The spatial multiscale variability of heavy metals based on factorial kriging analysis: A case study in the northeastern Beibu Gulf

Factorial kriging analysis is applied to the research on the spatial multiscale variability of heavy metals in submarine. It is used to analyze the multiscale spatial structures of seven heavy metals, Ni, Cu, Zn, Pb, Cr, As and Cd in the surface sediment from the northeastern of Beibu Gulf, identify and separate spatial variations at different scales of heavy metals, and discuss the provenance of heavy metals and the influencing factors. The results show that the existence of three-scale spatial variations those consist of nugget effect, a spherical structure with range of 30 km（short-range scale） and a spherical structure with range of 140 km（long-range scale） in the linear model of coregionalization fitted. The spatial distribution features of seven heavy metals at short-range scale reflect ＂spot-like＂ or ＂stripe-like＂ local-scale spatial variations; the spatial distribution features of the seven heavy metals at long-range scale represent ＂slice-like＂ regional-scale spatial variations. At local scale, Zn, Cr, Ni,Cu, Pb and Cd are derived primarily from parent materials of Hainan Island, Leizhou Peninsula and Guangxi land, whose spatial distribution characteristics are controlled by granularity of sediments, while As is influenced dominantly by human pollution components from Hainan Island and Leizhou Peninsula. At regional scale, Zn,Cr, Ni and Cu originate primarily from parent rock materials of Leizhou Peninsula and Hainan Island, secondly from Guangxi land; As originated primarily from parent rock materials from Hainan Island, secondly from Leizhou Peninsula and Guangxi land. These metals are transported and migrated with sediments dominated by the anticlockwise circulation of Beibu Gulf year-round, deposited in ＂convergence center＂, forming the whole sedimentary pattern in direction of NWW-NNW at regional scale. The difference in distribution type between As and other metals at regional scale is mainly due to their different geochemical behavior.

The difference analysis of physical-mechanical properties of sediments in the central South Yellow Sea and Zhe-Min coastal area in China

The difference analysis of physical-mechanical properties of muddy sediments is made in the central South Yellow Sea and the Zhe-Min（Zhejiang Province to Fujian Province of China） coastal area. The results show that sediments in the two regions are both dominated by mud. There are perfect negative power function correlations between the water content and the density, the compression coefficient and the compression modulus; a good positive power function correlation between the liquid limit and the plastic limit, a perfect positive linear correlation between the water content and the void ratio, and a perfect polynomial function correlation between the miniature vane shear strength and the pocket penetration resistance. In general, compared with sediments in the Zhe-Min coastal area, sediments in the central South Yellow Sea possess high water content, high void ratio,low density, high plasticity, high compressibility, low shear strength. The causes of the differences between physical-mechanical properties of sediments are analyzed from the topographic features, material sources,hydrodynamic conditions, deposition rate, and material composition. Compared with the Zhe-Min coastal area,the central South Yellow Sea is far from the Mainland and low-lying; has poor hydrodynamic condition; the materials diffused to the area are less and dominated by fine clay, have the high content of smectite and organic matters. These factors lead to sediments of the central South Yellow Sea has the higher water content, the higher plasticity, the lower density, and the lower strength than sediments in the Zhe-Min coastal area.

Paleoclimate Study of Mountain Ecosystems by Multiple Group Biological Analysis

Methodological problems of climatic reconstruction for different periods of Holocene are discussed on the basis of a multiple group biological analysis on peat-sapropel sediments. The possibility of biological analysis is exemplified by the paleoclimatic reconstruction for Carpathian and Altai Mountain ranges. For the ＂Skolevsky Beskidy＂ national park of Carpaty the paleoclimatic scenarios have been drown up aiming at the more precise definition of climatic conditions for the period of mass mountain slope terracing. The stability of terrace systems of various designs in the current climatic conditions has been assessed. It is shown that during periods of humid climate the terraces, whose designs have been focused on drainage, were built. In periods of dry and warm climate the terrace systems capable of accumulating water were built. Both these types of terrace systems are destroyed in nowadays. Only those terrace systems are stable which were adjusted by their builders to contrast variations of precipitation. For Western Altais the paleoclimatic scenario has been done to forecast the safety of the Bronze Age kurgans （burial earth mounds） with permafrost inside the construction. In the Altay region during the Holocene it has revealed two periods of sharp cooling, the peaks of which occurred in the intervals 4500- 4300 and 2500-2300 years pronounced climatic drying ago, and two periods of 4900-4700 and 130-70 years ago. Depletion of the algae composition in the layer corresponding to the last period of drying climate indicates a very sharp change in the parameters of moisture and turning the lake into a dry swamp. Periods of cold weather may have contributed to the formation of special ritual traditions of the Sakan tribes that require the frozen ground to bury the dead. The later climate fluctuations identified have not affected the safety of permafrost in burial mounds constructed in the V-III cc BC.

Characteristics of Clay Minerals in the Northern South China Sea and Its Implications for Evolution of East Asian Monsoon since Miocene

Clay mineral assemblages, crystallinity, chemistry, and micromorphology of clay particles in sediments from ODP Site 1146 in the northern South China Sea （SCS） were analyzed, and used to trace sediment sources and obtain proxy records of the past changes in the East Asian monsoon climate since the Miocene, based on a multi-approach, including X-ray diffraction （XRD） and scanning electron microscopy combined with energy dispersive X-ray spectrometry （SEM-EDS）. Clay minerals consist mainly of illite and smectite, with associated chlorite and kaolinite. The illite at ODP Site 1146 has very well-to-well crystallinity, and smectite has moderate-to-poor crystallinity. In SEM the smectite particles at ODP Site 1146 often appear cauliflower-like, a typical micromorphology of volcanic smecites. The smectite at ODP Site 1146 is relatively rich in Si element, but poor in Fe, very similar to the smectite from the West Philippine Sea. In contrast, the chemical composition of illite at ODP Site 1146 has no obvious differences from those of the Loess plateau, Yellow River, Yangtze River, and Pearl River. A further study on sediment source indicates that smectite originates mainly from Luzon, kaolinite from the Pearl River, and illite and chlorite from the Pearl River, Taiwan and/or the Yangtze River. The clay mineral assemblages at ODP Site 1146 were not only controlled by continental eathering regimes surrounding the SCS, but also by the changing strength of the transport processes. The ratios of （illite＋chlorite）/smectite at ODP Site 1146 were adopted as proxies for the East Asian monsoon evolution. Relatively higher ratios reflect strongly intensified winter monsoon relative to summer monsoon, in contrast, lower ratios indicate a strengthened summer monsoon relative to winter monsoon. The consistent variation of this clay proxy from those of Loess plateau, eolian deposition in the North Pacific, planktonic, benthic foraminifera, and black carbon in the SCS since 20 Ma shows that three profound shifts of the East Asian winter monsoon intensity, and aridity in the Asian inland and the intensity of winter monsoon relative to summer monsoon, occurred at about 15 Ma, 8 Ma, and the younger at about 3 Ma. The phased uplift of the Himalaya-Tibetan plateau may have played a significant role in strengthening the Asian monsoon at 15 Ma, 8 Ma, and 3 Ma.

Distribution and dispersal pattern of clay minerals in surface sediments,eastern Beibu Gulf,South China Sea

Clay minerology of sediments are useful in determining distribution, sources and dispersal routes of fine-grained sediments. In the present paper, clay minerals of surface sediments throughout the eastern part of Beibu Gulf has been investigated to reveal sources and transport of detrital fine- grained sediments. Four distinct clay mineral suites were observed from cluster analysis of clay mineral compositions of the samples. From the distribution pattern of clay minerals, we conclude that kaolinte in the eastern gulf is mainly derived from South China Landmass; Smectite could not be transported mainly by surface current from north-western Hainan Island, and maybe minor portion of it from Red River; Illite is mainly transported by the currents fl＇om South China Sea. Chlorite has two sources, namely South China Sea and South China Landmass. The Zhujiang River derived sediments could not be one of the sources for the clay mineral here, because of very different composition and ratios. The distribution pattern of clay minerals in the eastern Beibu Gulf is mainly controlled by fine-grained sediment source and local currents. The Silt/Clay, Smectite/Kaolinte, and Smetite/（Chlorite＋Illite） ratios could be used as indicators of fine-grained sediment dispersal in the gulf.

Speleogenesis of Selected Caves beneath the Lunan Shilin and Caves of Fenglin Karst in Qiubei, Yunnan

Yunnan is famous for its attractive karst landscapes especially shilins, fengcong and fenglin. The development of caves beneath the shilins in the vicinity of Lunan is closely connected with the formation of shilins. Most of the waters percolating through shilins run through the caves beneath them and are responsible for their formation. The study of cave speleogenesis deepens knowledge about both the development of shilins and karst structure. In the vicinity of the Lunan Shilin, speleological, morphological and structural geological studies of four karst caves have been accomplished. At Puzhehei, Qiubei, which is characterised by numerous fenglin, fengcong and caves, speleological and morphological studies have been performed. Cave sediments for paleomagnetic analyses have been taken from all studied areas (samples CH 1-9). Karst caves in SE Yunnan are probably much older than the age of the cave sediments (<780,000 years B.P.). The studied areas are located in the vicinity of the Xiaojiang fault (N-S direction I and the Red River fault (NW-SE direction). The general directions of both active faults are assumed to influence the direction of the most frequent fissures as well as the cave passages near the Lunan Shilin. The Xiaojiang fault more strongly influences cave passage orientation, while the more distant Red River fault most strongly influences fissure orientation.

Impacts of precipitation variation and soil and water conservation measures on runoff and sediment yield in the Loess Plateau Gully Region, China

The Loess Plateau of China has experienced a lengthy drought and severe soil erosion.Changes in precipitation and land use largely determine the dynamics of runoff and sediment yield in this region. Trend and mutation analyses were performed on hydrological data(1981–2012) from the Yanwachuan watershed in the Loess Plateau Gully Region to study the evolution characteristics of runoff and sediment yield. A time-series contrasting method also was used to evaluate the effects of precipitation and soil and water conservation(SWC) on runoff and sediment yield. Annual sediment yield declined markedly from 1981 to 2012 although there was no significant change in annual precipitation and annual runoff. Change points of annual runoff and annual sediment yield occurred in 1996 and 1997,respectively. Compared with that in the baseline period(1981–1996), annual runoff and annual sediment yield in the change period(1997–2012)decreased by 17.0% and 76.0%, respectively, but annual precipitation increased by 6.3%. Runoff decreased in the flood season and normal season, but increased in the dry season, while sediment yield significantly declined in the whole study period. The SWC measures contributed significantly to the reduction of annual runoff(137.9%) and annual sediment yield(135%) and were more important than precipitation. Biological measures(forestland and grassland) accounted for 61.04% of total runoff reduction, while engineering measures(terraces and dams) accounted for 102.84% of total sediment yield reduction. Furthermore, SWC measures had positive ecological effects. This study provides a scientific basis for soil erosion control on the Loess Plateau.

Baiyun Cave in Naigu Shilin,Yunnan Karst,China

The Baiyun cave is a 380 m long karst cave in the Naigu Shilin, situated 70 km southeast of Kunming, Yunnan Province, China. The prevailing orientations of the cave passages are N110°–120°E and N0°-10°W and those of the fissures in the cave are N30°–40°W and N20°–30°W. The cave is developed in the thick-bedded Lower Permian Qixia Formation. The cave has an active water flow and is currently at the near water-table stage. There are large amounts of different infills of cave sediments. The cave shows different stages of paragenesis. The palaeomagnetic analysis of cave sediments shows that their ages are younger than 780 ka B.P. (the Brunhes Chron). The upper part of the sampled profile belongs to the reverse Blake event (112.3–117.9 ka B.P.). The formation of the Baiyun cave is directly connected with the development of the Naigu Shilin. The formation of karst underground and surface features depends on the regional tectonic deformation and the Cenozoic extension of the study area.

Diatom distribution and its relationship to sediment property in the Minjiang Estuary, southeast China

The distribution of diatoms in surface sediments in the Minjiang Estuary, southeast China, was investigated in2009. Total 56 species and other species belonging to 25 genera were identified, among them 11 species were dominant over 5%. Dominant species included Actinocyclus ehrenbergii, Coscinodiscus curvatulus, C. divisus, C.jonesianus, C. radiatus, C. rothii, C. subtilis, Cyclotella stylorum, Epithemia hyndmanii, Hydrosera whampoensis,and Trachyneis aspera. Diatom abundance varied spatially, with the absolute abundance of diatoms ranging from13 valves/g to 11×104 valves/g, and averaging 2.5×104 valves/g. A canonical correspondence analysis（CCA） was used to explain the relationships between diatom distribution and sediment properties in the Minjiang Estuary.CCA revealed that the major elements（Fe_2O_3, Na_2O, CaO, MgO, TiO_2, SiO_2, Al_2O_3, and K_2O） were closely related to diatom abundance. Four diatom assemblages were distinguished, representing different sediment properties,which may assist late Quaternary palaeoceanographic reconstructions of the Minjiang Estuary.

Classifying the sedimentary environments of the Xincun Lagoon,Hainan Island,by system cluster and principal component analyses

An understanding of the sedimentary environment in relation to its controlling factors is of great importance in coastal geomorphology,ecology,tourism and aquaculture studies.We attempt to deal with this issue,using a case study from the Xincun Lagoon,Hainan Island in southern China.For the study,surficial sediment samples were collected,together with hydrodynamic and bathymetric surveys,during August 2013.Numerical simulation was carried out to obtain high-spatial resolution tidal current data.The sediment samples were analyzed to derive mean grain size,sorting coefficient,skewness and kurtosis,together with the sand,silt and clay contents.The modern sedimentary environments were classified using system cluster and principal component analyses.Grain size analysis reveals that the sediments are characterized by extremely slightly sandy silty mud（ESSSM） and slightly silty sand（SSS）,which are distributed in the central lagoon and near-shore shallow water areas,respectively.Mean grain size varies from 0 to 8.0Ф,with an average of 4.6Ф.The silt content is the highest,i.e.,52% on average,with the average contents of sand and clay being 43% and 5%,respectively.There exists a significant correlation between mean size and water depth,suggesting that the surficial sediments become finer with increasing water depth.Cluster analyses reveals two groups of samples.The first group is characterized by mean grain size of more than 5.5Ф,whilst the second group has mean grain size of below 3.5Ф.Further,these groups also have different correlations between mean grain size and the other grain size parameters.In terms of the tidal current,the average values of the root mean square velocity（RMSV） are 7.5 cm/s and 6.9 cm/s on springs and neaps,respectively.For the RMSVs that are higher than 4 cm/s,a significant positive correlation is found between the content of the 63–125 μm fraction and the RMSV,suggesting that the RMSV determines the variability of the very fine sand fraction.Based on system cluster and principal component analyses（PCA）,the modern sedimentary environments are classified into three types according to the grain size parameters,RMSVs and water depth data.The results suggest the importance of grain size parameters and high-spatial resolution hydrodynamic data in differentiating the coastal sedimentary environments.

Microbial ecological associations in the surface sediments of Bohai Strait

Microbial communities play key roles in the marine ecosystem. Despite a few studies on marine microbial communities in deep straits, ecological associations among microbial communities in the sediments of shallow straits have not been fully investigated. The Bohai Strait in northern China(average depth less than 20 m) separates the Bohai Sea from the Yellow Sea and has organic-rich sediments. In this study, in the summer of 2014, six stations across the strait were selected to explore the taxonomic composition of microbial communities and their ecological associations. The four most abundant classes were Gammaproteobacteria, Deltaproteobacteria, Bacilli and Flavobacteriia. Temperature, total carbon, depth, nitrate, fishery breeding and cold water masses influenced the microbial communities, as suggested by representational dif ference and composition analyses. Network analysis of microbial associations revealed that key families included Flavobacteriaceae, Pirellulaceae and Piscirickettsiaceae. Our findings suggest that the families with high phylogenetic diversity are key populations in the microbial association network that ensure the stability of microbial ecosystems. Our study contributes to a better understanding of microbial ecology in complex hydrological environments.

Theoretical analysis of acoustic suspended sediment observation

A theoretical analysis of designing an acoustic backscatter system for observations of suspended sediments has been made through a derived sonar equation. Some formulae and data for reference in determining several main technical parameters of the system, such as optimum frequency, sound transmission power, aperture of transducer etc., airs provided. And some key problems on the acoustic observation of suspended sediments, such as data processing of a time--Varying stochastic process, compensation of sound propagation loss in complicated conditions and in-situ calibration of sediment concentration, are discussed in detail. The results of the analysis could be helpful to the development and application of a specific acoustic backscatter instrument (e.g. the acoustic sediment concentration profiler, the acoustic Doppler current profiler etc.).

Risk Assessment of Heavy Metal Pollution in Sediments of the Fenghe River by the Fuzzy Synthetic Evaluation Model and Multivariate Statistical Methods

Concentrations of heavy metals in 74 sediment samples from the Fenghe River, which originates from the north of the Qinling Mountains and flows through Xi'an, Shaanxi Province, China, were characterized by employing geographic information system(GIS)mapping, fuzzy synthetic assessment, and multivariate statistical analysis to determine the enrichment characteristics of heavy metals as well as their potential risks of pollution to sediments. Al, Cd, and Co were the major pollutants, with a high enrichment factor(EF) value. Heavy metal concentrations from samples near the paper plant were maintained at a high level. Significant enrichment of Al, Ba, Cr, Ni, Pb, and Co was found in the midstream and downstream, while high concentration of Cu occurred in the headwater stream. Based on the cluster and principal component analyses, sediment metals mainly came from the paper plants, agronomic practices, natural sources, and tourism, with a contribution of 51.59%, 23.01%, 14.21%, and 9.88%, respectively. Sediment pollution assessment explored using fuzzy theory based on the entropy method and toxicity coefficient showed that 26, 32, and 11 sites fell into Class III(slightly polluted), Class IV(moderately polluted), and Class V(heavily polluted), respectively, and their scores of membership degree in the polluted level were on the rise, suggesting a relatively high degree of sediment metal pollution in the study area. Closely related to the excessive industrial and agricultural applications, metal pollution in sediment is necessary to be addressed in the Fenghe River.

Spatial distribution and pollution assessment of mercury in sediments of Lake Taihu,China

Spatial distribution patterns of total mercury （THg） in 36 surficial sediment samples representing five regions of Lake Taihu were assessed using the ArcGis geostatistical analyst module. The pollution levels of THg were also evaluated from the same five lake regions. Concentrations of THg were in a ranged of 23-168 ng/g （mean 55 ng/g） in surfical sediments, which was significantly higher than those established baseline levels of the lake. Results of THg indicated that the northern region exhibited notably higher values, the bay regions showed elevated values relative to open areas, and the lakeside regions were higher than those observed in the central area. Lake Taihu suffered moderate to high Hg pollution, and expressed clear Hg enrichment status according to monomial pollution index I geo and human activity factors. The concentrations of THg in the surficial sediments of Lake Taihu showed moderate-strong variation （coefficient of variation 52%）. Geostatistical analysis indicated a weak spatial self-correlation, suggesting the contamination of Hg in Lake Taihu is primarily the result of anthropogenic activities.

Attenuation of arsenic in a karst subterranean stream and correlation with geochemical factors: A case study at Lihu,South China

Arsenic （As） pollutants generated by human activities in karst areas flow into subterranean streams and contaminate groundwater easily because of the unique hydrogeological characteristics of karst areas. To elucidate the reaction mechanisms of arsenic in karst subterranean streams, physical-chemical analysis was conducted by an inductively coupled plasma mass spectrometer and an X-ray fluorescence spectrometer. The results show that inorganic species account for most of the total arsenic, whereas organic arsenic is not detected or occurs in infinitesimal amounts. As（III） accounts for 51.0% ± 9.9% of the total inorganic arsenic. Arsenic attenuation occurs and the attenuation rates of total As, As（III） and As（V） in the Lihu subterranean stream are 51%, 36% and 59%, respectively. To fully explain the main geochemical factors influencing arsenic attenuation, SPSS 13.0 and CANOCO 4.5 bundled with CanoDraw for Windows were used for simple statistical analysis and redundancy analysis （RDA）. Eight main factors, i.e., sediment iron （SFe）, sediment aluminum （SAI）, sediment calcium （SCa）, sediment organic matter （SOM）, sediment manganese （SMn）, water calcium （WCa^2＋）, water magnesium （WMg^2＋）, and water bicarbonate ion （WILCOX） were extracted from thirteen indicators. Their impacts on arsenic content rank as： SFe〉SCa〉WCa^2＋〉SAl〉wHCO3^-〉SMn〉SOM〉WMg^2＋. Of these factors, SFe, SAl, SCa, SOM, SMn, WMg^2＋ and WCa＆2＋ promote arsenic attenuation, whereas WHCO3^- inhibits it. Further investigation revealed that the redox potential （Eh） and pH are adverse to arsenic removal. The dramatic distinction between karst and non-karst terrain is that calcium and bicarbonate are the primary factors influencing arsenic migration in karst areas due to the high calcium concentration and alkalinity of karst water.