OXIDATION RESISTANCE AND SELF-SEALING PROPERTY OF CERAMIC COATINGS FOR C/C COMPOSITES

The oxidation behavior and damage mechanism of modifiers and compounds of many types of ceramic coatings were investigated experimentally. A MoSi 2/SiC coating was produced by infiltration process. The oxidation behavior of the coated C/C composites was studied at various temperatures below 1650℃. The oxidation results showed that the MoSi 2/SiC coating for thermal protection of C/C composites has high oxidation resistance at temperature up to 1650℃. In the present work, a new model of an oxidation protective, self sealing multi layer coating system was proposed for C/C composites. The multi layer coating possessing the self sealing property was obtained by pack cementation and infiltration process. The protection coating system for C/C composites consists of an inner layer of SiC and an outer layer of porous refractory oxides filled by modified SiO 2 glass. Isothermal and cyclic thermal oxidation tests showed the multi layer coating was capable of protecting the C/C composites in an oxidizing atmosphere at temperature up to 1800℃.

Self-Healing Behavior of Phosphate Coating Post-Sealed with Molybdate

The phosphated zinc layer was post-sealed with molybdate to obtain the composite coating without pores.The composition of the formed coating was investigated. The corrosion behavior of the coated samples was studied.The coated samples were first scratched and subsequently corroded in a neutral salt spray( NSS) chamber for 2-72 h; the microstructure of the corrosion products was analyzed via SEM and EDS; and the self-healing performance was discussed. The coating obtained contains Zn_3( PO_4)_2· 4H_2 O,Mo_2O_3 and MoO_4^(2-). The electrochemical impedance first increases and then decreases with the immersion time. However,after immersion for 6 days,it remains at about 10 kΩ·cm^2,much higher than the value for the single-treated samples without corrosion. Micro structural observations show that the corrosion products in scratch increase in size and finally cover the whole scratch completely. The initial corrosion products have high P,Mo and O contents but almost no Cl,while in later stages the first three components decrease and Cl increases. The corrosion products form a compact mass of needle-like crystals,effectively inhibiting zinc corrosion. The composite coating exhibits good self-healing.

Protection Performance of Plasma Sprayed Al_(2)O_(3)-13 wt%TiO_(2) Coating Sealed with an Organic-inorganic Hybrid Agent

An organic-inorganic hybrid sealing agent was fabricated and used in the plasma sprayed Al_(2)O_(3)-13 wt%TiO_(2)coating,and conventional silicone agent was also used for comparison.Protection performance of the coatings was comprehensively evaluated based on both anti-corrosion and anti-biofouling properties.The results reveal that the sealing treatment is remarkably useful to decrease the porosity of the coating,and the porosity of the coating sealed with the hybrid agent is only 0.035%.Immersion corrosion test and Tafel polarization test reveal that the sealed coating with the hybrid agent exhibits a better corrosion resistance by compared with the coating sealed with silicone agent.The corrosion current density i_(corr) of the hybrid agent sealed coating is only 0.7×10^(-6)A·cm^(-2).Moreover,anti-biofouling tests both in the outdoor analogue hydraulic environment and in the natural marine environment prove that the mentioned novel coating presents a better combination of corrosion resistance and anti-biofouling property by compared with the other coatings,and it could be used as a protection of metal components in the marine environment.

Parameter Self - Learning of Generalized Predictive Control Using BP Neural Network

This paper describes the self—adjustment of some tuning-knobs of the generalized predictive controller(GPC).A three feedforward neural network was utilized to on line learn two key tuning-knobs of GPC,and BP algorithm was used for the training of the linking-weights of the neural network.Hence it gets rid of the difficulty of choosing these tuning-knobs manually and provides easier condition for the wide applications of GPC on industrial plants.Simulation results illustrated the effectiveness of the method.

Self - Crosslinking Behavior of Self - Emulsion Water - Based Polyure-thane Coating Agents

The relation between structures and properties of polyurethane are investigated by modern physical and chemical methods.The results obtained are as follows:the effects of the content of self-crosslinking agent on the properties of polyurethane,i.e.,dispersion stability,dynamical viscoelasticity and mechanical properties are discussed.It is found that the optimum molar ratio of epichlorohydrin and diethylenetriamine is 1:2.A mois-

Culture Self- Consciousness in Transmission of Chinese Philosophy from the Perspective of English Globalization -- Taking the Belt and Road Initiative for Example

The Belt and Road Initiative contains the aspiration of Chinese nation to pursue ideological freedom and desire of strengthening international exchanges and cooperation. This paper takes the Belt and Road Initiative for example,emphasizing the interpretation of the inheritance and development of Chinese culture so as to study the importance of Culture Self-Consciousness in Chinese Philosophy,in the context of English globalization. That is to say,this paper stresses the spirits and the stand of nation 's demonstration on pursuing peace,cooperation and sustainable development in the civilization continuity from traditional China to the contemporary China,with practical philosophic view.

Computer Aided Modeling and Deign of a New Magnetic Sealing Mechanism in Engineering Applications

This article introduces a new type of magnetic sealing mechanism that reduces the lubrication oil pollution and media gaseous leakage in general reciprocating machinery including air compressors and refrigerators. The feasible function and reliable performance of this new sealing mechanism are introduced and analyzed in this paper. The computer aided design, modeling and analysis are being used to study this new sealing mechanism, and the prototype of this sealing mechanism is being tested. The study indicated the proper function of this sealing mechanism. The major advantages of this sealing mechanism include: improved sealing capacity to prevent the gaseous leakage and oil leakage, simple and compact in structure, lower precision requirement on surfaces of reciprocating pistons and shafts in production and manufacturing, and longer services in sealing life span. Also there is almost no frictional loss during the reciprocating motion of piston or shaft.

高压自紧式聚酰亚胺垫片密封性能影响因素分析及结构优化

为了解决液体火箭发动机在异常工况下的密封失效问题,建立了发动机充气阀阀芯密封结构的有限元模型,分析了密封结构参数、加工误差及卡滞偏斜对充气阀阀芯密封性能的影响,并进行了试验验证。结果表明:综合考虑可加工性、密封效果,圆阀座是充气阀的首选结构;在不同圆角半径下,圆角半径在0.35~0.45 mm范围内使用效果最佳;平面度偏差及卡滞偏斜在0~0.07 mm范围内对密封效果和使用寿命几乎没有影响。本研究可为航天军工用高精密密封的设计和优化提供参考,有助于提高我国高精密密封的技术水平。

一种自密封紧凑型地铁轴箱轴承的设计简介

本文介绍了一种新型的自密封地铁轴箱轴承,其设计要点:1)轴承采用自密封紧凑型单元化结构;2)对密封方式做了改进;3)在内圈端面和挡圈之间增设C形塑钢垫圈。经验证,该轴承性能可以满足地铁工况使用要求。

不停航条件下跑道深厚软土地基处理方案研究

机场不停航施工通常会遇到净空要求严、作业时间短、对作业面平整度要求高等问题,本文以某软基机场跑道延长线为例,开展不停航施工条件下深厚软基处理方案研究。首先,总结分析了一期跑道的软基处理方案和勘察、监测及试验等成果,在此基础上,结合本场区的地层特性和软土参数的差异性,获得了本期软基处理设计的物理力学特性参数。其次,针对本场区存在深厚软土、不停航施工和净空限制等复杂条件,提出了直排式真空预压的地基处理方案;并针对软土上部土石混合料填筑层难以密封的问题,首次提出了自凝灰密封墙新技术,确保了设计要求的膜下真空压力。最后,采用PLAXIS软件对处理后的典型断面进行了沉降复核分析。截至目前,机场延长线已运行3年,沉降满足设计要求,该方案可为类似工程提供技术借鉴。

扩压式自泵送流体动压机械密封综合性能研究

扩压式自泵送流体动压机械密封作为1种新的密封结构形式具有优异的密封性能和广泛的应用前景.分别设计出具有等截面型扩压环槽、发散型扩压环槽、收敛型扩压环槽和圆弧型扩压环槽4种扩压式自泵送流体动压机械密封,引入综合评价因子η,通过Fluent数值模拟分别对其综合密封性能进行了分析.基于最佳的扩压环槽结构,通过正交试验,对密封面结构参数进行优化.结果表明:等截面型扩压式自泵送流体动压机械密封综合密封性能最优;在试验参数范围内,螺旋槽数Ng和密封环外径rk对泄漏率均有影响,且螺旋槽数Ng影响最为显著.密封环外径rk和螺旋角α对开启力均有影响,其中密封环外径rk的影响更为显著,随密封环外径的增大,开启力迅速增大.依据正交试验分析结果,对密封面结构参数进行了优化,在其他边界条件均不变的情况下,新的因素水平组合得到的泄漏率最低为0.784361 ml/h,此时开启力大小为3.958962 kN.

Zn-Al-Mg-RE涂层自封闭特性在复合涂层中的作用机制

通过铜加速醋酸盐雾腐蚀试验,研究了自封闭特性在Zn-Al-Mg-RE高速电弧喷涂层与舰船涂料结合成防腐复合涂层中的作用。经过480h的试验,在基体上直接涂装涂料的试样表面的划痕里充满了铁锈,而中间喷有高速电弧喷涂层的试样表面划痕里只有少量的白锈。这说明在腐蚀环境中,Zn-Al-Mg-RE高速电弧喷涂层表面的微观孔隙能够被自身的腐蚀产物堵塞,生成的腐蚀产物非常致密,能够阻止缺陷处继续被腐蚀。从试验结果可知在复合涂层体系中,高速电弧喷涂层的自封闭特性起到了积极的作用。

基于电化学阻抗谱的Zn及Zn-Al涂层的自封闭机理研究

目前,热喷涂Zn–Al合金涂层已替代Zn及Al涂层,成为海洋环境下钢结构件腐蚀防护的首选方法。使用高速电弧喷涂和粉芯丝材技术制备了Zn–Al涂层,采用电化学阻抗谱法(EIS),结合涂层腐蚀产物X–射线衍射(XRD)及涂层腐蚀后表面形貌分析,对比研究了Zn及Zn–Al涂层的耐蚀性,并探讨了涂层的自封闭机理。结果表明,活化溶解是Zn涂层腐蚀的主要机制,在腐蚀过程中Zn涂层表现出自封闭作用,但由于腐蚀产物是疏松的,其自封闭效果微弱;Zn–Al涂层表现出了更好的耐蚀性,涂层表现出一定的自封闭效果。

密封沉积处理对纤维素纳米晶体薄膜光学特性的调控

纤维素纳米晶体(Cellulose nanocrystal,CNC)在特定浓度下可自组装排列,赋予体系独特的光学性能。为阐明CNC薄膜形成过程中CNC自组装行为机制,本文通过分析CNC薄膜在宏观颜色、紫外可见光谱、偏振光学、微观形貌以及晶体结构等方面的变化,探究了密封沉积时间和CNC浓度对自然蒸发干燥薄膜内部胆甾相液晶形成与排列的影响。结果表明,当密封沉积时间延长至48 h后,CNC薄膜的结构色显色范围、胆甾相结构的长程有序性均得到明显提升。随着浓度的升高,CNC颗粒间距减小,相邻颗粒间扭转角增大,螺距被压缩,从480 nm减小至344 nm。此外,密封沉积处理对高浓度CNC悬浮液形成长程有序性胆甾相结构具有明显优势。本研究结果表明,延长密封沉积时间和提高CNC浓度可以提高薄膜中长程有序性的提高,并促进胆甾相结构域的形成。这进一步完善了CNC基智能包装材料制备的科学基础,对于新型可视化食品包装和检测材料的开发具有积极作用。

自修复轮胎的全自动3D打印成型及性能研究

设计一种自修复轮胎的全自动3D打印成型设备及其工艺,设备主体结构包括热喂料挤出机、齿轮泵滤胶机及全自动涂覆设备3个部分,能够实现乘用车轮胎的自修复密封胶全自动涂覆成型。试验结果表明:涂覆成型的自修复轮胎扎钉拔出后的耐久性能和高速性能符合国家标准要求,轮胎具备足够的自修复能力;涂覆成型的自修复轮胎的滚动阻力与同规格普通轮胎相当。

钛合金微弧氧化-聚四氟乙烯复合自润滑膜的制备及其性能

为了提高钛合金表面微弧氧化膜的减摩耐磨性能,在硅酸盐溶液中,对Ti6Al4V钛合金进行微弧氧化处理,采用聚四氟乙烯(PTFE)对微弧氧化膜进行封孔处理后对其进行高温固化,制备了具有自润滑和高耐磨性的微弧氧化-PTFE自润滑膜。采用扫描电镜观察了自润滑膜的表面形貌;采用摩擦磨损试验机研究了其耐磨性能;采用极化曲线研究了其耐腐蚀性能。结果表明:PTFE颗粒已进入微弧氧化膜中,自润滑膜的摩擦系数低至0.15左右,自腐蚀电位较基体大幅正移,腐蚀电流密度大幅降低,自润滑膜的耐磨性能及耐蚀性能均较基体及微弧氧化膜大幅提升。

扩压式自泵送流体动静压型机械密封自清洁特性研究

传统的流体楔入式机械密封需增设外部流体阻塞系统来降低杂质颗粒对密封性能影响。针对一种具有自清洁特性的新型扩压式自泵送机械密封,采用FLUENT中的DPM模型研究不同离散相参数、螺旋槽结构参数和工况参数对颗粒在动压槽内的运动规律和排出特性的影响。研究结果表明:含固工况下的端面液膜开启力和泄漏量较纯流体状态下更大,泄漏量最大增加6.1%;在低颗粒体积分数下,排屑率逐渐上升,在体积分数7%时达到最大,随后排屑率快速降低;随着颗粒直径增加,排屑率整体呈下降趋势,且颗粒直径越大,排屑率下降得越快;螺旋槽结构参数主要改变了螺旋槽内压力梯度分布幅值和分布范围,在低转速下,颗粒受压差梯度力影响更加显著;高转速和低介质压力工况能够显著提高端面排屑效率,排屑率最高能达到92.3%。

一种新型自封焊小型化光电探测模块

提出了一种基于LTCC陶瓷基板的自封焊小型化光电探测模块,通过LTCC内埋电阻发热快速实现器件的密封。该模块不仅可以支持内部集成多种功能的光电芯片,还可与外部单元实现平面化、表贴式贴装,大幅提升模块安装适配性与可靠性。通过测试,模块在18GHz频率范围内具有高响应度与高平坦度,在体积上相较分立器件缩小了一个数量级,同时模块成本预计可降低一半以上,在机载、星载、弹载等平台的宽带相控阵系统中具有广阔的应用前景。

非线性转子-密封系统动力学行为演变机理研究

旋转机械广泛应用于民用、航空、航天和航海等各个领域,其稳定的动力学行为是保证工程机械安全运行的前提。本文主要针对转子-密封系统丰富的非线性动力学行为,利用非线性动力学等理论分析了转子-密封系统发生Hopf分岔和1:2亚谐共振等动力学行为的产生条件和机理,进一步给出了非线性转子-密封系统由自激振动引发亚谐共振的动力学行为演变机理,并通过理论分析,阐明了转子-密封系统的气流阻尼和刚度等动力学参数对系统动力学稳定性的影响规律,同时也利用数值计算验证了分析结果。其理论分析结果对实际工程振动分析和结构设计具有一定的理论指导意义。