The pH /temperature dually responsive microgels of interpenetrating polymer network( IPN) structure composed of poly( N-isopropylacrylamide)( PNIPAM) network and poly( acrylic acid)( PAA) network( PNIPAM /PAA IPN micr...The pH /temperature dually responsive microgels of interpenetrating polymer network( IPN) structure composed of poly( N-isopropylacrylamide)( PNIPAM) network and poly( acrylic acid)( PAA) network( PNIPAM /PAA IPN microgels) were synthesized by seed emulsion polymerization. The results obtained by dynamic laser light scattering( DLLS) show that the microgels have good pH /temperature dual sensitivities. The temperature sensitive component and the pH sensitive component inside the microgels have little interference with each other. The rheological properties of the concentrated PNIPAM /PAA IPN microgel dispersions as a function of temperature at pH 4. 0 or 7. 0 were investigated by viscometer,and the results displayed that only at pH 7. 0 the dispersions presented thermoreversible thickening behavior. Then the PNIPAM /PAA fibers were prepared by self-assembly of the PNIPAM /PAA IPN microgels in the ice-crystal templates formed by unidirectional liquid nitrogen freezing method. Field emission scanning electron microscopy( FESEM) images indicate that the PNIPAM /PAA fibers are rounded,randomly orientated and interweaved.展开更多
In order to acquire the flow pattern and investigate the settling behavior of the red mud in the separation thickener,computational fluid dynamics(CFD),custom subroutines and agglomerates settling theory were employed...In order to acquire the flow pattern and investigate the settling behavior of the red mud in the separation thickener,computational fluid dynamics(CFD),custom subroutines and agglomerates settling theory were employed to simulate the three-dimensional flow field in an industrial scale thickener with the introduction of a self-dilute feed system.The simulation results show good agreement with the measurement onsite and the flow patterns of the thickener are presented and discussed on both velocity and concentration field.Optimization experiments on feed well and self-dilute system were also carried out,and indicate that the optimal thickener system can dilute the solid concentration in feed well from 110 g/L to 86 g/L which would help the agglomerates' formation and improve the red mud settling speed.Furthermore,the additional power of recirculation pump can be saved and flocculants dosage was reduced from 105g/t to 85g/t in the operation.展开更多
This paper describes the self—adjustment of some tuning-knobs of the generalized predictive controller(GPC).A three feedforward neural network was utilized to on line learn two key tuning-knobs of GPC,and BP algorith...This paper describes the self—adjustment of some tuning-knobs of the generalized predictive controller(GPC).A three feedforward neural network was utilized to on line learn two key tuning-knobs of GPC,and BP algorithm was used for the training of the linking-weights of the neural network.Hence it gets rid of the difficulty of choosing these tuning-knobs manually and provides easier condition for the wide applications of GPC on industrial plants.Simulation results illustrated the effectiveness of the method.展开更多
The relation between structures and properties of polyurethane are investigated by modern physical and chemical methods.The results obtained are as follows:the effects of the content of self-crosslinking agent on the ...The relation between structures and properties of polyurethane are investigated by modern physical and chemical methods.The results obtained are as follows:the effects of the content of self-crosslinking agent on the properties of polyurethane,i.e.,dispersion stability,dynamical viscoelasticity and mechanical properties are discussed.It is found that the optimum molar ratio of epichlorohydrin and diethylenetriamine is 1:2.A mois-展开更多
The Belt and Road Initiative contains the aspiration of Chinese nation to pursue ideological freedom and desire of strengthening international exchanges and cooperation. This paper takes the Belt and Road Initiative f...The Belt and Road Initiative contains the aspiration of Chinese nation to pursue ideological freedom and desire of strengthening international exchanges and cooperation. This paper takes the Belt and Road Initiative for example,emphasizing the interpretation of the inheritance and development of Chinese culture so as to study the importance of Culture Self-Consciousness in Chinese Philosophy,in the context of English globalization. That is to say,this paper stresses the spirits and the stand of nation 's demonstration on pursuing peace,cooperation and sustainable development in the civilization continuity from traditional China to the contemporary China,with practical philosophic view.展开更多
The self-assembling behavior of random copolymers of sodium 2-(acrylamido)-2-methylpropanesulfonate (AMPS)and hydrophobic comonomers possessing dodecyl groups linked by various spacer bonds was discussed with a focus ...The self-assembling behavior of random copolymers of sodium 2-(acrylamido)-2-methylpropanesulfonate (AMPS)and hydrophobic comonomers possessing dodecyl groups linked by various spacer bonds was discussed with a focus on theeffect of the spacer. The characterization of association behavior of such polymers in water using quasielastic light scattering,capillary electrophoresis, NMR relaxation, various fluorescence, and viscoelastic methods was described. These copolymersform a variety of self-assembled nanostructures depending on the type of the spacer. Random copolymers of AMPS and N-dodecylmethacrylamide show a strong preference for intrapolymer self-association even in concentrated aqueous solutionsforming single-macromolecular self-assemblies (unimolecular micelles). In contrast, random copolymers of AMPS anddodecyl methacrylate are prone to undergo interpolymer associations yielding multipolymer micelles. In random copolymersof AMPS and a methacrylate substituted a nonionic surfactant (HO(CH_2CH_2O)_(25)C_(12)H_(25)) (C_(12)E_(25)), dodecyl groups are muchless restricted by the polymer backbone because they are linked via a long, flexible hydrophilic spacer. Thus, the polymer-bound C_(12)E_(25) surfactant moieties form micelles similar to those formed by discrete surfactants, but they are bridged bypolymer chains forming a network structure.展开更多
以乙二胺、溴代十四烷、氯乙酸钠和碘甲烷为原料,经烷基取代、羧基取代、季铵化三步反应合成了十四烷基羧基甜菜碱型双子表面活性剂SCB-14。烷基取代反应条件为:n(乙二胺):n(溴代十四烷)=1∶2,温度70℃,时间6 h,产率83%;羧基取代反应条...以乙二胺、溴代十四烷、氯乙酸钠和碘甲烷为原料,经烷基取代、羧基取代、季铵化三步反应合成了十四烷基羧基甜菜碱型双子表面活性剂SCB-14。烷基取代反应条件为:n(乙二胺):n(溴代十四烷)=1∶2,温度70℃,时间6 h,产率83%;羧基取代反应条件为:n(二元仲胺)∶n(氯乙酸钠)=1∶3.8,温度90℃,时间10 h,产率80%;季铵化反应条件为:n(二元叔胺)∶n(碘甲烷)=1∶8,温度35℃,时间8 h,产率73%。SCB-14的水溶液在25℃测得CMC为3.28×10-5mol/L,表面张力为29.46 m N/m。在温度80℃,剪切速率170 s-1,盐酸质量分数5%,SCB-14加量5%的条件下,SCB-14的残酸黏度达162 m Pa·s。利用旋转岩盘测定,SCB-14酸液体系和盐酸体系的酸岩反应动力学参数,证实SCB-14酸液体系具有增黏性能,降低了酸岩反应速率,有利于增长酸蚀作用距离。展开更多
基金National Natural Science Foundations of China(Nos.51073033,51373030)the Fundamental Research Funds for the Central Universities,China(No.2232014D3-43)
文摘The pH /temperature dually responsive microgels of interpenetrating polymer network( IPN) structure composed of poly( N-isopropylacrylamide)( PNIPAM) network and poly( acrylic acid)( PAA) network( PNIPAM /PAA IPN microgels) were synthesized by seed emulsion polymerization. The results obtained by dynamic laser light scattering( DLLS) show that the microgels have good pH /temperature dual sensitivities. The temperature sensitive component and the pH sensitive component inside the microgels have little interference with each other. The rheological properties of the concentrated PNIPAM /PAA IPN microgel dispersions as a function of temperature at pH 4. 0 or 7. 0 were investigated by viscometer,and the results displayed that only at pH 7. 0 the dispersions presented thermoreversible thickening behavior. Then the PNIPAM /PAA fibers were prepared by self-assembly of the PNIPAM /PAA IPN microgels in the ice-crystal templates formed by unidirectional liquid nitrogen freezing method. Field emission scanning electron microscopy( FESEM) images indicate that the PNIPAM /PAA fibers are rounded,randomly orientated and interweaved.
基金Project(50876116)supported by the National Natural Science Foundation of China
文摘In order to acquire the flow pattern and investigate the settling behavior of the red mud in the separation thickener,computational fluid dynamics(CFD),custom subroutines and agglomerates settling theory were employed to simulate the three-dimensional flow field in an industrial scale thickener with the introduction of a self-dilute feed system.The simulation results show good agreement with the measurement onsite and the flow patterns of the thickener are presented and discussed on both velocity and concentration field.Optimization experiments on feed well and self-dilute system were also carried out,and indicate that the optimal thickener system can dilute the solid concentration in feed well from 110 g/L to 86 g/L which would help the agglomerates' formation and improve the red mud settling speed.Furthermore,the additional power of recirculation pump can be saved and flocculants dosage was reduced from 105g/t to 85g/t in the operation.
基金Supported by the National 863 CIMS Project Foundation(863-511-010)Tianjin Natural Science Foundation(983602011)Backbone Young Teacher Project Foundation of Ministry of Education
文摘This paper describes the self—adjustment of some tuning-knobs of the generalized predictive controller(GPC).A three feedforward neural network was utilized to on line learn two key tuning-knobs of GPC,and BP algorithm was used for the training of the linking-weights of the neural network.Hence it gets rid of the difficulty of choosing these tuning-knobs manually and provides easier condition for the wide applications of GPC on industrial plants.Simulation results illustrated the effectiveness of the method.
文摘The relation between structures and properties of polyurethane are investigated by modern physical and chemical methods.The results obtained are as follows:the effects of the content of self-crosslinking agent on the properties of polyurethane,i.e.,dispersion stability,dynamical viscoelasticity and mechanical properties are discussed.It is found that the optimum molar ratio of epichlorohydrin and diethylenetriamine is 1:2.A mois-
文摘The Belt and Road Initiative contains the aspiration of Chinese nation to pursue ideological freedom and desire of strengthening international exchanges and cooperation. This paper takes the Belt and Road Initiative for example,emphasizing the interpretation of the inheritance and development of Chinese culture so as to study the importance of Culture Self-Consciousness in Chinese Philosophy,in the context of English globalization. That is to say,this paper stresses the spirits and the stand of nation 's demonstration on pursuing peace,cooperation and sustainable development in the civilization continuity from traditional China to the contemporary China,with practical philosophic view.
文摘The self-assembling behavior of random copolymers of sodium 2-(acrylamido)-2-methylpropanesulfonate (AMPS)and hydrophobic comonomers possessing dodecyl groups linked by various spacer bonds was discussed with a focus on theeffect of the spacer. The characterization of association behavior of such polymers in water using quasielastic light scattering,capillary electrophoresis, NMR relaxation, various fluorescence, and viscoelastic methods was described. These copolymersform a variety of self-assembled nanostructures depending on the type of the spacer. Random copolymers of AMPS and N-dodecylmethacrylamide show a strong preference for intrapolymer self-association even in concentrated aqueous solutionsforming single-macromolecular self-assemblies (unimolecular micelles). In contrast, random copolymers of AMPS anddodecyl methacrylate are prone to undergo interpolymer associations yielding multipolymer micelles. In random copolymersof AMPS and a methacrylate substituted a nonionic surfactant (HO(CH_2CH_2O)_(25)C_(12)H_(25)) (C_(12)E_(25)), dodecyl groups are muchless restricted by the polymer backbone because they are linked via a long, flexible hydrophilic spacer. Thus, the polymer-bound C_(12)E_(25) surfactant moieties form micelles similar to those formed by discrete surfactants, but they are bridged bypolymer chains forming a network structure.
文摘以乙二胺、溴代十四烷、氯乙酸钠和碘甲烷为原料,经烷基取代、羧基取代、季铵化三步反应合成了十四烷基羧基甜菜碱型双子表面活性剂SCB-14。烷基取代反应条件为:n(乙二胺):n(溴代十四烷)=1∶2,温度70℃,时间6 h,产率83%;羧基取代反应条件为:n(二元仲胺)∶n(氯乙酸钠)=1∶3.8,温度90℃,时间10 h,产率80%;季铵化反应条件为:n(二元叔胺)∶n(碘甲烷)=1∶8,温度35℃,时间8 h,产率73%。SCB-14的水溶液在25℃测得CMC为3.28×10-5mol/L,表面张力为29.46 m N/m。在温度80℃,剪切速率170 s-1,盐酸质量分数5%,SCB-14加量5%的条件下,SCB-14的残酸黏度达162 m Pa·s。利用旋转岩盘测定,SCB-14酸液体系和盐酸体系的酸岩反应动力学参数,证实SCB-14酸液体系具有增黏性能,降低了酸岩反应速率,有利于增长酸蚀作用距离。