Collisional quantum interference （CQI） on the intramolecular rotational energy transfer is observed in an experiment with a static cell, and the integral interference angles are measured. To obtain more accurate inf...Collisional quantum interference （CQI） on the intramolecular rotational energy transfer is observed in an experiment with a static cell, and the integral interference angles are measured. To obtain more accurate information, an experiment with a molecular beam is carried out, and thereby the relationship between the differential interference angle and the scattering angle is obtained. Based on the first-Born approximation of time-dependent perturbation theory, the theoretical model of CQI is developed in an atom-diatom system in the condition of the molecular beam, with the long-range interaction potential taken into account. The method of measuring correctly the differential interference angle is presented. The tendencies of the differential interference angle changing with the impact parameter and rel- ative velocity are discussed. The theoretical model presented here is important for understanding or performing the experiment in the molecular beam.展开更多
Collisional quantum interference （CQI） on rotational energy transfer was observed in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14） system in collision with Na [Chem. Phys. Lett. 318 （2000） 107], and the degree of the inter...Collisional quantum interference （CQI） on rotational energy transfer was observed in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14） system in collision with Na [Chem. Phys. Lett. 318 （2000） 107], and the degree of the interference was measured. The integral interference angle was obtaJned through theoretical calculation. We will research the factors that have effect on collisional quantum interference on rotational energy transfer in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14）-Na system. Basing on the time-dependent first order Born approximation, and taking into account the anlsotroplc Lennard Jones interaction potentials and ＂straight-line＂ trajectory approximation, we obtain the factors that have effect on CQI in Na2-Na system, and obtain the relation between the integral interference angle and rotational quantum number.展开更多
Here wc report calculation of the differential interference angles （including b≤p gild b≥p ） for singlet-triplet mixed states of Na2（A^1∑u^＋,ν=8-b^3∏0u,ν=14） system in collision with Na, in order to study t...Here wc report calculation of the differential interference angles （including b≤p gild b≥p ） for singlet-triplet mixed states of Na2（A^1∑u^＋,ν=8-b^3∏0u,ν=14） system in collision with Na, in order to study the collision- induced quantum interference on rotational energy transfer in an atom-diatom system. The calculation is based on the first-order Born approximation of time-dependent perturbation theory, and the anisotropic Lennard-Jones intcraction potentials are also employed, The relationships between differential interference angle and impact parameter, including collision diameter and velocity, are obtained,展开更多
To study theoretically the relationship between the differential interference angle and the scattering angle in collisional quantum interference （CQI）, we have investigated the differential interference angle of the...To study theoretically the relationship between the differential interference angle and the scattering angle in collisional quantum interference （CQI）, we have investigated the differential interference angle of the atom-diatomic [case（a）] molecule system in detail. For the 2∏ electronic state in Hund＇s case （a）, the degree of the differential interference is also discussed. The differential interference angles of NO（X^2∏） are calculated quantitatively for the rotational energy transfer in Hund＇s case （a） induced by collision with He, Ne and Ar atoms. The method to calculate the differential interference angle is presented. Several factors that affect the differential interference angle are investigated. Finally the variation of the differential interference angle with the impact parameter and relative velocity is discussed.展开更多
In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 （2003） 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO （...In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 （2003） 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO （A ^1 Π,v = 3） with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.展开更多
To study theoretically the relationship between the integral interference angle and the scat- tering angle in collisional quantum interference, the integral interference angle of atom- ^2П[case（a）] diatomic molecul...To study theoretically the relationship between the integral interference angle and the scat- tering angle in collisional quantum interference, the integral interference angle of atom- ^2П[case（a）] diatomic molecules system is described. To simulate the experiment theoretically, the theoretical model on collision-induced rotational energy transfer in an atom- ^2П[case（a）]diatom system is presented based on the first order Born approximation taking into account of the long-range interaction potential. For the ^2П electronic state in the Hund＇s case（a） diatom, the degree of the interference is discussed. The interference angles of collision-induced rotational energy transfer of CN（A^2П） in Hund＇s case（a） with He, Ne, and Ar are calculated quantitatively. The key parameters in the determination of integral interference angles are obtained.展开更多
Collisional quantum interference （CQI） was observed in the intramolecular rotational energy transfer in the experiment of the static cell, and the integral interference angles were measured. To observe more precise ...Collisional quantum interference （CQI） was observed in the intramolecular rotational energy transfer in the experiment of the static cell, and the integral interference angles were measured. To observe more precise information, the experiment in the molecular beam should be taken,from which the relationship between the differential interference angle and the scattering angle can be obtained. In this paper, the theoretical model of CQI is described in an atom-diatom system in the condition of the molecular beam, based on the first-Born approximation of time-dependent perturbation theory, taking into accounts the long-range interaction potential. The method of observing and measuring correctly the differential interference angle is presented. The changing tendency of the differential interference angle with the impact parameter and relative velocity is discussed. The changing tendencies of the differential interference angle with the parameter of experiment in the molecular beam, including the impact parameter and the velocity are discussed. This theoretical model is important to understand or perform the experiment in the molecular beam.展开更多
As a further theoretical study of the collision-induced quantum interference on rotational energy transfer in an atom-diatom system, based on the first-Born approximation of time-dependent perturbation theory, taking ...As a further theoretical study of the collision-induced quantum interference on rotational energy transfer in an atom-diatom system, based on the first-Born approximation of time-dependent perturbation theory, taking into account the anisotropic Lennard-Jones interaction potential and the long-range interaction potential, the differential interference angles in singlet-triplet mixed states of CO A^1Π（v=9）-e3∑-（v=1） system in collision with He, Ne, Ar, and other partners were calculated theoretically. The relationships of differential interference angle versus impact parameters, including collision parameter b and velocity, are obtained.展开更多
Due to the fact that conventional heuristic attribute reduction algorithms are poor in running efficiency and difficult in accomplishing the co-evolutionary reduction mechanism in the decision table, an adaptive multi...Due to the fact that conventional heuristic attribute reduction algorithms are poor in running efficiency and difficult in accomplishing the co-evolutionary reduction mechanism in the decision table, an adaptive multicascade attribute reduction algorithm based on quantum-inspired mixed co-evolution is proposed. First, a novel and efficient self- adaptive quantum rotation angle strategy is designed to direct the participating populations to mutual adaptive evolution and to accelerate convergence speed. Then, a multicascade model of cooperative and competitive mixed co-evolution is adopted to decompose the evolutionary attribute species into subpopulations according to their historical performance records, which can increase the diversity of subpopulations and select some elitist individuals so as to strengthen the sharing ability of their searching experience. So the global optimization reduction set can be obtained quickly. The experimental results show that, compared with the existing algorithms, the proposed algorithm can achieve a higher performance for attribute reduction, and it can be considered as a more competitive heuristic algorithm on the efficiency and accuracy of minimum attribute reduction.展开更多
沙国河等人在CO(A1∏(v=0)～e3∑-(v=1))体系与He, Ne 和Ar碰撞诱导转动传能中首次观测到了量子干涉效应,并测量了干涉度.从理论上进一步研究原子-双原子分子体系碰撞诱导转动传能中量子干涉效应与转动量子数以及能量间隔的关系是十分...沙国河等人在CO(A1∏(v=0)～e3∑-(v=1))体系与He, Ne 和Ar碰撞诱导转动传能中首次观测到了量子干涉效应,并测量了干涉度.从理论上进一步研究原子-双原子分子体系碰撞诱导转动传能中量子干涉效应与转动量子数以及能量间隔的关系是十分必要的.我们考虑长程相互作用势,应用一级玻恩近似和直线轨迹近似,分别计算了CO(A1∏(v=0)～e3∑-(v=1))体系和He, Ne,Ar碰撞诱导转动传能中不同转动量子数以及不同能量间隔下的干涉角,得到了干涉角随转动量子数和能量间隔的变化趋势.这些结果对设计、分析这种类型的实验有一定的指导意义.展开更多
基金Project supported by the National Natural Science Foundation of China （Grant No 10374040）,
文摘Collisional quantum interference （CQI） on the intramolecular rotational energy transfer is observed in an experiment with a static cell, and the integral interference angles are measured. To obtain more accurate information, an experiment with a molecular beam is carried out, and thereby the relationship between the differential interference angle and the scattering angle is obtained. Based on the first-Born approximation of time-dependent perturbation theory, the theoretical model of CQI is developed in an atom-diatom system in the condition of the molecular beam, with the long-range interaction potential taken into account. The method of measuring correctly the differential interference angle is presented. The tendencies of the differential interference angle changing with the impact parameter and rel- ative velocity are discussed. The theoretical model presented here is important for understanding or performing the experiment in the molecular beam.
基金The project supported by National Natural Science Foundation of China under Grant No. 10374040
文摘Collisional quantum interference （CQI） on rotational energy transfer was observed in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14） system in collision with Na [Chem. Phys. Lett. 318 （2000） 107], and the degree of the interference was measured. The integral interference angle was obtaJned through theoretical calculation. We will research the factors that have effect on collisional quantum interference on rotational energy transfer in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14）-Na system. Basing on the time-dependent first order Born approximation, and taking into account the anlsotroplc Lennard Jones interaction potentials and ＂straight-line＂ trajectory approximation, we obtain the factors that have effect on CQI in Na2-Na system, and obtain the relation between the integral interference angle and rotational quantum number.
基金This work was supported by National Natural Science Foundation of China(No.10374040).
文摘Here wc report calculation of the differential interference angles （including b≤p gild b≥p ） for singlet-triplet mixed states of Na2（A^1∑u^＋,ν=8-b^3∏0u,ν=14） system in collision with Na, in order to study the collision- induced quantum interference on rotational energy transfer in an atom-diatom system. The calculation is based on the first-order Born approximation of time-dependent perturbation theory, and the anisotropic Lennard-Jones intcraction potentials are also employed, The relationships between differential interference angle and impact parameter, including collision diameter and velocity, are obtained,
基金Project supported by the National Natural Science Foundation of China (Grant No 10374040)the Fund of the Educational Department of Liaoning Province, China (Grant No 20060347)
文摘To study theoretically the relationship between the differential interference angle and the scattering angle in collisional quantum interference （CQI）, we have investigated the differential interference angle of the atom-diatomic [case（a）] molecule system in detail. For the 2∏ electronic state in Hund＇s case （a）, the degree of the differential interference is also discussed. The differential interference angles of NO（X^2∏） are calculated quantitatively for the rotational energy transfer in Hund＇s case （a） induced by collision with He, Ne and Ar atoms. The method to calculate the differential interference angle is presented. Several factors that affect the differential interference angle are investigated. Finally the variation of the differential interference angle with the impact parameter and relative velocity is discussed.
基金The project supported by National Natural Science Foundation of China under Grant No. 10374040
文摘In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 （2003） 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO （A ^1 Π,v = 3） with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.10374040） and the Fund of the Educational Department of Liaoning Province of China （No.20060347 and No.2008290）.
文摘To study theoretically the relationship between the integral interference angle and the scat- tering angle in collisional quantum interference, the integral interference angle of atom- ^2П[case（a）] diatomic molecules system is described. To simulate the experiment theoretically, the theoretical model on collision-induced rotational energy transfer in an atom- ^2П[case（a）]diatom system is presented based on the first order Born approximation taking into account of the long-range interaction potential. For the ^2П electronic state in the Hund＇s case（a） diatom, the degree of the interference is discussed. The interference angles of collision-induced rotational energy transfer of CN（A^2П） in Hund＇s case（a） with He, Ne, and Ar are calculated quantitatively. The key parameters in the determination of integral interference angles are obtained.
基金The project supported by National Natural Science Foundation of China under Grant No. 10374040 and Fund of the Department of Education of Liaoning Province of China under Grant No. 2004 F 004 . Thanks are given to Dr. Sun Meng-Tao （Department of Chemical Physics, Lund University, Lund, Sweden） due to his help in this work.
文摘Collisional quantum interference （CQI） was observed in the intramolecular rotational energy transfer in the experiment of the static cell, and the integral interference angles were measured. To observe more precise information, the experiment in the molecular beam should be taken,from which the relationship between the differential interference angle and the scattering angle can be obtained. In this paper, the theoretical model of CQI is described in an atom-diatom system in the condition of the molecular beam, based on the first-Born approximation of time-dependent perturbation theory, taking into accounts the long-range interaction potential. The method of observing and measuring correctly the differential interference angle is presented. The changing tendency of the differential interference angle with the impact parameter and relative velocity is discussed. The changing tendencies of the differential interference angle with the parameter of experiment in the molecular beam, including the impact parameter and the velocity are discussed. This theoretical model is important to understand or perform the experiment in the molecular beam.
基金This work was supported by the National Natural Science Foundation of China （No.10374040） and the Educational Department of Liaoning Province （No.20060347）.
文摘As a further theoretical study of the collision-induced quantum interference on rotational energy transfer in an atom-diatom system, based on the first-Born approximation of time-dependent perturbation theory, taking into account the anisotropic Lennard-Jones interaction potential and the long-range interaction potential, the differential interference angles in singlet-triplet mixed states of CO A^1Π（v=9）-e3∑-（v=1） system in collision with He, Ne, Ar, and other partners were calculated theoretically. The relationships of differential interference angle versus impact parameters, including collision parameter b and velocity, are obtained.
基金The National Natural Science Foundation of China(No. 61139002,61171132)the Funding of Jiangsu Innovation Program for Graduate Education (No. CXZZ11_0219 )+2 种基金the Natural Science Foundation of Jiangsu Province (No. BK2010280)the Open Project of Jiangsu Provincial Key Laboratory of Computer Information Processing Technology (No. KJS1023)the Applying Study Foundation of Nantong(No. BK2011062)
文摘Due to the fact that conventional heuristic attribute reduction algorithms are poor in running efficiency and difficult in accomplishing the co-evolutionary reduction mechanism in the decision table, an adaptive multicascade attribute reduction algorithm based on quantum-inspired mixed co-evolution is proposed. First, a novel and efficient self- adaptive quantum rotation angle strategy is designed to direct the participating populations to mutual adaptive evolution and to accelerate convergence speed. Then, a multicascade model of cooperative and competitive mixed co-evolution is adopted to decompose the evolutionary attribute species into subpopulations according to their historical performance records, which can increase the diversity of subpopulations and select some elitist individuals so as to strengthen the sharing ability of their searching experience. So the global optimization reduction set can be obtained quickly. The experimental results show that, compared with the existing algorithms, the proposed algorithm can achieve a higher performance for attribute reduction, and it can be considered as a more competitive heuristic algorithm on the efficiency and accuracy of minimum attribute reduction.
文摘沙国河等人在CO(A1∏(v=0)～e3∑-(v=1))体系与He, Ne 和Ar碰撞诱导转动传能中首次观测到了量子干涉效应,并测量了干涉度.从理论上进一步研究原子-双原子分子体系碰撞诱导转动传能中量子干涉效应与转动量子数以及能量间隔的关系是十分必要的.我们考虑长程相互作用势,应用一级玻恩近似和直线轨迹近似,分别计算了CO(A1∏(v=0)～e3∑-(v=1))体系和He, Ne,Ar碰撞诱导转动传能中不同转动量子数以及不同能量间隔下的干涉角,得到了干涉角随转动量子数和能量间隔的变化趋势.这些结果对设计、分析这种类型的实验有一定的指导意义.
