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A NOVEL SECOND-ORDER TRANSITION IN ORGANIC HYBRIDS CONSISTING OF POLYMERS AND SMALL MOLECULES 被引量:1
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作者 Chi-fei Wu Department of Chemistry and Chemical Engineering Kanazawa University 2-40-20 Kodatsuno Kanazawa, Ishikawa 920-8667 Japan 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2001年第5期455-466,共12页
A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to ... A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to the dissociation ofintermolecular hydrogen bonds between the polymer ard additive within the edditive rich phase. Of particular interest is thata novel pyramid crystal was observed in the annealed CPE/hindered phenol blends. Another intriguing observation is thatthese polymer/small molecule blends organized by intermolecular hydrogen bonding have several potential properties, suchas shape-memorization, self-restoration, self-adhesiveness and super damping. 展开更多
关键词 Organic hybrid Second-order transition Shape memory effect DAMPING self restoration
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