In this paper,we mainly discuss a discrete estimation of the average differential entropy for a continuous time-stationary ergodic space-time random field.By estimating the probability value of a time-stationary rando...In this paper,we mainly discuss a discrete estimation of the average differential entropy for a continuous time-stationary ergodic space-time random field.By estimating the probability value of a time-stationary random field in a small range,we give an entropy estimation and obtain the average entropy estimation formula in a certain bounded space region.It can be proven that the estimation of the average differential entropy converges to the theoretical value with a probability of 1.In addition,we also conducted numerical experiments for different parameters to verify the convergence result obtained in the theoretical proofs.展开更多
2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed...2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.展开更多
By combining multiscale stationary wavelet analysis with fuzzy c-means, a robust edge detection algorithm is presented. Based on the translation invafiance built in multiscale stationary wavelet transform, components ...By combining multiscale stationary wavelet analysis with fuzzy c-means, a robust edge detection algorithm is presented. Based on the translation invafiance built in multiscale stationary wavelet transform, components in different transformed sub-images corresponding to a pixel are employed to form a feature vector of the pixel. All the feature vectors are classified with unsupervised fuzzy c-means to segment the image, and then the edge pixels are checked out by the Canny detector. A series of images contaminated with different intensive Gaussian noises are used to test the novel algorithm. Experiments show that fairly precise edges can be checked out robustly from those images with fairly intensive noise by the proposed algorithm.展开更多
A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It ex...A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It exhibited separation abilities to disubstituted benzene isomers and some chiral solutes. It was also found that the polarity of CD derivatives can be lowered both by chemically bonding it to polysiloxane and by diluting it in polysiloxane. The separation abilities of the polysiloxane anchored CDs (SP CD) are higher than that of the unbonded CDs (S CD) and the diluted S CD at lower column temperature. Hydrosilylation reaction is one of the best methods to lower the operating temperature of CDs.展开更多
In the literature,stationary phase analysis of Kirchhoff-type demigrated fields is carried out mainly under the following two conditions:(1) The considered isochrone and the target reflector are tangential to each ...In the literature,stationary phase analysis of Kirchhoff-type demigrated fields is carried out mainly under the following two conditions:(1) The considered isochrone and the target reflector are tangential to each other;(2) The spatial duration of the wavelet of the depthmigrated image is short.For the isochrones that are not tangential to the target reflector and for the depth-migrated images that have a large spatial duration,the published stationary phase equation for the demigrated field will become invalid.For performing the stationary phase analysis of the Kirchhoff-type demigrated field under the conditions that the considered isochrone and the target reflector are not tangential to each other and that the spatial duration of the wavelet of the depth-migrated image is not short(the general conditions),I derive the formulas for the factors appearing in the stationary phase formula in two dimensions,from which I find that for different isochrones the horizontal coordinates of the stationary point of the depth difference function are different.Also,the equation for the Kirchhoff-type demigrated field consists of two parts.One is the true-amplitude demigrated signal and the other is the amplitude distortion factor.From these facts the following two conclusions can be drawn:(1) A demigrated signal is composed of many depth-migrated images and one depth-migrated image trace provides only one sample to the demigrated signal;and(2) The amplitude distortion effect is an effect inherent in the Kirchhoff-type demigration and cannot be eliminated during demigration.If this effect should be eliminated,one should do an amplitude correction after demigration.展开更多
Predicting the time-varying auto-spectral density of a spacecraft in high-altitude orbits requires an accurate model for the non-stationary random vibration signals with densely spaced modal frequency. The traditional...Predicting the time-varying auto-spectral density of a spacecraft in high-altitude orbits requires an accurate model for the non-stationary random vibration signals with densely spaced modal frequency. The traditional time-varying algorithm limits prediction accuracy, thus affecting a number of operational decisions. To solve this problem, a time-varying auto regressive (TVAR) model based on the process neural network (PNN) and the empirical mode decomposition (EMD) is proposed. The time-varying system is tracked on-line by establishing a time-varying parameter model, and then the relevant parameter spectrum is obtained. Firstly, the EMD method is utilized to decompose the signal into several intrinsic mode functions (IMFs). Then for each IMF, the PNN is established and the time-varying auto-spectral density is obtained. Finally, the time-frequency distribution of the signals can be reconstructed by linear superposition. The simulation and the analytical results from an example demonstrate that this approach possesses simplicity, effectiveness, and feasibility, as well as higher frequency resolution.展开更多
The motion of the self-gravitational gaseous stars can be described by the Euler-Poisson equations. The main purpose of this paper is concerned with the existence of stationary solutions of Euler-Poisson equations for...The motion of the self-gravitational gaseous stars can be described by the Euler-Poisson equations. The main purpose of this paper is concerned with the existence of stationary solutions of Euler-Poisson equations for some velocity fields and entropy functions that solve the conservation of mass and energy. Under different restriction to the strength of velocity field, we get the existence and multiplicity of the stationary solutions of Euler-Poisson system.展开更多
A class of stationary models of singular stochastic control has been studied, in which the state is extended to solution of a class of S.D.E. from Wiener process. The existence of optimal control has been proved in al...A class of stationary models of singular stochastic control has been studied, in which the state is extended to solution of a class of S.D.E. from Wiener process. The existence of optimal control has been proved in all cases under some weaker conditions, and the structure of optimal control may be characterized.展开更多
The current development of precision plastic injection molding machines mainly focuses on how to save material and improve precision, but the two aims contradict each other. For a clamp unit, clamping precision improv...The current development of precision plastic injection molding machines mainly focuses on how to save material and improve precision, but the two aims contradict each other. For a clamp unit, clamping precision improving depends on the design quality of the stationary platen. Compared with the parametric design of stationary platen, structural scheme design could obtain the optimization model with double objectives and multi-constraints. In this paper, a SE-160 precision plastic injection molding machine with 1600 kN clamping force is selected as the subject in the case study. During the motion of mold closing and opening, the stationary platen of SE-160 is subjected to a cyclic loading, which would cause the fatigue rupture of the tie bars in periodically long term operations. In order to reduce the deflection of the stationary platen, the FEA method is introduced to optimize the structure of the stationary platen. Firstly, an optimal topology model is established by variable density method. Then, structural topology optimizations of the stationary platen are done with the removable material from 50%, 60% to 70%. Secondly, the other two recommended optimization schemes are given and compared with the original structure. The result of performances comparison shows that the scheme II of the platen is the best one. By choosing the best alternative, the volume and the local maximal stress of the platen could be decreased, corresponding to cost-saving material and better mechanical properties. This paper proposes a structural optimization design scheme, which can save the material as well as improve the clamping precision of the precision plastic injection molding machine.展开更多
Using 1958-2002 NCEPNCAR reanalysis data, we investigate stationary and transient planetary wave propagation and its role in wave-mean flow interaction which influences the state of the polar vortex (PV) in the stra...Using 1958-2002 NCEPNCAR reanalysis data, we investigate stationary and transient planetary wave propagation and its role in wave-mean flow interaction which influences the state of the polar vortex (PV) in the stratosphere in Northern Hemisphere (NH) winter. This is done by analyzing the Eliassen-Palm (E-P) flux and its divergence. We find that the stationary and transient waves propagate upward and equatorward in NH winter, with stronger upward propagation of stationary waves from the troposphere to the stratosphere, and stronger equatorward propagation of transient waves from mid-latitudes to the subtropics in the troposphere. Stationary waves exhibit more upward propagation in the polar stratosphere during the weak polar vortex regime (WVR) than during the strong polar vortex regime (SVR). On the other hand, transient waves have more upward propagation during SVR than during WVR in the subpolar stratosphere, with a domain of low frequency waves. With different paths of upward propagation, both stationary and transient waves contribute to the maintenance of the observed stratospheric PV regimes in NH winter.展开更多
This paper presents the enantioseparation using glucose, cellobiose, lactose and raffinose as chiral selector bonded to silica gel via an arm in HPLC. Surprisingly, they also possess high enantioseparation selectivity...This paper presents the enantioseparation using glucose, cellobiose, lactose and raffinose as chiral selector bonded to silica gel via an arm in HPLC. Surprisingly, they also possess high enantioseparation selectivity, may be used in normal-phase and reversed- phase mode, and there is a big chiral discriminating complementary. This work indicates that oligosaccharides could soon become very attractive as a new class of chiral stationary phase for HPLC.展开更多
In this article, a new stable nonconforming mixed finite element scheme is proposed for the stationary Navier-Stokes equations, in which a new low order Crouzeix- Raviart type nonconforming rectangular element is take...In this article, a new stable nonconforming mixed finite element scheme is proposed for the stationary Navier-Stokes equations, in which a new low order Crouzeix- Raviart type nonconforming rectangular element is taken for approximating space for the velocity and the piecewise constant element for the pressure. The optimal order error estimates for the approximation of both the velocity and the pressure in L2-norm are established, as well as one in broken H1-norm for the velocity. Numerical experiments are given which are consistent with our theoretical analysis.展开更多
Single-walled carbon nanotubes(SWNTs) have a high adsorption ability and nanoscale interactions. Cellulose trisphenylcarbamates possess high enantioseparation ability in high-performance liquid chromatography(HPLC...Single-walled carbon nanotubes(SWNTs) have a high adsorption ability and nanoscale interactions. Cellulose trisphenylcarbamates possess high enantioseparation ability in high-performance liquid chromatography(HPLC). Single-walled carbon nanotubes mixed with cellulose trisphenylcarbamate are coated on the silica gel as chiral stationary phases and higher enantioseparation factors are obtained. After a single-walled carbon nanotube is linked to the 6-pesition of cellulose 2,3-bisphenylcarbamate, its enantioseparation resolution increases compared to that of the cellulose trisphenylcarbamate. It is the first time that SWNTs have been applied to enantioseparation. The results indicate that the single-walled carbon nanotubes are good promoters of chiral recognition. This method can be used to improve the enantioseparation efficiency of the polysaccharide chiral stationary phases.展开更多
The enantiomers separation of thirteen drugs collected in Ch.P2010 was performed on chiral stationary phase of cellulose ramification (chiralpak OD and chiralpak OJ) by high performance liquid chromatographic (HPLC) m...The enantiomers separation of thirteen drugs collected in Ch.P2010 was performed on chiral stationary phase of cellulose ramification (chiralpak OD and chiralpak OJ) by high performance liquid chromatographic (HPLC) methods, which included ibuprofen (C1), ketoprofen (C2), nitrendipine (C3), nimodipine (C4), felodipine (C5), omeprazole (C6), praziquantel (C7), propranolol hydrochloride (C8), atenolol (C9), sulpiride (C10), clenbuterol hydrochloride (C11), verapamil hydrochloride (C12), and chlorphenamine maleate (C13). The mobile phase consisted of isopropanol and n-hexane. The detection wavelength was set at 254 nm and the fiow rate was 0.7 mL/min. The enantiomers separation of these thirteen racemates on chiralpak OD column and chiralpak OJ column was studied, while the effects of proportion of organic additives, alcohol displacer and temperature on the separation were studied. And the mechanism of some of racemates was discussed. The results indicated that thirteen chiral drugs could be separated onchiral stationary phase of cellulose ramification in normal phase chromatographic system. The chromatographic retention and resolution of enantiomers could be adjusted by factors including column temperature and the concentration of alcohol displacer and organic alkaline modifier in mobile phase. It was shown that the resolution was improved with reducing concentration of alcohol displacer. When concentration of organic alkaline modifier was 0.2% (v/v), the resolution and the peak shape were fairly good. Most racemates mentioned above had better resolution at column temperature of 25 1C. When racemates were separated, the temperature should be kept so as to obtain stable separation results.展开更多
In this paper, the uniqueness of stationary solutions with vacuum of Euler-Poisson equations is considered. Through a nonlinear transformation which is a function of density and entropy, the corresponding problem can ...In this paper, the uniqueness of stationary solutions with vacuum of Euler-Poisson equations is considered. Through a nonlinear transformation which is a function of density and entropy, the corresponding problem can be reduced to a semilinear elliptic equation with a nonlinear source term consisting of a power function, for which the classical theory of the elliptic equations leads the authors to the uniqueness result under some assumptions on the entropy function S(x). As an example, the authors get the uniqueness of stationary solutions with vacuum of Euler-Poisson equations for S(x) =|x|θandθ∈{0}∪[2(N-2),+∞).展开更多
Three novel chiral selectors 4a-c were synthesized from (S)-amino acids and (R)-1-phenyl-2-(4-methylphenyl)ethylamine. 4a-c were connected to 3-aminopropylsilanized silica gel to be used as the chiral stationary...Three novel chiral selectors 4a-c were synthesized from (S)-amino acids and (R)-1-phenyl-2-(4-methylphenyl)ethylamine. 4a-c were connected to 3-aminopropylsilanized silica gel to be used as the chiral stationary phase for HPLC. Five amino acid derivatives and two pyrethroid insecticides were fairly resolved on these three new chiral stationary phases under normal phase condition.展开更多
In this article, we are concerned with the stability of stationary solution for outflow problem on the Navier-Stokes-Poisson system. We obtain the unique existence and the asymptotic stability of stationary solution. ...In this article, we are concerned with the stability of stationary solution for outflow problem on the Navier-Stokes-Poisson system. We obtain the unique existence and the asymptotic stability of stationary solution. Moreover, the convergence rate of solution towards stationary solution is obtained. Precisely, if an initial perturbation decays with the algebraic or the exponential rate in space, the solution converges to the corresponding stationary solution as time tends to infinity with the algebraic or the exponential rate in time. The proof is based on the weighted energy method by taking into account the effect of the self-consistent electric field on the viscous compressible fluid.展开更多
基金supported by the Shenzhen sustainable development project:KCXFZ 20201221173013036 and the National Natural Science Foundation of China(91746107).
文摘In this paper,we mainly discuss a discrete estimation of the average differential entropy for a continuous time-stationary ergodic space-time random field.By estimating the probability value of a time-stationary random field in a small range,we give an entropy estimation and obtain the average entropy estimation formula in a certain bounded space region.It can be proven that the estimation of the average differential entropy converges to the theoretical value with a probability of 1.In addition,we also conducted numerical experiments for different parameters to verify the convergence result obtained in the theoretical proofs.
基金supported by the Research and Development Project of“Jianbing”in Zhejiang Province(2024C01085)Natural Science and Foundation of Ningbo(2022J052).
文摘2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.
文摘By combining multiscale stationary wavelet analysis with fuzzy c-means, a robust edge detection algorithm is presented. Based on the translation invafiance built in multiscale stationary wavelet transform, components in different transformed sub-images corresponding to a pixel are employed to form a feature vector of the pixel. All the feature vectors are classified with unsupervised fuzzy c-means to segment the image, and then the edge pixels are checked out by the Canny detector. A series of images contaminated with different intensive Gaussian noises are used to test the novel algorithm. Experiments show that fairly precise edges can be checked out robustly from those images with fairly intensive noise by the proposed algorithm.
文摘A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It exhibited separation abilities to disubstituted benzene isomers and some chiral solutes. It was also found that the polarity of CD derivatives can be lowered both by chemically bonding it to polysiloxane and by diluting it in polysiloxane. The separation abilities of the polysiloxane anchored CDs (SP CD) are higher than that of the unbonded CDs (S CD) and the diluted S CD at lower column temperature. Hydrosilylation reaction is one of the best methods to lower the operating temperature of CDs.
基金supported by the National Natural Science Foundation of China (Grant No.40574052)
文摘In the literature,stationary phase analysis of Kirchhoff-type demigrated fields is carried out mainly under the following two conditions:(1) The considered isochrone and the target reflector are tangential to each other;(2) The spatial duration of the wavelet of the depthmigrated image is short.For the isochrones that are not tangential to the target reflector and for the depth-migrated images that have a large spatial duration,the published stationary phase equation for the demigrated field will become invalid.For performing the stationary phase analysis of the Kirchhoff-type demigrated field under the conditions that the considered isochrone and the target reflector are not tangential to each other and that the spatial duration of the wavelet of the depth-migrated image is not short(the general conditions),I derive the formulas for the factors appearing in the stationary phase formula in two dimensions,from which I find that for different isochrones the horizontal coordinates of the stationary point of the depth difference function are different.Also,the equation for the Kirchhoff-type demigrated field consists of two parts.One is the true-amplitude demigrated signal and the other is the amplitude distortion factor.From these facts the following two conclusions can be drawn:(1) A demigrated signal is composed of many depth-migrated images and one depth-migrated image trace provides only one sample to the demigrated signal;and(2) The amplitude distortion effect is an effect inherent in the Kirchhoff-type demigration and cannot be eliminated during demigration.If this effect should be eliminated,one should do an amplitude correction after demigration.
基金Aeronautical Science Foundation of China (20071551016)
文摘Predicting the time-varying auto-spectral density of a spacecraft in high-altitude orbits requires an accurate model for the non-stationary random vibration signals with densely spaced modal frequency. The traditional time-varying algorithm limits prediction accuracy, thus affecting a number of operational decisions. To solve this problem, a time-varying auto regressive (TVAR) model based on the process neural network (PNN) and the empirical mode decomposition (EMD) is proposed. The time-varying system is tracked on-line by establishing a time-varying parameter model, and then the relevant parameter spectrum is obtained. Firstly, the EMD method is utilized to decompose the signal into several intrinsic mode functions (IMFs). Then for each IMF, the PNN is established and the time-varying auto-spectral density is obtained. Finally, the time-frequency distribution of the signals can be reconstructed by linear superposition. The simulation and the analytical results from an example demonstrate that this approach possesses simplicity, effectiveness, and feasibility, as well as higher frequency resolution.
基金supported by NSFC (10631030, 11071094)the fund of CCNU for Ph.D students (2009021)
文摘The motion of the self-gravitational gaseous stars can be described by the Euler-Poisson equations. The main purpose of this paper is concerned with the existence of stationary solutions of Euler-Poisson equations for some velocity fields and entropy functions that solve the conservation of mass and energy. Under different restriction to the strength of velocity field, we get the existence and multiplicity of the stationary solutions of Euler-Poisson system.
基金Supported by the National Science Foundation of China.
文摘A class of stationary models of singular stochastic control has been studied, in which the state is extended to solution of a class of S.D.E. from Wiener process. The existence of optimal control has been proved in all cases under some weaker conditions, and the structure of optimal control may be characterized.
基金Supported by National Natural Science Foundation of China(Grant No.51205350)Hong Kong Scholars Program of China(Grant No.XJ2013015)Zhejiang Provincial Research Program of Public Welfare Technology Application of China(Grant No.2013C31027)
文摘The current development of precision plastic injection molding machines mainly focuses on how to save material and improve precision, but the two aims contradict each other. For a clamp unit, clamping precision improving depends on the design quality of the stationary platen. Compared with the parametric design of stationary platen, structural scheme design could obtain the optimization model with double objectives and multi-constraints. In this paper, a SE-160 precision plastic injection molding machine with 1600 kN clamping force is selected as the subject in the case study. During the motion of mold closing and opening, the stationary platen of SE-160 is subjected to a cyclic loading, which would cause the fatigue rupture of the tie bars in periodically long term operations. In order to reduce the deflection of the stationary platen, the FEA method is introduced to optimize the structure of the stationary platen. Firstly, an optimal topology model is established by variable density method. Then, structural topology optimizations of the stationary platen are done with the removable material from 50%, 60% to 70%. Secondly, the other two recommended optimization schemes are given and compared with the original structure. The result of performances comparison shows that the scheme II of the platen is the best one. By choosing the best alternative, the volume and the local maximal stress of the platen could be decreased, corresponding to cost-saving material and better mechanical properties. This paper proposes a structural optimization design scheme, which can save the material as well as improve the clamping precision of the precision plastic injection molding machine.
基金supported by the National Basic Research Program of China (Grant Nos2010CB428602 and 2010CB428502)the National Natural Science Foundation of China (Grant No 41005023)the Program for New Century Excellent Talents in University (Grant No NCET-09-0227)
文摘Using 1958-2002 NCEPNCAR reanalysis data, we investigate stationary and transient planetary wave propagation and its role in wave-mean flow interaction which influences the state of the polar vortex (PV) in the stratosphere in Northern Hemisphere (NH) winter. This is done by analyzing the Eliassen-Palm (E-P) flux and its divergence. We find that the stationary and transient waves propagate upward and equatorward in NH winter, with stronger upward propagation of stationary waves from the troposphere to the stratosphere, and stronger equatorward propagation of transient waves from mid-latitudes to the subtropics in the troposphere. Stationary waves exhibit more upward propagation in the polar stratosphere during the weak polar vortex regime (WVR) than during the strong polar vortex regime (SVR). On the other hand, transient waves have more upward propagation during SVR than during WVR in the subpolar stratosphere, with a domain of low frequency waves. With different paths of upward propagation, both stationary and transient waves contribute to the maintenance of the observed stratospheric PV regimes in NH winter.
基金National Natural Science Foundation and Yunnan Province's Natural Science Foundation of China(No.20775066No.2005E0006Z).
文摘This paper presents the enantioseparation using glucose, cellobiose, lactose and raffinose as chiral selector bonded to silica gel via an arm in HPLC. Surprisingly, they also possess high enantioseparation selectivity, may be used in normal-phase and reversed- phase mode, and there is a big chiral discriminating complementary. This work indicates that oligosaccharides could soon become very attractive as a new class of chiral stationary phase for HPLC.
文摘In this article, a new stable nonconforming mixed finite element scheme is proposed for the stationary Navier-Stokes equations, in which a new low order Crouzeix- Raviart type nonconforming rectangular element is taken for approximating space for the velocity and the piecewise constant element for the pressure. The optimal order error estimates for the approximation of both the velocity and the pressure in L2-norm are established, as well as one in broken H1-norm for the velocity. Numerical experiments are given which are consistent with our theoretical analysis.
基金Supported by the National Natural Science Foundation of China(No.30160092)the Natural Science Foundation of Yunnan Province,China(No.2005E0006Z).
文摘Single-walled carbon nanotubes(SWNTs) have a high adsorption ability and nanoscale interactions. Cellulose trisphenylcarbamates possess high enantioseparation ability in high-performance liquid chromatography(HPLC). Single-walled carbon nanotubes mixed with cellulose trisphenylcarbamate are coated on the silica gel as chiral stationary phases and higher enantioseparation factors are obtained. After a single-walled carbon nanotube is linked to the 6-pesition of cellulose 2,3-bisphenylcarbamate, its enantioseparation resolution increases compared to that of the cellulose trisphenylcarbamate. It is the first time that SWNTs have been applied to enantioseparation. The results indicate that the single-walled carbon nanotubes are good promoters of chiral recognition. This method can be used to improve the enantioseparation efficiency of the polysaccharide chiral stationary phases.
基金supported by the National Science and Technology Special Projects (No.2009zx09301-003-5 -1 and2009zx09301-003-7-1)
文摘The enantiomers separation of thirteen drugs collected in Ch.P2010 was performed on chiral stationary phase of cellulose ramification (chiralpak OD and chiralpak OJ) by high performance liquid chromatographic (HPLC) methods, which included ibuprofen (C1), ketoprofen (C2), nitrendipine (C3), nimodipine (C4), felodipine (C5), omeprazole (C6), praziquantel (C7), propranolol hydrochloride (C8), atenolol (C9), sulpiride (C10), clenbuterol hydrochloride (C11), verapamil hydrochloride (C12), and chlorphenamine maleate (C13). The mobile phase consisted of isopropanol and n-hexane. The detection wavelength was set at 254 nm and the fiow rate was 0.7 mL/min. The enantiomers separation of these thirteen racemates on chiralpak OD column and chiralpak OJ column was studied, while the effects of proportion of organic additives, alcohol displacer and temperature on the separation were studied. And the mechanism of some of racemates was discussed. The results indicated that thirteen chiral drugs could be separated onchiral stationary phase of cellulose ramification in normal phase chromatographic system. The chromatographic retention and resolution of enantiomers could be adjusted by factors including column temperature and the concentration of alcohol displacer and organic alkaline modifier in mobile phase. It was shown that the resolution was improved with reducing concentration of alcohol displacer. When concentration of organic alkaline modifier was 0.2% (v/v), the resolution and the peak shape were fairly good. Most racemates mentioned above had better resolution at column temperature of 25 1C. When racemates were separated, the temperature should be kept so as to obtain stable separation results.
基金the Natural Science Foundation of China and the Excellent Teachers Foundation of Ministry of Education of China.
文摘In this paper, the uniqueness of stationary solutions with vacuum of Euler-Poisson equations is considered. Through a nonlinear transformation which is a function of density and entropy, the corresponding problem can be reduced to a semilinear elliptic equation with a nonlinear source term consisting of a power function, for which the classical theory of the elliptic equations leads the authors to the uniqueness result under some assumptions on the entropy function S(x). As an example, the authors get the uniqueness of stationary solutions with vacuum of Euler-Poisson equations for S(x) =|x|θandθ∈{0}∪[2(N-2),+∞).
基金the National Natural Science Foundation of China (No. 20472111) is gratefully acknowledged.
文摘Three novel chiral selectors 4a-c were synthesized from (S)-amino acids and (R)-1-phenyl-2-(4-methylphenyl)ethylamine. 4a-c were connected to 3-aminopropylsilanized silica gel to be used as the chiral stationary phase for HPLC. Five amino acid derivatives and two pyrethroid insecticides were fairly resolved on these three new chiral stationary phases under normal phase condition.
基金supported by the National Natural Science Foundation of China(11331005,11471134)the Program for Changjiang Scholars and Innovative Research Team in University(IRT13066)the Scientific Research Funds of Huaqiao University(15BS201,15BS309)
文摘In this article, we are concerned with the stability of stationary solution for outflow problem on the Navier-Stokes-Poisson system. We obtain the unique existence and the asymptotic stability of stationary solution. Moreover, the convergence rate of solution towards stationary solution is obtained. Precisely, if an initial perturbation decays with the algebraic or the exponential rate in space, the solution converges to the corresponding stationary solution as time tends to infinity with the algebraic or the exponential rate in time. The proof is based on the weighted energy method by taking into account the effect of the self-consistent electric field on the viscous compressible fluid.