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A Self-Stabilized Field Theory of Neutrinos 被引量:3
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作者 Edwin Eugene Klingman 《Journal of High Energy Physics, Gravitation and Cosmology》 2021年第3期936-948,共13页
In “<i>A Self-linking Field Formalism</i>” I establish a self-dual field structure with higher order self-induced symmetries that reinforce the first-order dynamics. The structure was derived from Gauss-... In “<i>A Self-linking Field Formalism</i>” I establish a self-dual field structure with higher order self-induced symmetries that reinforce the first-order dynamics. The structure was derived from Gauss-linking integrals in R<sup>3</sup> based on the Biot-Savart law and Ampere’s law applied to Heaviside’s equations, derived in strength-independent fashion in “<i>Primordial Principle of Self-Interaction</i>”. The derivation involves Geometric Calculus, topology, and field equations. My goal in this paper is to derive the simplest solution of a self-stabilized solitonic structure and discuss this model of a neutrino. 展开更多
关键词 self-Stabilized field Theory First-Order Dynamics The Biot-Savart Law The Ampere’s Law Neutrino Heaviside Equations Gravitational field Solitons self-DUAL Gauss-Linking
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Self-consistent field theory of adsorption of flexible polyelectrolytes onto an oppositely charged sphere
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作者 童朝阳 诸跃进 童朝晖 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第3期577-582,共6页
The adsorption of flexible polyelectrolyte (PE) with the smeared charge distribution onto an oppositely charged sphere immersed in a PE solution is studied numerically with the continuum self-consistent field theory... The adsorption of flexible polyelectrolyte (PE) with the smeared charge distribution onto an oppositely charged sphere immersed in a PE solution is studied numerically with the continuum self-consistent field theory. The power law scaling relationships between the boundary layer thickness and the surface charge density and the charge fraction of PE chains revealed in the study are in good agreement with the existing analytical result. The curvature effect on the degree of charge compensation of the total amount of charges on the adsorbed PE chains over the surface charges is examined, and a clear understanding of it based on the dependences of the degree of charge compensation on the surface charge density and the charge fraction of PE chains is established. 展开更多
关键词 POLYELECTROLYTE ADSORPTION self-consistent field theory
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Self-assembly of lipids and nanoparticles in aqueous solution:Self-consistent field simulations 被引量:1
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作者 Weihua Xie Guangkui Xu Xiqiao Feng 《Theoretical & Applied Mechanics Letters》 2012年第1期22-26,共5页
Self-assembled nanostructures of lipids and nanoparticles hold great promise for applications in such fields as nanomedicine. This paper uses the self-consistent field theory to investigate the self-assembly behavior ... Self-assembled nanostructures of lipids and nanoparticles hold great promise for applications in such fields as nanomedicine. This paper uses the self-consistent field theory to investigate the self-assembly behavior of lipid molecules and nanoparticles with different shapes in an aqueous solution. It is found that the lipid molecules can form monolayered and bilayered nanostructures around the nanopartieles with different shapes (e.g., triangular, square, hexagonal and octangular). With decreasing the size of nanoparticles or increasing the number of polygon edges, the shape of lipid layers will approach an approximately spherical shape. These findings may help to predict and design novel drug delivery nanocarriers. 展开更多
关键词 LIPOSOME NANOPARTICLE self-ASSEMBLY self-consistent field theory drug delivery
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A numerical Hartree self-consistent field calculation of an autoionization resonance parameters for a doubly excited 2s^2, 3s^2, and 4s^2 states of He atom with a complex absorbing potential
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作者 Tsogbayar Tsednee Danny L Yeager 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第8期114-122,共9页
The self-consistent Hartree-Fock equation for the He atom is solved using the pseudospectral method. The Feshbach- type autoionization resonance parameters for doubly excited 2s2, 3s2, and 4s2 IS states of He have bee... The self-consistent Hartree-Fock equation for the He atom is solved using the pseudospectral method. The Feshbach- type autoionization resonance parameters for doubly excited 2s2, 3s2, and 4s2 IS states of He have been determined by adding a complex absorbing potential to the Hamiltonian. The Riss-Meyer iterative and Pad6 extrapolation methods are applied to obtain reliable values for the autoionization resonance parameters, which are compared to previous results in the literature. 展开更多
关键词 self-consistent field Hartree-Fock equation helium autoionization pseudospectral method
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Application of self-consistent field theory to self-assembled bilayer membranes
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作者 张平文 史安昌 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第12期45-52,共8页
Bilayer membranes self-assembled from amphiphilic molecules such as lipids, surfactants, and block copolymers are ubiquitous in biological and physiochemical systems. The shape and structure of bilayer membranes depen... Bilayer membranes self-assembled from amphiphilic molecules such as lipids, surfactants, and block copolymers are ubiquitous in biological and physiochemical systems. The shape and structure of bilayer membranes depend crucially on their mechanical properties such as surface tension, bending moduli, and line tension. Understanding how the molecular properties of the amphiphiles determine the structure and mechanics of the self-assembled bilayers requires a molecularly detailed theoretical framework. The self-consistent field theory provides such a theoretical framework, which is capable of accurately predicting the mechanical parameters of self-assembled bilayer membranes. In this mini review we summarize the formulation of the self-consistent field theory, as exemplified by a model system composed of flexible amphiphilic chains dissolved in hydrophilic polymeric solvents, and its application to the study of self-assembled bilayer membranes. 展开更多
关键词 amphiphilic molecules bilayer membranes elastic moduli self-consistent field theory
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Dependence of elastic strain field on the self-organized ordering of quantum dot superlattices
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作者 Yumin Liu Zhongyuan Yu Yongzhen Huang 《Journal of University of Science and Technology Beijing》 CSCD 2007年第5期477-481,共5页
A systematic investigation of the strain distribution of self-organized, lens-shaped quantum dot in the case of groffth direction on (001) substrate was presented. The three-dimensional finite element analysis for a... A systematic investigation of the strain distribution of self-organized, lens-shaped quantum dot in the case of groffth direction on (001) substrate was presented. The three-dimensional finite element analysis for an array of dots was used for the strain calculation. The dependence of the strain energy density distribution on the thickness of the capping layer was investigated in detail when the elastic characteristics of the matrix material were anisotropic. It is shown that the elastic anisotropic greatly influences the stress, strain, and strain energy density in the quantum dot structures. The anisotropic ratio of the matrix material and the combination with different thicknesses of the capping layer, may lead to different strain energy density minimum locations on the capping layer surface, which can result in various vertical ordering phenomena for the next layer of quantum dots, i.e. partial alignment, random alignment, and complete alignment. 展开更多
关键词 quantum dot self-ORGANIZATION elastic strain field SUPERLATTICE
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Higher Order Self-Induced Self-Interacting Field
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作者 Edwin Eugene Klingman 《Journal of High Energy Physics, Gravitation and Cosmology》 2022年第2期285-302,共18页
The genesis of physical particles is essentially a mystery. Quantum field theory creation operators provide an abstract mechanism by which particles come into existence, but quantum fields do not possess energy densit... The genesis of physical particles is essentially a mystery. Quantum field theory creation operators provide an abstract mechanism by which particles come into existence, but quantum fields do not possess energy density. I reference several recent treatments of this problem and develop ideas based on self-stabilizing field structures with focus on higher order self-induced self-stabilizing field structures. I extend this treatment in this paper to related issues of topological charge. 展开更多
关键词 self-Stabilized field Theory self-Organizing Structure Topological Charge First-Order Dynamics The Biot-Savart Law Ampere’s Law Neutrino Heaviside Equations Gravitational field Solitons self-DUAL self-Aware Gauss-Linking
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Influence of a Magnetic Guide Field on Self-Injection in Wakefield Acceleration
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作者 Alain Bourdier Guillaume Girard +2 位作者 Sébastien Rassou Xavier Davoine Mathieu Drouin 《Journal of Modern Physics》 2012年第12期1983-1990,共8页
The influence of an external static field applied in the direction of propagation of a high intensity driving laser pulse on the electron trapping in laser wakefield acceleration is explored. It is shown that, in the ... The influence of an external static field applied in the direction of propagation of a high intensity driving laser pulse on the electron trapping in laser wakefield acceleration is explored. It is shown that, in the case of self-injection, the electric charge accelerated can be enhanced in some physical situations. 展开更多
关键词 Laser WAKEfield ACCELERATION MAGNETIC Guide field Electron INJECTION self-TRAPPING
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APPROXIMATION OPERATORS AND SELFSIMILARITY OVER P-ADIC FIELD
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作者 Zheng Weixing(Dept. of Math,Nanjing Univ.Nanjing 210008) 《数学研究》 CSCD 1994年第1期9-13,共5页
APPROXIMATIONOPERATORSANDSELFSIMILARITYOVERP-ADICFIELD¥ZhengWeixing(Dept.ofMath,NanjingUniv.Nanjing210008)Ab... APPROXIMATIONOPERATORSANDSELFSIMILARITYOVERP-ADICFIELD¥ZhengWeixing(Dept.ofMath,NanjingUniv.Nanjing210008)Abstract:Fourierana... 展开更多
关键词 局部场 近似算子 自相似 流形
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微尺度下场致发射对电晕放电的影响机理
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作者 黄向慧 刘振祖 +1 位作者 张晶园 张蓓 《真空科学与技术学报》 CAS CSCD 北大核心 2024年第2期146-155,共10页
场致离子化微电晕器件基于一维纳米材料的电场增强效应,可产生大气压非平衡微等离子体,适用于气体检测以及生物医疗等领域,具有响应快、低功耗等特点。但微尺度下的电晕放电属于局部自持的低能放电,其场致发射的作用及影响机制尚不清晰... 场致离子化微电晕器件基于一维纳米材料的电场增强效应,可产生大气压非平衡微等离子体,适用于气体检测以及生物医疗等领域,具有响应快、低功耗等特点。但微尺度下的电晕放电属于局部自持的低能放电,其场致发射的作用及影响机制尚不清晰。因此文章基于流体-化学混合模型框架,融合F-N发射模型,建立了常温常压N2-O2混合气体的二维微电晕放电模型。通过与无场致发射放电模型对比,探索不同间距下场致发射对放电动态过程的影响,发现针-板间距减至15μm时,两种模型放电过程差异很小,表明放电以二次电子发射机制为主导,当间距减至10μm时,两种模型的放电强度相差近1倍,场致发射的作用及影响不可忽略;通过进一步对电子密度分布、空间电场分布、电流密度等参量进行动态分析,发现场致发射、空间碰撞电离反应和离子轰击二次电子发射之间存在链锁影响规律。 展开更多
关键词 微电晕结构 局部自持放电 场致发射 数值模拟
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A Modified Method for Deriving Self-Conjugate Dirac Hamiltonians in Arbitrary Gravitational Fields and Its Application to Centrally and Axially Symmetric Gravitational Fields
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作者 M. V. Gorbatenko V. P. Neznamov 《Journal of Modern Physics》 2015年第3期303-326,共24页
We have proposed previously a method for constructing self-conjugate Hamiltonians Hh in the h-representation with a flat scalar product to describe the dynamics of Dirac particles in arbitrary gravitational fields. In... We have proposed previously a method for constructing self-conjugate Hamiltonians Hh in the h-representation with a flat scalar product to describe the dynamics of Dirac particles in arbitrary gravitational fields. In this paper, we prove that, for block-diagonal metrics, the Hamiltonians Hh can be obtained, in particular, using “reduced” parts of Dirac Hamiltonians, i.e. expressions for Dirac Hamiltonians derived using tetrad vectors in the Schwinger gauge without or with a few summands with bispinor connectivities. Based on these results, we propose a modified method for constructing Hamiltonians in the h-representation with a significantly smaller amount of required calculations. Using this method, here we for the first time find self-conjugate Hamiltonians for a number of metrics, including the Kerr metric in the Boyer-Lindquist coordinates, the Eddington-Finkelstein, Finkelstein-Lemaitre, Kruskal, Clifford torus metrics and for non-stationary metrics of open and spatially flat Friedmann models. 展开更多
关键词 self-CONJUGATE Hamiltonian DIRAC Particle ARBITRARY Gravitational field SCHWINGER Gauge Kerr Metric
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基于激光自混合干涉的磁场测量方法研究
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作者 赵岩 李康达 +2 位作者 林茂华 孙文强 张正阳 《激光杂志》 CAS 北大核心 2024年第3期106-110,共5页
针对光纤磁流体磁场传感器易受环境干扰及磁流体薄膜制作工艺复杂的问题,激光自混合干涉具有抗干扰能力强、稳定性好的特点,提出一种基于空间光的水平偏振激光自混合干涉的磁场测量方法,在外部磁场的作用下,水平偏振自混合干涉信号幅值... 针对光纤磁流体磁场传感器易受环境干扰及磁流体薄膜制作工艺复杂的问题,激光自混合干涉具有抗干扰能力强、稳定性好的特点,提出一种基于空间光的水平偏振激光自混合干涉的磁场测量方法,在外部磁场的作用下,水平偏振自混合干涉信号幅值发生变化,在一定范围内,磁场与信号幅值变化成正比,通过用施加磁场前后信号幅值的均值比与磁场的变化关系实现对磁场的传感检测。经过实验验证,信号的幅值在1%浓度的磁流体中衰减明显,薄膜厚度为0.5 mm,减小了薄膜的制作难度。在实验结果中对5.02 mt到19.112 mt磁场强度范围内的均值比进行线性拟合,相对误差最小为0.17%。 展开更多
关键词 自混合干涉 磁场测量 水平偏振 磁流体薄膜
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遥控自走式雪茄植株中下层烟叶植保喷雾机设计与试验
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作者 张青松 陈志凌 +3 位作者 杜文斌 杨锦鹏 廖庆喜 杨春雷 《农业机械学报》 EI CAS CSCD 北大核心 2024年第1期122-133,共12页
针对雪茄烟叶在旺长期及成熟期因植株高大及叶片生长致使烟田垄间空间小,且雪茄烟叶生产对烟叶色泽及完整度要求高,田间管理要求不能损伤烟叶,导致生产中雪茄烟叶植株中下层烟叶植保困难的问题,结合烟叶植株生长特征,设计了一种遥控自... 针对雪茄烟叶在旺长期及成熟期因植株高大及叶片生长致使烟田垄间空间小,且雪茄烟叶生产对烟叶色泽及完整度要求高,田间管理要求不能损伤烟叶,导致生产中雪茄烟叶植株中下层烟叶植保困难的问题,结合烟叶植株生长特征,设计了一种遥控自走式雪茄植株中下层烟叶植保喷雾机,该装置主要包括喷雾系统、履带底盘及控制系统,可实现装置在烟田垄间遥控行走、中下层烟叶喷雾及路况可视等功能。为获取烟株生长特征,运用三维激光扫描仪对其进行扫描并建立了植株叶片田间空间分布模型;根据烟叶田间分布特征,确定装置总体结构和工作方式;结合烟叶形态特征和植保农艺要求,对喷雾系统进行了结构设计及分析,确定了参数范围;根据田间作业需求,对履带底盘进行了动力学分析,对控制系统进行了设计。开展了场地试验,利用Box-Behnken优化了喷雾系统参数,当喷雾压力为0.65 MPa、喷嘴夹角为20.4°、喷嘴孔径为0.4 mm时,经垂直雾滴分布测量仪模拟雪茄烟叶叶片层垂直方向的药液附着性能试验表明,雾滴沉积量垂直分布满足雪茄烟叶植保要求。田间试验结果表明,雪茄植株中下层烟叶正面药液覆盖率为52%~83%,背面药液覆盖率为22%~45%,可实现雪茄植株中下层烟叶药液的有效喷施。 展开更多
关键词 雪茄烟叶 喷雾机 履带底盘 遥控自走式 喷雾系统 田间试验
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Dynamic self-adaptive ANP algorithm and its application to electric field simulation of aluminum reduction cell 被引量:1
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作者 王雅琳 陈冬冬 +2 位作者 陈晓方 蔡国民 阳春华 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第12期4731-4739,共9页
Region partition(RP) is the key technique to the finite element parallel computing(FEPC),and its performance has a decisive influence on the entire process of analysis and computation.The performance evaluation index ... Region partition(RP) is the key technique to the finite element parallel computing(FEPC),and its performance has a decisive influence on the entire process of analysis and computation.The performance evaluation index of RP method for the three-dimensional finite element model(FEM) has been given.By taking the electric field of aluminum reduction cell(ARC) as the research object,the performance of two classical RP methods,which are Al-NASRA and NGUYEN partition(ANP) algorithm and the multi-level partition(MLP) method,has been analyzed and compared.The comparison results indicate a sound performance of ANP algorithm,but to large-scale models,the computing time of ANP algorithm increases notably.This is because the ANP algorithm determines only one node based on the minimum weight and just adds the elements connected to the node into the sub-region during each iteration.To obtain the satisfied speed and the precision,an improved dynamic self-adaptive ANP(DSA-ANP) algorithm has been proposed.With consideration of model scale,complexity and sub-RP stage,the improved algorithm adaptively determines the number of nodes and selects those nodes with small enough weight,and then dynamically adds these connected elements.The proposed algorithm has been applied to the finite element analysis(FEA) of the electric field simulation of ARC.Compared with the traditional ANP algorithm,the computational efficiency of the proposed algorithm has been shortened approximately from 260 s to 13 s.This proves the superiority of the improved algorithm on computing time performance. 展开更多
关键词 finite element parallel computing(FEPC) region partition(RP) dynamic self-adaptive ANP(DSA-ANP) algorithm electric field simulation aluminum reduction cell(ARC)
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集成LCC-S拓扑的二维全向无线电能传输系统无盲区能量捕获方法研究
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作者 张献 王冉 +4 位作者 王奉献 苑朝阳 李慕松 杨庆新 代中余 《中国电机工程学报》 EI CSCD 北大核心 2024年第10期4038-4049,I0024,共13页
针对二维全向无线电能传输技术存在空间磁场完整度与电流控制策略复杂度的竞争问题,该文提出一种集成LCC-S拓扑的二维全向无线电能传输系统无盲区能量捕获方法。该系统以二维正交线圈为电磁耦合机构,并将其集成于LCC-S型补偿拓扑。同时... 针对二维全向无线电能传输技术存在空间磁场完整度与电流控制策略复杂度的竞争问题,该文提出一种集成LCC-S拓扑的二维全向无线电能传输系统无盲区能量捕获方法。该系统以二维正交线圈为电磁耦合机构,并将其集成于LCC-S型补偿拓扑。同时提出一种自调整参数设计方法,实现系统在二维空间内产生时均旋转磁场以及系统的零相角输入。通过场-路耦合有限元模型分析系统在二维空间内磁场分布情况,随时间峰值磁场强度矢量轨迹为圆形。搭建集成型二维全向无线电能传输的实验样机,实验结果表明,该系统实现单一电源驱动下无盲区的二维全向电磁能量捕获。 展开更多
关键词 全向无线电能传输 拓扑集成 时均旋转磁场 零相角输入
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连续分布电荷体系电荷元的自能问题
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作者 付全红 常健 郑建邦 《物理通报》 CAS 2024年第4期131-135,共5页
连续分布电荷体系可分割为无穷多个电荷元,系统研究了电荷元的自能问题.利用均匀带电球体和均匀带电圆面的自能公式和夹逼定理,分两步严格证明了连续分布电荷体系电荷元的自能之和为零.第一步,证明自由电荷体系电荷元的自能之和为零;第... 连续分布电荷体系可分割为无穷多个电荷元,系统研究了电荷元的自能问题.利用均匀带电球体和均匀带电圆面的自能公式和夹逼定理,分两步严格证明了连续分布电荷体系电荷元的自能之和为零.第一步,证明自由电荷体系电荷元的自能之和为零;第二步,证明一般电荷体系电荷元的自能之和为零.因此,连续分布电荷体系的电场能就等于电荷元之间的相互作用能. 展开更多
关键词 电场能 自能 相互作用能 电荷元 夹逼定理
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The Theoretically Studies and Field Testing of Self-Insulation Exterior Wall in the Hot Summer and Cold Winter Zone
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作者 Huifang Yu Quanbiao Xu +2 位作者 Sanming Zhang Weijun Gao Jianfeng Xu 《Energy and Power Engineering》 2017年第10期654-686,共33页
The energy efficiency design of the exterior wall in the buildings of the hot summer and cold winter zone of China should consider the heat prevention in summer and the heat insulation in winter. The self-insulation o... The energy efficiency design of the exterior wall in the buildings of the hot summer and cold winter zone of China should consider the heat prevention in summer and the heat insulation in winter. The self-insulation of the exterior?wall is a more feasible design to satisfy the energy efficiency of buildings in the?zone. However, the systematic research is urgently needed for the self-insulation of the exterior wall in the hot summer and cold winter zone of China. The paper tested the thermal performance of the common non-clay materials such as shale sintered hollow brick, sand autoclaved aerated concrete block, etc. by means of indoor experiments. The energy efficiency effect of the common materials was verified using dynamic calculation soft PKPM and several constitutions of exterior wall with different main bricks and insulation materials on the heat bridge were simulated, too. Besides, the tests of the thermal performance of exterior wall in real constructions were carried out to testify the practical effect of the recommended constitutions of exterior wall with different main bricks and insulation materials on the heat bridge. The conclusions are: the physical and thermal properties of the six non-clay wall material are better than the clay porous brick;the thermal performance of the non-clay brick can be improved obviously through the rational arrangement of the holes;shale sintered hollow brick after increasing the holes and rationalizing the hole arrangement and sand autoclaved aerated concrete block are recommended for buildings in the hot summer and cold winter area of China. The dynamic calculation results show that the thermal performances?of the non-clay materials are all satisfied with the energy efficiency;The heat transfer coefficient of the exterior wall with composition?③,?in which?the main wall was sand autoclaved aerated concrete block and the material on the heat bridge was sand autoclaved aerated concrete plate, is the smallest among the three recommended compositions. 展开更多
关键词 self-INSULATION EXTERIOR Wall INDOOR Experiments Dynamic Simulation field Testing Hot SUMMER and Cold WINTER ZONE
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静电场能量之两种表述及等价性探讨
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作者 陈三 朱光平 杨远贵 《淮北师范大学学报(自然科学版)》 CAS 2024年第1期82-86,共5页
为给出静电场能量电荷体密度积分形式成立的条件和澄清把体密度积分形式直接改写为面密度积分形式的不恰当,从静电场能量的定义式出发,采用麦克斯韦方程和静电势公式推导出静电场能量的另一表达式,并对该静电场能量表达式作一般性推广,... 为给出静电场能量电荷体密度积分形式成立的条件和澄清把体密度积分形式直接改写为面密度积分形式的不恰当,从静电场能量的定义式出发,采用麦克斯韦方程和静电势公式推导出静电场能量的另一表达式,并对该静电场能量表达式作一般性推广,用于处理电荷分布不连续的任意无限空间或有限空间区域内的静电场能量问题,具有普适性。举例说明2种能量表述形式的等价性。澄清面电荷积分形式1/2∬σϕdS来自于积分-1/2∳ϕD∙dS,而非来自积分1/2∭ϕρdV。 展开更多
关键词 静电场能量 电荷密度 自能和互能
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基于FOCA的永磁游标电机PI参数自整定
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作者 王伟炳 宋伟豪 《电机与控制应用》 2024年第7期94-102,共9页
针对磁场定向控制中电流内环和转速外环比例积分(PI)控制器参数整定困难且耗时长的问题,基于Matlab/Simulink的磁场定向控制自整定(FOCA)模块搭建了永磁游标电机磁场定向控制双闭环调速系统参数自整定模型。该模块在PI控制器输出端注入... 针对磁场定向控制中电流内环和转速外环比例积分(PI)控制器参数整定困难且耗时长的问题,基于Matlab/Simulink的磁场定向控制自整定(FOCA)模块搭建了永磁游标电机磁场定向控制双闭环调速系统参数自整定模型。该模块在PI控制器输出端注入正弦扰动信号,根据系统输入输出数据计算频率响应,基于频率响应自动整定PI参数,同时实现指定的目标带宽和相位裕度。最后通过仿真对比分析各个环路整定前后的控制性能,仿真结果表明使用FOCA模块能够快速自动整定PI控制器参数并且拥有良好的控制性能。 展开更多
关键词 永磁游标电机 磁场定向控制 参数自整定 目标带宽 相位裕度
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基于席夫碱配体和两种苯甲酸盐构筑的两例Dy_(4)配合物的合成、结构及单分子磁体性质
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作者 李大伟 胡瑞 +5 位作者 师素云 涉叶叶 张夏梅 李亚红 张义权 姚金雷 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第2期307-315,共9页
使用Dy(NO_(3))_(3)·6H_(2)O与席夫碱配体2-(((2-羟基-3-甲氧基苄基)亚氨基)甲基)-4-甲氧基苯酚(H_(2)L)和2个辅助配体PhCO_(2)H和2-NO_(2)-PhCO_(2)H在乙醇中反应,得到2例Dy_(4)配合物[Dy_(4)(L)_(4)(PhCO_(2))_(2)(NO_(3))_(2)(E... 使用Dy(NO_(3))_(3)·6H_(2)O与席夫碱配体2-(((2-羟基-3-甲氧基苄基)亚氨基)甲基)-4-甲氧基苯酚(H_(2)L)和2个辅助配体PhCO_(2)H和2-NO_(2)-PhCO_(2)H在乙醇中反应,得到2例Dy_(4)配合物[Dy_(4)(L)_(4)(PhCO_(2))_(2)(NO_(3))_(2)(EtOH)_(2)](1)和[Dy_(4)(L)_(4)(2-NO_(2)-PhCO_(2))_(2)(NO_(3))_(2)(EtOH)2](2)。单晶X射线衍射解析表明配合物1和2均由Dy_(2)基本单元构建,形成中心对称的四核线性链状结构。配合物1和2中Dy_(2)单元中的一个Dy(Ⅲ)离子呈现七配位几何构型,另一个Dy(Ⅲ)离子呈现八配位几何构型。2例配合物均为单分子磁体,其能垒分别为110和108 K。通过理论计算对1和2的磁性能进行了分析。 展开更多
关键词 席夫碱 单分子磁体 四核 完全活性空间自洽场
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