Four kinds of galvanized steel sheets having different surface roughness values were used to prepare the steel sheets with a self-lubricated coating. The effects of surface roughness on the surface lubrication perform...Four kinds of galvanized steel sheets having different surface roughness values were used to prepare the steel sheets with a self-lubricated coating. The effects of surface roughness on the surface lubrication performance of the steel sheets were examined using a friction coefficient tester. Results revealed large dynamic friction coefficients for the galvanized steel sheets, which increased remarkably with surface roughness. Once the self-lubricated coating was applied, significant drops in the dynamic friction coefficients were measured. After the first stage of the friction test,the coefficients were almost unchanged, which reflected a weak dependence on the surface roughness of the self-lubricated steel sheets. However, the dynamic friction coefficients gradually increased as the test progressed, where these increase clearly correlated with the surface roughness of the self-lubricated steel sheets.展开更多
The surface modification on the AA6082 Al?Mg?Si aging-hardenable aluminum alloy was investigated by electricaldischarge alloying (EDA) process. Kerosene, used as a dielectric fluid, was pyrolytically decomposed into c...The surface modification on the AA6082 Al?Mg?Si aging-hardenable aluminum alloy was investigated by electricaldischarge alloying (EDA) process. Kerosene, used as a dielectric fluid, was pyrolytically decomposed into carbon for the formationof a self-lubricated carbide layer on the aluminum alloy surface during EDA process. Transmission electron microscopy (TEM)image found that the self-lubricated carbide layer was a multi-phase material with carbides and graphite. As a result, theEDA-modified aluminum alloy had a negligible wear rate of ~2?10?4 mg/m (c. f. ~1.1?10?2 mg/m for aluminum alloy substrate).Notably, a new characteristic was found that the EDA-processed carbide layer was a soft magnet, which improved theelectromagnetic interference (EMI) shielding performance of the alloy.展开更多
Three different thicknesses of self-lubricated coatings were prepared on galvanized steel sheets with differ- ent surface roughness (Ra). Performances of the coatings were evaluated by various laboratory tests. Scan...Three different thicknesses of self-lubricated coatings were prepared on galvanized steel sheets with differ- ent surface roughness (Ra). Performances of the coatings were evaluated by various laboratory tests. Scanning elec- tron microscopy (SEM), atomic force microscope (AFM), neutral salt spraying test (NSST), reciprocating friction and wear test were taken in order to characterize the coatings. Results show that the self-lubricated coating has good corrosion resistance and lubricating property. In 0. 857--1. 629 /~m of Ra value, the relationship between friction co- efficients of the self lubricated steel sheets and the surface roughness of the galvanized steel sheets likes a parabolic curve, and has a peak value of friction coefficient in certain range of Ra. Affected by the hereditary surface topogra- phy of the galvanized steel sheet, dents on the surface of sel^lubricated steel become deeper and larger with the in crease of the surface roughness of the galvanized steel sheets. The influence of the surface roughness of the galvanized steel sheet on the corrosion resistance of the self lubricated coating steel is similar to that on friction coefficient of selPlubricated coatings, like a parabolic curve.展开更多
In the dry-sliding process of the woven self-lubricating liner which is used in the self-lubricating spherical plain bearing, the friction heat plays an important role in the tribological performances of the liner. It...In the dry-sliding process of the woven self-lubricating liner which is used in the self-lubricating spherical plain bearing, the friction heat plays an important role in the tribological performances of the liner. It has important value to study on the relationship between tribological performances of the liner and the friction heat. Unforttmately, up to now, published work on this relationship is quite scarce. Therefore, the effect of friction heat on the tribological performances of the liner was investigated in the present work. The tribological behaviors of the liner were evaluated by using the high temperature end surface wear tester. Scanning electron microscopy (SEM) was utilized to examine the morphologies of worn surfaces of the liner and study the failure modes. Differential scanning calorimetry (DSC) measurement and X-ray diffraction (XRD) analysis were performed to study the behaviors of the wear debris. The temperature rise on the worn surface was calculated according to classical models. SEM observation shows that the dominating wear mechanism for the liner is mainly affected by friction shear force, contact pressure and friction heat. Higher fusion heat for the wear debris than that for the pure polytetrafluroethylene (PTFE) indicates that the PTFE is the main portion of the wear debris, and, the PTFE in the wear debris shows a higher crystallisation degree owing to the effects of friction shear force and the friction heat. Combining the calculated temperature rise results with the wear rate of the liner, it can be concluded that the effects of temperature rise o n the tribological performances of the liner become more obvious when the temperature rise exceeds the glass transition temperature (Tg) of the PTFE. The wear resistance of the liner deteriorates dramatically when the temperature rise approaches to the melting point (Ton) of the PTFE. The tribological performances of the liner can be improved when the temperature rise exceeds Tg but is far lower than Ton- The present study on the relationship between the temperature rise and the tribological performances of the liner may provide the basis for further understanding of the wear mechanisms of the liner as well as the relationship between the formation of the PTFE transfer film and the friction heat during the dry-sliding of the Finer.展开更多
A test method based on the condition simulation and a friction and wear test machine featuring in oscillatory movement were set up for self-lubricating spherical plain bearings (SPB). In the machine the condition para...A test method based on the condition simulation and a friction and wear test machine featuring in oscillatory movement were set up for self-lubricating spherical plain bearings (SPB). In the machine the condition parameters such as load, angle and frequency of oscillation and number of test cycles can be properly controlled. The data relating to the tribological properties of the bearing, in terms of friction coefficient, linear wear amount, temperature near friction surface and applied load, can be monitored and recorded simultaneously during test process by a computerized measuring system of the machine. Efforts were made to improve the measurement technology of the friction coefficient in oscillating motion. In result, a well-designed bearing torque mechanism was developed, which could reveal the relation between the friction coefficient and the displacement of oscillating angle in any defined cycle while the curve of friction coefficient vs number of testing cycles was continuously plotted. The tribological properties and service life of four kinds of the bearings, i.e, the sampleⅠ-Ⅳ with different self-lubricating composite liners, including three kinds of polytetrafluoroethylene (PTFE) fiber weave/epoxy resin composite liners and a PTFE plastic/copper grid composite liner, were evaluated by testing, and the wear mechanisms of the liner materials were analyzed.展开更多
Eutectic high entropy alloys(EHEAs)have high temperature stability,good mechanical properties,and are promising for tribological applications at high temperatures.To study the high temperature lubrication behavior,Fe_...Eutectic high entropy alloys(EHEAs)have high temperature stability,good mechanical properties,and are promising for tribological applications at high temperatures.To study the high temperature lubrication behavior,Fe_(22)Co_(26)Cr_(20)Ni_(22)Ta_(10)−(BaF_(2)/CaF_(2))x(x=3−20,wt.%)composites were prepared by spark plasma sintering(SPS),with BaF_(2)/CaF_(2) eutectic powder used as solid lubricant.The lubrication behavior and mechanical properties were studied at both room and high temperatures.With the increase of the content of BaF_(2)/CaF_(2) eutectic powder,the friction coefficients and the wear rates of the composites at 600 and 800℃ decrease significantly.The composites with eutectic powder content of 15 and 20 wt.%have the best lubricating performance at 600℃,with low friction coefficient and wear rates,mainly due to the good mechanical properties of EHEA matrix,the lubrication effect of BaF_(2)/CaF_(2) phase and the oxides formed on the worn surface.展开更多
Graphite antimony composites were prepared using a mechanical pressure infiltration method to force molten antimony into graphite preforms having a percolation micro-structure and a hop-pocket power filler. The micro-...Graphite antimony composites were prepared using a mechanical pressure infiltration method to force molten antimony into graphite preforms having a percolation micro-structure and a hop-pocket power filler. The micro-structural and macroscopic properties of the graphite antimony composites were analysed. Observations included metallographic analysis, physical properties and friction and wear behaviour. The results show that the wear loss is decreased by 12.24% and that the friction coefficient is re-duced by 32.61% after hop-pocket power was used. The research indicates that the hop-pocket power method gives a useful way to reduce friction coefficients and wear loss, and to increase service life and self-lubrication properties, of the graphite antimony seal-ing material as compared to carbon black.展开更多
The graphite (Gr)/MoS2 reinforced Mg self-lubricating composites were prepared through powder metallurgy. The composites were characterized for microstructure, physical, mechanical and wear properties. Gr/MoS2 p...The graphite (Gr)/MoS2 reinforced Mg self-lubricating composites were prepared through powder metallurgy. The composites were characterized for microstructure, physical, mechanical and wear properties. Gr/MoS2 phase in the composites was identified by XRD analysis. Microstructural observation showed that the Gr/MoS2 particles were homogeneously dispersed within the magnesium matrix. Micro-hardness was measured using an applied load of 5 g with a dwell time of 15 s at room temperature. Hardness of all the composites was measured to be in the range of VHN 29?34. The mechanical properties were studied using micro-hardness, tensile and compression tests. A fractographic analysis was performed using scanning electron microscope. The highest values of hardness, compressive strength and tensile strength were attained using Mg-10MoS2 composite. A pin-on-disk tribometer was used to measure the friction coefficient and the wear loss of the sintered composites. In addition to that, the friction and wear mechanism of the composites were systematically studied by worn surface characterization and wear debris studies using SEM analysis. The reduced friction coefficient and wear loss were achieved in MoS2 rather than Gr.展开更多
Two kinds of bronze-graphite-MoS_(2) self-lubricating materials with copper-coated MoS_(2) and uncoated MoS_(2) were prepared by powder metallurgy.Friction and wear experiments were carried out under 4 N and 10 N load...Two kinds of bronze-graphite-MoS_(2) self-lubricating materials with copper-coated MoS_(2) and uncoated MoS_(2) were prepared by powder metallurgy.Friction and wear experiments were carried out under 4 N and 10 N loads respectively,and the effects of copper-coated MoS_(2) on the friction performances of the materials were studied.Results showed that the way of copper-coated on the surface of MoS_(2) could reinforce the bonding between MoS_(2) and matrix,and inhibited the formation of MoO_(2).Moreover,both materials formed a MoS_(2) lubricating film on the surface during the friction process.While the lubricating film formed after copper coating on MoS_(2) was thicker and had uneven morphology,it was more conducive to improving the friction performance of the material.Compared with conventional materials,the wear rate of copper-coated materials was reduced by one order of magnitude,and the friction coefficient was also reduced by 22.44% and 22.53%,respectively,when sliding under 4 N and 10 N loads.It shows that copper-coated MoS_(2)can improve friction properties of bronze-graphite-MoS_(2)self-lubricating materials furtherly.展开更多
The tribological properties of Nickel-based composites containing Ti3 SiC2 and Ag2 W2 O7 fabricated by spark plasma sintering against Si3 N4 balls were investigated using a ball-on-disk tribometer from room temperatur...The tribological properties of Nickel-based composites containing Ti3 SiC2 and Ag2 W2 O7 fabricated by spark plasma sintering against Si3 N4 balls were investigated using a ball-on-disk tribometer from room temperature to 600 ℃. The tribolayers formed on the friction surface and their effects on the tribological properties of composites at different temperatures were discussed based on the worn surface characterization. The results show that Ag2 W2 O7 is decomposed into metallic silver and CrWO4 during the high-temperature fabrication process. The composite with the addition of 20 wt% Ti3 SiC2 and 5 wt% Ag2 W2 O7 exhibits a friction coefficient of 0.33-0.49 and a wear rate of 7.07×10-5-9.89×10-5 mm3/(Nm) over a wide temperature range from room temperature to 600 ℃. The excellent tribological properties at a wide temperature range are attributed to the formation of a glaze layer at low temperature and a tribooxide layer at high temperature, which can provide a low shearing strength for the synergistic effects of Ag and tribooxides.展开更多
In order to improve the tribological properties of ceramic composites, Al2O3/TiC-Al2O3/ TiC/CaF2 self-lubricating laminated ceramic composites were prepared by vacuum hot pressing sintering. Experiments were conducted...In order to improve the tribological properties of ceramic composites, Al2O3/TiC-Al2O3/ TiC/CaF2 self-lubricating laminated ceramic composites were prepared by vacuum hot pressing sintering. Experiments were conducted to get mechanical properties and the friction and wear properties were also measured with friction and wear tester. The worn surfaces were observed by scanning electron microscope (SEM) and energy dispersion spectrum (EDS). The wear resistance properties and the self-lubricating effect of ceramic composites were analyzed. Results show that the Al2O3/TiC-Al2O3/TiC/CaF2 self-lubricating laminated ceramic composites layers are well-defined with a higher bonding strength and the mechanical performances are uniform enough to overcome the anisotropy of weak laminated ceramic composites. In addition, the fracture toughness of Al2O3/TiC layers is also improved. Its friction coefficient and wear rates decrease with the increase of rotation speed and load. Al2O3/TiC-Al2O3/TiC/CaF2 self-lubricating laminated ceramic composites have good wear resistance because of the tribofilm formed by the CaF2 solid lubricants. The wear mechanisms of Al2O3/TiC/ CaF2 layers are abrasive wear and Al2O3/TiC layers are adhesive wear.展开更多
In this study, the friction performance of self-lubricating material with the counterpart steel ball-plate rubbing was investigated in vacuum conditions and the thermal distortion of the heat sink sample was tested. T...In this study, the friction performance of self-lubricating material with the counterpart steel ball-plate rubbing was investigated in vacuum conditions and the thermal distortion of the heat sink sample was tested. The analysis and test results show that the self-lubricating ma- terial has excellent anti-friction properties in high vacuum condition and can decrease the thermal stress and avoid damage to the PFCs during physical experiments.展开更多
Tribology at cryogenic temperatures has attracted much attention since the 1950s with the acceleration of its applications in high-tech equipment such as cryogenic wind tunnels,liquid fuel rockets,space infrared teles...Tribology at cryogenic temperatures has attracted much attention since the 1950s with the acceleration of its applications in high-tech equipment such as cryogenic wind tunnels,liquid fuel rockets,space infrared telescopes,superconducting devices,and planetary exploration,which require solid lubrication for moving parts at low temperatures down to 4 K in cryogenic liquid,gaseous,or vacuum environments.Herein,the research progress regarding cryo-tribology is reviewed.The tribological properties and mechanisms of solid lubricants listed as carbon materials,molybdenum disulfide,polymers,and polymer-based composites with decreasing temperature are summarized.The friction coefficient increases with decreasing temperature induced by thermally activated processes.The mechanism of transfer film formation should be considered as a significant way to enhance the tribological properties of solid lubricants.In addition,applications of solid lubrication on moving parts under cryogenic conditions,such as spherical plain bearings and roller bearings,are introduced.The technology for tribological testing of materials and bearings at cryogenic temperatures is summarized,where the environmental control,motion and loading realization,as well as friction and wear measurement together in a low-temperature environment,result in the difficulties and challenges of the low-temperature tribotester.In particular,novel technologies and tribotesters have been developed for tribotests and tribological studies of solid lubricants,spherical plain bearings,and roller bearings,overcoming limitations regarding cooling in vacuum and resolution of friction measurement,among others,and concentrating on in-situ observation of friction interface.These not only promote a deep understanding of friction and wear mechanism at low temperatures,but also provide insights into the performance of moving parts or components in cryogenic applications.展开更多
Titanium alloys are of keen interest as lightweight structural materials for aerospace and automotive in-dustries.However,a longstanding problem for these materials is their poor tribological performances.Herein,we de...Titanium alloys are of keen interest as lightweight structural materials for aerospace and automotive in-dustries.However,a longstanding problem for these materials is their poor tribological performances.Herein,we designed and fabricated a multiphase Ti-Mo-Ag composite(TMA)with heterogeneous triple-phase precipitation(TPP)structure by spark plasma sintering.A lamellarα-phase(αL)precipitates from theβ-phase under furnace cooling conditions and maintains a Burgers orientation relationship(BOR)withβ-matrix.An active eutectic transition also occurs in the titanium matrix,resulting in TiAg phase.The intersecting acicular TiAg and lamellarαL cutβgrains into fine blocks and the primary equiaxedαphase also provides many interfaces withβphase,which together effectively impede dislocation move-ment and increase strength.Compared with other titanium composites,TMA with TPP microstructure gets an excellent combination of strength(yield strength 1205 MPa)and toughness(fracture strain 27%).Furthermore,the TPP structure endows TMA with strong cracking resistance,which aids in reducing abra-sive debris at high temperatures during sliding and obtaining a low wear rate.Simultaneously,Ag parti-cles distributed at grain boundaries will easily diffuse to the wear surface,in situ forming the necessary lubricating phase Ag_(2)MoO_(4) with Mo-rich matrix debris via oxidation.TMA possesses excellent tribologi-cal properties with especially low wear rate of 8.0 x 10^(-6)mm^(3)N^(-1)m^(-1) and friction coefficient(CoF)of merely 0.20 at 600℃.Unlike other self-lubricating composites with high volume fraction of soft ceramic lubricants,which inevitably sacrifice their mechanical strength and ductility,the composite TMA pos-sesses well-balanced strength,toughness and self-lubricating properties.It holds important implications to design other metal matrix self-lubricating composites(MMSCs)used for load-bearing moving parts.展开更多
The tribological properties of self-lubricating composites are influenced by many variables and complex mechanisms.Data-driven methods,including machine learning(ML)algorithms,can yield a better comprehensive understa...The tribological properties of self-lubricating composites are influenced by many variables and complex mechanisms.Data-driven methods,including machine learning(ML)algorithms,can yield a better comprehensive understanding of complex problems under the influence of multiple parameters,typically for how tribological performances and material properties correlate.Correlation of friction coefficients and wear rates of copper/aluminum-graphite(Cu/Al-graphite)self-lubricating composites with their inherent material properties(composition,lubricant content,particle size,processing process,and interfacial bonding strength)and the variables related to the testing method(normal load,sliding speed,and sliding distance)were analyzed using traditional approaches,followed by modeling and prediction of tribological properties through five different ML algorithms,namely support vector machine(SVM),K-Nearest neighbor(KNN),random forest(RF),eXtreme gradient boosting(XGBoost),and least-squares boosting(LSBoost),based on the tribology experimental data.Results demonstrated that ML models could satisfactorily predict friction coefficient and wear rate from the material properties and testing method variables data.Herein,the LSBoost model based on the integrated learning algorithm presented the best prediction performance for friction coefficients and wear rates,with R^(2) of 0.9219 and 0.9243,respectively.Feature importance analysis also revealed that the content of graphite and the hardness of the matrix have the greatest influence on the friction coefficients,and the normal load,the content of graphite,and the hardness of the matrix influence the wear rates the most.展开更多
To expand the use of metal–organic frameworks(MOFs)based self-lubricating composite,flexible MOFs MIL-88D has been studied as a nanocontainer for loading lubricant.In this work,the mechanism of oleamine adsorption an...To expand the use of metal–organic frameworks(MOFs)based self-lubricating composite,flexible MOFs MIL-88D has been studied as a nanocontainer for loading lubricant.In this work,the mechanism of oleamine adsorption and desorption by MIL-88D was investigated through molecular simulations and experiments.Molecular simulations showed that the oleamines can be physically adsorbed into open MIL-88Ds with the Fe and O atoms of MIL-88D interacting with oleamine NH2-group.Higher temperature can cause Ole@MIL-88D to release more oleamines,while higher pressure on Ole@MIL-88D caused less oleamines released.Moreover the Ole@MIL-88D was incorporated into epoxy resin(EP)for friction tests.The optimum mass ratio of MIL-88D to EP is 15 wt%,and the EP/Ole@MIL-88D prefers light load and high frequency friction.This work suggests that flexible MOFs can be used as a nanocontainer for loading lubricant,and can be used as a new self-lubricating composite.展开更多
Multi-walled carbon nanotubes (MWNTs) were wet-milled in the presence of ammonia and cationic surfactant and then used as reinforcements to prepare Ni-P-MWNTs composite coatings by electroless plating. The tribologi...Multi-walled carbon nanotubes (MWNTs) were wet-milled in the presence of ammonia and cationic surfactant and then used as reinforcements to prepare Ni-P-MWNTs composite coatings by electroless plating. The tribological performances of the composite coatings under dry condition were investigated in comparison with 45 steel and conventional Ni-P coating, Micrographs show that short MWNTs with uniform length and open tips were obtained through the wet-milling process. The results of wear test reveal that the Ni-P-MWNTs composite coatings posses much better friction reduction and anti-wear performances when compared with 45 steel and Ni-P coating. Within the MWNTs content range of 0.74%-1.97%, the friction coefficient and the volume wear rate of the composite coatings decrease gradually and reach the minimum values of 0.08 and 6.22x10-15 m3/(N.m), respectively. The excellent tribological performances of the composite coatings can be attributed to the introduction of MWNTs, which play both roles of reinforcements and solid lubricant during the wear process.展开更多
The friction and wear properties of the electrolessly-deposited Ni-P-Gr-SiC composites were investigated. The effects of graphite content, load and rotation speed on the friction coefficient and wear resistance of the...The friction and wear properties of the electrolessly-deposited Ni-P-Gr-SiC composites were investigated. The effects of graphite content, load and rotation speed on the friction coefficient and wear resistance of the composite coatings were mainly investigated. The worn surface and cross section of the coatings were characterized by scanning electron microscopy and energy-dispersive X-ray analysis. The results show that the composite coatings reveal good antifriction and wear resistance due to the synergic effect of graphite and SiC particles. The formation of graphite-rich mechanically mixed layer (GRMML) on the surface of Ni-P-Gr-SiC coating contributes to the good tribological behavior of the wear counterparts and SiC particles play a load bearing role in protecting GRMML from shearing easily.展开更多
Silicon carbide/pyrolytic carbon (SiC/PyC) composite materials with excellent performance of self-lubrication and wear resistance were prepared on SiC substrates by electromagnetic-field-assisted chemical vapor infilt...Silicon carbide/pyrolytic carbon (SiC/PyC) composite materials with excellent performance of self-lubrication and wear resistance were prepared on SiC substrates by electromagnetic-field-assisted chemical vapor infiltration (CVI). The composition and microstructure of the SiC/PyC materials were investigated in detail by XRD, SEM and EDS, etc. The effects of the deposition temperature on the section features and wear resistance of the SiC/PyC were studied. The results show that the PyC layers were deposited onto SiC substrates spontaneously at a lower deposition temperature. The SiC substrates deposited with PyC can significantly reduce the wear rate of the self-dual composite materials under dry sliding condition. The wear tests suggest that the SiC/PyC composite materials own a better wear resistance property when the deposition temperature is 800 °C, and the wear rate is about 64.6% of that without the deposition of PyC.展开更多
This article introduces a new type of magnetic sealing mechanism that reduces the lubrication oil pollution and media gaseous leakage in general reciprocating machinery including air compressors and refrigerators. The...This article introduces a new type of magnetic sealing mechanism that reduces the lubrication oil pollution and media gaseous leakage in general reciprocating machinery including air compressors and refrigerators. The feasible function and reliable performance of this new sealing mechanism are introduced and analyzed in this paper. The computer aided design, modeling and analysis are being used to study this new sealing mechanism, and the prototype of this sealing mechanism is being tested. The study indicated the proper function of this sealing mechanism. The major advantages of this sealing mechanism include: improved sealing capacity to prevent the gaseous leakage and oil leakage, simple and compact in structure, lower precision requirement on surfaces of reciprocating pistons and shafts in production and manufacturing, and longer services in sealing life span. Also there is almost no frictional loss during the reciprocating motion of piston or shaft.展开更多
文摘Four kinds of galvanized steel sheets having different surface roughness values were used to prepare the steel sheets with a self-lubricated coating. The effects of surface roughness on the surface lubrication performance of the steel sheets were examined using a friction coefficient tester. Results revealed large dynamic friction coefficients for the galvanized steel sheets, which increased remarkably with surface roughness. Once the self-lubricated coating was applied, significant drops in the dynamic friction coefficients were measured. After the first stage of the friction test,the coefficients were almost unchanged, which reflected a weak dependence on the surface roughness of the self-lubricated steel sheets. However, the dynamic friction coefficients gradually increased as the test progressed, where these increase clearly correlated with the surface roughness of the self-lubricated steel sheets.
文摘The surface modification on the AA6082 Al?Mg?Si aging-hardenable aluminum alloy was investigated by electricaldischarge alloying (EDA) process. Kerosene, used as a dielectric fluid, was pyrolytically decomposed into carbon for the formationof a self-lubricated carbide layer on the aluminum alloy surface during EDA process. Transmission electron microscopy (TEM)image found that the self-lubricated carbide layer was a multi-phase material with carbides and graphite. As a result, theEDA-modified aluminum alloy had a negligible wear rate of ~2?10?4 mg/m (c. f. ~1.1?10?2 mg/m for aluminum alloy substrate).Notably, a new characteristic was found that the EDA-processed carbide layer was a soft magnet, which improved theelectromagnetic interference (EMI) shielding performance of the alloy.
基金Sponsored by National Natural Science Foundation of China(51071052)National Key Technology Research and Development Program in 12th Five-year Plan of China(2012BAJ13B03)
文摘Three different thicknesses of self-lubricated coatings were prepared on galvanized steel sheets with differ- ent surface roughness (Ra). Performances of the coatings were evaluated by various laboratory tests. Scanning elec- tron microscopy (SEM), atomic force microscope (AFM), neutral salt spraying test (NSST), reciprocating friction and wear test were taken in order to characterize the coatings. Results show that the self-lubricated coating has good corrosion resistance and lubricating property. In 0. 857--1. 629 /~m of Ra value, the relationship between friction co- efficients of the self lubricated steel sheets and the surface roughness of the galvanized steel sheets likes a parabolic curve, and has a peak value of friction coefficient in certain range of Ra. Affected by the hereditary surface topogra- phy of the galvanized steel sheet, dents on the surface of sel^lubricated steel become deeper and larger with the in crease of the surface roughness of the galvanized steel sheets. The influence of the surface roughness of the galvanized steel sheet on the corrosion resistance of the self lubricated coating steel is similar to that on friction coefficient of selPlubricated coatings, like a parabolic curve.
文摘In the dry-sliding process of the woven self-lubricating liner which is used in the self-lubricating spherical plain bearing, the friction heat plays an important role in the tribological performances of the liner. It has important value to study on the relationship between tribological performances of the liner and the friction heat. Unforttmately, up to now, published work on this relationship is quite scarce. Therefore, the effect of friction heat on the tribological performances of the liner was investigated in the present work. The tribological behaviors of the liner were evaluated by using the high temperature end surface wear tester. Scanning electron microscopy (SEM) was utilized to examine the morphologies of worn surfaces of the liner and study the failure modes. Differential scanning calorimetry (DSC) measurement and X-ray diffraction (XRD) analysis were performed to study the behaviors of the wear debris. The temperature rise on the worn surface was calculated according to classical models. SEM observation shows that the dominating wear mechanism for the liner is mainly affected by friction shear force, contact pressure and friction heat. Higher fusion heat for the wear debris than that for the pure polytetrafluroethylene (PTFE) indicates that the PTFE is the main portion of the wear debris, and, the PTFE in the wear debris shows a higher crystallisation degree owing to the effects of friction shear force and the friction heat. Combining the calculated temperature rise results with the wear rate of the liner, it can be concluded that the effects of temperature rise o n the tribological performances of the liner become more obvious when the temperature rise exceeds the glass transition temperature (Tg) of the PTFE. The wear resistance of the liner deteriorates dramatically when the temperature rise approaches to the melting point (Ton) of the PTFE. The tribological performances of the liner can be improved when the temperature rise exceeds Tg but is far lower than Ton- The present study on the relationship between the temperature rise and the tribological performances of the liner may provide the basis for further understanding of the wear mechanisms of the liner as well as the relationship between the formation of the PTFE transfer film and the friction heat during the dry-sliding of the Finer.
文摘A test method based on the condition simulation and a friction and wear test machine featuring in oscillatory movement were set up for self-lubricating spherical plain bearings (SPB). In the machine the condition parameters such as load, angle and frequency of oscillation and number of test cycles can be properly controlled. The data relating to the tribological properties of the bearing, in terms of friction coefficient, linear wear amount, temperature near friction surface and applied load, can be monitored and recorded simultaneously during test process by a computerized measuring system of the machine. Efforts were made to improve the measurement technology of the friction coefficient in oscillating motion. In result, a well-designed bearing torque mechanism was developed, which could reveal the relation between the friction coefficient and the displacement of oscillating angle in any defined cycle while the curve of friction coefficient vs number of testing cycles was continuously plotted. The tribological properties and service life of four kinds of the bearings, i.e, the sampleⅠ-Ⅳ with different self-lubricating composite liners, including three kinds of polytetrafluoroethylene (PTFE) fiber weave/epoxy resin composite liners and a PTFE plastic/copper grid composite liner, were evaluated by testing, and the wear mechanisms of the liner materials were analyzed.
基金The authors acknowledge the financial support from the National Natural Science Foundation of China(51671217).
文摘Eutectic high entropy alloys(EHEAs)have high temperature stability,good mechanical properties,and are promising for tribological applications at high temperatures.To study the high temperature lubrication behavior,Fe_(22)Co_(26)Cr_(20)Ni_(22)Ta_(10)−(BaF_(2)/CaF_(2))x(x=3−20,wt.%)composites were prepared by spark plasma sintering(SPS),with BaF_(2)/CaF_(2) eutectic powder used as solid lubricant.The lubrication behavior and mechanical properties were studied at both room and high temperatures.With the increase of the content of BaF_(2)/CaF_(2) eutectic powder,the friction coefficients and the wear rates of the composites at 600 and 800℃ decrease significantly.The composites with eutectic powder content of 15 and 20 wt.%have the best lubricating performance at 600℃,with low friction coefficient and wear rates,mainly due to the good mechanical properties of EHEA matrix,the lubrication effect of BaF_(2)/CaF_(2) phase and the oxides formed on the worn surface.
基金Project 2006A021 supported by the Science Foundation of China University of Mining & Technology
文摘Graphite antimony composites were prepared using a mechanical pressure infiltration method to force molten antimony into graphite preforms having a percolation micro-structure and a hop-pocket power filler. The micro-structural and macroscopic properties of the graphite antimony composites were analysed. Observations included metallographic analysis, physical properties and friction and wear behaviour. The results show that the wear loss is decreased by 12.24% and that the friction coefficient is re-duced by 32.61% after hop-pocket power was used. The research indicates that the hop-pocket power method gives a useful way to reduce friction coefficients and wear loss, and to increase service life and self-lubrication properties, of the graphite antimony seal-ing material as compared to carbon black.
文摘The graphite (Gr)/MoS2 reinforced Mg self-lubricating composites were prepared through powder metallurgy. The composites were characterized for microstructure, physical, mechanical and wear properties. Gr/MoS2 phase in the composites was identified by XRD analysis. Microstructural observation showed that the Gr/MoS2 particles were homogeneously dispersed within the magnesium matrix. Micro-hardness was measured using an applied load of 5 g with a dwell time of 15 s at room temperature. Hardness of all the composites was measured to be in the range of VHN 29?34. The mechanical properties were studied using micro-hardness, tensile and compression tests. A fractographic analysis was performed using scanning electron microscope. The highest values of hardness, compressive strength and tensile strength were attained using Mg-10MoS2 composite. A pin-on-disk tribometer was used to measure the friction coefficient and the wear loss of the sintered composites. In addition to that, the friction and wear mechanism of the composites were systematically studied by worn surface characterization and wear debris studies using SEM analysis. The reduced friction coefficient and wear loss were achieved in MoS2 rather than Gr.
文摘Two kinds of bronze-graphite-MoS_(2) self-lubricating materials with copper-coated MoS_(2) and uncoated MoS_(2) were prepared by powder metallurgy.Friction and wear experiments were carried out under 4 N and 10 N loads respectively,and the effects of copper-coated MoS_(2) on the friction performances of the materials were studied.Results showed that the way of copper-coated on the surface of MoS_(2) could reinforce the bonding between MoS_(2) and matrix,and inhibited the formation of MoO_(2).Moreover,both materials formed a MoS_(2) lubricating film on the surface during the friction process.While the lubricating film formed after copper coating on MoS_(2) was thicker and had uneven morphology,it was more conducive to improving the friction performance of the material.Compared with conventional materials,the wear rate of copper-coated materials was reduced by one order of magnitude,and the friction coefficient was also reduced by 22.44% and 22.53%,respectively,when sliding under 4 N and 10 N loads.It shows that copper-coated MoS_(2)can improve friction properties of bronze-graphite-MoS_(2)self-lubricating materials furtherly.
基金Funded by National Natural Science Foundation of China(No.51805183)
文摘The tribological properties of Nickel-based composites containing Ti3 SiC2 and Ag2 W2 O7 fabricated by spark plasma sintering against Si3 N4 balls were investigated using a ball-on-disk tribometer from room temperature to 600 ℃. The tribolayers formed on the friction surface and their effects on the tribological properties of composites at different temperatures were discussed based on the worn surface characterization. The results show that Ag2 W2 O7 is decomposed into metallic silver and CrWO4 during the high-temperature fabrication process. The composite with the addition of 20 wt% Ti3 SiC2 and 5 wt% Ag2 W2 O7 exhibits a friction coefficient of 0.33-0.49 and a wear rate of 7.07×10-5-9.89×10-5 mm3/(Nm) over a wide temperature range from room temperature to 600 ℃. The excellent tribological properties at a wide temperature range are attributed to the formation of a glaze layer at low temperature and a tribooxide layer at high temperature, which can provide a low shearing strength for the synergistic effects of Ag and tribooxides.
基金Funded by the National Natural Science Foundation for Young Scholars of China(No.51005100)Higher Education Science and Technology Program of Shandong(No.J11LD14)Science and Technology Development Plan of Shandong(No.2012GGX10324)
文摘In order to improve the tribological properties of ceramic composites, Al2O3/TiC-Al2O3/ TiC/CaF2 self-lubricating laminated ceramic composites were prepared by vacuum hot pressing sintering. Experiments were conducted to get mechanical properties and the friction and wear properties were also measured with friction and wear tester. The worn surfaces were observed by scanning electron microscope (SEM) and energy dispersion spectrum (EDS). The wear resistance properties and the self-lubricating effect of ceramic composites were analyzed. Results show that the Al2O3/TiC-Al2O3/TiC/CaF2 self-lubricating laminated ceramic composites layers are well-defined with a higher bonding strength and the mechanical performances are uniform enough to overcome the anisotropy of weak laminated ceramic composites. In addition, the fracture toughness of Al2O3/TiC layers is also improved. Its friction coefficient and wear rates decrease with the increase of rotation speed and load. Al2O3/TiC-Al2O3/TiC/CaF2 self-lubricating laminated ceramic composites have good wear resistance because of the tribofilm formed by the CaF2 solid lubricants. The wear mechanisms of Al2O3/TiC/ CaF2 layers are abrasive wear and Al2O3/TiC layers are adhesive wear.
文摘In this study, the friction performance of self-lubricating material with the counterpart steel ball-plate rubbing was investigated in vacuum conditions and the thermal distortion of the heat sink sample was tested. The analysis and test results show that the self-lubricating ma- terial has excellent anti-friction properties in high vacuum condition and can decrease the thermal stress and avoid damage to the PFCs during physical experiments.
基金supported by National Natural Science Foundation of China(Grant Nos.51935006,52225502)。
文摘Tribology at cryogenic temperatures has attracted much attention since the 1950s with the acceleration of its applications in high-tech equipment such as cryogenic wind tunnels,liquid fuel rockets,space infrared telescopes,superconducting devices,and planetary exploration,which require solid lubrication for moving parts at low temperatures down to 4 K in cryogenic liquid,gaseous,or vacuum environments.Herein,the research progress regarding cryo-tribology is reviewed.The tribological properties and mechanisms of solid lubricants listed as carbon materials,molybdenum disulfide,polymers,and polymer-based composites with decreasing temperature are summarized.The friction coefficient increases with decreasing temperature induced by thermally activated processes.The mechanism of transfer film formation should be considered as a significant way to enhance the tribological properties of solid lubricants.In addition,applications of solid lubrication on moving parts under cryogenic conditions,such as spherical plain bearings and roller bearings,are introduced.The technology for tribological testing of materials and bearings at cryogenic temperatures is summarized,where the environmental control,motion and loading realization,as well as friction and wear measurement together in a low-temperature environment,result in the difficulties and challenges of the low-temperature tribotester.In particular,novel technologies and tribotesters have been developed for tribotests and tribological studies of solid lubricants,spherical plain bearings,and roller bearings,overcoming limitations regarding cooling in vacuum and resolution of friction measurement,among others,and concentrating on in-situ observation of friction interface.These not only promote a deep understanding of friction and wear mechanism at low temperatures,but also provide insights into the performance of moving parts or components in cryogenic applications.
基金National Natural Science Foundation of China(No.51871051)Fourth Batch of Ningxia Youth Talents Supporting Program(No.TJGC2019028).
文摘Titanium alloys are of keen interest as lightweight structural materials for aerospace and automotive in-dustries.However,a longstanding problem for these materials is their poor tribological performances.Herein,we designed and fabricated a multiphase Ti-Mo-Ag composite(TMA)with heterogeneous triple-phase precipitation(TPP)structure by spark plasma sintering.A lamellarα-phase(αL)precipitates from theβ-phase under furnace cooling conditions and maintains a Burgers orientation relationship(BOR)withβ-matrix.An active eutectic transition also occurs in the titanium matrix,resulting in TiAg phase.The intersecting acicular TiAg and lamellarαL cutβgrains into fine blocks and the primary equiaxedαphase also provides many interfaces withβphase,which together effectively impede dislocation move-ment and increase strength.Compared with other titanium composites,TMA with TPP microstructure gets an excellent combination of strength(yield strength 1205 MPa)and toughness(fracture strain 27%).Furthermore,the TPP structure endows TMA with strong cracking resistance,which aids in reducing abra-sive debris at high temperatures during sliding and obtaining a low wear rate.Simultaneously,Ag parti-cles distributed at grain boundaries will easily diffuse to the wear surface,in situ forming the necessary lubricating phase Ag_(2)MoO_(4) with Mo-rich matrix debris via oxidation.TMA possesses excellent tribologi-cal properties with especially low wear rate of 8.0 x 10^(-6)mm^(3)N^(-1)m^(-1) and friction coefficient(CoF)of merely 0.20 at 600℃.Unlike other self-lubricating composites with high volume fraction of soft ceramic lubricants,which inevitably sacrifice their mechanical strength and ductility,the composite TMA pos-sesses well-balanced strength,toughness and self-lubricating properties.It holds important implications to design other metal matrix self-lubricating composites(MMSCs)used for load-bearing moving parts.
基金the National Key R&D Program of China(Grant No.2022YFB3809000)the Intellectual Property Program of Gansu(Grant No.22ZSCQ043).
文摘The tribological properties of self-lubricating composites are influenced by many variables and complex mechanisms.Data-driven methods,including machine learning(ML)algorithms,can yield a better comprehensive understanding of complex problems under the influence of multiple parameters,typically for how tribological performances and material properties correlate.Correlation of friction coefficients and wear rates of copper/aluminum-graphite(Cu/Al-graphite)self-lubricating composites with their inherent material properties(composition,lubricant content,particle size,processing process,and interfacial bonding strength)and the variables related to the testing method(normal load,sliding speed,and sliding distance)were analyzed using traditional approaches,followed by modeling and prediction of tribological properties through five different ML algorithms,namely support vector machine(SVM),K-Nearest neighbor(KNN),random forest(RF),eXtreme gradient boosting(XGBoost),and least-squares boosting(LSBoost),based on the tribology experimental data.Results demonstrated that ML models could satisfactorily predict friction coefficient and wear rate from the material properties and testing method variables data.Herein,the LSBoost model based on the integrated learning algorithm presented the best prediction performance for friction coefficients and wear rates,with R^(2) of 0.9219 and 0.9243,respectively.Feature importance analysis also revealed that the content of graphite and the hardness of the matrix have the greatest influence on the friction coefficients,and the normal load,the content of graphite,and the hardness of the matrix influence the wear rates the most.
基金Foundation of State Key Laboratory of Tribology in Advanced Equipment at Tsinghua University(Grant No.SKLTKF21B13)Natural Science Foundation of Hebei Province of China(Grant No.E2021203092)National Natural Science Foundation of China(Grant No.51905297)are acknowledged.
文摘To expand the use of metal–organic frameworks(MOFs)based self-lubricating composite,flexible MOFs MIL-88D has been studied as a nanocontainer for loading lubricant.In this work,the mechanism of oleamine adsorption and desorption by MIL-88D was investigated through molecular simulations and experiments.Molecular simulations showed that the oleamines can be physically adsorbed into open MIL-88Ds with the Fe and O atoms of MIL-88D interacting with oleamine NH2-group.Higher temperature can cause Ole@MIL-88D to release more oleamines,while higher pressure on Ole@MIL-88D caused less oleamines released.Moreover the Ole@MIL-88D was incorporated into epoxy resin(EP)for friction tests.The optimum mass ratio of MIL-88D to EP is 15 wt%,and the EP/Ole@MIL-88D prefers light load and high frequency friction.This work suggests that flexible MOFs can be used as a nanocontainer for loading lubricant,and can be used as a new self-lubricating composite.
基金Project (JPPT-115-5-1759) supported by the National Defense Science and Technology Industry Committee of China Project (20090162120080) supported by Research Fund for the Doctoral Program of Higher Education of ChinaProject (2010FJ3012) supported by the Program of Science and Technology of Hunan Province, China
文摘Multi-walled carbon nanotubes (MWNTs) were wet-milled in the presence of ammonia and cationic surfactant and then used as reinforcements to prepare Ni-P-MWNTs composite coatings by electroless plating. The tribological performances of the composite coatings under dry condition were investigated in comparison with 45 steel and conventional Ni-P coating, Micrographs show that short MWNTs with uniform length and open tips were obtained through the wet-milling process. The results of wear test reveal that the Ni-P-MWNTs composite coatings posses much better friction reduction and anti-wear performances when compared with 45 steel and Ni-P coating. Within the MWNTs content range of 0.74%-1.97%, the friction coefficient and the volume wear rate of the composite coatings decrease gradually and reach the minimum values of 0.08 and 6.22x10-15 m3/(N.m), respectively. The excellent tribological performances of the composite coatings can be attributed to the introduction of MWNTs, which play both roles of reinforcements and solid lubricant during the wear process.
基金Project (51204105) supported by the National Natural Science Foundation of ChinaProject (11ZR1418000) supported by the Shanghai Natural Science Foundation, China
文摘The friction and wear properties of the electrolessly-deposited Ni-P-Gr-SiC composites were investigated. The effects of graphite content, load and rotation speed on the friction coefficient and wear resistance of the composite coatings were mainly investigated. The worn surface and cross section of the coatings were characterized by scanning electron microscopy and energy-dispersive X-ray analysis. The results show that the composite coatings reveal good antifriction and wear resistance due to the synergic effect of graphite and SiC particles. The formation of graphite-rich mechanically mixed layer (GRMML) on the surface of Ni-P-Gr-SiC coating contributes to the good tribological behavior of the wear counterparts and SiC particles play a load bearing role in protecting GRMML from shearing easily.
基金Project(2011CB605801)supported by the National Basic Research Program of ChinaProject(2011M500127)supported by the China Postdoctoral Science Foundation+2 种基金Projects(51102089,50802115)supported by the National Natural Science Foundation of ChinaProjects(12JJ4046,12JJ9014)supported by the Natural Science Foundation of Hunan Province,ChinaProject(74341015817)supported by the Post-doctoral Fund of Central South University,China
文摘Silicon carbide/pyrolytic carbon (SiC/PyC) composite materials with excellent performance of self-lubrication and wear resistance were prepared on SiC substrates by electromagnetic-field-assisted chemical vapor infiltration (CVI). The composition and microstructure of the SiC/PyC materials were investigated in detail by XRD, SEM and EDS, etc. The effects of the deposition temperature on the section features and wear resistance of the SiC/PyC were studied. The results show that the PyC layers were deposited onto SiC substrates spontaneously at a lower deposition temperature. The SiC substrates deposited with PyC can significantly reduce the wear rate of the self-dual composite materials under dry sliding condition. The wear tests suggest that the SiC/PyC composite materials own a better wear resistance property when the deposition temperature is 800 °C, and the wear rate is about 64.6% of that without the deposition of PyC.
文摘This article introduces a new type of magnetic sealing mechanism that reduces the lubrication oil pollution and media gaseous leakage in general reciprocating machinery including air compressors and refrigerators. The feasible function and reliable performance of this new sealing mechanism are introduced and analyzed in this paper. The computer aided design, modeling and analysis are being used to study this new sealing mechanism, and the prototype of this sealing mechanism is being tested. The study indicated the proper function of this sealing mechanism. The major advantages of this sealing mechanism include: improved sealing capacity to prevent the gaseous leakage and oil leakage, simple and compact in structure, lower precision requirement on surfaces of reciprocating pistons and shafts in production and manufacturing, and longer services in sealing life span. Also there is almost no frictional loss during the reciprocating motion of piston or shaft.