A selective and efficient process for the electrophilic nitration is described using N_2O_5 as a green nitrating agent,Hβ zeolite as a solid acid catalyst and shape controlling agent under mild conditions.
The hierarchical metal-organic frameworks（MOFs）,such as Y（BTC）（H_2O）_6,are prepared with yttrium nitrate and benzene-1,3,5-tricarboxylic acid at room temperature.The product is characterized by Fourier transform...The hierarchical metal-organic frameworks（MOFs）,such as Y（BTC）（H_2O）_6,are prepared with yttrium nitrate and benzene-1,3,5-tricarboxylic acid at room temperature.The product is characterized by Fourier transform infrared（FT-IR）,X-ray diffraction（XRD）,scanning electron microscopy（SEM）and thermogravimetric analysis（TGA）.The Y（BTC）（H_2O）_6 particles are sufficiently rigid for performing solid phase extraction and they exhibit favorable selectivity toward the adsorption of hemoglobin.The adsorption behavior of hemoglobin onto the Y（BTC）（H_2O）_6 fits the Langmuir adsorption model with a theoretical adsorption capacity of 555.6 mg g 1.An adsorption efficiency of 87.7%for 100μg mL 1hemoglobin in 1 mL sample solution（at pH 6.0）is achieved with 0.40 mg Y（BTC）（H20）6.77.3%of the retained hemoglobin is readily recovered using a 0.5%（m/v）SDS solution as the stripping reagent.Circular dichroism spectra indicated that the conformation of hemoglobin is maintained during the adsorption-desorption process.The MOFs material is applied for the isolation of hemoglobin from human blood and the purity of the obtained hemoglobin is further verified by sodium dodecyl sulfate polyacrylamide gel electrophoresis（SDS-PAGE）.展开更多
基金the financial support from the National Natural Science Foundation of China-Academy of Engineering Physics(No.10976014)the Natural Science Foundation of Jiangsu Province(No.BK2011697)Independent Scientific Research Special Plan of NJUST(No.2011YBXM06)
文摘A selective and efficient process for the electrophilic nitration is described using N_2O_5 as a green nitrating agent,Hβ zeolite as a solid acid catalyst and shape controlling agent under mild conditions.
基金financial supports from the National Natural Science Foundation of China(Nos.21235001,21375013,21475017,21575020)Fundamental Research Funds for the Central Universities(Nos.N140505003N141008001)
文摘The hierarchical metal-organic frameworks（MOFs）,such as Y（BTC）（H_2O）_6,are prepared with yttrium nitrate and benzene-1,3,5-tricarboxylic acid at room temperature.The product is characterized by Fourier transform infrared（FT-IR）,X-ray diffraction（XRD）,scanning electron microscopy（SEM）and thermogravimetric analysis（TGA）.The Y（BTC）（H_2O）_6 particles are sufficiently rigid for performing solid phase extraction and they exhibit favorable selectivity toward the adsorption of hemoglobin.The adsorption behavior of hemoglobin onto the Y（BTC）（H_2O）_6 fits the Langmuir adsorption model with a theoretical adsorption capacity of 555.6 mg g 1.An adsorption efficiency of 87.7%for 100μg mL 1hemoglobin in 1 mL sample solution（at pH 6.0）is achieved with 0.40 mg Y（BTC）（H20）6.77.3%of the retained hemoglobin is readily recovered using a 0.5%（m/v）SDS solution as the stripping reagent.Circular dichroism spectra indicated that the conformation of hemoglobin is maintained during the adsorption-desorption process.The MOFs material is applied for the isolation of hemoglobin from human blood and the purity of the obtained hemoglobin is further verified by sodium dodecyl sulfate polyacrylamide gel electrophoresis（SDS-PAGE）.
