1),II_(2),and III kerogens are 790,510,270,and 85 mg/g TOC,respectively.The Ro values of the hydrocarbon generation threshold for type I-III source rocks gradually increase from 0.42%to 0.74%,and Ro values of the hydrocarbon expulsion threshold increase from 0.49%to 0.87%.Types I and II_(1)source rocks are characterized by earlier hydrocarbon generation,more rapid hydrocarbon expulsion,and narrower hydrocarbon generation windows than types II_(2)and III source rocks.The kerogen types also affect the HGE history and resource potential.Three types(conventional,tight,and shale oil/gas)and three levels(realistic,expected,and prospective)of hydrocarbon resources of different members in the Liaohe Western Depression are evaluated.Findings suggest that the Es3 member has considerable conventional and unconventional hydrocarbon resources.This study can quantitatively characterize the hydrocarbon generation potential of source rocks with different kerogen types,and facilitate a quick and accurate assessment of hydrocarbon resources,providing strategies for future oil and gas exploration.
基金Supported by the National Natural Science Foundation of China(Nos.41876077,41376085)。
文摘Geochemical behaviors of heavy metals are closely related to their chemical state that can be divided by sequential extraction into exchangeable(F1),bound to carbonates(F2),bound to Fe-Mn oxides(F3),bound to organic matter or sulfide(F4),and residual(F5).Uranium in sediment of the Huanghe(Yellow)River,China,in different chemical states was extracted using the five-step procedure of Tessier and the source and sink were analyzed.Results show that more than 70%of the total uranium was immobile residual F5 in abundance,followed in order of F4>F3>F2>F1,indicating that the main source of uranium in the sediments was from weathered rock in the drainage basin.In addition,the uranium in the sediments presents potential exogenous input in the Lanzhou,Baotou,and Tongguan reach.Fe-Mn oxides are main carriers of unstable uranium,especially those of F1 and F3.Calcite and illite are secondary adsorption minerals of unstable uranium in sediments under natural conditions.Human activities can also produce an obvious impact on uranium speciation.This study provides a reference for the application of sequential extraction in analyzing the source and sink of uranium in river sediments.
基金financial support from the National Key Research and Development Program of China(2019YFC0605502)the National Natural Science Foundation of China(42302156)+1 种基金the Major Projects of Petro China Science and Technology Fund(2021DJ0206)the Natural Science Foundation of China University of Petroleum(22CX06046A)。
文摘The organic-rich mudstones and dolostones of the Permian Fengcheng Formation(Fm.)are typically alkaline lacustrine source rocks,which are typified by impressively abundantβ-carotane.Abundant β-carotane has been well acknowledged as an effective indicator of biological sources or depositional environments.However,the specific biological sources of β-carotane and the coupling control of biological sources and environmental factors on the enrichment of β-carotane in the Fengcheng Fm.remains obscure.Based on a comprehensive investigation of the bulk,molecular geochemistry,and organic petrology of sedimentary rocks and the biochemistry of phytoplankton in modern alkaline lakes,we proposed a new understanding of the biological precursors of β-carotane and elucidated the enrichment mechanism of β-carotane in the Fengcheng Fm.The results show that the biological precursors crucially control the enrichment of β-carotane in the Fengcheng Fm.The haloalkaliphilic cyanobacteria are the primary biological sources of β-carotane,which is suggested by a good positive correlation between the 2-methylhopane index,7-+8-methyl heptadecanes/C_(max),C_(29%),and β-carotane/C_(max)in sedimentary rocks and the predominance of cyanobacteria with abundantβ-carotene in modern alkaline lakes.The enrichment of β-carotane requires the reducing condition,and the paleoredox state that affects the enrichment of β-carotane appears to have a threshold.The paleoclimate conditions do not considerably impact the enrichment of β-carotane,but they have some influence on the water's paleosalinity by affecting evaporation and precipitation.While it does not directly affect the enrichment of β-carotane in the Fengcheng Fm.,paleosalinity does have an impact on the cyanobacterial precursor supply and the preservation conditions.
基金supported by the National Natural Science Foundation of China(42272162)the Natural Science Foundation of Guangdong Province(2021A1515011381 and 2021A1515011635)the Science Project of the CNOOC(KJZH-2021-0003-00).
文摘Hydrocarbon resources in the Qiongdongnan Basin have become an important exploration target in China.However,the development of high-quality source rocks in this basin,especially in its deep-water areas,are still not fully understood.In this study,evolutions of sedimentary facies and palaeoenvironment and their influences on the development of source rocks in diverse tectonic regions of the Qiongdongnan Basin were investigated.The results show that during the Oligocene and to Miocene periods,the sedimentary environment of this basin progressively varied from a semi-closed gulf to an open marine environment,which resulted in significant differences in palaeoenvironmental conditions of the water column for various tectonic regions of the basin.In shallow-water areas,the palaeoproductivity and reducibility successively decrease,and the hydrodynamic intensity gradually increases for the water columns of the Yacheng,Lingshui,and Sanya-Meishan strata.In deep-water areas,the water column of the Yacheng and Lingshui strata has a higher palaeoproductivity and a weaker hydrodynamic intensity than that of the Sanya-Meishan strata,while the reducibility gradually increases for the water columns of the Yacheng,Lingshui,and Sanya-Meishan strata.In general,the palaeoenvironmental conditions of the water column are the most favorable to the development of the Yacheng organic-rich source rocks.Meanwhile,the Miocene marine source rocks in the deep-water areas of the Qiongdongnan Basin may also have a certain hydrocarbon potential.The differences in the development models of source rocks in various tectonic regions of continental margin basins should be fully evaluated in the exploration and development of hydrocarbons.
基金Provincial Innovation and Entrepreneurship Training Program for College Students of Jiangxi Provincial Department of Education(S202210846039X)University-level Natural Science Project of Jiangxi University of Technology(ZR2010).
文摘With the rapid development of China's social economy and the acceleration of urbanization,a large quantity of production and domestic sewage is discharged into rivers and lakes,and the concentration of pollutants leads to serious excessive heavy metals in sediment,which affects the ecological environment.In this paper,the treatment technology of heavy metal pollution in sediment and its resource utilization in building ceramics in China are systematically analyzed and summarized,in order to provide a reference for the treatment of sediment in rivers and lakes and the sustainable development of building ceramics industry.
文摘Triassic-Jurassic carbonates widely distributed in Eastern Indonesia are believed as oils source rock. The Mesozoic Tokala Formation exhibit source rock potential, as evidenced by high contents of organic matter. Recent exploration has been conducted in southeastern Sulawesi, targeting the Mesozoic intervals. Therefore, in this study, we attempted to determine source rock potential of Tokala Formation outcropped in southeastern Sulawesi area and its capability to generate hydrocarbon. Five distinct lithofacies were delineated, emphasizing lithological and mineralogical features: foraminifera wackestone (FW), lime mudstone (LM), massive bioturbated calcareous-argillaceous shale (MBCAS), weakly laminated argillaceous-calcareous shale (WLACS), and strongly laminated calcareous-argillaceous shale (SLCAS). Subsequent analyses showed that carbonate-rich samples (FW and LM facies, >50% CaO) had poor source rock potential. Conversely, shale facies with moderate carbonate content (WLACS, MBCAS, and SLCAS, 15% - 50% CaO) had good to excellent source rock characteristics, qualifying them as preferable source rock. In addition, levels of SiO2 and Al2O3 should not be neglected, as these constituents play important roles in clay mineral adsorption. Laminated shale facies with moderate CaO content tended to be more promising as source rock than bioturbated facies. The shale facies of Tokala Formation indicate prospective source rock horizon.